{"id":"https://openalex.org/W2902060423","doi":"https://doi.org/10.1021/jacs.8b09653","title":"Benzimidazoles as Metal-Free and Recyclable Hydrides for CO2 Reduction to Formate","display_name":"Benzimidazoles as Metal-Free and Recyclable Hydrides for CO2 Reduction to Formate","publication_year":2018,"publication_date":"2018-11-27","ids":{"openalex":"https://openalex.org/W2902060423","doi":"https://doi.org/10.1021/jacs.8b09653","mag":"2902060423","pmid":"https://pubmed.ncbi.nlm.nih.gov/30477302"},"language":"en","primary_location":{"id":"doi:10.1021/jacs.8b09653","doi":"https://doi.org/10.1021/jacs.8b09653","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.8b09653","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://www.osti.gov/servlets/purl/1558602","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5026712634","display_name":"Chern\u2010Hooi Lim","orcid":"https://orcid.org/0000-0003-1823-6305","observed_orcids":["https://orcid.org/0000-0003-1823-6305"]},"institutions":[{"id":"https://openalex.org/I188538660","display_name":"University of Colorado Boulder","ror":"https://ror.org/02ttsq026","country_code":"US","type":"education","lineage":["https://openalex.org/I188538660"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Chern-Hooi Lim","raw_affiliation_strings":["Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, United States","Department of Chemistry, University of Colorado, Boulder, Colorado 80309, United States"],"raw_orcid":"https://orcid.org/0000-0003-1823-6305","affiliations":[{"raw_affiliation_string":"Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, United States","institution_ids":["https://openalex.org/I188538660"]},{"raw_affiliation_string":"Department of Chemistry, University of Colorado, Boulder, Colorado 80309, United States","institution_ids":["https://openalex.org/I188538660"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5072610849","display_name":"Stefan Ili\u0107","orcid":"https://orcid.org/0000-0002-6305-4001","observed_orcids":["https://orcid.org/0000-0002-6305-4001"]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I39422238","display_name":"University of Illinois Chicago","ror":"https://ror.org/02mpq6x41","country_code":"US","type":"education","lineage":["https://openalex.org/I39422238"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Stefan Ilic","raw_affiliation_strings":["Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States","Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois 60607, United States"],"raw_orcid":"https://orcid.org/0000-0002-6305-4001","affiliations":[{"raw_affiliation_string":"Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States","institution_ids":["https://openalex.org/I1282105669"]},{"raw_affiliation_string":"Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois 60607, United States","institution_ids":["https://openalex.org/I39422238"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5018905904","display_name":"Abdulaziz W. Alherz","orcid":"https://orcid.org/0000-0001-7529-3483","observed_orcids":["https://orcid.org/0000-0001-7529-3483"]},"institutions":[{"id":"https://openalex.org/I188538660","display_name":"University of Colorado Boulder","ror":"https://ror.org/02ttsq026","country_code":"US","type":"education","lineage":["https://openalex.org/I188538660"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Abdulaziz Alherz","raw_affiliation_strings":["Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, United States"],"raw_orcid":"https://orcid.org/0000-0001-7529-3483","affiliations":[{"raw_affiliation_string":"Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, United States","institution_ids":["https://openalex.org/I188538660"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062949467","display_name":"Brady T. Worrell","orcid":"https://orcid.org/0000-0001-7472-2063","observed_orcids":["https://orcid.org/0000-0001-7472-2063"]},"institutions":[{"id":"https://openalex.org/I188538660","display_name":"University of Colorado Boulder","ror":"https://ror.org/02ttsq026","country_code":"US","type":"education","lineage":["https://openalex.org/I188538660"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Brady T. Worrell","raw_affiliation_strings":["Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, United States","institution_ids":["https://openalex.org/I188538660"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5112400130","display_name":"Samuel S. Bacon","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I188538660","display_name":"University of Colorado Boulder","ror":"https://ror.org/02ttsq026","country_code":"US","type":"education","lineage":["https://openalex.org/I188538660"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Samuel S. Bacon","raw_affiliation_strings":["Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, United States","institution_ids":["https://openalex.org/I188538660"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000113075","display_name":"James T. Hynes","orcid":"https://orcid.org/0000-0003-2683-0304","observed_orcids":["https://orcid.org/0000-0003-2683-0304"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I188538660","display_name":"University of Colorado Boulder","ror":"https://ror.org/02ttsq026","country_code":"US","type":"education","lineage":["https://openalex.org/I188538660"]},{"id":"https://openalex.org/I2746051580","display_name":"Universit\u00e9 Paris Sciences et Lettres","ror":"https://ror.org/013cjyk83","country_code":"FR","type":"education","lineage":["https://openalex.org/I2746051580"]},{"id":"https://openalex.org/I29607241","display_name":"\u00c9cole Normale Sup\u00e9rieure - PSL","ror":"https://ror.org/05a0dhs15","country_code":"FR","type":"other","lineage":["https://openalex.org/I2746051580","https://openalex.org/I29607241"]},{"id":"https://openalex.org/I4405264447","display_name":"Universit\u00e9 Pierre-et-Marie-Curie","ror":"https://ror.org/01yvrd251","country_code":"FR","type":"education","lineage":["https://openalex.org/I39804081","https://openalex.org/I4405264447"]}],"countries":["FR","US"],"is_corresponding":false,"raw_author_name":"James T. Hynes","raw_affiliation_strings":["Department of Chemistry, University of Colorado, Boulder, Colorado 80309, United States","PASTEUR, D\u00e9partement de Chimie, \u00c9cole Normale Sup\u00e9rieure, UPMC Univ. Paris 06, CNRS, PSL Research University, 75005 Paris, France","Sorbonne Universit\u00e9s, UPMC Univ. Paris 06, \u00c9cole Normale Sup\u00e9rieure, CNRS, PASTEUR, 75005 Paris, France"],"raw_orcid":"https://orcid.org/0000-0003-2683-0304","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Colorado, Boulder, Colorado 80309, United States","institution_ids":["https://openalex.org/I188538660"]},{"raw_affiliation_string":"PASTEUR, D\u00e9partement de Chimie, \u00c9cole Normale Sup\u00e9rieure, UPMC Univ. Paris 06, CNRS, PSL Research University, 75005 Paris, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I2746051580","https://openalex.org/I29607241","https://openalex.org/I4405264447"]},{"raw_affiliation_string":"Sorbonne Universit\u00e9s, UPMC Univ. Paris 06, \u00c9cole Normale Sup\u00e9rieure, CNRS, PASTEUR, 75005 Paris, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4405264447"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5035954011","display_name":"Ksenija D. Glusac","orcid":"https://orcid.org/0000-0002-2734-057X","observed_orcids":["https://orcid.org/0000-0002-2734-057X"]},"institutions":[{"id":"https://openalex.org/I1282105669","display_name":"Argonne National Laboratory","ror":"https://ror.org/05gvnxz63","country_code":"US","type":"facility","lineage":["https://openalex.org/I1282105669","https://openalex.org/I1330989302","https://openalex.org/I39565521","https://openalex.org/I40347166"]},{"id":"https://openalex.org/I39422238","display_name":"University of Illinois Chicago","ror":"https://ror.org/02mpq6x41","country_code":"US","type":"education","lineage":["https://openalex.org/I39422238"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ksenija D. Glusac","raw_affiliation_strings":["Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States","Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois 60607, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, Illinois 60439, United States","institution_ids":["https://openalex.org/I1282105669"]},{"raw_affiliation_string":"Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois 60607, United States","institution_ids":["https://openalex.org/I39422238"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5087057269","display_name":"Charles B. Musgrave","orcid":"https://orcid.org/0000-0002-5732-3180","observed_orcids":["https://orcid.org/0000-0002-5732-3180","https://orcid.org/0000-0002-3432-0817"]},"institutions":[{"id":"https://openalex.org/I1297288678","display_name":"National Laboratory of the Rockies","ror":"https://ror.org/036266993","country_code":"US","type":"facility","lineage":["https://openalex.org/I1297288678","https://openalex.org/I1330989302","https://openalex.org/I2800842121"]},{"id":"https://openalex.org/I188538660","display_name":"University of Colorado Boulder","ror":"https://ror.org/02ttsq026","country_code":"US","type":"education","lineage":["https://openalex.org/I188538660"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Charles B. Musgrave","raw_affiliation_strings":["Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, United States","Department of Chemistry, University of Colorado, Boulder, Colorado 80309, United States","Materials Science and Engineering Program, University of Colorado, Boulder, Colorado 80309, United States","National Renewable Energy Laboratory, Golden, Colorado 80401, United States"],"raw_orcid":"https://orcid.org/0000-0002-5732-3180","affiliations":[{"raw_affiliation_string":"Department of Chemical and Biological Engineering, University of Colorado, Boulder, Colorado 80309, United States","institution_ids":["https://openalex.org/I188538660"]},{"raw_affiliation_string":"Department of Chemistry, University of Colorado, Boulder, Colorado 80309, United States","institution_ids":["https://openalex.org/I188538660"]},{"raw_affiliation_string":"Materials Science and Engineering Program, University of Colorado, Boulder, Colorado 80309, United States","institution_ids":["https://openalex.org/I188538660"]},{"raw_affiliation_string":"National Renewable Energy Laboratory, Golden, Colorado 80401, United States","institution_ids":["https://openalex.org/I1297288678"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":8,"corresponding_author_ids":["https://openalex.org/A5026712634","https://openalex.org/A5087057269"],"corresponding_institution_ids":["https://openalex.org/I1297288678","https://openalex.org/I188538660"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.6833,"has_fulltext":false,"cited_by_count":114,"citation_normalized_percentile":{"value":0.90509421,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":98,"max":100},"biblio":{"volume":"141","issue":"1","first_page":"272","last_page":"280"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.6606000065803528,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.6606000065803528,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11784","display_name":"CO2 Reduction Techniques and Catalysts","score":0.33719998598098755,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10967","display_name":"Carbon Dioxide Capture Technologies","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/2210","display_name":"Mechanical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/co2-reduction","display_name":"CO2 reduction","score":0.875},{"id":"https://openalex.org/keywords/formate-production","display_name":"formate production","score":0.875},{"id":"https://openalex.org/keywords/metal-free-reduction","display_name":"metal-free reduction","score":0.7039999961853027},{"id":"https://openalex.org/keywords/benzimidazolium-cations","display_name":"benzimidazolium cations","score":0.871999979019165},{"id":"https://openalex.org/keywords/electrochemical-co2-reduction","display_name":"electrochemical CO2 reduction","score":0.9629999995231628},{"id":"https://openalex.org/keywords/potassium-tetrafluoroborate","display_name":"potassium tetrafluoroborate","score":0.859000027179718},{"id":"https://openalex.org/keywords/13co2-labeling","display_name":"13CO2 labeling","score":0.7179999947547913},{"id":"https://openalex.org/keywords/hydride-donors","display_name":"hydride donors","score":0.6309999823570251},{"id":"https://openalex.org/keywords/quantum-chemical-calculations","display_name":"quantum chemical calculations","score":0.5809999704360962}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9547023773193359},{"id":"https://openalex.org/C2780178953","wikidata":"https://www.wikidata.org/wiki/Q2001841","display_name":"Formate","level":3,"score":0.8070493340492249},{"id":"https://openalex.org/C2777961443","wikidata":"https://www.wikidata.org/wiki/Q106520","display_name":"Hydride","level":3,"score":0.7663229703903198},{"id":"https://openalex.org/C2778484023","wikidata":"https://www.wikidata.org/wiki/Q415190","display_name":"Benzimidazole","level":2,"score":0.6145010590553284},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.5959627032279968},{"id":"https://openalex.org/C2780872544","wikidata":"https://www.wikidata.org/wiki/Q7706343","display_name":"Tetrafluoroborate","level":4,"score":0.5902199745178223},{"id":"https://openalex.org/C154881586","wikidata":"https://www.wikidata.org/wiki/Q898579","display_name":"Ionic liquid","level":3,"score":0.5013480186462402},{"id":"https://openalex.org/C186423591","wikidata":"https://www.wikidata.org/wiki/Q216830","display_name":"Reducing agent","level":2,"score":0.4596331715583801},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.39746785163879395},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2960125505924225},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.22321465611457825}],"mesh":[{"descriptor_ui":"D001562","descriptor_name":"Benzimidazoles","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D002245","descriptor_name":"Carbon Dioxide","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D004095","descriptor_name":"Dihydropyridines","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D004563","descriptor_name":"Electrochemistry","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D005561","descriptor_name":"Formates","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D008958","descriptor_name":"Models, Molecular","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D008968","descriptor_name":"Molecular Conformation","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D012492","descriptor_name":"Salts","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D012997","descriptor_name":"Solvents","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false}],"locations_count":5,"locations":[{"id":"doi:10.1021/jacs.8b09653","doi":"https://doi.org/10.1021/jacs.8b09653","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.8b09653","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:30477302","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/30477302","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"},{"id":"pmh:oai:osti.gov:1558602","doi":null,"is_oa":true,"landing_page_url":"https://www.osti.gov/biblio/1558602","pdf_url":"https://www.osti.gov/servlets/purl/1558602","source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},{"id":"pmh:oai:HAL:hal-04005989v1","doi":null,"is_oa":false,"landing_page_url":"https://ens.hal.science/hal-04005989","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal of the American Chemical Society, 2019, 141 (1), pp.272-280. ⟨10.1021/jacs.8b09653⟩","raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:oai:figshare.com:article/10769033","doi":null,"is_oa":true,"landing_page_url":"https://figshare.com/articles/journal_contribution/Benzimidazoles_as_Metal-Free_and_Recyclable_Hydrides_for_CO2_Reduction_to_Formate/10769033","pdf_url":null,"source":{"id":"https://openalex.org/S4377196282","display_name":"Figshare","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4210132348","host_organization_name":"Figshare (United Kingdom)","host_organization_lineage":["https://openalex.org/I4210132348"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Text"}],"best_oa_location":{"id":"pmh:oai:osti.gov:1558602","doi":null,"is_oa":true,"landing_page_url":"https://www.osti.gov/biblio/1558602","pdf_url":"https://www.osti.gov/servlets/purl/1558602","source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},"sustainable_development_goals":[{"display_name":"Responsible consumption and production","id":"https://metadata.un.org/sdg/12","score":0.6000000238418579},{"display_name":"Climate action","id":"https://metadata.un.org/sdg/13","score":0.5351999998092651}],"study_designs":[],"awards":[{"id":"https://openalex.org/G1509238881","display_name":"Theory of Reactions in Solution and at Surfaces","funder_award_id":"1112564","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G1845359908","display_name":"Singlet Fission for Highly Efficient Organic Photovoltaics","funder_award_id":"1214131","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G3146135901","display_name":null,"funder_award_id":"1214131","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G3443144068","display_name":null,"funder_award_id":"54436-ND4","funder_id":"https://openalex.org/F4320332454","funder_display_name":"American Chemical Society Petroleum Research Fund"},{"id":"https://openalex.org/G6119075960","display_name":null,"funder_award_id":"1112564","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G7590903509","display_name":"MRI-Consortium:   Acquisition of a Supercomputer by the Front Range Computing Consortium","funder_award_id":"0821794","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G7866597304","display_name":"Strongly Reducing Organic Photocatalysts as the \"New Iridium\" in Photoredox Catalysis","funder_award_id":"F32GM122392","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320306253","display_name":"Arnold and Mabel Beckman Foundation","ror":"https://ror.org/05avmtm72"},{"id":"https://openalex.org/F4320332454","display_name":"American Chemical Society Petroleum Research Fund","ror":"https://ror.org/059dqb057"},{"id":"https://openalex.org/F4320332538","display_name":"University of Colorado Boulder","ror":"https://ror.org/02ttsq026"},{"id":"https://openalex.org/F4320337354","display_name":"National Institute of General Medical Sciences","ror":"https://ror.org/04q48ey07"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2902060423.pdf","grobid_xml":"https://content.openalex.org/works/W2902060423.grobid-xml"},"referenced_works_count":67,"referenced_works":["https://openalex.org/W422932616","https://openalex.org/W1492157200","https://openalex.org/W1654060761","https://openalex.org/W1986506484","https://openalex.org/W1986829915","https://openalex.org/W1992591486","https://openalex.org/W1992948400","https://openalex.org/W1994459705","https://openalex.org/W2004760794","https://openalex.org/W2006420601","https://openalex.org/W2006852457","https://openalex.org/W2015528261","https://openalex.org/W2017267600","https://openalex.org/W2025312240","https://openalex.org/W2027414105","https://openalex.org/W2033923150","https://openalex.org/W2035168278","https://openalex.org/W2036657339","https://openalex.org/W2037621576","https://openalex.org/W2038613461","https://openalex.org/W2039892768","https://openalex.org/W2040952845","https://openalex.org/W2045445198","https://openalex.org/W2047596969","https://openalex.org/W2048503986","https://openalex.org/W2054841001","https://openalex.org/W2057653609","https://openalex.org/W2061590707","https://openalex.org/W2061977671","https://openalex.org/W2063129680","https://openalex.org/W2068275679","https://openalex.org/W2077910786","https://openalex.org/W2079380348","https://openalex.org/W2080782169","https://openalex.org/W2089307567","https://openalex.org/W2089783309","https://openalex.org/W2092744078","https://openalex.org/W2094642658","https://openalex.org/W2097570551","https://openalex.org/W2117364025","https://openalex.org/W2127066840","https://openalex.org/W2128703814","https://openalex.org/W2145110720","https://openalex.org/W2150697053","https://openalex.org/W2166617552","https://openalex.org/W2206932601","https://openalex.org/W2246944211","https://openalex.org/W2297401062","https://openalex.org/W2319735561","https://openalex.org/W2320050688","https://openalex.org/W2324586646","https://openalex.org/W2324667290","https://openalex.org/W2328492257","https://openalex.org/W2332056529","https://openalex.org/W2340541550","https://openalex.org/W2342502077","https://openalex.org/W2438457320","https://openalex.org/W2511123279","https://openalex.org/W2518085510","https://openalex.org/W2565870685","https://openalex.org/W2604726133","https://openalex.org/W2761959175","https://openalex.org/W2779909874","https://openalex.org/W2782879485","https://openalex.org/W2793822271","https://openalex.org/W2793996726","https://openalex.org/W2949731875"],"related_works":["https://openalex.org/W4360610198","https://openalex.org/W4214778258","https://openalex.org/W4328050805","https://openalex.org/W7212383273","https://openalex.org/W6945665151","https://openalex.org/W3116324671","https://openalex.org/W4414305617","https://openalex.org/W2092861679","https://openalex.org/W3096547422","https://openalex.org/W4415922520"],"abstract_inverted_index":{"We":[0],"report":[1],"a":[2,11,64,69,193],"novel":[3],"metal-free":[4,208],"chemical":[5,21],"reduction":[6,47,92,200],"of":[7,31,61,84,113,120,129,195,201],"CO":[8,45,78,90,148,186,202],"2":[9,40,46,79,91,149,187,203],"by":[10,19,89,98,204],"recyclable":[12],"benzimidazole-based":[13,24,152],"organo-hydride,":[14],"whose":[15],"choice":[16],"was":[17,55,115,155],"guided":[18],"quantum":[20],"calculations.":[22],"Notably,":[23],"hydride":[25,153],"donors":[26],"rival":[27],"the":[28,49,59,73,82,94,118,141,144,151,171,198],"hydride-donating":[29],"abilities":[30],"noble-metal-based":[32],"hydrides":[33],"such":[34],"as":[35,192],"[Ru(tpy)(bpy)H]":[36],"+":[37,42],"and":[38,102,107,139,207],"[Pt(depe)":[39],"H]":[41],".":[43],"Chemical":[44],"to":[48,71,137,158,174],"formate":[50,95,111],"anion":[51],"(HCOO":[52],"\u2013":[53,88],")":[54],"carried":[56],"out":[57],"in":[58,117,133,178],"absence":[60],"biological":[62],"enzymes,":[63],"sacrificial":[65],"Lewis":[66],"acid,":[67],"or":[68,75],"base":[70],"activate":[72],"substrate":[74],"reductant.":[76],"13":[77,86,103],"experiments":[80],"confirmed":[81],"formation":[83],"H":[85,100],"COO":[87],"with":[93],"product":[96],"characterized":[97],"1":[99],"NMR":[101,105],"C":[104],"spectroscopy":[106],"ESI-MS.":[108],"The":[109,126],"highest":[110],"yield":[112],"66%":[114],"obtained":[116],"presence":[119],"potassium":[121],"tetrafluoroborate":[122],"under":[123],"mild":[124],"conditions.":[125],"likely":[127],"role":[128],"exogenous":[130],"salt":[131],"additives":[132],"this":[134],"reaction":[135],"is":[136],"stabilize":[138],"shift":[140],"equilibrium":[142],"toward":[143],"ionic":[145],"products.":[146],"After":[147],"reduction,":[150],"donor":[154],"quantitatively":[156],"oxidized":[157],"its":[159,164,175,182],"aromatic":[160],"benzimidazolium":[161,172],"cation,":[162],"establishing":[163],"recyclability.":[165],"In":[166],"addition,":[167],"we":[168],"electrochemically":[169],"reduced":[170],"cation":[173],"organo-hydride":[176],"form":[177],"quantitative":[179],"yield,":[180],"demonstrating":[181],"potential":[183],"for":[184,197],"electrocatalytic":[185,199],"reduction.":[188],"These":[189],"results":[190],"serve":[191],"proof":[194],"concept":[196],"sustainable,":[205],"recyclable,":[206],"organo-hydrides.":[209]},"counts_by_year":[{"year":2026,"cited_by_count":12},{"year":2025,"cited_by_count":19},{"year":2024,"cited_by_count":21},{"year":2023,"cited_by_count":20},{"year":2022,"cited_by_count":8},{"year":2021,"cited_by_count":17},{"year":2020,"cited_by_count":11},{"year":2019,"cited_by_count":6}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2018-12-11T00:00:00"}