{"id":"https://openalex.org/W2936725658","doi":"https://doi.org/10.1002/cctc.201900459","title":"Scope and Limitations of TBA[Fe]\u2010Catalyzed Carbene Transfer to X\u2212H\u2010bonds \u2013 Indication of a Mechanistic Dichotomy","display_name":"Scope and Limitations of TBA[Fe]\u2010Catalyzed Carbene Transfer to X\u2212H\u2010bonds \u2013 Indication of a Mechanistic Dichotomy","publication_year":2019,"publication_date":"2019-04-08","ids":{"openalex":"https://openalex.org/W2936725658","doi":"https://doi.org/10.1002/cctc.201900459","mag":"2936725658"},"language":"en","primary_location":{"id":"doi:10.1002/cctc.201900459","doi":"https://doi.org/10.1002/cctc.201900459","is_oa":false,"landing_page_url":"https://doi.org/10.1002/cctc.201900459","pdf_url":null,"source":{"id":"https://openalex.org/S206633562","display_name":"ChemCatChem","issn_l":"1867-3880","issn":["1867-3880","1867-3899"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemCatChem","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5048846753","display_name":"Annika R\u00f6ske","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I100066346","display_name":"University of Stuttgart","ror":"https://ror.org/04vnq7t77","country_code":"DE","type":"education","lineage":["https://openalex.org/I100066346"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Annika R\u00f6ske","raw_affiliation_strings":["Institute of Organic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Organic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany","institution_ids":["https://openalex.org/I100066346"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043909934","display_name":"Isabel T. Alt","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I100066346","display_name":"University of Stuttgart","ror":"https://ror.org/04vnq7t77","country_code":"DE","type":"education","lineage":["https://openalex.org/I100066346"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Isabel Alt","raw_affiliation_strings":["Institute of Organic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Organic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany","institution_ids":["https://openalex.org/I100066346"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5082588682","display_name":"Bernd J. Plietker","orcid":"https://orcid.org/0000-0001-8423-6173","observed_orcids":["https://orcid.org/0000-0001-8423-6173"]},"institutions":[{"id":"https://openalex.org/I100066346","display_name":"University of Stuttgart","ror":"https://ror.org/04vnq7t77","country_code":"DE","type":"education","lineage":["https://openalex.org/I100066346"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Bernd Plietker","raw_affiliation_strings":["Institute of Organic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany"],"raw_orcid":"https://orcid.org/0000-0001-8423-6173","affiliations":[{"raw_affiliation_string":"Institute of Organic Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany","institution_ids":["https://openalex.org/I100066346"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5082588682"],"corresponding_institution_ids":["https://openalex.org/I100066346"],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":0.9347,"has_fulltext":false,"cited_by_count":15,"citation_normalized_percentile":{"value":0.65794906,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"11","issue":"21","first_page":"5260","last_page":"5263"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.5073000192642212,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.5073000192642212,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.20409999787807465,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11611","display_name":"Cyclopropane Reaction Mechanisms","score":0.19179999828338623,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/carbene-transfer","display_name":"carbene transfer","score":0.7559999823570251},{"id":"https://openalex.org/keywords/iron-nitrosyl-complexes","display_name":"iron nitrosyl complexes","score":0.5569999814033508},{"id":"https://openalex.org/keywords/thiols","display_name":"thiols","score":0.7009999752044678},{"id":"https://openalex.org/keywords/secondary-amines","display_name":"secondary amines","score":0.9760000109672546},{"id":"https://openalex.org/keywords/silane","display_name":"silane","score":0.9330000281333923},{"id":"https://openalex.org/keywords/hammett-equation","display_name":"Hammett correlation","score":0.7639999985694885},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.8650000095367432},{"id":"https://openalex.org/keywords/alcohol-reactivity","display_name":"alcohol reactivity","score":0.39500001072883606}],"concepts":[{"id":"https://openalex.org/C2777164566","wikidata":"https://www.wikidata.org/wiki/Q419257","display_name":"Carbene","level":3,"score":0.8808552026748657},{"id":"https://openalex.org/C2778183973","wikidata":"https://www.wikidata.org/wiki/Q2476769","display_name":"Silanes","level":3,"score":0.7975728511810303},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7908434271812439},{"id":"https://openalex.org/C178907741","wikidata":"https://www.wikidata.org/wiki/Q745930","display_name":"Nucleophile","level":3,"score":0.7662112712860107},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7272014617919922},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.570262610912323},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3428254723548889},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3399363160133362},{"id":"https://openalex.org/C2778024649","wikidata":"https://www.wikidata.org/wiki/Q410572","display_name":"Silane","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/cctc.201900459","doi":"https://doi.org/10.1002/cctc.201900459","is_oa":false,"landing_page_url":"https://doi.org/10.1002/cctc.201900459","pdf_url":null,"source":{"id":"https://openalex.org/S206633562","display_name":"ChemCatChem","issn_l":"1867-3880","issn":["1867-3880","1867-3899"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-c","jufo-1","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemCatChem","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320320879","display_name":"Deutsche Forschungsgemeinschaft","ror":"https://ror.org/018mejw64"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":44,"referenced_works":["https://openalex.org/W1148208603","https://openalex.org/W1967476900","https://openalex.org/W1980344730","https://openalex.org/W1980657542","https://openalex.org/W1984232099","https://openalex.org/W2013665598","https://openalex.org/W2018580941","https://openalex.org/W2029617469","https://openalex.org/W2034816859","https://openalex.org/W2056138258","https://openalex.org/W2061142370","https://openalex.org/W2063913713","https://openalex.org/W2084561927","https://openalex.org/W2086484956","https://openalex.org/W2086720222","https://openalex.org/W2090044818","https://openalex.org/W2091748401","https://openalex.org/W2125285191","https://openalex.org/W2131136753","https://openalex.org/W2137021774","https://openalex.org/W2151518267","https://openalex.org/W2153810710","https://openalex.org/W2153976979","https://openalex.org/W2155587860","https://openalex.org/W2160373876","https://openalex.org/W2161999177","https://openalex.org/W2195739249","https://openalex.org/W2222842705","https://openalex.org/W2286721367","https://openalex.org/W2334919103","https://openalex.org/W2549690057","https://openalex.org/W2582750885","https://openalex.org/W2589522946","https://openalex.org/W2607951682","https://openalex.org/W2761111935","https://openalex.org/W2767046718","https://openalex.org/W2791097542","https://openalex.org/W2883672907","https://openalex.org/W2950711545","https://openalex.org/W4231492338","https://openalex.org/W4243714007","https://openalex.org/W4244812902","https://openalex.org/W4252193107","https://openalex.org/W4254928910"],"related_works":["https://openalex.org/W3128609725","https://openalex.org/W4399694006","https://openalex.org/W6963299300","https://openalex.org/W2028047546","https://openalex.org/W2035605774","https://openalex.org/W4313729884","https://openalex.org/W4313431233","https://openalex.org/W2472773178","https://openalex.org/W4396782548","https://openalex.org/W4417355096"],"abstract_inverted_index":{"Abstract":[0],"An":[1],"in\u2010depth":[2],"study":[3],"of":[4,39],"carbene":[5],"transfer":[6],"reactions":[7],"into":[8],"polar":[9],"X\u2212H\u2010bonds":[10],"catalyzed":[11],"by":[12],"the":[13,37],"nucleophilic":[14],"Fe\u2010complex":[15],"Bu4N[Fe(CO)3(NO)]":[16],"(TBA[Fe])":[17],"is":[18],"presented.":[19],"Whereas":[20],"alcohols":[21],"are":[22,28],"unreactive,":[23],"thiols":[24],"and":[25],"secondary":[26],"amines":[27],"reactive,":[29],"silanes":[30],"showed":[31],"modest":[32],"activities.":[33],"Hammett":[34],"correlations":[35],"indicate":[36],"presence":[38],"an":[40],"X\u2212H\u2010acidity":[41],"dependent":[42],"mechanistic":[43],"dichotomy.":[44]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":3}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2019-04-25T00:00:00"}
