{"id":"https://openalex.org/W2948954085","doi":"https://doi.org/10.1016/j.tet.2019.05.043","title":"Photoredox-catalyzed deoxyfluorination of activated alcohols with Selectfluor\u00ae","display_name":"Photoredox-catalyzed deoxyfluorination of activated alcohols with Selectfluor\u00ae","publication_year":2019,"publication_date":"2019-06-03","ids":{"openalex":"https://openalex.org/W2948954085","doi":"https://doi.org/10.1016/j.tet.2019.05.043","mag":"2948954085","pmid":"https://pubmed.ncbi.nlm.nih.gov/32831415","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/7441851"},"language":"en","primary_location":{"id":"doi:10.1016/j.tet.2019.05.043","doi":"https://doi.org/10.1016/j.tet.2019.05.043","is_oa":false,"landing_page_url":"https://doi.org/10.1016/j.tet.2019.05.043","pdf_url":null,"source":{"id":"https://openalex.org/S205754296","display_name":"Tetrahedron","issn_l":"0040-4020","issn":["0040-4020","1464-5416"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Tetrahedron","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/7441851","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5055758727","display_name":"Mar\u00eda Gonz\u00e1lez\u2010Esguevillas","orcid":"https://orcid.org/0000-0003-3779-5516","observed_orcids":["https://orcid.org/0000-0003-3779-5516"]},"institutions":[{"id":"https://openalex.org/I20089843","display_name":"Princeton University","ror":"https://ror.org/00hx57361","country_code":"US","type":"education","lineage":["https://openalex.org/I20089843"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Mar\u00eda Gonz\u00e1lez-Esguevillas","raw_affiliation_strings":["Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States","Merck Center for Catalysis at Princeton University, Princeton, NJ 08544, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States","institution_ids":["https://openalex.org/I20089843"]},{"raw_affiliation_string":"Merck Center for Catalysis at Princeton University, Princeton, NJ 08544, United States","institution_ids":["https://openalex.org/I20089843"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5006423897","display_name":"Javier Mir\u00f3","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I20089843","display_name":"Princeton University","ror":"https://ror.org/00hx57361","country_code":"US","type":"education","lineage":["https://openalex.org/I20089843"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Javier Mir\u00f3","raw_affiliation_strings":["Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States","Merck Center for Catalysis at Princeton University, Princeton, NJ 08544, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States","institution_ids":["https://openalex.org/I20089843"]},{"raw_affiliation_string":"Merck Center for Catalysis at Princeton University, Princeton, NJ 08544, United States","institution_ids":["https://openalex.org/I20089843"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5084888956","display_name":"Jenna L. Jeffrey","orcid":"https://orcid.org/0000-0001-9249-5984","observed_orcids":["https://orcid.org/0000-0001-9249-5984"]},"institutions":[{"id":"https://openalex.org/I20089843","display_name":"Princeton University","ror":"https://ror.org/00hx57361","country_code":"US","type":"education","lineage":["https://openalex.org/I20089843"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jenna L. Jeffrey","raw_affiliation_strings":["Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States","Merck Center for Catalysis at Princeton University, Princeton, NJ 08544, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States","institution_ids":["https://openalex.org/I20089843"]},{"raw_affiliation_string":"Merck Center for Catalysis at Princeton University, Princeton, NJ 08544, United States","institution_ids":["https://openalex.org/I20089843"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5025805979","display_name":"David W. C. MacMillan","orcid":"https://orcid.org/0000-0001-6447-0587","observed_orcids":["https://orcid.org/0000-0001-6447-0587"]},"institutions":[{"id":"https://openalex.org/I20089843","display_name":"Princeton University","ror":"https://ror.org/00hx57361","country_code":"US","type":"education","lineage":["https://openalex.org/I20089843"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"David W.C. MacMillan","raw_affiliation_strings":["Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States","Merck Center for Catalysis at Princeton University, Princeton, NJ 08544, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Merck Center for Catalysis at Princeton University, Princeton, New Jersey 08544, United States","institution_ids":["https://openalex.org/I20089843"]},{"raw_affiliation_string":"Merck Center for Catalysis at Princeton University, Princeton, NJ 08544, United States","institution_ids":["https://openalex.org/I20089843"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5025805979"],"corresponding_institution_ids":["https://openalex.org/I20089843"],"apc_list":{"value":2450,"currency":"USD","value_usd":2450},"apc_paid":null,"fwci":3.7252,"has_fulltext":false,"cited_by_count":71,"citation_normalized_percentile":{"value":0.94869898,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":97,"max":99},"biblio":{"volume":"75","issue":"32","first_page":"4222","last_page":"4227"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.9922000169754028,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.9922000169754028,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10947","display_name":"Fluorine in Organic Chemistry","score":0.006200000178068876,"subfield":{"id":"https://openalex.org/subfields/3003","display_name":"Pharmaceutical Science"},"field":{"id":"https://openalex.org/fields/30","display_name":"Pharmacology, Toxicology and Pharmaceutics"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/deoxyfluorination","display_name":"deoxyfluorination","score":0.9869999885559082},{"id":"https://openalex.org/keywords/photoredox-catalysis","display_name":"photoredox catalysis","score":0.8930000066757202},{"id":"https://openalex.org/keywords/visible-light-photocatalysis","display_name":"visible light photocatalysis","score":0.7799999713897705},{"id":"https://openalex.org/keywords/selectfluor","display_name":"Selectfluor","score":0.7889999747276306},{"id":"https://openalex.org/keywords/radical-mediated-reactions","display_name":"radical-mediated reactions","score":0.6660000085830688},{"id":"https://openalex.org/keywords/activated-alcohols","display_name":"activated alcohols","score":0.8600000143051147},{"id":"https://openalex.org/keywords/secondary-alcohols","display_name":"secondary alcohols","score":0.8679999709129333},{"id":"https://openalex.org/keywords/tertiary-alcohols","display_name":"tertiary alcohols","score":1.0}],"concepts":[{"id":"https://openalex.org/C2778656812","wikidata":"https://www.wikidata.org/wiki/Q2649515","display_name":"Selectfluor","level":3,"score":0.9699083566665649},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9594014286994934},{"id":"https://openalex.org/C45849291","wikidata":"https://www.wikidata.org/wiki/Q17166058","display_name":"Photoredox catalysis","level":4,"score":0.8781540989875793},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7591792345046997},{"id":"https://openalex.org/C50027330","wikidata":"https://www.wikidata.org/wiki/Q908086","display_name":"Electrophile","level":3,"score":0.7543702125549316},{"id":"https://openalex.org/C178907741","wikidata":"https://www.wikidata.org/wiki/Q745930","display_name":"Nucleophile","level":3,"score":0.7305606603622437},{"id":"https://openalex.org/C506198293","wikidata":"https://www.wikidata.org/wiki/Q650","display_name":"Fluorine","level":2,"score":0.6309802532196045},{"id":"https://openalex.org/C2778824931","wikidata":"https://www.wikidata.org/wiki/Q5358518","display_name":"Electrophilic fluorination","level":4,"score":0.6304354071617126},{"id":"https://openalex.org/C2909312076","wikidata":"https://www.wikidata.org/wiki/Q156","display_name":"Tertiary alcohols","level":3,"score":0.498746395111084},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4518180191516876},{"id":"https://openalex.org/C104663316","wikidata":"https://www.wikidata.org/wiki/Q76299","display_name":"Visible spectrum","level":2,"score":0.4405771493911743},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.43942055106163025},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.43167755007743835},{"id":"https://openalex.org/C65165184","wikidata":"https://www.wikidata.org/wiki/Q218831","display_name":"Photocatalysis","level":3,"score":0.12480941414833069},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1016/j.tet.2019.05.043","doi":"https://doi.org/10.1016/j.tet.2019.05.043","is_oa":false,"landing_page_url":"https://doi.org/10.1016/j.tet.2019.05.043","pdf_url":null,"source":{"id":"https://openalex.org/S205754296","display_name":"Tetrahedron","issn_l":"0040-4020","issn":["0040-4020","1464-5416"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320990","host_organization_name":"Elsevier BV","host_organization_lineage":["https://openalex.org/P4310320990"],"host_organization_lineage_names":["Elsevier BV"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Tetrahedron","raw_type":"journal-article"},{"id":"pmid:32831415","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/32831415","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Tetrahedron","raw_type":"Journal Article"},{"id":"pmh:oai:pubmedcentral.nih.gov:7441851","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/7441851","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"Tetrahedron","raw_type":"Text"}],"best_oa_location":{"id":"pmh:oai:pubmedcentral.nih.gov:7441851","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/7441851","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"Tetrahedron","raw_type":"Text"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G3882020948","display_name":"New Strategies in Metallaphotoredox Catalysis","funder_award_id":"R01GM093213","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G7210425831","display_name":"Beta Functionalization of Aldehydes and Ketones Using Photoredox Organocatalysis","funder_award_id":"F32GM109536","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"}],"funders":[{"id":"https://openalex.org/F4320321974","display_name":"Universitat de Val\u00e8ncia","ror":"https://ror.org/043nxc105"},{"id":"https://openalex.org/F4320332161","display_name":"National Institutes of Health","ror":"https://ror.org/01cwqze88"},{"id":"https://openalex.org/F4320337354","display_name":"National Institute of General Medical Sciences","ror":"https://ror.org/04q48ey07"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":38,"referenced_works":["https://openalex.org/W1453281523","https://openalex.org/W1797427343","https://openalex.org/W1973772445","https://openalex.org/W1993195042","https://openalex.org/W1996941025","https://openalex.org/W2012230416","https://openalex.org/W2013351505","https://openalex.org/W2013781835","https://openalex.org/W2024983023","https://openalex.org/W2037084723","https://openalex.org/W2042802895","https://openalex.org/W2049917615","https://openalex.org/W2057509100","https://openalex.org/W2057513800","https://openalex.org/W2066494487","https://openalex.org/W2072982389","https://openalex.org/W2094129737","https://openalex.org/W2109739351","https://openalex.org/W2141471401","https://openalex.org/W2179395831","https://openalex.org/W2237872262","https://openalex.org/W2315095124","https://openalex.org/W2330367760","https://openalex.org/W2333129245","https://openalex.org/W2338948298","https://openalex.org/W2410599452","https://openalex.org/W2504256884","https://openalex.org/W2512094518","https://openalex.org/W2514462360","https://openalex.org/W2528694815","https://openalex.org/W2547227763","https://openalex.org/W2555075110","https://openalex.org/W2555513080","https://openalex.org/W2794822175","https://openalex.org/W2795534721","https://openalex.org/W2886543611","https://openalex.org/W2899067076","https://openalex.org/W2902520412"],"related_works":["https://openalex.org/W4387440462","https://openalex.org/W2899067076","https://openalex.org/W4412123810","https://openalex.org/W2970154719","https://openalex.org/W4205172686","https://openalex.org/W4405695054","https://openalex.org/W4224228423","https://openalex.org/W4390096671","https://openalex.org/W4417527823","https://openalex.org/W2196355784"],"abstract_inverted_index":null,"counts_by_year":[{"year":2026,"cited_by_count":3},{"year":2025,"cited_by_count":9},{"year":2024,"cited_by_count":9},{"year":2023,"cited_by_count":12},{"year":2022,"cited_by_count":10},{"year":2021,"cited_by_count":12},{"year":2020,"cited_by_count":12},{"year":2019,"cited_by_count":4}],"updated_date":"2026-10-28T10:33:24.094632","created_date":"2019-06-14T00:00:00"}