{"id":"https://openalex.org/W2946436972","doi":"https://doi.org/10.1039/c9nr02376c","title":"Thiographene synthesized from fluorographene via xanthogenate with immobilized enzymes for environmental remediation","display_name":"Thiographene synthesized from fluorographene via xanthogenate with immobilized enzymes for environmental remediation","publication_year":2019,"publication_date":"2019-01-01","ids":{"openalex":"https://openalex.org/W2946436972","doi":"https://doi.org/10.1039/c9nr02376c","mag":"2946436972","pmid":"https://pubmed.ncbi.nlm.nih.gov/31120458"},"language":"en","primary_location":{"id":"doi:10.1039/c9nr02376c","doi":"https://doi.org/10.1039/c9nr02376c","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c9nr02376c","pdf_url":null,"source":{"id":"https://openalex.org/S23181512","display_name":"Nanoscale","issn_l":"2040-3364","issn":["2040-3364","2040-3372"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-3","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nanoscale","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5050065720","display_name":"Ji\u0159\u00ed \u0160turala","orcid":"https://orcid.org/0000-0002-8113-0709","observed_orcids":["https://orcid.org/0000-0002-8113-0709"]},"institutions":[{"id":"https://openalex.org/I9073902","display_name":"University of Chemistry and Technology, Prague","ror":"https://ror.org/05ggn0a85","country_code":"CZ","type":"education","lineage":["https://openalex.org/I9073902"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Jiri Sturala","raw_affiliation_strings":["16628 Prague 6","Center for Advanced Functional Nanorobots","Department of Inorganic Chemistry","Faculty of Chemical Technology","University of Chemistry and Technology Prague"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"16628 Prague 6","institution_ids":[]},{"raw_affiliation_string":"Center for Advanced Functional Nanorobots","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic Chemistry","institution_ids":[]},{"raw_affiliation_string":"Faculty of Chemical Technology","institution_ids":[]},{"raw_affiliation_string":"University of Chemistry and Technology Prague","institution_ids":["https://openalex.org/I9073902"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5072932869","display_name":"So\u0148a Hermanov\u00e1","orcid":"https://orcid.org/0000-0002-9491-9100","observed_orcids":["https://orcid.org/0000-0002-9491-9100"]},"institutions":[{"id":"https://openalex.org/I9073902","display_name":"University of Chemistry and Technology, Prague","ror":"https://ror.org/05ggn0a85","country_code":"CZ","type":"education","lineage":["https://openalex.org/I9073902"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"So\u0148a Hermanov\u00e1","raw_affiliation_strings":["16628 Prague 6","Center for Advanced Functional Nanorobots","Department of Inorganic Chemistry","Faculty of Chemical Technology","University of Chemistry and Technology Prague"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"16628 Prague 6","institution_ids":[]},{"raw_affiliation_string":"Center for Advanced Functional Nanorobots","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic Chemistry","institution_ids":[]},{"raw_affiliation_string":"Faculty of Chemical Technology","institution_ids":[]},{"raw_affiliation_string":"University of Chemistry and Technology Prague","institution_ids":["https://openalex.org/I9073902"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5021516108","display_name":"Lucie Artigues","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I9073902","display_name":"University of Chemistry and Technology, Prague","ror":"https://ror.org/05ggn0a85","country_code":"CZ","type":"education","lineage":["https://openalex.org/I9073902"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Lucie Artigues","raw_affiliation_strings":["16628 Prague 6","Czech Republic","Department of Polymers","Faculty of Chemical Technology","University of Chemistry and Technology Prague","Polytech Montpellier, Montpellier Cedex 5, Languedoc-Roussillon, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"16628 Prague 6","institution_ids":[]},{"raw_affiliation_string":"Czech Republic","institution_ids":[]},{"raw_affiliation_string":"Department of Polymers","institution_ids":[]},{"raw_affiliation_string":"Faculty of Chemical Technology","institution_ids":[]},{"raw_affiliation_string":"University of Chemistry and Technology Prague","institution_ids":["https://openalex.org/I9073902"]},{"raw_affiliation_string":"Polytech Montpellier, Montpellier Cedex 5, Languedoc-Roussillon, France","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077357570","display_name":"Zden\u011bk Sofer","orcid":"https://orcid.org/0000-0002-1391-4448","observed_orcids":["https://orcid.org/0000-0002-1391-4448"]},"institutions":[{"id":"https://openalex.org/I9073902","display_name":"University of Chemistry and Technology, Prague","ror":"https://ror.org/05ggn0a85","country_code":"CZ","type":"education","lineage":["https://openalex.org/I9073902"]}],"countries":["CZ"],"is_corresponding":false,"raw_author_name":"Zden\u011bk Sofer","raw_affiliation_strings":["16628 Prague 6","Center for Advanced Functional Nanorobots","Department of Inorganic Chemistry","Faculty of Chemical Technology","University of Chemistry and Technology Prague"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"16628 Prague 6","institution_ids":[]},{"raw_affiliation_string":"Center for Advanced Functional Nanorobots","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic Chemistry","institution_ids":[]},{"raw_affiliation_string":"Faculty of Chemical Technology","institution_ids":[]},{"raw_affiliation_string":"University of Chemistry and Technology Prague","institution_ids":["https://openalex.org/I9073902"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5027346868","display_name":"Martin Pumera","orcid":"https://orcid.org/0000-0001-5846-2951","observed_orcids":["https://orcid.org/0000-0001-5846-2951"]},"institutions":[{"id":"https://openalex.org/I193775966","display_name":"Yonsei University","ror":"https://ror.org/01wjejq96","country_code":"KR","type":"education","lineage":["https://openalex.org/I193775966"]},{"id":"https://openalex.org/I9073902","display_name":"University of Chemistry and Technology, Prague","ror":"https://ror.org/05ggn0a85","country_code":"CZ","type":"education","lineage":["https://openalex.org/I9073902"]}],"countries":["CZ","KR"],"is_corresponding":true,"raw_author_name":"Martin Pumera","raw_affiliation_strings":["16628 Prague 6","Center for Advanced Functional Nanorobots","Department of Inorganic Chemistry","Faculty of Chemical Technology","University of Chemistry and Technology Prague","Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, Korea"],"raw_orcid":"https://orcid.org/0000-0001-5846-2951","affiliations":[{"raw_affiliation_string":"16628 Prague 6","institution_ids":[]},{"raw_affiliation_string":"Center for Advanced Functional Nanorobots","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic Chemistry","institution_ids":[]},{"raw_affiliation_string":"Faculty of Chemical Technology","institution_ids":[]},{"raw_affiliation_string":"University of Chemistry and Technology Prague","institution_ids":["https://openalex.org/I9073902"]},{"raw_affiliation_string":"Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, Korea","institution_ids":["https://openalex.org/I193775966"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5027346868"],"corresponding_institution_ids":["https://openalex.org/I193775966","https://openalex.org/I9073902"],"apc_list":null,"apc_paid":null,"fwci":0.4395,"has_fulltext":false,"cited_by_count":9,"citation_normalized_percentile":{"value":0.54142438,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":96},"biblio":{"volume":"11","issue":"22","first_page":"10695","last_page":"10701"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10404","display_name":"Enzyme Catalysis and Immobilization","score":0.9574999809265137,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},"topics":[{"id":"https://openalex.org/T10404","display_name":"Enzyme Catalysis and Immobilization","score":0.9574999809265137,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T10083","display_name":"Graphene research and applications","score":0.03240000084042549,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12627","display_name":"Graphene and Nanomaterials Applications","score":0.002400000113993883,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/fluorographene","display_name":"fluorographene","score":0.9980000257492065},{"id":"https://openalex.org/keywords/xanthogenates","display_name":"xanthogenates","score":0.9369999766349792},{"id":"https://openalex.org/keywords/thiol-functionalization","display_name":"thiol functionalization","score":0.8650000095367432},{"id":"https://openalex.org/keywords/enzyme-immobilization","display_name":"enzyme immobilization","score":0.9549999833106995},{"id":"https://openalex.org/keywords/heterogeneous-biocatalysts","display_name":"heterogeneous biocatalysts","score":0.8669999837875366},{"id":"https://openalex.org/keywords/mucor-miehei-lipase","display_name":"Mucor miehei lipase","score":0.8799999952316284},{"id":"https://openalex.org/keywords/catalase","display_name":"catalase","score":0.9670000076293945},{"id":"https://openalex.org/keywords/ester-hydrolysis","display_name":"ester hydrolysis","score":0.7609999775886536},{"id":"https://openalex.org/keywords/bioremediation","display_name":"bioremediation","score":0.7770000100135803},{"id":"https://openalex.org/keywords/environmental-remediation","display_name":"environmental remediation","score":0.5619999766349792}],"concepts":[{"id":"https://openalex.org/C2779697368","wikidata":"https://www.wikidata.org/wiki/Q380967","display_name":"Lipase","level":3,"score":0.6548541784286499},{"id":"https://openalex.org/C2781324293","wikidata":"https://www.wikidata.org/wiki/Q220410","display_name":"Thiol","level":2,"score":0.6357227563858032},{"id":"https://openalex.org/C115537861","wikidata":"https://www.wikidata.org/wiki/Q7645993","display_name":"Surface modification","level":2,"score":0.6169642210006714},{"id":"https://openalex.org/C191503008","wikidata":"https://www.wikidata.org/wiki/Q16007026","display_name":"Biocatalysis","level":4,"score":0.6161681413650513},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.554913341999054},{"id":"https://openalex.org/C33633552","wikidata":"https://www.wikidata.org/wiki/Q904145","display_name":"Immobilized enzyme","level":3,"score":0.4797897934913635},{"id":"https://openalex.org/C2124996","wikidata":"https://www.wikidata.org/wiki/Q816441","display_name":"Bioremediation","level":3,"score":0.46902337670326233},{"id":"https://openalex.org/C30080830","wikidata":"https://www.wikidata.org/wiki/Q169917","display_name":"Graphene","level":2,"score":0.44722452759742737},{"id":"https://openalex.org/C522964758","wikidata":"https://www.wikidata.org/wiki/Q2019586","display_name":"Environmental remediation","level":3,"score":0.417512446641922},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.39834290742874146},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.3320891261100769},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.2878970503807068},{"id":"https://openalex.org/C181199279","wikidata":"https://www.wikidata.org/wiki/Q8047","display_name":"Enzyme","level":2,"score":0.22143682837486267},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.20265546441078186},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.1118490993976593},{"id":"https://openalex.org/C112570922","wikidata":"https://www.wikidata.org/wiki/Q60528603","display_name":"Contamination","level":2,"score":0.05627259612083435},{"id":"https://openalex.org/C86803240","wikidata":"https://www.wikidata.org/wiki/Q420","display_name":"Biology","level":0,"score":0.05240440368652344},{"id":"https://openalex.org/C18903297","wikidata":"https://www.wikidata.org/wiki/Q7150","display_name":"Ecology","level":1,"score":0.0},{"id":"https://openalex.org/C154881586","wikidata":"https://www.wikidata.org/wiki/Q898579","display_name":"Ionic liquid","level":3,"score":0.0},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D004800","descriptor_name":"Enzymes, Immobilized","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D006108","descriptor_name":"Graphite","qualifier_ui":"Q000138","qualifier_name":"chemical synthesis","is_major_topic":true},{"descriptor_ui":"D006108","descriptor_name":"Graphite","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D008049","descriptor_name":"Lipase","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D009089","descriptor_name":"Mucor","qualifier_ui":"Q000201","qualifier_name":"enzymology","is_major_topic":true},{"descriptor_ui":"D052918","descriptor_name":"Environmental Restoration and Remediation","qualifier_ui":null,"qualifier_name":null,"is_major_topic":true}],"locations_count":2,"locations":[{"id":"doi:10.1039/c9nr02376c","doi":"https://doi.org/10.1039/c9nr02376c","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c9nr02376c","pdf_url":null,"source":{"id":"https://openalex.org/S23181512","display_name":"Nanoscale","issn_l":"2040-3364","issn":["2040-3364","2040-3372"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-3","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nanoscale","raw_type":"journal-article"},{"id":"pmid:31120458","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/31120458","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nanoscale","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/12","score":0.7811999917030334,"display_name":"Responsible consumption and production"},{"id":"https://metadata.un.org/sdg/6","score":0.7778000235557556,"display_name":"Clean water and sanitation"}],"study_designs":[],"awards":[{"id":"https://openalex.org/G4107703137","display_name":null,"funder_award_id":"GACR 16-05167S","funder_id":"https://openalex.org/F4320321005","funder_display_name":"Ministerstvo \u0160kolstv\u00ed, Ml\u00e1de\u017ee a T\u011blov\u00fdchovy"},{"id":"https://openalex.org/G5508601680","display_name":"New efficient membranes for effective H2 / CO2 separation (HySME)","funder_award_id":"GA17-05421S","funder_id":"https://openalex.org/F4320321006","funder_display_name":"Grantov\u00e1 Agentura \u010cesk\u00e9 Republiky"},{"id":"https://openalex.org/G8720576029","display_name":null,"funder_award_id":"CZ.02.1.01/0.0/0.0/15_003/0000444","funder_id":"https://openalex.org/F4320321005","funder_display_name":"Ministerstvo \u0160kolstv\u00ed, Ml\u00e1de\u017ee a T\u011blov\u00fdchovy"}],"funders":[{"id":"https://openalex.org/F4320321005","display_name":"Ministerstvo \u0160kolstv\u00ed, Ml\u00e1de\u017ee a T\u011blov\u00fdchovy","ror":"https://ror.org/037n8p820"},{"id":"https://openalex.org/F4320321006","display_name":"Grantov\u00e1 Agentura \u010cesk\u00e9 Republiky","ror":"https://ror.org/01pv73b02"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":32,"referenced_works":["https://openalex.org/W1849299596","https://openalex.org/W1989173693","https://openalex.org/W2024256830","https://openalex.org/W2030929377","https://openalex.org/W2034949678","https://openalex.org/W2047834391","https://openalex.org/W2070199888","https://openalex.org/W2070987621","https://openalex.org/W2071668818","https://openalex.org/W2095923886","https://openalex.org/W2095963233","https://openalex.org/W2128635872","https://openalex.org/W2131662926","https://openalex.org/W2135724087","https://openalex.org/W2151803725","https://openalex.org/W2163822354","https://openalex.org/W2166172820","https://openalex.org/W2318362323","https://openalex.org/W2331927912","https://openalex.org/W2530580704","https://openalex.org/W2537663545","https://openalex.org/W2589080787","https://openalex.org/W2614603801","https://openalex.org/W2614797546","https://openalex.org/W2759547804","https://openalex.org/W2780825361","https://openalex.org/W2791809218","https://openalex.org/W2804414700","https://openalex.org/W2807899294","https://openalex.org/W2887298371","https://openalex.org/W2889169734","https://openalex.org/W2892911053"],"related_works":["https://openalex.org/W2887298371","https://openalex.org/W3193943470","https://openalex.org/W2904078834","https://openalex.org/W7132667345","https://openalex.org/W1983801726","https://openalex.org/W2530580704","https://openalex.org/W2897287295","https://openalex.org/W4389333517","https://openalex.org/W2088432662","https://openalex.org/W4234453703"],"abstract_inverted_index":{"Graphene,":[0],"graphene":[1,64],"oxide":[2],"and":[3,124],"their":[4],"related":[5],"thiographene-,":[6],"hydroxygraphene-":[7],"or":[8,69],"fluorographene-based":[9],"materials":[10],"have":[11],"broad":[12],"applications.":[13,81,105,158],"We":[14,141],"report":[15],"on":[16,113],"the":[17,31,38,49,59,98,110,118,125,131,138],"thiol-functionalization":[18],"of":[19,28,33,51,54,61,109,117,130,137],"fluorographene":[20],"via":[21,67],"xanthogenate.":[22],"Such":[23,45],"thiographene":[24,47,100],"contains":[25],"5.1":[26],"at%":[27],"sulphur":[29],"in":[30,93,155],"form":[32],"thiol":[34,40,111],"groups,":[35],"which":[36],"is":[37,101],"highest":[39],"content":[41],"reported":[42],"to":[43],"date.":[44],"tailored":[46],"allows":[48],"immobilization":[50],"two":[52],"types":[53],"enzymes.":[55],"Here,":[56],"we":[57],"explore":[58],"functionalization":[60],"highly":[62,146],"thiolated":[63],"with":[65,84],"enzymes":[66],"physisorption":[68],"covalent":[70],"linkage":[71],"producing":[72],"an":[73],"important":[74],"heterogeneous":[75,148],"biocatalyst":[76,150],"platform":[77],"for":[78,103],"wastewater":[79,95],"treatment":[80,96],"Thiographene":[82],"modified":[83],"a":[85,145,153],"lipase":[86,133],"from":[87],"Mucor":[88],"miehei":[89],"can":[90],"find":[91,152],"utilization":[92],"lipid-rich":[94],"whereas":[97],"catalase-modified":[99],"intended":[102],"bioremediation":[104],"Upon":[106],"increasing":[107],"concentration":[108],"groups":[112],"graphene,":[114],"protein":[115],"loading":[116],"catalase":[119],"was":[120,134],"increased":[121],"by":[122],"16%":[123],"ester":[126],"bond":[127],"cleavage":[128],"activity":[129],"thiographene-immobilized":[132],"129%":[135],"that":[136,143],"free":[139],"lipase.":[140],"expect":[142],"such":[144],"active":[147],"thiographene-based":[149],"will":[151],"use":[154],"water":[156],"remediation":[157]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":3}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2019-05-29T00:00:00"}