{"id":"https://openalex.org/W2916635065","doi":"https://doi.org/10.1080/00268976.2019.1580781","title":"Photodissociation dynamics of the methylsulfinyl radical at 248 nm","display_name":"Photodissociation dynamics of the methylsulfinyl radical at 248 nm","publication_year":2019,"publication_date":"2019-02-20","ids":{"openalex":"https://openalex.org/W2916635065","doi":"https://doi.org/10.1080/00268976.2019.1580781","mag":"2916635065"},"language":"en","primary_location":{"id":"doi:10.1080/00268976.2019.1580781","doi":"https://doi.org/10.1080/00268976.2019.1580781","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00268976.2019.1580781","pdf_url":null,"source":{"id":"https://openalex.org/S204809294","display_name":"Molecular Physics","issn_l":"0026-8976","issn":["0026-8976","1362-3028"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","norway-1","poland-70","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Molecular Physics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5047735781","display_name":"Isaac A. Ramphal","orcid":"https://orcid.org/0000-0002-6102-2065","observed_orcids":["https://orcid.org/0000-0002-6102-2065"]},"institutions":[{"id":"https://openalex.org/I148283060","display_name":"Lawrence Berkeley National Laboratory","ror":"https://ror.org/02jbv0t02","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I148283060","https://openalex.org/I39565521"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Isaac A. Ramphal","raw_affiliation_strings":["Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California, USA","Department of Chemistry, University of California, Berkeley, California, USA"],"raw_orcid":"https://orcid.org/0000-0002-6102-2065","affiliations":[{"raw_affiliation_string":"Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California, USA","institution_ids":["https://openalex.org/I148283060"]},{"raw_affiliation_string":"Department of Chemistry, University of California, Berkeley, California, USA","institution_ids":["https://openalex.org/I95457486"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101544437","display_name":"Chin Lee","orcid":"https://orcid.org/0000-0001-9011-0526","observed_orcids":["https://orcid.org/0000-0001-9011-0526"]},"institutions":[{"id":"https://openalex.org/I148283060","display_name":"Lawrence Berkeley National Laboratory","ror":"https://ror.org/02jbv0t02","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I148283060","https://openalex.org/I39565521"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Chin Lee","raw_affiliation_strings":["Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California, USA","Department of Chemistry, University of California, Berkeley, California, USA"],"raw_orcid":"https://orcid.org/0000-0001-9011-0526","affiliations":[{"raw_affiliation_string":"Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California, USA","institution_ids":["https://openalex.org/I148283060"]},{"raw_affiliation_string":"Department of Chemistry, University of California, Berkeley, California, USA","institution_ids":["https://openalex.org/I95457486"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5005884690","display_name":"Daniel M. Neumark","orcid":"https://orcid.org/0000-0002-3762-9473","observed_orcids":["https://orcid.org/0000-0002-3762-9473"]},"institutions":[{"id":"https://openalex.org/I148283060","display_name":"Lawrence Berkeley National Laboratory","ror":"https://ror.org/02jbv0t02","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I148283060","https://openalex.org/I39565521"]},{"id":"https://openalex.org/I95457486","display_name":"University of California, Berkeley","ror":"https://ror.org/01an7q238","country_code":"US","type":"education","lineage":["https://openalex.org/I95457486"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Daniel M. Neumark","raw_affiliation_strings":["Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California, USA","Department of Chemistry, University of California, Berkeley, California, USA"],"raw_orcid":"https://orcid.org/0000-0002-3762-9473","affiliations":[{"raw_affiliation_string":"Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California, USA","institution_ids":["https://openalex.org/I148283060"]},{"raw_affiliation_string":"Department of Chemistry, University of California, Berkeley, California, USA","institution_ids":["https://openalex.org/I95457486"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5005884690"],"corresponding_institution_ids":["https://openalex.org/I148283060","https://openalex.org/I95457486"],"apc_list":null,"apc_paid":null,"fwci":0.1924,"has_fulltext":false,"cited_by_count":4,"citation_normalized_percentile":{"value":0.31793122,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":95},"biblio":{"volume":"117","issue":"21","first_page":"3043","last_page":"3055"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.7103999853134155,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12967","display_name":"Molecular Spectroscopy and Structure","score":0.7103999853134155,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.09560000151395798,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10002","display_name":"Advanced Chemical Physics Studies","score":0.06390000134706497,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/photodissociation-dynamics","display_name":"photodissociation dynamics","score":0.9890000224113464},{"id":"https://openalex.org/keywords/248-nm-excitation","display_name":"248 nm excitation","score":0.9190000295639038},{"id":"https://openalex.org/keywords/s-o-bond-cleavage","display_name":"S-O bond cleavage","score":0.843999981880188},{"id":"https://openalex.org/keywords/c-s-bond-cleavage","display_name":"C\u2013S bond cleavage","score":0.9380000233650208},{"id":"https://openalex.org/keywords/internal-conversion","display_name":"internal conversion","score":0.7059999704360962},{"id":"https://openalex.org/keywords/photofragment-translational-spectroscopy","display_name":"photofragment translational spectroscopy","score":0.8510000109672546},{"id":"https://openalex.org/keywords/jet-cooled-molecules","display_name":"jet-cooled molecules","score":0.7200000286102295},{"id":"https://openalex.org/keywords/sulfines","display_name":"sulfines","score":0.7070000171661377},{"id":"https://openalex.org/keywords/hydrogen-atoms","display_name":"hydrogen atom","score":0.5839999914169312}],"concepts":[{"id":"https://openalex.org/C54582936","wikidata":"https://www.wikidata.org/wiki/Q16814","display_name":"Photodissociation","level":2,"score":0.8979306817054749},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.8259022831916809},{"id":"https://openalex.org/C102931765","wikidata":"https://www.wikidata.org/wiki/Q189673","display_name":"Dissociation (chemistry)","level":2,"score":0.8010380268096924},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7695953845977783},{"id":"https://openalex.org/C69523127","wikidata":"https://www.wikidata.org/wiki/Q4480008","display_name":"Ground state","level":2,"score":0.7461864948272705},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.5670206546783447},{"id":"https://openalex.org/C54419926","wikidata":"https://www.wikidata.org/wiki/Q1246432","display_name":"Molecular beam","level":3,"score":0.5125219821929932},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4972997009754181},{"id":"https://openalex.org/C3044715","wikidata":"https://www.wikidata.org/wiki/Q3952437","display_name":"Bond cleavage","level":3,"score":0.4839623272418976},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.47776854038238525},{"id":"https://openalex.org/C62396407","wikidata":"https://www.wikidata.org/wiki/Q863696","display_name":"Bond-dissociation energy","level":3,"score":0.4496241509914398},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.3578605055809021},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.25430911779403687},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.16909131407737732},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.07404166460037231},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.07212802767753601},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.06394749879837036},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1080/00268976.2019.1580781","doi":"https://doi.org/10.1080/00268976.2019.1580781","is_oa":false,"landing_page_url":"https://doi.org/10.1080/00268976.2019.1580781","pdf_url":null,"source":{"id":"https://openalex.org/S204809294","display_name":"Molecular Physics","issn_l":"0026-8976","issn":["0026-8976","1362-3028"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","norway-1","poland-70","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320547","host_organization_name":"Taylor & Francis","host_organization_lineage":["https://openalex.org/P4310320547","https://openalex.org/P4310320449"],"host_organization_lineage_names":["Taylor & Francis","Informa"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Molecular Physics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G42916606","display_name":null,"funder_award_id":"DE AC02 05CH11231","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"}],"funders":[{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"},{"id":"https://openalex.org/F4320337480","display_name":"Basic Energy Sciences","ror":"https://ror.org/05mg91w61"},{"id":"https://openalex.org/F4320337744","display_name":"Chemical Sciences, Geosciences, and Biosciences Division","ror":null}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":86,"referenced_works":["https://openalex.org/W341851730","https://openalex.org/W1415305120","https://openalex.org/W1521726949","https://openalex.org/W1566881142","https://openalex.org/W1589757706","https://openalex.org/W1967110856","https://openalex.org/W1968602577","https://openalex.org/W1973159931","https://openalex.org/W1973676260","https://openalex.org/W1976347016","https://openalex.org/W1977346443","https://openalex.org/W1978676501","https://openalex.org/W1980147263","https://openalex.org/W1983929668","https://openalex.org/W1984247314","https://openalex.org/W1984270738","https://openalex.org/W1985149977","https://openalex.org/W1988930856","https://openalex.org/W1989104443","https://openalex.org/W1992415812","https://openalex.org/W1993795153","https://openalex.org/W1995201738","https://openalex.org/W1996534202","https://openalex.org/W1999107743","https://openalex.org/W1999541915","https://openalex.org/W2001191855","https://openalex.org/W2004428337","https://openalex.org/W2013121801","https://openalex.org/W2014189263","https://openalex.org/W2016845051","https://openalex.org/W2019788782","https://openalex.org/W2021978015","https://openalex.org/W2026108594","https://openalex.org/W2026363039","https://openalex.org/W2031398755","https://openalex.org/W2031885363","https://openalex.org/W2036752766","https://openalex.org/W2037394135","https://openalex.org/W2038263790","https://openalex.org/W2038748497","https://openalex.org/W2041910381","https://openalex.org/W2045717026","https://openalex.org/W2048264410","https://openalex.org/W2048649827","https://openalex.org/W2048836446","https://openalex.org/W2050321271","https://openalex.org/W2052561010","https://openalex.org/W2053223828","https://openalex.org/W2066410486","https://openalex.org/W2069365943","https://openalex.org/W2071007402","https://openalex.org/W2074694926","https://openalex.org/W2075711588","https://openalex.org/W2077416598","https://openalex.org/W2082505351","https://openalex.org/W2084848425","https://openalex.org/W2092185497","https://openalex.org/W2095583624","https://openalex.org/W2096173804","https://openalex.org/W2097768016","https://openalex.org/W2109057255","https://openalex.org/W2115075125","https://openalex.org/W2116365914","https://openalex.org/W2117018191","https://openalex.org/W2123965801","https://openalex.org/W2134758219","https://openalex.org/W2147682760","https://openalex.org/W2153745071","https://openalex.org/W2158798785","https://openalex.org/W2174413018","https://openalex.org/W2199103381","https://openalex.org/W2206599005","https://openalex.org/W2252732916","https://openalex.org/W2276356986","https://openalex.org/W2301774107","https://openalex.org/W2312272542","https://openalex.org/W2323137678","https://openalex.org/W2326565617","https://openalex.org/W2333986729","https://openalex.org/W2475589048","https://openalex.org/W2786593835","https://openalex.org/W2799823195","https://openalex.org/W3004700709","https://openalex.org/W3217528490","https://openalex.org/W4234993611","https://openalex.org/W4240751010"],"related_works":["https://openalex.org/W1558077170","https://openalex.org/W2069412429","https://openalex.org/W2007283541","https://openalex.org/W2465576369","https://openalex.org/W1976347016","https://openalex.org/W2276356986","https://openalex.org/W2071007402","https://openalex.org/W1993609587","https://openalex.org/W1541341461","https://openalex.org/W2015928049"],"abstract_inverted_index":{"The":[0,20,48],"photodissociation":[1],"dynamics":[2],"of":[3,39,87,106],"jet-cooled":[4],"methylsulfinyl":[5],"radicals,":[6],"CH3SO,":[7],"at":[8],"248":[9],"nm":[10],"have":[11],"been":[12],"investigated":[13],"using":[14],"molecular":[15],"beam":[16],"photofragment":[17],"translational":[18],"spectroscopy.":[19],"primary":[21],"channel":[22,53],"is":[23],"CH3S":[24],"+":[25,51],"O,":[26],"which":[27],"occurs":[28],"via":[29],"the":[30,40,69,94],"initially":[31],"prepared":[32],"excited":[33,70,77],"CH3SO":[34,88],"state":[35,46,71,100],"by":[36,90],"rapid":[37,65],"cleavage":[38,67],"S-O":[41],"bond":[42],"to":[43,64,72,84],"produce":[44,73],"ground":[45,95,99],"products.":[47],"minor":[49],"SO":[50],"CH3":[52,74],"has":[54],"two":[55],"components":[56],"in":[57],"comparable":[58],"proportions:":[59],"a":[60,80],"fast":[61],"feature":[62,82],"corresponding":[63],"C-S":[66],"on":[68,93],"and":[75,79,110],"electronically":[76],"SO,":[78],"slow":[81],"due":[83],"internal":[85],"conversion":[86],"followed":[89],"statistical":[91],"dissociation":[92,101],"electronic":[96],"state.":[97],"Statistical":[98],"also":[102],"produces":[103],"small":[104],"amounts":[105],"CH2SO,":[107],"likely":[108],"sulfine,":[109],"H-atoms.":[111]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2022,"cited_by_count":2}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2019-03-02T00:00:00"}