{"id":"https://openalex.org/W2914354767","doi":"https://doi.org/10.1021/jacs.8b13119","title":"Mechanistic Study and Development of Catalytic Reactions of Sm(II)","display_name":"Mechanistic Study and Development of Catalytic Reactions of Sm(II)","publication_year":2019,"publication_date":"2019-01-27","ids":{"openalex":"https://openalex.org/W2914354767","doi":"https://doi.org/10.1021/jacs.8b13119","mag":"2914354767","pmid":"https://pubmed.ncbi.nlm.nih.gov/30685971"},"language":"en","primary_location":{"id":"doi:10.1021/jacs.8b13119","doi":"https://doi.org/10.1021/jacs.8b13119","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.8b13119","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://doi.org/10.26434/chemrxiv.7355069","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5067647873","display_name":"Sandeepan Maity","orcid":"https://orcid.org/0000-0002-2870-1314","observed_orcids":["https://orcid.org/0000-0002-2870-1314"]},"institutions":[{"id":"https://openalex.org/I186143895","display_name":"Lehigh University","ror":"https://ror.org/012afjb06","country_code":"US","type":"education","lineage":["https://openalex.org/I186143895"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Sandeepan Maity","raw_affiliation_strings":["Department of Chemistry, Lehigh University, Bethlehem, Pennsylvania 18015, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Lehigh University, Bethlehem, Pennsylvania 18015, United States","institution_ids":["https://openalex.org/I186143895"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5072523681","display_name":"Robert A. II Flowers","orcid":"https://orcid.org/0000-0003-2295-1336","observed_orcids":["https://orcid.org/0000-0003-2295-1336"]},"institutions":[{"id":"https://openalex.org/I186143895","display_name":"Lehigh University","ror":"https://ror.org/012afjb06","country_code":"US","type":"education","lineage":["https://openalex.org/I186143895"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Robert A. Flowers","raw_affiliation_strings":["Department of Chemistry, Lehigh University, Bethlehem, Pennsylvania 18015, United States"],"raw_orcid":"https://orcid.org/0000-0003-2295-1336","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Lehigh University, Bethlehem, Pennsylvania 18015, United States","institution_ids":["https://openalex.org/I186143895"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5072523681"],"corresponding_institution_ids":["https://openalex.org/I186143895"],"apc_list":{"value":5000,"currency":"USD","value_usd":5000},"apc_paid":null,"fwci":2.0699,"has_fulltext":false,"cited_by_count":54,"citation_normalized_percentile":{"value":0.86404647,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":99},"biblio":{"volume":"141","issue":"7","first_page":"3207","last_page":"3216"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.625,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.625,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.22290000319480896,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.04320000112056732,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/samarium-diiodide","display_name":"samarium diiodide","score":0.9929999709129333},{"id":"https://openalex.org/keywords/catalytic-reduction","display_name":"catalytic reduction","score":0.6420000195503235},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.6190000176429749},{"id":"https://openalex.org/keywords/trimethylchlorosilane","display_name":"trimethylchlorosilane","score":0.8999999761581421},{"id":"https://openalex.org/keywords/samarium-chloride","display_name":"samarium chloride","score":0.5630000233650208}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8933852910995483},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7443265318870544},{"id":"https://openalex.org/C40875361","wikidata":"https://www.wikidata.org/wiki/Q2356542","display_name":"Reagent","level":2,"score":0.6057718992233276},{"id":"https://openalex.org/C51886252","wikidata":"https://www.wikidata.org/wiki/Q4118667","display_name":"Olefin fiber","level":3,"score":0.5429943799972534},{"id":"https://openalex.org/C2778128264","wikidata":"https://www.wikidata.org/wiki/Q900863","display_name":"Ketyl","level":3,"score":0.5246736407279968},{"id":"https://openalex.org/C536819264","wikidata":"https://www.wikidata.org/wiki/Q1819","display_name":"Samarium","level":2,"score":0.5229081511497498},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.5065268278121948},{"id":"https://openalex.org/C48424934","wikidata":"https://www.wikidata.org/wiki/Q898912","display_name":"Coupling reaction","level":3,"score":0.47377896308898926},{"id":"https://openalex.org/C55904794","wikidata":"https://www.wikidata.org/wiki/Q82682","display_name":"Redox","level":2,"score":0.4479597508907318},{"id":"https://openalex.org/C144082473","wikidata":"https://www.wikidata.org/wiki/Q213185","display_name":"Stoichiometry","level":2,"score":0.44483208656311035},{"id":"https://openalex.org/C38316802","wikidata":"https://www.wikidata.org/wiki/Q648191","display_name":"Organic reaction","level":3,"score":0.43399718403816223},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.41616371273994446},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3405047059059143},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.33846181631088257},{"id":"https://openalex.org/C139066938","wikidata":"https://www.wikidata.org/wiki/Q185056","display_name":"Radical","level":2,"score":0.2940146028995514},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0}],"mesh":[],"locations_count":5,"locations":[{"id":"doi:10.1021/jacs.8b13119","doi":"https://doi.org/10.1021/jacs.8b13119","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.8b13119","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"doi:10.26434/chemrxiv.7355069","doi":"https://doi.org/10.26434/chemrxiv.7355069","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.7355069","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},{"id":"doi:10.26434/chemrxiv.7355069.v1","doi":"https://doi.org/10.26434/chemrxiv.7355069.v1","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.7355069.v1","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},{"id":"pmid:30685971","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/30685971","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"},{"id":"pmh:oai:figshare.com:article/7355069","doi":null,"is_oa":true,"landing_page_url":"https://figshare.com/articles/Mechanistic_Study_and_Development_of_Catalytic_Reactions_of_Sm_II_/7355069","pdf_url":null,"source":{"id":"https://openalex.org/S7407051385","display_name":"Royal College of Surgeons in Ireland","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I142762351","host_organization_name":"Royal College of Surgeons in Ireland","host_organization_lineage":["https://openalex.org/I142762351"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Preprint"}],"best_oa_location":{"id":"doi:10.26434/chemrxiv.7355069","doi":"https://doi.org/10.26434/chemrxiv.7355069","is_oa":true,"landing_page_url":"https://doi.org/10.26434/chemrxiv.7355069","pdf_url":null,"source":{"id":"https://openalex.org/S4393918830","display_name":"ChemRxiv","issn_l":"2573-2293","issn":["2573-2293"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"posted-content"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G7680511794","display_name":null,"funder_award_id":"1565741","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":72,"referenced_works":["https://openalex.org/W658459357","https://openalex.org/W1963982778","https://openalex.org/W1966512781","https://openalex.org/W1966644575","https://openalex.org/W1968479718","https://openalex.org/W1971849813","https://openalex.org/W1971988873","https://openalex.org/W1977026202","https://openalex.org/W1993372864","https://openalex.org/W1994423152","https://openalex.org/W1999139342","https://openalex.org/W2004248212","https://openalex.org/W2006670752","https://openalex.org/W2019765081","https://openalex.org/W2034513553","https://openalex.org/W2035386856","https://openalex.org/W2038861344","https://openalex.org/W2040775603","https://openalex.org/W2058785536","https://openalex.org/W2059140240","https://openalex.org/W2068906159","https://openalex.org/W2070500044","https://openalex.org/W2071181513","https://openalex.org/W2072028543","https://openalex.org/W2072304474","https://openalex.org/W2076143659","https://openalex.org/W2082815458","https://openalex.org/W2083459542","https://openalex.org/W2086590480","https://openalex.org/W2096708867","https://openalex.org/W2099232458","https://openalex.org/W2103911511","https://openalex.org/W2117829265","https://openalex.org/W2120705954","https://openalex.org/W2122145090","https://openalex.org/W2122253330","https://openalex.org/W2126461464","https://openalex.org/W2126492927","https://openalex.org/W2151651809","https://openalex.org/W2156607919","https://openalex.org/W2176810755","https://openalex.org/W2316023690","https://openalex.org/W2319706602","https://openalex.org/W2329408659","https://openalex.org/W2330024285","https://openalex.org/W2331173106","https://openalex.org/W2419147344","https://openalex.org/W2561735017","https://openalex.org/W2566240194","https://openalex.org/W2694362746","https://openalex.org/W2742826843","https://openalex.org/W2755464369","https://openalex.org/W2761068780","https://openalex.org/W2767055002","https://openalex.org/W2767817928","https://openalex.org/W2781163444","https://openalex.org/W2783531647","https://openalex.org/W2792141189","https://openalex.org/W2808632305","https://openalex.org/W2883223019","https://openalex.org/W2887317315","https://openalex.org/W2949430054","https://openalex.org/W2949462977","https://openalex.org/W2949610590","https://openalex.org/W2949617304","https://openalex.org/W2950129242","https://openalex.org/W2952539107","https://openalex.org/W2952639395","https://openalex.org/W2952761522","https://openalex.org/W2952779789","https://openalex.org/W2953168678","https://openalex.org/W4235447564"],"related_works":["https://openalex.org/W7132948777","https://openalex.org/W4415130979","https://openalex.org/W3186862658","https://openalex.org/W3200016837","https://openalex.org/W7163147397","https://openalex.org/W2784979294","https://openalex.org/W7132994985","https://openalex.org/W3129611362","https://openalex.org/W1777050205","https://openalex.org/W2914061402"],"abstract_inverted_index":{"Despite":[0],"the":[1,11,92],"broad":[2],"utility":[3],"and":[4,18,56],"application":[5],"of":[6,29,40,49,94],"SmI":[7],"2":[8],"in":[9,15,25,60],"synthesis,":[10],"reagent":[12],"is":[13],"used":[14,32],"stoichiometric":[16],"amounts":[17],"has":[19],"a":[20,26,52,63,89],"high":[21],"molecular":[22],"weight,":[23],"resulting":[24],"large":[27],"amount":[28],"material":[30],"being":[31],"for":[33],"reactions":[34,48],"requiring":[35],"one":[36],"or":[37],"more":[38],"equivalents":[39],"electrons.":[41],"We":[42],"report":[43],"mechanistic":[44,82],"studies":[45],"on":[46],"catalytic":[47,95],"Sm(II)":[50,96],"employing":[51,86],"terminal":[53],"magnesium":[54],"reductant":[55],"trimethyl":[57],"silyl":[58],"chloride":[59],"concert":[61],"with":[62,74],"non-coordinating":[64],"proton":[65],"donor":[66],"source.":[67],"Reactions":[68],"using":[69],"this":[70],"approach":[71,83],"permitted":[72],"reductions":[73],"as":[75,77,88],"little":[76],"1":[78],"mol%":[79],"Sm.":[80],"The":[81],"enabled":[84],"catalysis":[85],"HMPA":[87],"ligand,":[90],"facilitating":[91],"development":[93],"5-":[97],"exo":[98],"-":[99],"trig":[100],"ketyl":[101],"olefin":[102],"cyclization":[103],"reactions.":[104]},"counts_by_year":[{"year":2026,"cited_by_count":5},{"year":2025,"cited_by_count":12},{"year":2024,"cited_by_count":13},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":10},{"year":2021,"cited_by_count":8},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":2}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2019-02-21T00:00:00"}
