{"id":"https://openalex.org/W2912682802","doi":"https://doi.org/10.5562/cca3396","title":"Intrinsically Flame Retardant Polyurethane Prepared with Epoxidized Soybean Oil and Vinylphosphonic Acid","display_name":"Intrinsically Flame Retardant Polyurethane Prepared with Epoxidized Soybean Oil and Vinylphosphonic Acid","publication_year":2018,"publication_date":"2018-01-01","ids":{"openalex":"https://openalex.org/W2912682802","doi":"https://doi.org/10.5562/cca3396","mag":"2912682802"},"language":"en","primary_location":{"id":"doi:10.5562/cca3396","doi":"https://doi.org/10.5562/cca3396","is_oa":true,"landing_page_url":"https://doi.org/10.5562/cca3396","pdf_url":"https://doi.org/10.5562/cca3396","source":{"id":"https://openalex.org/S36275936","display_name":"Croatica Chemica Acta","issn_l":"0011-1643","issn":["0011-1643","1334-417X"],"is_oa":true,"is_in_doaj":true,"is_core":false,"listed_in":["ddh","doaj","dongbi-c","norway-1","poland-20","russia-white-list-3"],"host_organization":"https://openalex.org/P4310314830","host_organization_name":"Croatian Chemical Society","host_organization_lineage":["https://openalex.org/P4310314830"],"host_organization_lineage_names":["Croatian Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Croatica Chemica Acta","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","doaj"],"open_access":{"is_oa":true,"oa_status":"diamond","oa_url":"https://doi.org/10.5562/cca3396","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5020940016","display_name":"Aynur \u00d6z\u015feker","orcid":"https://orcid.org/0000-0002-5705-390X","observed_orcids":["https://orcid.org/0000-0002-5705-390X"]},"institutions":[{"id":"https://openalex.org/I103703290","display_name":"Sakarya University","ror":"https://ror.org/04ttnw109","country_code":"TR","type":"education","lineage":["https://openalex.org/I103703290"]}],"countries":["TR"],"is_corresponding":false,"raw_author_name":"Aynur \u00d6z\u015feker","raw_affiliation_strings":["Department of Chemistry, Faculty of Science and Literature, Sakarya University, Esentepe Campus, Serdivan, 54187, Sakarya, Turkey"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Faculty of Science and Literature, Sakarya University, Esentepe Campus, Serdivan, 54187, Sakarya, Turkey","institution_ids":["https://openalex.org/I103703290"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5086570046","display_name":"Kemal Karadeniz","orcid":"https://orcid.org/0000-0003-0677-4958","observed_orcids":["https://orcid.org/0000-0003-0677-4958"]},"institutions":[{"id":"https://openalex.org/I103703290","display_name":"Sakarya University","ror":"https://ror.org/04ttnw109","country_code":"TR","type":"education","lineage":["https://openalex.org/I103703290"]}],"countries":["TR"],"is_corresponding":true,"raw_author_name":"Kemal Karadeniz","raw_affiliation_strings":["Department of Chemistry, Faculty of Science and Literature, Sakarya University, Esentepe Campus, Serdivan, 54187, Sakarya, Turkey"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Faculty of Science and Literature, Sakarya University, Esentepe Campus, Serdivan, 54187, Sakarya, Turkey","institution_ids":["https://openalex.org/I103703290"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5049266507","display_name":"Ra\u015fit Fikret Y\u0131lmaz","orcid":"https://orcid.org/0000-0001-5505-1727","observed_orcids":["https://orcid.org/0000-0001-5505-1727"]},"institutions":[{"id":"https://openalex.org/I103703290","display_name":"Sakarya University","ror":"https://ror.org/04ttnw109","country_code":"TR","type":"education","lineage":["https://openalex.org/I103703290"]}],"countries":["TR"],"is_corresponding":false,"raw_author_name":"Ra\u015fit Fikret Y\u0131lmaz","raw_affiliation_strings":["Department of Chemistry, Faculty of Science and Literature, Sakarya University, Esentepe Campus, Serdivan, 54187, Sakarya, Turkey"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Faculty of Science and Literature, Sakarya University, Esentepe Campus, Serdivan, 54187, Sakarya, Turkey","institution_ids":["https://openalex.org/I103703290"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5086570046"],"corresponding_institution_ids":["https://openalex.org/I103703290"],"apc_list":null,"apc_paid":null,"fwci":0.392,"has_fulltext":true,"cited_by_count":11,"citation_normalized_percentile":{"value":0.51330179,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"91","issue":"4","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11360","display_name":"Flame retardant materials and properties","score":0.9976000189781189,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11360","display_name":"Flame retardant materials and properties","score":0.9976000189781189,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13171","display_name":"Polymer Science and PVC","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10661","display_name":"biodegradable polymer synthesis and properties","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/2502","display_name":"Biomaterials"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/epoxidized-soybean-oil","display_name":"epoxidized soybean oil","score":0.9649999737739563},{"id":"https://openalex.org/keywords/vinylphosphonic-acid","display_name":"vinylphosphonic acid","score":0.9819999933242798},{"id":"https://openalex.org/keywords/ring-opening-polymerization","display_name":"ring-opening polymerization","score":0.7630000114440918},{"id":"https://openalex.org/keywords/bio-based-polyols","display_name":"bio-based polyols","score":0.8040000200271606},{"id":"https://openalex.org/keywords/limiting-oxygen-index","display_name":"limiting oxygen index","score":0.8600000143051147},{"id":"https://openalex.org/keywords/thermal-stability","display_name":"thermal stability","score":0.7680000066757202}],"concepts":[{"id":"https://openalex.org/C205474432","wikidata":"https://www.wikidata.org/wiki/Q1354051","display_name":"Fire retardant","level":2,"score":0.8788882493972778},{"id":"https://openalex.org/C2779578285","wikidata":"https://www.wikidata.org/wiki/Q146322","display_name":"Polyurethane","level":2,"score":0.7356208562850952},{"id":"https://openalex.org/C2778662921","wikidata":"https://www.wikidata.org/wiki/Q5383825","display_name":"Epoxidized soybean oil","level":3,"score":0.5909878015518188},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5242769122123718},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.4831516146659851},{"id":"https://openalex.org/C2779885280","wikidata":"https://www.wikidata.org/wiki/Q926892","display_name":"Soybean oil","level":2,"score":0.4157123863697052},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3579505681991577},{"id":"https://openalex.org/C126348684","wikidata":"https://www.wikidata.org/wiki/Q3456979","display_name":"Polymer science","level":1,"score":0.3575747609138489},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3487289547920227},{"id":"https://openalex.org/C206139338","wikidata":"https://www.wikidata.org/wiki/Q192355","display_name":"Raw material","level":2,"score":0.06706458330154419},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.05630752444267273}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.5562/cca3396","doi":"https://doi.org/10.5562/cca3396","is_oa":true,"landing_page_url":"https://doi.org/10.5562/cca3396","pdf_url":"https://doi.org/10.5562/cca3396","source":{"id":"https://openalex.org/S36275936","display_name":"Croatica Chemica Acta","issn_l":"0011-1643","issn":["0011-1643","1334-417X"],"is_oa":true,"is_in_doaj":true,"is_core":false,"listed_in":["ddh","doaj","dongbi-c","norway-1","poland-20","russia-white-list-3"],"host_organization":"https://openalex.org/P4310314830","host_organization_name":"Croatian Chemical Society","host_organization_lineage":["https://openalex.org/P4310314830"],"host_organization_lineage_names":["Croatian Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Croatica Chemica Acta","raw_type":"journal-article"},{"id":"pmh:oai:hrcak.srce.hr:216131","doi":null,"is_oa":true,"landing_page_url":"https://hrcak.srce.hr/216131","pdf_url":null,"source":{"id":"https://openalex.org/S4306400677","display_name":"Hr\u010dak Portal of scientific journals of Croatia (University Computing Centre)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4210104502","host_organization_name":"United Nations University","host_organization_lineage":["https://openalex.org/I4210104502"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Croatica Chemica Acta","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"doi:10.5562/cca3396","doi":"https://doi.org/10.5562/cca3396","is_oa":true,"landing_page_url":"https://doi.org/10.5562/cca3396","pdf_url":"https://doi.org/10.5562/cca3396","source":{"id":"https://openalex.org/S36275936","display_name":"Croatica Chemica Acta","issn_l":"0011-1643","issn":["0011-1643","1334-417X"],"is_oa":true,"is_in_doaj":true,"is_core":false,"listed_in":["ddh","doaj","dongbi-c","norway-1","poland-20","russia-white-list-3"],"host_organization":"https://openalex.org/P4310314830","host_organization_name":"Croatian Chemical Society","host_organization_lineage":["https://openalex.org/P4310314830"],"host_organization_lineage_names":["Croatian Chemical Society"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Croatica Chemica Acta","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320322660","display_name":"Sakarya \u00dcniversitesi","ror":"https://ror.org/04ttnw109"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2912682802.pdf","grobid_xml":"https://content.openalex.org/works/W2912682802.grobid-xml"},"referenced_works_count":34,"referenced_works":["https://openalex.org/W1976137092","https://openalex.org/W1979467414","https://openalex.org/W1991868444","https://openalex.org/W1992333508","https://openalex.org/W1997814023","https://openalex.org/W2000556272","https://openalex.org/W2013327212","https://openalex.org/W2014536229","https://openalex.org/W2019086227","https://openalex.org/W2020698822","https://openalex.org/W2023760588","https://openalex.org/W2028984848","https://openalex.org/W2045928206","https://openalex.org/W2054224515","https://openalex.org/W2054803369","https://openalex.org/W2063659110","https://openalex.org/W2069061805","https://openalex.org/W2081881363","https://openalex.org/W2085510751","https://openalex.org/W2087280402","https://openalex.org/W2090798553","https://openalex.org/W2093013142","https://openalex.org/W2123333244","https://openalex.org/W2142222435","https://openalex.org/W2165621179","https://openalex.org/W2168238350","https://openalex.org/W2168943403","https://openalex.org/W2479266142","https://openalex.org/W2509014556","https://openalex.org/W2583905930","https://openalex.org/W6600175266","https://openalex.org/W6600302053","https://openalex.org/W6603036350","https://openalex.org/W6605438980"],"related_works":["https://openalex.org/W7051794826","https://openalex.org/W4313530199","https://openalex.org/W4366769841","https://openalex.org/W4318023076","https://openalex.org/W4396544846","https://openalex.org/W2757763513","https://openalex.org/W3007403810","https://openalex.org/W2090798553","https://openalex.org/W6996709593","https://openalex.org/W4297841538"],"abstract_inverted_index":{"The":[0],"synthesis":[1],"of":[2,11,67,75,120,147],"novel":[3],"polyol":[4,34],"was":[5,69,80,89,112],"carried":[6],"out":[7],"by":[8,71],"the":[9,64,84],"reaction":[10,19],"epoxidized":[12],"soy-bean":[13],"oil":[14,132],"(ESBO)":[15],"throught":[16],"ring":[17,66,85],"opening":[18],"with":[20,141],"vinyl":[21,29,78],"phosphonic":[22,31,72],"acid":[23,73],"(VPA)":[24],"bearing":[25],"two":[26],"functional":[27],"groups,":[28],"and":[30,36,46,57,77,98,108,117],"acid.The":[32],"synthesized":[33],"(PolP)":[35],"4,4":[37],"\u00b4-methylenebis(phenyl":[38],"isocyanate)":[39],"(MDI)":[40],"were":[41,101],"reacted":[42],"to":[43,126],"prepare":[44],"biobased":[45],"inherently":[47],"flame":[48,138],"retardant":[49,139],"polyurethane":[50,88,121],"foam":[51],"(PPPU).FTIR,":[52],"1":[53],"H,":[54],"13":[55],"C":[56],"31":[58],"P":[59],"NMR":[60],"spectroscopy":[61,95],"confirmed":[62],"that":[63],"epoxy":[65],"ESBO":[68],"opened":[70],"group":[74,79],"VPA,":[76],"not":[81],"involved":[82],"in":[83],"opening.The":[86],"prepared":[87],"characterized":[90],"using":[91,103],"fourier":[92],"transformed":[93],"infrared":[94],"(":[96],"FTIR)":[97],"thermal":[99],"properties":[100],"measured":[102],"differential":[104],"scanning":[105],"calorimetry":[106],"(DSC)":[107],"thermogravimetric":[109],"analysis":[110],"(TGA).XRD":[111],"used":[113],"for":[114],"crystallografic":[115],"structure":[116],"SEM":[118],"image":[119],"showed":[122],"smooth":[123],"surface.When":[124],"compared":[125],"phosphorous-free":[127],"polyurethanes":[128],"derived":[129],"from":[130],"soybean":[131],"based":[133],"polyols,":[134],"PPUP":[135],"exibited":[136],"better":[137],"property":[140],"a":[142],"limiting":[143],"oxygen":[144],"value":[145],"index":[146],"26.4.":[148]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":4},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":1}],"updated_date":"2026-11-03T10:50:19.383937","created_date":"2019-02-21T00:00:00"}