{"id":"https://openalex.org/W2897009201","doi":"https://doi.org/10.1021/acs.jpclett.8b02473","title":"Breakdown of Linear Dielectric Theory for the Interaction between Hydrated Ions and Graphene","display_name":"Breakdown of Linear Dielectric Theory for the Interaction between Hydrated Ions and Graphene","publication_year":2018,"publication_date":"2018-10-12","ids":{"openalex":"https://openalex.org/W2897009201","doi":"https://doi.org/10.1021/acs.jpclett.8b02473","mag":"2897009201","pmid":"https://pubmed.ncbi.nlm.nih.gov/30382706"},"language":"en","primary_location":{"id":"doi:10.1021/acs.jpclett.8b02473","doi":"https://doi.org/10.1021/acs.jpclett.8b02473","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jpclett.8b02473","pdf_url":null,"source":{"id":"https://openalex.org/S123480357","display_name":"The Journal of Physical Chemistry Letters","issn_l":"1948-7185","issn":["1948-7185"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-1","medline","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry Letters","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","datacite","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://doi.org/10.17169/refubium-26158","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5034469907","display_name":"Philip Loche","orcid":"https://orcid.org/0000-0002-9112-0010","observed_orcids":["https://orcid.org/0000-0002-9112-0010"]},"institutions":[{"id":"https://openalex.org/I75951250","display_name":"Freie Universit\u00e4t Berlin","ror":"https://ror.org/046ak2485","country_code":"DE","type":"education","lineage":["https://openalex.org/I75951250"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Philip Loche","raw_affiliation_strings":["Fachbereich Physik, Freie Universit\u00e4t Berlin, Arnimallee 14, 14195 Berlin, Germany"],"raw_orcid":"https://orcid.org/0000-0002-9112-0010","affiliations":[{"raw_affiliation_string":"Fachbereich Physik, Freie Universit\u00e4t Berlin, Arnimallee 14, 14195 Berlin, Germany","institution_ids":["https://openalex.org/I75951250"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067844293","display_name":"Cihan Ayaz","orcid":"https://orcid.org/0000-0001-7154-9744","observed_orcids":["https://orcid.org/0000-0001-7154-9744"]},"institutions":[{"id":"https://openalex.org/I75951250","display_name":"Freie Universit\u00e4t Berlin","ror":"https://ror.org/046ak2485","country_code":"DE","type":"education","lineage":["https://openalex.org/I75951250"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Cihan Ayaz","raw_affiliation_strings":["Fachbereich Physik, Freie Universit\u00e4t Berlin, Arnimallee 14, 14195 Berlin, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fachbereich Physik, Freie Universit\u00e4t Berlin, Arnimallee 14, 14195 Berlin, Germany","institution_ids":["https://openalex.org/I75951250"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5080395222","display_name":"Alexander Schlaich","orcid":"https://orcid.org/0000-0002-4250-363X","observed_orcids":["https://orcid.org/0000-0002-4250-363X"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210113150","display_name":"Laboratoire Interdisciplinaire de Physique","ror":"https://ror.org/023n9q531","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I4210113150","https://openalex.org/I899635006"]},{"id":"https://openalex.org/I75951250","display_name":"Freie Universit\u00e4t Berlin","ror":"https://ror.org/046ak2485","country_code":"DE","type":"education","lineage":["https://openalex.org/I75951250"]},{"id":"https://openalex.org/I899635006","display_name":"Universit\u00e9 Grenoble Alpes","ror":"https://ror.org/02rx3b187","country_code":"FR","type":"education","lineage":["https://openalex.org/I899635006"]}],"countries":["DE","FR"],"is_corresponding":false,"raw_author_name":"Alexander Schlaich","raw_affiliation_strings":["Fachbereich Physik, Freie Universit\u00e4t Berlin, Arnimallee 14, 14195 Berlin, Germany","Laboratoire Interdisciplinaire de Physique, CNRS and Universit\u00e9 Grenoble Alpes, UMR CNRS 5588, 38000 Grenoble, France"],"raw_orcid":"https://orcid.org/0000-0002-4250-363X","affiliations":[{"raw_affiliation_string":"Fachbereich Physik, Freie Universit\u00e4t Berlin, Arnimallee 14, 14195 Berlin, Germany","institution_ids":["https://openalex.org/I75951250"]},{"raw_affiliation_string":"Laboratoire Interdisciplinaire de Physique, CNRS and Universit\u00e9 Grenoble Alpes, UMR CNRS 5588, 38000 Grenoble, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210113150","https://openalex.org/I899635006"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5027997928","display_name":"Douwe Jan Bonthuis","orcid":"https://orcid.org/0000-0002-1252-7745","observed_orcids":["https://orcid.org/0000-0002-1252-7745"]},"institutions":[{"id":"https://openalex.org/I75951250","display_name":"Freie Universit\u00e4t Berlin","ror":"https://ror.org/046ak2485","country_code":"DE","type":"education","lineage":["https://openalex.org/I75951250"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Douwe Jan Bonthuis","raw_affiliation_strings":["Fachbereich Physik, Freie Universit\u00e4t Berlin, Arnimallee 14, 14195 Berlin, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fachbereich Physik, Freie Universit\u00e4t Berlin, Arnimallee 14, 14195 Berlin, Germany","institution_ids":["https://openalex.org/I75951250"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5035250426","display_name":"Roland R. Netz","orcid":"https://orcid.org/0000-0003-0147-0162","observed_orcids":["https://orcid.org/0000-0003-0147-0162"]},"institutions":[{"id":"https://openalex.org/I75951250","display_name":"Freie Universit\u00e4t Berlin","ror":"https://ror.org/046ak2485","country_code":"DE","type":"education","lineage":["https://openalex.org/I75951250"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Roland R. Netz","raw_affiliation_strings":["Fachbereich Physik, Freie Universit\u00e4t Berlin, Arnimallee 14, 14195 Berlin, Germany"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Fachbereich Physik, Freie Universit\u00e4t Berlin, Arnimallee 14, 14195 Berlin, Germany","institution_ids":["https://openalex.org/I75951250"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5035250426"],"corresponding_institution_ids":["https://openalex.org/I75951250"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.6591,"has_fulltext":false,"cited_by_count":54,"citation_normalized_percentile":{"value":0.91611716,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":95,"max":99},"biblio":{"volume":"9","issue":"22","first_page":"6463","last_page":"6468"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12274","display_name":"Electrostatics and Colloid Interactions","score":0.9843999743461609,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12274","display_name":"Electrostatics and Colloid Interactions","score":0.9843999743461609,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11582","display_name":"Nanopore and Nanochannel Transport Studies","score":0.004600000102072954,"subfield":{"id":"https://openalex.org/subfields/2204","display_name":"Biomedical Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10002","display_name":"Advanced Chemical Physics Studies","score":0.002899999963119626,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/hydrated-ions","display_name":"hydrated ions","score":0.8460000157356262},{"id":"https://openalex.org/keywords/nonlinear-dielectric-effect","display_name":"nonlinear dielectric effect","score":0.9200000166893005},{"id":"https://openalex.org/keywords/van-der-waals-attraction","display_name":"van der Waals attraction","score":0.9309999942779541},{"id":"https://openalex.org/keywords/monovalent-ions","display_name":"monovalent ions","score":0.7110000252723694},{"id":"https://openalex.org/keywords/atomistic-molecular-dynamics","display_name":"atomistic molecular dynamics","score":0.6940000057220459}],"concepts":[{"id":"https://openalex.org/C30080830","wikidata":"https://www.wikidata.org/wiki/Q169917","display_name":"Graphene","level":2,"score":0.8375399112701416},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.6705107092857361},{"id":"https://openalex.org/C133386390","wikidata":"https://www.wikidata.org/wiki/Q184996","display_name":"Dielectric","level":2,"score":0.6673269867897034},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.5853779911994934},{"id":"https://openalex.org/C2987621370","wikidata":"https://www.wikidata.org/wiki/Q184996","display_name":"Dielectric response","level":3,"score":0.47529590129852295},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.38446134328842163},{"id":"https://openalex.org/C26873012","wikidata":"https://www.wikidata.org/wiki/Q214781","display_name":"Condensed matter physics","level":1,"score":0.3362482786178589},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.23813071846961975},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.22030264139175415},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.12545344233512878},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.12353524565696716}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1021/acs.jpclett.8b02473","doi":"https://doi.org/10.1021/acs.jpclett.8b02473","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.jpclett.8b02473","pdf_url":null,"source":{"id":"https://openalex.org/S123480357","display_name":"The Journal of Physical Chemistry Letters","issn_l":"1948-7185","issn":["1948-7185"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-1","medline","norway-1","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry Letters","raw_type":"journal-article"},{"id":"pmid:30382706","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/30382706","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The journal of physical chemistry letters","raw_type":"Journal Article"},{"id":"pmh:oai:refubium.fu-berlin.de:fub188/26398","doi":null,"is_oa":false,"landing_page_url":"https://refubium.fu-berlin.de/handle/fub188/26398","pdf_url":null,"source":{"id":"https://openalex.org/S4306402444","display_name":"Refubium (Universit\u00e4tsbibliothek der Freien Universit\u00e4t Berlin)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I75951250","host_organization_name":"Freie Universit\u00e4t Berlin","host_organization_lineage":["https://openalex.org/I75951250"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"doc-type:article"},{"id":"doi:10.17169/refubium-26158","doi":"https://doi.org/10.17169/refubium-26158","is_oa":true,"landing_page_url":"https://doi.org/10.17169/refubium-26158","pdf_url":null,"source":{"id":"https://openalex.org/S7407052913","display_name":"Universit\u00e4tsbibliothek der FU Berlin Hochschulschriftenstelle u. Dokumentenserver","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"article-journal"}],"best_oa_location":{"id":"doi:10.17169/refubium-26158","doi":"https://doi.org/10.17169/refubium-26158","is_oa":true,"landing_page_url":"https://doi.org/10.17169/refubium-26158","pdf_url":null,"source":{"id":"https://openalex.org/S7407052913","display_name":"Universit\u00e4tsbibliothek der FU Berlin Hochschulschriftenstelle u. Dokumentenserver","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"article-journal"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G5047987924","display_name":null,"funder_award_id":"SFB-765","funder_id":"https://openalex.org/F4320320879","funder_display_name":"Deutsche Forschungsgemeinschaft"},{"id":"https://openalex.org/G790261903","display_name":null,"funder_award_id":"NE810/11","funder_id":"https://openalex.org/F4320320879","funder_display_name":"Deutsche Forschungsgemeinschaft"}],"funders":[{"id":"https://openalex.org/F4320320879","display_name":"Deutsche Forschungsgemeinschaft","ror":"https://ror.org/018mejw64"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":53,"referenced_works":["https://openalex.org/W27727037","https://openalex.org/W1031578623","https://openalex.org/W1572709184","https://openalex.org/W1581103620","https://openalex.org/W1963819448","https://openalex.org/W1969550189","https://openalex.org/W1969678991","https://openalex.org/W1970201026","https://openalex.org/W1972175237","https://openalex.org/W1973664279","https://openalex.org/W1995816895","https://openalex.org/W2001861985","https://openalex.org/W2008682560","https://openalex.org/W2017092746","https://openalex.org/W2018030092","https://openalex.org/W2018652376","https://openalex.org/W2020964987","https://openalex.org/W2022047868","https://openalex.org/W2028123089","https://openalex.org/W2046078275","https://openalex.org/W2048452802","https://openalex.org/W2055858503","https://openalex.org/W2059737929","https://openalex.org/W2061545818","https://openalex.org/W2065527369","https://openalex.org/W2070260018","https://openalex.org/W2075320109","https://openalex.org/W2077811084","https://openalex.org/W2081727601","https://openalex.org/W2086154818","https://openalex.org/W2088960562","https://openalex.org/W2089159346","https://openalex.org/W2110479326","https://openalex.org/W2119877238","https://openalex.org/W2156963746","https://openalex.org/W2163980958","https://openalex.org/W2165172960","https://openalex.org/W2166169036","https://openalex.org/W2296171931","https://openalex.org/W2325087798","https://openalex.org/W2325806333","https://openalex.org/W2330662234","https://openalex.org/W2331348375","https://openalex.org/W2495373278","https://openalex.org/W2519860664","https://openalex.org/W2543853137","https://openalex.org/W2762107502","https://openalex.org/W2767647504","https://openalex.org/W2778253780","https://openalex.org/W2808198009","https://openalex.org/W3096986715","https://openalex.org/W3100474188","https://openalex.org/W3105164824"],"related_works":["https://openalex.org/W2928864457","https://openalex.org/W2312314496","https://openalex.org/W4290659049","https://openalex.org/W4404650069","https://openalex.org/W4412136765","https://openalex.org/W4213188516","https://openalex.org/W2296899957","https://openalex.org/W7113136531","https://openalex.org/W6980405002","https://openalex.org/W4313909744"],"abstract_inverted_index":{"Many":[0],"vital":[1],"processes":[2],"taking":[3],"place":[4],"in":[5,29],"electrolytes,":[6],"such":[7],"as":[8],"nanoparticle":[9],"self-assembly,":[10],"water":[11],"purification,":[12],"and":[13,27,40,60,78,105],"the":[14,21,34,53,103],"operation":[15],"of":[16,57,93,107],"aqueous":[17],"supercapacitors,":[18],"rely":[19],"on":[20],"precise":[22],"many-body":[23],"interactions":[24],"between":[25,36],"surfaces":[26],"ions":[28],"water.":[30],"Here":[31],"we":[32,74],"study":[33],"interaction":[35],"a":[37,41],"hydrated":[38],"ion":[39],"charge-neutral":[42],"graphene":[43],"layer":[44],"using":[45],"atomistic":[46],"molecular":[47],"dynamics":[48],"simulations.":[49],"For":[50],"small":[51],"separations,":[52,63],"ion-graphene":[54],"repulsion":[55],"is":[56],"nonelectrostatic":[58],"nature,":[59],"for":[61,88,102],"intermediate":[62],"van":[64],"der":[65],"Waals":[66],"attraction":[67],"becomes":[68],"important.":[69],"Contrary":[70],"to":[71,85],"prevailing":[72],"theory,":[73],"show":[75],"that":[76],"nonlinear":[77],"tensorial":[79],"dielectric":[80,97],"effects":[81],"become":[82],"non-negligible":[83],"close":[84],"surfaces,":[86],"even":[87],"monovalent":[89],"ions.":[90],"This":[91],"breakdown":[92],"standard":[94],"isotropic":[95],"linear":[96],"theory":[98],"has":[99],"important":[100],"consequences":[101],"understanding":[104],"modeling":[106],"charged":[108],"objects":[109],"at":[110],"surfaces.":[111]},"counts_by_year":[{"year":2026,"cited_by_count":8},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":4},{"year":2023,"cited_by_count":7},{"year":2022,"cited_by_count":11},{"year":2021,"cited_by_count":10},{"year":2020,"cited_by_count":7},{"year":2019,"cited_by_count":4}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2018-10-26T00:00:00"}