{"id":"https://openalex.org/W2944199201","doi":"https://doi.org/10.1039/c9cp00946a","title":"In situ reversible redox switching of first hyperpolarizability of bimetallic ruthenium complexes","display_name":"In situ reversible redox switching of first hyperpolarizability of bimetallic ruthenium complexes","publication_year":2019,"publication_date":"2019-01-01","ids":{"openalex":"https://openalex.org/W2944199201","doi":"https://doi.org/10.1039/c9cp00946a","mag":"2944199201","pmid":"https://pubmed.ncbi.nlm.nih.gov/31093630"},"language":"en","primary_location":{"id":"doi:10.1039/c9cp00946a","doi":"https://doi.org/10.1039/c9cp00946a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c9cp00946a","pdf_url":null,"source":{"id":"https://openalex.org/S181332294","display_name":"Physical Chemistry Chemical Physics","issn_l":"1463-9076","issn":["1463-9076","1463-9084"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-3","ki-jl-1","medline","norway-2","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical Chemistry Chemical Physics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5056212260","display_name":"Chinnachamy Karthika","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I59270414","display_name":"Indian Institute of Science Bangalore","ror":"https://ror.org/04dese585","country_code":"IN","type":"education","lineage":["https://openalex.org/I59270414"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"C. Karthika","raw_affiliation_strings":["Bangalore 560012","Department of Inorganic and Physical Chemistry, Indian Institute of Science","India","Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Bangalore 560012","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic and Physical Chemistry, Indian Institute of Science","institution_ids":["https://openalex.org/I59270414"]},{"raw_affiliation_string":"India","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India","institution_ids":["https://openalex.org/I59270414"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5025935500","display_name":"Sarath Kumar","orcid":"https://orcid.org/0000-0001-8802-256X","observed_orcids":["https://orcid.org/0000-0001-8802-256X"]},"institutions":[{"id":"https://openalex.org/I59270414","display_name":"Indian Institute of Science Bangalore","ror":"https://ror.org/04dese585","country_code":"IN","type":"education","lineage":["https://openalex.org/I59270414"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"S. R. Sarath Kumar","raw_affiliation_strings":["Bangalore 560012","Department of Inorganic and Physical Chemistry, Indian Institute of Science","India","Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Bangalore 560012","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic and Physical Chemistry, Indian Institute of Science","institution_ids":["https://openalex.org/I59270414"]},{"raw_affiliation_string":"India","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India","institution_ids":["https://openalex.org/I59270414"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5052989409","display_name":"Lakshay Kathuria","orcid":"https://orcid.org/0000-0002-3261-8804","observed_orcids":["https://orcid.org/0000-0002-3261-8804"]},"institutions":[{"id":"https://openalex.org/I59270414","display_name":"Indian Institute of Science Bangalore","ror":"https://ror.org/04dese585","country_code":"IN","type":"education","lineage":["https://openalex.org/I59270414"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"L. Kathuria","raw_affiliation_strings":["Bangalore 560012","Department of Inorganic and Physical Chemistry, Indian Institute of Science","India","Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India"],"raw_orcid":"https://orcid.org/0000-0002-3261-8804","affiliations":[{"raw_affiliation_string":"Bangalore 560012","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic and Physical Chemistry, Indian Institute of Science","institution_ids":["https://openalex.org/I59270414"]},{"raw_affiliation_string":"India","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India","institution_ids":["https://openalex.org/I59270414"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5076295608","display_name":"Puspendu K. Das","orcid":"https://orcid.org/0000-0001-8091-5865","observed_orcids":["https://orcid.org/0000-0001-8091-5865","https://orcid.org/0000-0002-8509-5912"]},"institutions":[{"id":"https://openalex.org/I59270414","display_name":"Indian Institute of Science Bangalore","ror":"https://ror.org/04dese585","country_code":"IN","type":"education","lineage":["https://openalex.org/I59270414"]}],"countries":["IN"],"is_corresponding":true,"raw_author_name":"P. K. Das","raw_affiliation_strings":["Bangalore 560012","Department of Inorganic and Physical Chemistry, Indian Institute of Science","India","Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India"],"raw_orcid":"https://orcid.org/0000-0001-8091-5865","affiliations":[{"raw_affiliation_string":"Bangalore 560012","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic and Physical Chemistry, Indian Institute of Science","institution_ids":["https://openalex.org/I59270414"]},{"raw_affiliation_string":"India","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India","institution_ids":["https://openalex.org/I59270414"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5091566037","display_name":"Ashoka G. Samuelson","orcid":"https://orcid.org/0000-0001-9416-162X","observed_orcids":["https://orcid.org/0000-0001-9416-162X"]},"institutions":[{"id":"https://openalex.org/I59270414","display_name":"Indian Institute of Science Bangalore","ror":"https://ror.org/04dese585","country_code":"IN","type":"education","lineage":["https://openalex.org/I59270414"]}],"countries":["IN"],"is_corresponding":false,"raw_author_name":"A. G. Samuelson","raw_affiliation_strings":["Bangalore 560012","Department of Inorganic and Physical Chemistry, Indian Institute of Science","India","Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India"],"raw_orcid":"https://orcid.org/0000-0001-9416-162X","affiliations":[{"raw_affiliation_string":"Bangalore 560012","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic and Physical Chemistry, Indian Institute of Science","institution_ids":["https://openalex.org/I59270414"]},{"raw_affiliation_string":"India","institution_ids":[]},{"raw_affiliation_string":"Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560012, India","institution_ids":["https://openalex.org/I59270414"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5076295608"],"corresponding_institution_ids":["https://openalex.org/I59270414"],"apc_list":null,"apc_paid":null,"fwci":0.4727,"has_fulltext":false,"cited_by_count":8,"citation_normalized_percentile":{"value":0.54446209,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":92,"max":96},"biblio":{"volume":"21","issue":"21","first_page":"11079","last_page":"11086"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11025","display_name":"Nonlinear Optical Materials Research","score":0.9692000150680542,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11025","display_name":"Nonlinear Optical Materials Research","score":0.9692000150680542,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11708","display_name":"Photochromic and Fluorescence Chemistry","score":0.0035000001080334187,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10612","display_name":"Magnetism in coordination complexes","score":0.0034000000450760126,"subfield":{"id":"https://openalex.org/subfields/2504","display_name":"Electronic, Optical and Magnetic Materials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/first-hyperpolarizability","display_name":"first hyperpolarizability","score":0.9309999942779541},{"id":"https://openalex.org/keywords/bimetallic-ruthenium-complexes","display_name":"bimetallic ruthenium complexes","score":0.953000009059906},{"id":"https://openalex.org/keywords/redox-switching","display_name":"redox switching","score":0.921999990940094},{"id":"https://openalex.org/keywords/metal-oxidation-state","display_name":"metal oxidation state","score":0.8130000233650208},{"id":"https://openalex.org/keywords/nonlinear-optical-materials","display_name":"nonlinear optical materials","score":0.5680000185966492},{"id":"https://openalex.org/keywords/in-situ-measurement","display_name":"in situ measurement","score":0.3179999887943268}],"concepts":[{"id":"https://openalex.org/C43411465","wikidata":"https://www.wikidata.org/wiki/Q2997621","display_name":"Bimetallic strip","level":3,"score":0.9267688989639282},{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.9075973033905029},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.7545202374458313},{"id":"https://openalex.org/C2777822432","wikidata":"https://www.wikidata.org/wiki/Q216681","display_name":"In situ","level":2,"score":0.7406630516052246},{"id":"https://openalex.org/C2780694488","wikidata":"https://www.wikidata.org/wiki/Q2477036","display_name":"Hyperpolarizability","level":4,"score":0.7008132338523865},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.5093387365341187},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5079889893531799},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3403823971748352},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.33978140354156494},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.2904900312423706},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.2384064495563507},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.16285157203674316},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.14455652236938477},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.13547751307487488},{"id":"https://openalex.org/C139287275","wikidata":"https://www.wikidata.org/wiki/Q869891","display_name":"Polarizability","level":3,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1039/c9cp00946a","doi":"https://doi.org/10.1039/c9cp00946a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c9cp00946a","pdf_url":null,"source":{"id":"https://openalex.org/S181332294","display_name":"Physical Chemistry Chemical Physics","issn_l":"1463-9076","issn":["1463-9076","1463-9084"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-3","ki-jl-1","medline","norway-2","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical Chemistry Chemical Physics","raw_type":"journal-article"},{"id":"pmid:31093630","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/31093630","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Physical chemistry chemical physics : PCCP","raw_type":"Journal Article"},{"id":"pmh:oai:eprints.iisc.ac.in:63131","doi":null,"is_oa":false,"landing_page_url":"http://eprints.iisc.ac.in/63131/1/phy_che_che_phy_21-21_11079_2019.pdf","pdf_url":"http://eprints.iisc.ac.in/63131/1/phy_che_che_phy_21-21_11079_2019.pdf","source":{"id":"https://openalex.org/S4377196309","display_name":"NOT FOUND REPOSITORY (Indian Institute of Science Bangalore)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I59270414","host_organization_name":"Indian Institute of Science Bangalore","host_organization_lineage":["https://openalex.org/I59270414"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320320767","display_name":"University Grants Commission","ror":"https://ror.org/04p800546"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":51,"referenced_works":["https://openalex.org/W589212071","https://openalex.org/W1762996612","https://openalex.org/W1895462836","https://openalex.org/W1963737263","https://openalex.org/W1966182479","https://openalex.org/W1971316520","https://openalex.org/W1972895056","https://openalex.org/W1975879685","https://openalex.org/W1982424801","https://openalex.org/W1983317969","https://openalex.org/W1986249317","https://openalex.org/W1997151511","https://openalex.org/W1998208950","https://openalex.org/W1999832496","https://openalex.org/W2007495794","https://openalex.org/W2008599478","https://openalex.org/W2008803333","https://openalex.org/W2012489100","https://openalex.org/W2022763758","https://openalex.org/W2024881136","https://openalex.org/W2026436334","https://openalex.org/W2032061727","https://openalex.org/W2034655450","https://openalex.org/W2035887397","https://openalex.org/W2043725874","https://openalex.org/W2046572370","https://openalex.org/W2051600759","https://openalex.org/W2059645358","https://openalex.org/W2060306489","https://openalex.org/W2062213944","https://openalex.org/W2062852634","https://openalex.org/W2067454705","https://openalex.org/W2067908861","https://openalex.org/W2070430580","https://openalex.org/W2070925890","https://openalex.org/W2071776811","https://openalex.org/W2080562091","https://openalex.org/W2090253142","https://openalex.org/W2090791796","https://openalex.org/W2093277738","https://openalex.org/W2118991015","https://openalex.org/W2119884286","https://openalex.org/W2135034266","https://openalex.org/W2151440625","https://openalex.org/W2320484768","https://openalex.org/W2320599729","https://openalex.org/W2330282654","https://openalex.org/W2497007159","https://openalex.org/W2499753008","https://openalex.org/W2620381656","https://openalex.org/W2621124074"],"related_works":["https://openalex.org/W3126441155","https://openalex.org/W1999373344","https://openalex.org/W2022587285","https://openalex.org/W2008835949","https://openalex.org/W2008951530","https://openalex.org/W2067908861","https://openalex.org/W3123896483","https://openalex.org/W2086286530","https://openalex.org/W2068544530","https://openalex.org/W145442950"],"abstract_inverted_index":{"esu.":[0],"We":[1],"also":[2,35],"demonstrated":[3],"that":[4],"the":[5,10,13,17,21],"hyperpolarizability":[6],"is":[7],"reversible":[8],"with":[9],"change":[11],"of":[12,16,28],"oxidation":[14],"state":[15],"metal":[18],"and":[19],"both":[20],"complexes":[22],"are":[23,34],"stable":[24],"for":[25],"several":[26],"cycles":[27],"redox":[29],"switching.":[30],"The":[31],"experimental":[32],"results":[33],"supported":[36],"by":[37],"calculations.":[38]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":2}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2019-05-16T00:00:00"}
