{"id":"https://openalex.org/W2898565400","doi":"https://doi.org/10.1149/2.0341815jes","title":"Adsorbed Hydrogen as a Site-Occupying Species in the Electrocatalytic Oxidation of Formate on Pd/C in Alkaline Medium","display_name":"Adsorbed Hydrogen as a Site-Occupying Species in the Electrocatalytic Oxidation of Formate on Pd/C in Alkaline Medium","publication_year":2018,"publication_date":"2018-01-01","ids":{"openalex":"https://openalex.org/W2898565400","doi":"https://doi.org/10.1149/2.0341815jes","mag":"2898565400"},"language":"en","primary_location":{"id":"doi:10.1149/2.0341815jes","doi":"https://doi.org/10.1149/2.0341815jes","is_oa":true,"landing_page_url":"https://doi.org/10.1149/2.0341815jes","pdf_url":"https://iopscience.iop.org/article/10.1149/2.0341815jes/pdf","source":{"id":"https://openalex.org/S138759888","display_name":"Journal of The Electrochemical Society","issn_l":"0013-4651","issn":["0013-4651","1945-7111"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310311669","host_organization_name":"Institute of Physics","host_organization_lineage":["https://openalex.org/P4310311669"],"host_organization_lineage_names":["Institute of Physics"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of The Electrochemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"hybrid","oa_url":"https://iopscience.iop.org/article/10.1149/2.0341815jes/pdf","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5030141476","display_name":"Myounghoon Choun","orcid":"https://orcid.org/0000-0002-7477-1049","observed_orcids":["https://orcid.org/0000-0002-7477-1049"]},"institutions":[{"id":"https://openalex.org/I39534123","display_name":"Gwangju Institute of Science and Technology","ror":"https://ror.org/024kbgz78","country_code":"KR","type":"education","lineage":["https://openalex.org/I39534123"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Myounghoon Choun","raw_affiliation_strings":["Electrochemical Reaction and Technology Laboratory, School of Earth Sciences and Environmental Engineering, Gwangju Institute of Science and Technology (GIST), Gwangju 500-712, South Korea","Ertl Center for Electrochemistry and Catalysis, Gwangju Institute of Science and Technology (GIST), Gwangju 500-712, South Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Electrochemical Reaction and Technology Laboratory, School of Earth Sciences and Environmental Engineering, Gwangju Institute of Science and Technology (GIST), Gwangju 500-712, South Korea","institution_ids":["https://openalex.org/I39534123"]},{"raw_affiliation_string":"Ertl Center for Electrochemistry and Catalysis, Gwangju Institute of Science and Technology (GIST), Gwangju 500-712, South Korea","institution_ids":["https://openalex.org/I39534123"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5087381531","display_name":"Sujik Hong","orcid":"https://orcid.org/0000-0002-4837-3012","observed_orcids":["https://orcid.org/0000-0002-4837-3012"]},"institutions":[{"id":"https://openalex.org/I39534123","display_name":"Gwangju Institute of Science and Technology","ror":"https://ror.org/024kbgz78","country_code":"KR","type":"education","lineage":["https://openalex.org/I39534123"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Sujik Hong","raw_affiliation_strings":["Electrochemical Reaction and Technology Laboratory, School of Earth Sciences and Environmental Engineering, Gwangju Institute of Science and Technology (GIST), Gwangju 500-712, South Korea"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Electrochemical Reaction and Technology Laboratory, School of Earth Sciences and Environmental Engineering, Gwangju Institute of Science and Technology (GIST), Gwangju 500-712, South Korea","institution_ids":["https://openalex.org/I39534123"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5100334532","display_name":"Jaeyoung Lee","orcid":"https://orcid.org/0000-0002-9392-5576","observed_orcids":["https://orcid.org/0000-0002-9392-5576","https://orcid.org/0000-0003-1211-688X"]},"institutions":[{"id":"https://openalex.org/I39534123","display_name":"Gwangju Institute of Science and Technology","ror":"https://ror.org/024kbgz78","country_code":"KR","type":"education","lineage":["https://openalex.org/I39534123"]}],"countries":["KR"],"is_corresponding":false,"raw_author_name":"Jaeyoung Lee","raw_affiliation_strings":["Electrochemical Reaction and Technology Laboratory, School of Earth Sciences and Environmental Engineering, Gwangju Institute of Science and Technology (GIST), Gwangju 500-712, South Korea","Ertl Center for Electrochemistry and Catalysis, Gwangju Institute of Science and Technology (GIST), Gwangju 500-712, South Korea"],"raw_orcid":"https://orcid.org/0000-0002-9392-5576","affiliations":[{"raw_affiliation_string":"Electrochemical Reaction and Technology Laboratory, School of Earth Sciences and Environmental Engineering, Gwangju Institute of Science and Technology (GIST), Gwangju 500-712, South Korea","institution_ids":["https://openalex.org/I39534123"]},{"raw_affiliation_string":"Ertl Center for Electrochemistry and Catalysis, Gwangju Institute of Science and Technology (GIST), Gwangju 500-712, South Korea","institution_ids":["https://openalex.org/I39534123"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I39534123"],"apc_list":{"value":1950,"currency":"USD","value_usd":1950},"apc_paid":{"value":1950,"currency":"USD","value_usd":1950},"fwci":0.5547,"has_fulltext":true,"cited_by_count":23,"citation_normalized_percentile":{"value":0.58410655,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"165","issue":"15","first_page":"J3266","last_page":"J3270"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11784","display_name":"CO2 Reduction Techniques and Catalysts","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10192","display_name":"Catalytic Processes in Materials Science","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/formate-oxidation","display_name":"formate oxidation","score":0.9419999718666077},{"id":"https://openalex.org/keywords/palladium-electrocatalysts","display_name":"palladium electrocatalysts","score":0.7239999771118164},{"id":"https://openalex.org/keywords/palladium-on-carbon","display_name":"palladium on carbon","score":0.7369999885559082},{"id":"https://openalex.org/keywords/adsorbed-hydrogen","display_name":"adsorbed hydrogen","score":0.9319999814033508},{"id":"https://openalex.org/keywords/h-d-kinetic-isotope-effect","display_name":"H/D kinetic isotope effect","score":0.7889999747276306},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.8100000023841858},{"id":"https://openalex.org/keywords/rate-limiting-step","display_name":"rate-determining step","score":0.8299999833106995},{"id":"https://openalex.org/keywords/alkaline-media","display_name":"alkaline solution","score":0.7770000100135803},{"id":"https://openalex.org/keywords/co2-evolution","display_name":"CO2 evolution","score":0.5210000276565552},{"id":"https://openalex.org/keywords/stripping-voltammetry","display_name":"stripping voltammetry","score":0.7160000205039978}],"concepts":[{"id":"https://openalex.org/C2777869211","wikidata":"https://www.wikidata.org/wiki/Q1147647","display_name":"Cyclic voltammetry","level":4,"score":0.8184170126914978},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8102024793624878},{"id":"https://openalex.org/C2778173763","wikidata":"https://www.wikidata.org/wiki/Q620700","display_name":"Linear sweep voltammetry","level":5,"score":0.7556928396224976},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.6518030166625977},{"id":"https://openalex.org/C2780178953","wikidata":"https://www.wikidata.org/wiki/Q2001841","display_name":"Formate","level":3,"score":0.6122301816940308},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.5933840274810791},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5660150051116943},{"id":"https://openalex.org/C2779603750","wikidata":"https://www.wikidata.org/wiki/Q904093","display_name":"Voltammetry","level":4,"score":0.5243392586708069},{"id":"https://openalex.org/C126706214","wikidata":"https://www.wikidata.org/wiki/Q4867053","display_name":"Basic solution","level":4,"score":0.4148321747779846},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.33375784754753113},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.2985239028930664},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.08727800846099854},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.08252957463264465}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1149/2.0341815jes","doi":"https://doi.org/10.1149/2.0341815jes","is_oa":true,"landing_page_url":"https://doi.org/10.1149/2.0341815jes","pdf_url":"https://iopscience.iop.org/article/10.1149/2.0341815jes/pdf","source":{"id":"https://openalex.org/S138759888","display_name":"Journal of The Electrochemical Society","issn_l":"0013-4651","issn":["0013-4651","1945-7111"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310311669","host_organization_name":"Institute of Physics","host_organization_lineage":["https://openalex.org/P4310311669"],"host_organization_lineage_names":["Institute of Physics"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of The Electrochemical Society","raw_type":"journal-article"}],"best_oa_location":{"id":"doi:10.1149/2.0341815jes","doi":"https://doi.org/10.1149/2.0341815jes","is_oa":true,"landing_page_url":"https://doi.org/10.1149/2.0341815jes","pdf_url":"https://iopscience.iop.org/article/10.1149/2.0341815jes/pdf","source":{"id":"https://openalex.org/S138759888","display_name":"Journal of The Electrochemical Society","issn_l":"0013-4651","issn":["0013-4651","1945-7111"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-2","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310311669","host_organization_name":"Institute of Physics","host_organization_lineage":["https://openalex.org/P4310311669"],"host_organization_lineage_names":["Institute of Physics"],"type":"journal"},"license":"cc-by-nc-nd","license_id":"https://openalex.org/licenses/cc-by-nc-nd","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of The Electrochemical Society","raw_type":"journal-article"},"sustainable_development_goals":[{"display_name":"Affordable and clean energy","score":0.5690000057220459,"id":"https://metadata.un.org/sdg/7"}],"study_designs":[],"awards":[{"id":"https://openalex.org/G2649722119","display_name":null,"funder_award_id":"201 53030031720","funder_id":"https://openalex.org/F4320335199","funder_display_name":"Korea Institute of Energy Technology Evaluation and Planning"}],"funders":[{"id":"https://openalex.org/F4320307586","display_name":"Gravity Research Institute","ror":null},{"id":"https://openalex.org/F4320335199","display_name":"Korea Institute of Energy Technology Evaluation and Planning","ror":"https://ror.org/02zq38y32"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2898565400.pdf","grobid_xml":"https://content.openalex.org/works/W2898565400.grobid-xml"},"referenced_works_count":32,"referenced_works":["https://openalex.org/W1206217512","https://openalex.org/W1521623352","https://openalex.org/W1920341295","https://openalex.org/W1963902127","https://openalex.org/W1966147575","https://openalex.org/W1986653756","https://openalex.org/W2002511039","https://openalex.org/W2002710373","https://openalex.org/W2006774661","https://openalex.org/W2026354706","https://openalex.org/W2048331115","https://openalex.org/W2048917929","https://openalex.org/W2058299950","https://openalex.org/W2070398632","https://openalex.org/W2075636121","https://openalex.org/W2077891108","https://openalex.org/W2082159196","https://openalex.org/W2082795642","https://openalex.org/W2085535145","https://openalex.org/W2089020487","https://openalex.org/W2133257429","https://openalex.org/W2142356892","https://openalex.org/W2158926985","https://openalex.org/W2170207271","https://openalex.org/W2296874848","https://openalex.org/W2319712753","https://openalex.org/W2319801127","https://openalex.org/W2345472097","https://openalex.org/W2564593442","https://openalex.org/W2608690666","https://openalex.org/W2615600825","https://openalex.org/W4244586979"],"related_works":["https://openalex.org/W7119469845","https://openalex.org/W2079519132","https://openalex.org/W2082159196","https://openalex.org/W2064239785","https://openalex.org/W1966147575","https://openalex.org/W4379197676","https://openalex.org/W2760429629","https://openalex.org/W4387417878","https://openalex.org/W2045297662","https://openalex.org/W4399076856"],"abstract_inverted_index":{"We":[0,34],"investigate":[1],"the":[2,49,55,73,87,100,110,117],"mechanistic":[3],"origin":[4],"of":[5,7,51,63,75,104,112,119],"oxidation":[6,50,61,74,118],"HCOO":[8,37,76,120],"\u2212":[9,38,77,121],"on":[10],"Pd/C":[11],"in":[12,86,122],"alkaline":[13,123],"media":[14],"using":[15],"H/D":[16],"kinetic":[17],"isotope":[18],"effect":[19],"studies":[20],"and":[21,31,48,79,106],"electrochemical":[22],"experiments,":[23],"such":[24],"as":[25],"cyclic":[26],"voltammetry,":[27,30],"step-linear":[28],"sweep":[29],"stripping":[32],"voltammetry.":[33],"reveal":[35],"that":[36],"is":[39,54,84],"oxidized":[40],"to":[41,98],"CO":[42],"2":[43],"through":[44],"a":[45,69,80],"direct":[46],"pathway,":[47],"H":[52,64,91],"ads":[53,65,92],"rate":[56],"determining":[57],"step.":[58],"The":[59],"slow":[60],"kinetics":[62],",":[66,78],"which":[67],"causes":[68],"site-occupying":[70],"effect,":[71],"suppress":[72],"more":[81,113],"distinct":[82],"phenomenon":[83],"observed":[85],"potential":[88],"region":[89],"for":[90,109,116],".":[93],"These":[94],"observations":[95],"provide":[96],"clues":[97],"understanding":[99],"significant":[101],"electrocatalytic":[102],"activity":[103],"Pd":[105],"rational":[107],"approaches":[108],"development":[111],"active":[114],"catalysts":[115],"media.":[124]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":5},{"year":2023,"cited_by_count":6},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":4},{"year":2019,"cited_by_count":1}],"updated_date":"2026-09-24T07:57:37.273135","created_date":"2018-11-02T00:00:00"}