{"id":"https://openalex.org/W2913152304","doi":"https://doi.org/10.1002/aoc.4797","title":"Zinc (II), palladium (II) and cadmium (II) complexes containing 4\u2010methoxy\u2010N\u2010(pyridin\u20102\u2010ylmethylene) aniline derivatives: Synthesis, characterization and methyl methacrylate polymerization","display_name":"Zinc (II), palladium (II) and cadmium (II) complexes containing 4\u2010methoxy\u2010N\u2010(pyridin\u20102\u2010ylmethylene) aniline derivatives: Synthesis, characterization and methyl methacrylate polymerization","publication_year":2019,"publication_date":"2019-02-05","ids":{"openalex":"https://openalex.org/W2913152304","doi":"https://doi.org/10.1002/aoc.4797","mag":"2913152304"},"language":"en","primary_location":{"id":"doi:10.1002/aoc.4797","doi":"https://doi.org/10.1002/aoc.4797","is_oa":false,"landing_page_url":"https://doi.org/10.1002/aoc.4797","pdf_url":null,"source":{"id":"https://openalex.org/S134627157","display_name":"Applied Organometallic Chemistry","issn_l":"0268-2605","issn":["0268-2605","1099-0739"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","norway-1","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Applied Organometallic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5046379497","display_name":"Su Hyun Park","orcid":"https://orcid.org/0000-0002-9237-7600","observed_orcids":["https://orcid.org/0000-0002-9237-7600","https://orcid.org/0000-0002-5527-7520"]},"institutions":[{"id":"https://openalex.org/I31419693","display_name":"Kyungpook National University","ror":"https://ror.org/040c17130","country_code":"KR","type":"education","lineage":["https://openalex.org/I31419693"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Suhyun Park","raw_affiliation_strings":["Department of Chemistry and Green-Nano Materials Research Centre, Kyungpook National University, 80 Daehakro, Buk-gu, Daegu-city, 41566 Republic of Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Green-Nano Materials Research Centre, Kyungpook National University, 80 Daehakro, Buk-gu, Daegu-city, 41566 Republic of Korea","institution_ids":["https://openalex.org/I31419693"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070477711","display_name":"Jungkyu K. Lee","orcid":"https://orcid.org/0000-0001-9508-1488","observed_orcids":["https://orcid.org/0000-0001-9508-1488","https://orcid.org/0000-0002-3648-7725"]},"institutions":[{"id":"https://openalex.org/I31419693","display_name":"Kyungpook National University","ror":"https://ror.org/040c17130","country_code":"KR","type":"education","lineage":["https://openalex.org/I31419693"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Jungkyu K. Lee","raw_affiliation_strings":["Department of Chemistry and Green-Nano Materials Research Centre, Kyungpook National University, 80 Daehakro, Buk-gu, Daegu-city, 41566 Republic of Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Green-Nano Materials Research Centre, Kyungpook National University, 80 Daehakro, Buk-gu, Daegu-city, 41566 Republic of Korea","institution_ids":["https://openalex.org/I31419693"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5003465369","display_name":"Hyosun Lee","orcid":"https://orcid.org/0000-0002-0107-3100","observed_orcids":["https://orcid.org/0000-0002-0107-3100"]},"institutions":[{"id":"https://openalex.org/I31419693","display_name":"Kyungpook National University","ror":"https://ror.org/040c17130","country_code":"KR","type":"education","lineage":["https://openalex.org/I31419693"]}],"countries":["KR"],"is_corresponding":true,"raw_author_name":"Hyosun Lee","raw_affiliation_strings":["Department of Chemistry and Green-Nano Materials Research Centre, Kyungpook National University, 80 Daehakro, Buk-gu, Daegu-city, 41566 Republic of Korea"],"raw_orcid":"https://orcid.org/0000-0002-0107-3100","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Green-Nano Materials Research Centre, Kyungpook National University, 80 Daehakro, Buk-gu, Daegu-city, 41566 Republic of Korea","institution_ids":["https://openalex.org/I31419693"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5043317620","display_name":"Saira Nayab","orcid":"https://orcid.org/0000-0002-9014-1602","observed_orcids":["https://orcid.org/0000-0002-9014-1602"]},"institutions":[{"id":"https://openalex.org/I4405263273","display_name":"Shaheed Benazir Bhutto University, Sheringal","ror":"https://ror.org/04jnrse34","country_code":"PK","type":"education","lineage":["https://openalex.org/I4405263273"]}],"countries":["PK"],"is_corresponding":false,"raw_author_name":"Saira Nayab","raw_affiliation_strings":["Department of Chemistry, Shaheed Benazir Bhutto University, Sheringal Dir (U), Khyber Pakhtunkhwa, Islamic Republic of Pakistan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Shaheed Benazir Bhutto University, Sheringal Dir (U), Khyber Pakhtunkhwa, Islamic Republic of Pakistan","institution_ids":["https://openalex.org/I4405263273"]}]},{"author_position":"last","author":{"id":null,"display_name":"Jong Won Shin","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I878022262","display_name":"Korea Institute of Science & Technology Information","ror":"https://ror.org/01k4yrm29","country_code":"KR","type":"facility","lineage":["https://openalex.org/I2801339556","https://openalex.org/I4210144908","https://openalex.org/I4387152098","https://openalex.org/I878022262"]}],"countries":["KR"],"is_corresponding":true,"raw_author_name":"Jong Won Shin","raw_affiliation_strings":["Daegu-Gyeongbuk Branch, Korea Institute of Science and Technology Information (KISTI), 90 Yutongdanji-ro, Buk-gu, Daegu, 41515 Republic of Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Daegu-Gyeongbuk Branch, Korea Institute of Science and Technology Information (KISTI), 90 Yutongdanji-ro, Buk-gu, Daegu, 41515 Republic of Korea","institution_ids":["https://openalex.org/I878022262"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5003465369"],"corresponding_institution_ids":["https://openalex.org/I31419693","https://openalex.org/I878022262"],"apc_list":{"value":2500,"currency":"USD","value_usd":2500},"apc_paid":null,"fwci":1.011,"has_fulltext":false,"cited_by_count":21,"citation_normalized_percentile":{"value":0.76057887,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"33","issue":"4","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.33570000529289246,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},"topics":[{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.33570000529289246,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.21400000154972076,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.21330000460147858,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/zinc-ii-complexes","display_name":"zinc(II) complexes","score":0.7910000085830688},{"id":"https://openalex.org/keywords/palladium-ii-complexes","display_name":"palladium(II) complexes","score":1.0},{"id":"https://openalex.org/keywords/cadmium-ii-complexes","display_name":"cadmium(II) complexes","score":0.9990000128746033},{"id":"https://openalex.org/keywords/schiff-base-ligands","display_name":"Schiff base ligands","score":0.7689999938011169},{"id":"https://openalex.org/keywords/methyl-methacrylate-polymerization","display_name":"methyl methacrylate polymerization","score":0.8569999933242798},{"id":"https://openalex.org/keywords/ziegler-natta-catalysis","display_name":"Ziegler-Natta catalysis","score":0.7760000228881836},{"id":"https://openalex.org/keywords/modified-methylaluminoxane","display_name":"modified methylaluminoxane","score":0.8539999723434448},{"id":"https://openalex.org/keywords/poly-methyl-methacrylate","display_name":"poly(methyl methacrylate)","score":0.8870000243186951},{"id":"https://openalex.org/keywords/syndiotactic-polymers","display_name":"syndiotactic polymers","score":0.6679999828338623},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.5839999914169312},{"id":"https://openalex.org/keywords/coordination-geometry","display_name":"coordination geometry","score":0.7799999713897705}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8700019717216492},{"id":"https://openalex.org/C2779244968","wikidata":"https://www.wikidata.org/wiki/Q186414","display_name":"Aniline","level":2,"score":0.7231893539428711},{"id":"https://openalex.org/C111592845","wikidata":"https://www.wikidata.org/wiki/Q2867924","display_name":"Trigonal bipyramidal molecular geometry","level":3,"score":0.7200940251350403},{"id":"https://openalex.org/C2777174529","wikidata":"https://www.wikidata.org/wiki/Q408080","display_name":"Methylaluminoxane","level":5,"score":0.6886921525001526},{"id":"https://openalex.org/C502130503","wikidata":"https://www.wikidata.org/wiki/Q1089","display_name":"Palladium","level":3,"score":0.5587095618247986},{"id":"https://openalex.org/C2779485729","wikidata":"https://www.wikidata.org/wiki/Q210385","display_name":"Pyridine","level":2,"score":0.5218566656112671},{"id":"https://openalex.org/C535196362","wikidata":"https://www.wikidata.org/wiki/Q758","display_name":"Zinc","level":2,"score":0.5172998905181885},{"id":"https://openalex.org/C39297587","wikidata":"https://www.wikidata.org/wiki/Q2630364","display_name":"Octahedral molecular geometry","level":3,"score":0.4994947910308838},{"id":"https://openalex.org/C127709339","wikidata":"https://www.wikidata.org/wiki/Q2677111","display_name":"Tetrahedral molecular geometry","level":3,"score":0.49120256304740906},{"id":"https://openalex.org/C2777935641","wikidata":"https://www.wikidata.org/wiki/Q382897","display_name":"Methyl methacrylate","level":4,"score":0.4899519979953766},{"id":"https://openalex.org/C198819137","wikidata":"https://www.wikidata.org/wiki/Q188884","display_name":"Octahedron","level":3,"score":0.487037718296051},{"id":"https://openalex.org/C514695523","wikidata":"https://www.wikidata.org/wiki/Q237200","display_name":"Organometallic chemistry","level":3,"score":0.4505690336227417},{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.4495391845703125},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.43310368061065674},{"id":"https://openalex.org/C92840921","wikidata":"https://www.wikidata.org/wiki/Q2460890","display_name":"Square pyramidal molecular geometry","level":3,"score":0.43139469623565674},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3922361135482788},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3847493529319763},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3757939338684082},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.32359594106674194},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.09086728096008301},{"id":"https://openalex.org/C2780446808","wikidata":"https://www.wikidata.org/wiki/Q413676","display_name":"Metallocene","level":4,"score":0.07701733708381653},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/aoc.4797","doi":"https://doi.org/10.1002/aoc.4797","is_oa":false,"landing_page_url":"https://doi.org/10.1002/aoc.4797","pdf_url":null,"source":{"id":"https://openalex.org/S134627157","display_name":"Applied Organometallic Chemistry","issn_l":"0268-2605","issn":["0268-2605","1099-0739"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","norway-1","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Applied Organometallic Chemistry","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G6593697451","display_name":null,"funder_award_id":"2017R1A2B4002100","funder_id":"https://openalex.org/F4320322349","funder_display_name":"Ministry of Education, Science and Technology"}],"funders":[{"id":"https://openalex.org/F4320322349","display_name":"Ministry of Education, Science and Technology","ror":"https://ror.org/01p262204"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":69,"referenced_works":["https://openalex.org/W78751938","https://openalex.org/W1539796472","https://openalex.org/W1905197220","https://openalex.org/W1963728173","https://openalex.org/W1964485953","https://openalex.org/W1969075595","https://openalex.org/W1969360633","https://openalex.org/W1972355963","https://openalex.org/W1973331315","https://openalex.org/W1978212017","https://openalex.org/W1984381496","https://openalex.org/W1988139734","https://openalex.org/W2000832732","https://openalex.org/W2013443201","https://openalex.org/W2014665034","https://openalex.org/W2016726159","https://openalex.org/W2020420844","https://openalex.org/W2020750034","https://openalex.org/W2021372579","https://openalex.org/W2021457538","https://openalex.org/W2023630158","https://openalex.org/W2028572843","https://openalex.org/W2029831867","https://openalex.org/W2032524371","https://openalex.org/W2035852926","https://openalex.org/W2039731731","https://openalex.org/W2051805159","https://openalex.org/W2052266010","https://openalex.org/W2053831687","https://openalex.org/W2054742964","https://openalex.org/W2057960318","https://openalex.org/W2061163524","https://openalex.org/W2062642057","https://openalex.org/W2064274341","https://openalex.org/W2066975843","https://openalex.org/W2081111039","https://openalex.org/W2081468856","https://openalex.org/W2084329722","https://openalex.org/W2085480684","https://openalex.org/W2090775912","https://openalex.org/W2091609455","https://openalex.org/W2093018850","https://openalex.org/W2094874520","https://openalex.org/W2105249240","https://openalex.org/W2106764283","https://openalex.org/W2108173152","https://openalex.org/W2132454074","https://openalex.org/W2138887176","https://openalex.org/W2152494363","https://openalex.org/W2160744965","https://openalex.org/W2212826281","https://openalex.org/W2256803860","https://openalex.org/W2266143583","https://openalex.org/W2282470905","https://openalex.org/W2313378417","https://openalex.org/W2344655404","https://openalex.org/W2346738971","https://openalex.org/W2403649892","https://openalex.org/W2467400748","https://openalex.org/W2511355730","https://openalex.org/W2553729117","https://openalex.org/W2559081696","https://openalex.org/W2564153054","https://openalex.org/W2621309130","https://openalex.org/W2636159272","https://openalex.org/W2768820148","https://openalex.org/W2769765377","https://openalex.org/W2774655277","https://openalex.org/W4285719527"],"related_works":["https://openalex.org/W2091609455","https://openalex.org/W1905197220","https://openalex.org/W2029831867","https://openalex.org/W1969075595","https://openalex.org/W1972355963","https://openalex.org/W1978212017","https://openalex.org/W2792299155","https://openalex.org/W2803153678","https://openalex.org/W2905533291","https://openalex.org/W2466507304"],"abstract_inverted_index":{"A":[0],"series":[1],"of":[2,54,73,77,137,143,190,208],"Zn":[3,89,112],"(II),":[4],"Pd":[5,55,172],"(II)":[6,9,56,90],"and":[7,41,48,62,79,82,94,105,113,203],"Cd":[8,114,133],"complexes,":[10,157],"[(L)nMX2]m":[11],"(L":[12,59],"=":[13,16,20,23,26,30,60],"L\u2010a\u2013L\u2010c;":[14],"M":[15,22],"Zn,":[17],"Pd;":[18],"X":[19,25],"Cl;":[21],"Cd;":[24],"Br;":[27],"n,":[28],"m":[29],"1":[31],"or":[32],"2),":[33],"containing":[34],"4\u2010methoxy\u2010N\u2010(pyridin\u20102\u2010ylmethylene)":[35],"aniline":[36,39,43],"(L\u2010a),":[37],"4\u2010methoxy\u2010N\u2010(pyridin\u20102\u2010ylmethyl)":[38],"(L\u2010b)":[40],"4\u2010methoxy\u2010N\u2010methyl\u2010N\u2010(pyridin\u20102\u2010ylmethyl)":[42],"(L\u2010c)":[44],"have":[45],"been":[46],"synthesized":[47,151],"characterized.":[49],"The":[50,86,135],"X\u2010ray":[51],"crystal":[52],"structures":[53],"complexes":[57,152],"[L1PdCl2]":[58],"L\u2010b":[61],"L\u2010c)":[63],"revealed":[64],"distorted":[65,101],"square":[66],"planar":[67],"geometries":[68,110],"obtained":[69,194],"via":[70],"coordinative":[71],"interaction":[72],"the":[74,141,150,160,198,206,216,220],"nitrogen":[75],"atoms":[76],"pyridine":[78],"amine":[80,204],"moieties":[81],"two":[83],"chloro":[84],"ligands.":[85],"geometry":[87,131],"around":[88,111,132],"center":[91],"in":[92,140,197],"[(L\u2010a)ZnCl2]":[93],"[(L\u2010c)ZnCl2]":[95],"can":[96],"be":[97],"best":[98],"described":[99],"as":[100],"tetrahedral,":[102],"whereas":[103],"[(L\u2010b)2ZnCl2]":[104],"[(L\u2010b)2CdBr2]":[106],"achieved":[107],"6\u2010coordinated":[108],"octahedral":[109],"centers":[115],"through":[116],"2\u2010equivalent":[117],"ligands,":[118],"respectively.":[119],"In":[120],"addition,":[121],"a":[122],"dimeric":[123],"[(L\u2010c)Cd(\u03bc\u2010Br)Br]2":[124],"complex":[125],"exhibited":[126],"typical":[127],"5\u2010coordinated":[128],"trigonal":[129],"bipyramidal":[130],"center.":[134],"polymerization":[136],"methyl":[138],"methacrylate":[139],"presence":[142],"modified":[144],"methylaluminoxane":[145],"was":[146,193],"evaluated":[147],"by":[148],"all":[149],"at":[153],"60\u00b0C.":[154],"Among":[155],"these":[156],"[(L\u2010b)PdCl2]":[158],"showed":[159],"highest":[161],"catalytic":[162,217],"activity":[163],"[3.80":[164],"\u00d7":[165,179],"104":[166],"g":[167,181],"poly":[168],"(methyl":[169],"methacrylate)":[170],"(PMMA)/mol":[171],"hr\u22121],":[173],"yielding":[174],"high":[175],"molecular":[176],"weight":[177],"(9.12":[178],"105":[180],"mol\u22121)":[182],"PMMA.":[183],"Syndio\u2010enriched":[184],"PMMA":[185],"(characterized":[186],"using":[187],"1H\u2010NMR":[188],"spectroscopy)":[189],"about":[191],"0.68":[192],"with":[195],"Tg":[196],"range":[199],"120\u2013128\u00b0C.":[200],"Unlike":[201],"imine":[202],"moieties,":[205],"introduction":[207],"N\u2010methyl":[209],"moiety":[210],"has":[211],"an":[212],"adverse":[213],"effect":[214],"on":[215],"activity,":[218],"but":[219],"syndiotacticity":[221],"remained":[222],"unaffected.":[223]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":7},{"year":2022,"cited_by_count":5},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2019-02-21T00:00:00"}