{"id":"https://openalex.org/W2943666088","doi":"https://doi.org/10.1021/acs.organomet.9b00151","title":"Direct Access to IMesF and IMesF2 by Electrophilic Fluorination of Abnormal N-Heterocyclic Carbenes","display_name":"Direct Access to IMesF and IMesF2 by Electrophilic Fluorination of Abnormal N-Heterocyclic Carbenes","publication_year":2019,"publication_date":"2019-04-29","ids":{"openalex":"https://openalex.org/W2943666088","doi":"https://doi.org/10.1021/acs.organomet.9b00151","mag":"2943666088"},"language":"en","primary_location":{"id":"doi:10.1021/acs.organomet.9b00151","doi":"https://doi.org/10.1021/acs.organomet.9b00151","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.9b00151","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://hal.science/hal-02333068","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5060304911","display_name":"\u0410.\u0410. \u0413\u0440\u0438\u043d\u0435\u0432\u0430","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210108652","display_name":"NS Kurnakova Institute of General and Inorganic Chemistry","ror":"https://ror.org/01hy2c330","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210108652","https://openalex.org/I4210145551"]},{"id":"https://openalex.org/I4210119060","display_name":"Laboratoire de Chimie de Coordination","ror":"https://ror.org/01rtzw447","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I205747304","https://openalex.org/I4210119060","https://openalex.org/I4210128300","https://openalex.org/I4405258862"]},{"id":"https://openalex.org/I4405258862","display_name":"Universit\u00e9 de Toulouse","ror":"https://ror.org/01ahyrz84","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258862"]}],"countries":["FR","RU"],"is_corresponding":false,"raw_author_name":"Alina A. Grineva","raw_affiliation_strings":["Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Pr., Moscow 119991, Russia","LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France","LCC - Laboratoire de chimie de coordination (205 Route de Narbonne 31077 TOULOUSE CEDEX 4 - France)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Pr., Moscow 119991, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210108652"]},{"raw_affiliation_string":"LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060","https://openalex.org/I4405258862"]},{"raw_affiliation_string":"LCC - Laboratoire de chimie de coordination (205 Route de Narbonne 31077 TOULOUSE CEDEX 4 - France)","institution_ids":["https://openalex.org/I4210119060"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5004284214","display_name":"Oleg A. Filippov","orcid":"https://orcid.org/0000-0002-7963-2806","observed_orcids":["https://orcid.org/0000-0002-7963-2806"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I2802913842","display_name":"A. N. Nesmeyanov Institute of Organoelement Compounds","ror":"https://ror.org/03jzs4815","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I2802913842","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Oleg A. Filippov","raw_affiliation_strings":["A.N. Nesmeyanov Institute of Organoelement Compounds (INEOS), Russian Academy of Sciences, GSP-1, B-334, 28 Vavilov str., Moscow 119991, Russia"],"raw_orcid":"https://orcid.org/0000-0002-7963-2806","affiliations":[{"raw_affiliation_string":"A.N. Nesmeyanov Institute of Organoelement Compounds (INEOS), Russian Academy of Sciences, GSP-1, B-334, 28 Vavilov str., Moscow 119991, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I2802913842"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5063835310","display_name":"\u0421.\u0415. \u041d\u0435\u0444\u0435\u0434\u043e\u0432","orcid":"https://orcid.org/0000-0002-9314-290X","observed_orcids":["https://orcid.org/0000-0002-9314-290X"]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210108652","display_name":"NS Kurnakova Institute of General and Inorganic Chemistry","ror":"https://ror.org/01hy2c330","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210108652","https://openalex.org/I4210145551"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Sergei E. Nefedov","raw_affiliation_strings":["Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Pr., Moscow 119991, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky Pr., Moscow 119991, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210108652"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5022953044","display_name":"No\u00ebl Lugan","orcid":"https://orcid.org/0000-0002-3744-5252","observed_orcids":["https://orcid.org/0000-0002-3744-5252"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210119060","display_name":"Laboratoire de Chimie de Coordination","ror":"https://ror.org/01rtzw447","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I205747304","https://openalex.org/I4210119060","https://openalex.org/I4210128300","https://openalex.org/I4405258862"]},{"id":"https://openalex.org/I4405258862","display_name":"Universit\u00e9 de Toulouse","ror":"https://ror.org/01ahyrz84","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258862"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"No\u00ebl Lugan","raw_affiliation_strings":["LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France","LCC - Laboratoire de chimie de coordination (205 Route de Narbonne 31077 TOULOUSE CEDEX 4 - France)"],"raw_orcid":"https://orcid.org/0000-0002-3744-5252","affiliations":[{"raw_affiliation_string":"LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060","https://openalex.org/I4405258862"]},{"raw_affiliation_string":"LCC - Laboratoire de chimie de coordination (205 Route de Narbonne 31077 TOULOUSE CEDEX 4 - France)","institution_ids":["https://openalex.org/I4210119060"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5071786606","display_name":"Vincent C\u00e9sar","orcid":"https://orcid.org/0000-0002-6203-6434","observed_orcids":["https://orcid.org/0000-0002-6203-6434"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210119060","display_name":"Laboratoire de Chimie de Coordination","ror":"https://ror.org/01rtzw447","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I205747304","https://openalex.org/I4210119060","https://openalex.org/I4210128300","https://openalex.org/I4405258862"]},{"id":"https://openalex.org/I4405258862","display_name":"Universit\u00e9 de Toulouse","ror":"https://ror.org/01ahyrz84","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258862"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"Vincent C\u00e9sar","raw_affiliation_strings":["LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France","LCC - Laboratoire de chimie de coordination (205 Route de Narbonne 31077 TOULOUSE CEDEX 4 - France)"],"raw_orcid":"https://orcid.org/0000-0002-6203-6434","affiliations":[{"raw_affiliation_string":"LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060","https://openalex.org/I4405258862"]},{"raw_affiliation_string":"LCC - Laboratoire de chimie de coordination (205 Route de Narbonne 31077 TOULOUSE CEDEX 4 - France)","institution_ids":["https://openalex.org/I4210119060"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5024837620","display_name":"Dmitry A. Valyaev","orcid":"https://orcid.org/0000-0002-1772-844X","observed_orcids":["https://orcid.org/0000-0002-1772-844X"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210119060","display_name":"Laboratoire de Chimie de Coordination","ror":"https://ror.org/01rtzw447","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I205747304","https://openalex.org/I4210119060","https://openalex.org/I4210128300","https://openalex.org/I4405258862"]},{"id":"https://openalex.org/I4405258862","display_name":"Universit\u00e9 de Toulouse","ror":"https://ror.org/01ahyrz84","country_code":"FR","type":"education","lineage":["https://openalex.org/I4405258862"]}],"countries":["FR"],"is_corresponding":true,"raw_author_name":"Dmitry A. Valyaev","raw_affiliation_strings":["LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France","LCC - Laboratoire de chimie de coordination (205 Route de Narbonne 31077 TOULOUSE CEDEX 4 - France)"],"raw_orcid":"https://orcid.org/0000-0002-1772-844X","affiliations":[{"raw_affiliation_string":"LCC-CNRS, Universit\u00e9 de Toulouse, CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060","https://openalex.org/I4405258862"]},{"raw_affiliation_string":"LCC - Laboratoire de chimie de coordination (205 Route de Narbonne 31077 TOULOUSE CEDEX 4 - France)","institution_ids":["https://openalex.org/I4210119060"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":6,"corresponding_author_ids":["https://openalex.org/A5022953044","https://openalex.org/A5024837620","https://openalex.org/A5071786606"],"corresponding_institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210119060","https://openalex.org/I4405258862"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":1.4956,"has_fulltext":false,"cited_by_count":30,"citation_normalized_percentile":{"value":0.793033,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"38","issue":"11","first_page":"2330","last_page":"2337"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10947","display_name":"Fluorine in Organic Chemistry","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/n-heterocyclic-carbenes","display_name":"N-heterocyclic carbenes","score":0.8830000162124634},{"id":"https://openalex.org/keywords/electrophilic-fluorination","display_name":"electrophilic fluorination","score":0.8510000109672546},{"id":"https://openalex.org/keywords/abnormal-n-heterocyclic-carbenes","display_name":"abnormal N-heterocyclic carbenes","score":0.8029999732971191},{"id":"https://openalex.org/keywords/manganese-i-complexes","display_name":"manganese(I) complexes","score":0.5529999732971191},{"id":"https://openalex.org/keywords/n-fluorobenzenesulfonimide","display_name":"N-fluorobenzenesulfonimide","score":0.8939999938011169},{"id":"https://openalex.org/keywords/demetallation","display_name":"demetallation","score":0.8019999861717224},{"id":"https://openalex.org/keywords/trifluoromethanesulfonic-acid","display_name":"trifluoromethanesulfonic acid","score":0.8069999814033508},{"id":"https://openalex.org/keywords/electron-donating-ability","display_name":"electron-donating ability","score":0.5879999995231628},{"id":"https://openalex.org/keywords/ligand-electronic-properties","display_name":"ligand electronic properties","score":0.4300000071525574}],"concepts":[{"id":"https://openalex.org/C2780311995","wikidata":"https://www.wikidata.org/wiki/Q17125083","display_name":"IMes","level":4,"score":0.9470152854919434},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.874923586845398},{"id":"https://openalex.org/C2777164566","wikidata":"https://www.wikidata.org/wiki/Q419257","display_name":"Carbene","level":3,"score":0.8672385215759277},{"id":"https://openalex.org/C118629725","wikidata":"https://www.wikidata.org/wiki/Q2686738","display_name":"Deprotonation","level":3,"score":0.7442933320999146},{"id":"https://openalex.org/C50027330","wikidata":"https://www.wikidata.org/wiki/Q908086","display_name":"Electrophile","level":3,"score":0.7400208115577698},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.652592658996582},{"id":"https://openalex.org/C2776568683","wikidata":"https://www.wikidata.org/wiki/Q23005640","display_name":"Moiety","level":2,"score":0.5913395881652832},{"id":"https://openalex.org/C506198293","wikidata":"https://www.wikidata.org/wiki/Q650","display_name":"Fluorine","level":2,"score":0.5879648327827454},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.5445705652236938},{"id":"https://openalex.org/C177293861","wikidata":"https://www.wikidata.org/wiki/Q78974","display_name":"Electronegativity","level":2,"score":0.4925304353237152},{"id":"https://openalex.org/C2779128551","wikidata":"https://www.wikidata.org/wiki/Q304850","display_name":"Triflic acid","level":3,"score":0.43104758858680725},{"id":"https://openalex.org/C2778824931","wikidata":"https://www.wikidata.org/wiki/Q5358518","display_name":"Electrophilic fluorination","level":4,"score":0.411912739276886},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.36233460903167725},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.22019469738006592},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.11684262752532959},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.07924488186836243},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/acs.organomet.9b00151","doi":"https://doi.org/10.1021/acs.organomet.9b00151","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.9b00151","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},{"id":"pmh:oai:HAL:hal-02333068v1","doi":null,"is_oa":true,"landing_page_url":"https://hal.science/hal-02333068","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Organometallics, 2019, 38 (11), pp.2330-2337. ⟨10.1021/acs.organomet.9b00151⟩","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"pmh:oai:HAL:hal-02333068v1","doi":null,"is_oa":true,"landing_page_url":"https://hal.science/hal-02333068","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Organometallics, 2019, 38 (11), pp.2330-2337. ⟨10.1021/acs.organomet.9b00151⟩","raw_type":"info:eu-repo/semantics/article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320322892","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":48,"referenced_works":["https://openalex.org/W100084136","https://openalex.org/W1899556128","https://openalex.org/W1965479345","https://openalex.org/W1974878780","https://openalex.org/W1990170643","https://openalex.org/W1996273492","https://openalex.org/W1997113667","https://openalex.org/W2003143283","https://openalex.org/W2003555872","https://openalex.org/W2013985799","https://openalex.org/W2025945778","https://openalex.org/W2033990154","https://openalex.org/W2046412723","https://openalex.org/W2049996223","https://openalex.org/W2050229878","https://openalex.org/W2093847845","https://openalex.org/W2096641027","https://openalex.org/W2103607851","https://openalex.org/W2125545674","https://openalex.org/W2127856777","https://openalex.org/W2131350133","https://openalex.org/W2132525235","https://openalex.org/W2143981217","https://openalex.org/W2144629860","https://openalex.org/W2148284063","https://openalex.org/W2150047944","https://openalex.org/W2164318957","https://openalex.org/W2196095035","https://openalex.org/W2295475789","https://openalex.org/W2324562764","https://openalex.org/W2325339364","https://openalex.org/W2342534651","https://openalex.org/W2466604897","https://openalex.org/W2584256096","https://openalex.org/W2587695953","https://openalex.org/W2594583169","https://openalex.org/W2604156473","https://openalex.org/W2729172579","https://openalex.org/W2746701507","https://openalex.org/W2784725846","https://openalex.org/W2790571193","https://openalex.org/W2794655937","https://openalex.org/W2799372563","https://openalex.org/W2883327144","https://openalex.org/W2907278639","https://openalex.org/W2933233412","https://openalex.org/W4211219673","https://openalex.org/W4248316661"],"related_works":["https://openalex.org/W7002162341","https://openalex.org/W3135806402","https://openalex.org/W2511837465","https://openalex.org/W4387032789","https://openalex.org/W2345963089","https://openalex.org/W4402625311","https://openalex.org/W2168277522","https://openalex.org/W7126451049","https://openalex.org/W2011115254","https://openalex.org/W3095897557"],"abstract_inverted_index":{"The":[0,41],"incorporation":[1],"of":[2,24,32,43,65,93,104,121,139],"fluorine":[3,94,141],"atoms":[4],"into":[5],"the":[6,25,33,56,63,66,71,90,118,134,140],"N-heterocyclic":[7],"carbene":[8,36],"(NHC)":[9],"ligand":[10,75],"backbone":[11],"in":[12],"a":[13,22],"Mn(I)":[14],"complex":[15],"[CpMn(CO)":[16,46],"2":[17,47,74,88,124],"(IMes)]":[18],"was":[19,76],"achieved":[20],"via":[21],"sequence":[23],"C\u2013H":[26],"bond":[27],"deprotonation":[28],"and":[29,99],"electrophilic":[30],"fluorination":[31],"anionic":[34],"abnormal":[35],"moiety":[37],"with":[38,52],"N":[39],"-fluorobenzenesulfonimide.":[40],"demetallation":[42],"resulting":[44],"complexes":[45],"(IMes":[48],"F":[49,60,73,123],"1-2":[50,61],")]":[51],"triflic":[53],"acid":[54],"afforded":[55],"imidazolium":[57],"salts":[58],"IMes":[59,72,86,122],"\u00b7HOTf,":[62],"precursors":[64],"corresponding":[67],"fluorinated":[68],"NHCs.":[69],"Interestingly,":[70],"found":[77],"to":[78,110,133],"be":[79],"more":[80],"electron-donating":[81],"than":[82],"its":[83,128],"well-known":[84],"analogue":[85],"Cl":[87],"notwithstanding":[89],"higher":[91],"electronegativity":[92],"atoms.":[95],"A":[96],"systematic":[97],"experimental":[98],"density":[100],"functional":[101],"theory":[102],"study":[103],"this":[105,113],"NHC":[106],"series":[107],"allowed":[108],"us":[109],"fully":[111],"rationalize":[112],"unexpected":[114],"behavior,":[115],"revealing":[116],"that":[117],"weaker":[119],"\u03c3-donation":[120],"is":[125],"compensated":[126],"by":[127],"lower":[129],"\u03c0-accepting":[130],"properties":[131],"due":[132],"strong":[135],"mesomeric":[136],"+M":[137],"effect":[138],"substituents.":[142]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":7},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":11},{"year":2020,"cited_by_count":4}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2019-05-09T00:00:00"}