{"id":"https://openalex.org/W2896774438","doi":"https://doi.org/10.1002/slct.201802487","title":"Solvent and Catalyst\u2010Free Synthesis of Silicon\u2010Protected Alcohols","display_name":"Solvent and Catalyst\u2010Free Synthesis of Silicon\u2010Protected Alcohols","publication_year":2018,"publication_date":"2018-10-16","ids":{"openalex":"https://openalex.org/W2896774438","doi":"https://doi.org/10.1002/slct.201802487","mag":"2896774438"},"language":"en","primary_location":{"id":"doi:10.1002/slct.201802487","doi":"https://doi.org/10.1002/slct.201802487","is_oa":false,"landing_page_url":"https://doi.org/10.1002/slct.201802487","pdf_url":null,"source":{"id":"https://openalex.org/S4210221416","display_name":"ChemistrySelect","issn_l":"2365-6549","issn":["2365-6549"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","ki-jl-1","norway-1","poland-40","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemistrySelect","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5067435918","display_name":"Mateus Mittersteiner","orcid":"https://orcid.org/0000-0002-8501-844X","observed_orcids":["https://orcid.org/0000-0002-8501-844X"]},"institutions":[{"id":"https://openalex.org/I4210105683","display_name":"Universidade Regional de Blumenau","ror":"https://ror.org/01nsn0t21","country_code":"BR","type":"education","lineage":["https://openalex.org/I4210105683"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Mateus Mittersteiner","raw_affiliation_strings":["Departamento de Qu\u00edmica Universidade Regional de Blumenau  Antonio da Veiga 140, Blumenau \u2013SC 89019-917 Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departamento de Qu\u00edmica Universidade Regional de Blumenau  Antonio da Veiga 140, Blumenau \u2013SC 89019-917 Brazil","institution_ids":["https://openalex.org/I4210105683"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5055498478","display_name":"Morgana Aline Voigt","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4104125","display_name":"Universidade Federal de Santa Catarina","ror":"https://ror.org/041akq887","country_code":"BR","type":"education","lineage":["https://openalex.org/I4104125"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Morgana A. Voigt","raw_affiliation_strings":["Departamento de Ci\u00eancias Exatas e Educa\u00e7\u00e3o Universidade Federal de Santa Catarina, Jo\u00e3o Pessoa 2750, Blumenau \u2013 SC  89036-256 Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departamento de Ci\u00eancias Exatas e Educa\u00e7\u00e3o Universidade Federal de Santa Catarina, Jo\u00e3o Pessoa 2750, Blumenau \u2013 SC  89036-256 Brazil","institution_ids":["https://openalex.org/I4104125"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5030324700","display_name":"Paulo C\u00e9sar de Jesus","orcid":"https://orcid.org/0000-0002-1314-3444","observed_orcids":["https://orcid.org/0000-0002-1314-3444"]},"institutions":[{"id":"https://openalex.org/I4210105683","display_name":"Universidade Regional de Blumenau","ror":"https://ror.org/01nsn0t21","country_code":"BR","type":"education","lineage":["https://openalex.org/I4210105683"]}],"countries":["BR"],"is_corresponding":false,"raw_author_name":"Paulo C. de\u2005Jesus","raw_affiliation_strings":["Departamento de Qu\u00edmica Universidade Regional de Blumenau  Antonio da Veiga 140, Blumenau \u2013SC 89019-917 Brazil"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Departamento de Qu\u00edmica Universidade Regional de Blumenau  Antonio da Veiga 140, Blumenau \u2013SC 89019-917 Brazil","institution_ids":["https://openalex.org/I4210105683"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5014709239","display_name":"Patr\u00edcia Bulegon Brondani","orcid":"https://orcid.org/0000-0003-4786-8627","observed_orcids":["https://orcid.org/0000-0003-4786-8627"]},"institutions":[{"id":"https://openalex.org/I4104125","display_name":"Universidade Federal de Santa Catarina","ror":"https://ror.org/041akq887","country_code":"BR","type":"education","lineage":["https://openalex.org/I4104125"]}],"countries":["BR"],"is_corresponding":true,"raw_author_name":"Patr\u00edcia B. Brondani","raw_affiliation_strings":["Departamento de Ci\u00eancias Exatas e Educa\u00e7\u00e3o Universidade Federal de Santa Catarina, Jo\u00e3o Pessoa 2750, Blumenau \u2013 SC  89036-256 Brazil"],"raw_orcid":"https://orcid.org/0000-0003-4786-8627","affiliations":[{"raw_affiliation_string":"Departamento de Ci\u00eancias Exatas e Educa\u00e7\u00e3o Universidade Federal de Santa Catarina, Jo\u00e3o Pessoa 2750, Blumenau \u2013 SC  89036-256 Brazil","institution_ids":["https://openalex.org/I4104125"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5014709239"],"corresponding_institution_ids":["https://openalex.org/I4104125"],"apc_list":{"value":3880,"currency":"USD","value_usd":3880},"apc_paid":null,"fwci":0.4896,"has_fulltext":false,"cited_by_count":6,"citation_normalized_percentile":{"value":0.47873403,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"3","issue":"38","first_page":"10717","last_page":"10720"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.9878000020980835,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11831","display_name":"Chemical Synthesis and Reactions","score":0.9878000020980835,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13859","display_name":"Organic Chemistry Synthesis Methods","score":0.0032999999821186066,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.0027000000700354576,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/alcohol-protection","display_name":"alcohol protection","score":0.7509999871253967},{"id":"https://openalex.org/keywords/silyl-chlorides","display_name":"silyl chlorides","score":0.925000011920929},{"id":"https://openalex.org/keywords/solvent-free-synthesis","display_name":"solvent-free synthesis","score":0.753000020980835},{"id":"https://openalex.org/keywords/catalyst-free-synthesis","display_name":"catalyst-free synthesis","score":0.8510000109672546},{"id":"https://openalex.org/keywords/grinding","display_name":"grinding","score":0.5929999947547913},{"id":"https://openalex.org/keywords/triethylsilyl-chloride","display_name":"triethylsilyl chloride","score":0.7509999871253967},{"id":"https://openalex.org/keywords/diol-protection","display_name":"diol protection","score":0.6740000247955322},{"id":"https://openalex.org/keywords/phenolic-alcohols","display_name":"phenolic alcohols","score":0.7429999709129333},{"id":"https://openalex.org/keywords/primary-alcohols","display_name":"primary alcohols","score":0.5789999961853027},{"id":"https://openalex.org/keywords/secondary-alcohols","display_name":"secondary alcohols","score":0.7839999794960022}],"concepts":[{"id":"https://openalex.org/C187714232","wikidata":"https://www.wikidata.org/wiki/Q2745207","display_name":"Anhydrous","level":2,"score":0.8399129509925842},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7917187213897705},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.7562320232391357},{"id":"https://openalex.org/C2776701986","wikidata":"https://www.wikidata.org/wiki/Q278332","display_name":"Tetrahydrofuran","level":3,"score":0.7545661926269531},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.6599421501159668},{"id":"https://openalex.org/C5304478","wikidata":"https://www.wikidata.org/wiki/Q502457","display_name":"Silylation","level":3,"score":0.6384444236755371},{"id":"https://openalex.org/C2777712214","wikidata":"https://www.wikidata.org/wiki/Q409298","display_name":"Dimethylformamide","level":3,"score":0.5807545185089111},{"id":"https://openalex.org/C2777289219","wikidata":"https://www.wikidata.org/wiki/Q7632154","display_name":"Substrate (aquarium)","level":2,"score":0.5269665718078613},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.4813538193702698},{"id":"https://openalex.org/C2779515768","wikidata":"https://www.wikidata.org/wiki/Q421916","display_name":"Diol","level":2,"score":0.47786301374435425},{"id":"https://openalex.org/C2777977315","wikidata":"https://www.wikidata.org/wiki/Q7243056","display_name":"Primary (astronomy)","level":2,"score":0.4479144811630249},{"id":"https://openalex.org/C2779746882","wikidata":"https://www.wikidata.org/wiki/Q898525","display_name":"Protecting group","level":3,"score":0.4367803931236267},{"id":"https://openalex.org/C94412978","wikidata":"https://www.wikidata.org/wiki/Q103135","display_name":"Hydrolysis","level":2,"score":0.41874706745147705},{"id":"https://openalex.org/C127313418","wikidata":"https://www.wikidata.org/wiki/Q1069","display_name":"Geology","level":0,"score":0.0},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0},{"id":"https://openalex.org/C1276947","wikidata":"https://www.wikidata.org/wiki/Q333","display_name":"Astronomy","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C111368507","wikidata":"https://www.wikidata.org/wiki/Q43518","display_name":"Oceanography","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/slct.201802487","doi":"https://doi.org/10.1002/slct.201802487","is_oa":false,"landing_page_url":"https://doi.org/10.1002/slct.201802487","pdf_url":null,"source":{"id":"https://openalex.org/S4210221416","display_name":"ChemistrySelect","issn_l":"2365-6549","issn":["2365-6549"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","jufo-1","ki-jl-1","norway-1","poland-40","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemistrySelect","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G5367741959","display_name":null,"funder_award_id":"447110/2014-4","funder_id":"https://openalex.org/F4320322025","funder_display_name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico"}],"funders":[{"id":"https://openalex.org/F4320322025","display_name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico","ror":"https://ror.org/03swz6y49"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":32,"referenced_works":["https://openalex.org/W1965208694","https://openalex.org/W1974169361","https://openalex.org/W1984649682","https://openalex.org/W1989560493","https://openalex.org/W2000933026","https://openalex.org/W2007440519","https://openalex.org/W2013703532","https://openalex.org/W2015681461","https://openalex.org/W2035851557","https://openalex.org/W2065777499","https://openalex.org/W2068014093","https://openalex.org/W2075908203","https://openalex.org/W2076743368","https://openalex.org/W2078017931","https://openalex.org/W2086792309","https://openalex.org/W2108021188","https://openalex.org/W2111300087","https://openalex.org/W2132446507","https://openalex.org/W2146205397","https://openalex.org/W2180607396","https://openalex.org/W2317236511","https://openalex.org/W2333862823","https://openalex.org/W2465053076","https://openalex.org/W2520848195","https://openalex.org/W2555224455","https://openalex.org/W2949388362","https://openalex.org/W2950625536","https://openalex.org/W2951575621","https://openalex.org/W2952241982","https://openalex.org/W2952392433","https://openalex.org/W2952712910","https://openalex.org/W4211187039"],"related_works":["https://openalex.org/W7064738300","https://openalex.org/W2035851557","https://openalex.org/W2075908203","https://openalex.org/W2089736000","https://openalex.org/W2000842962","https://openalex.org/W1970449941","https://openalex.org/W2108021188","https://openalex.org/W2952858451","https://openalex.org/W2952683826","https://openalex.org/W1987437304"],"abstract_inverted_index":{"Abstract":[0],"The":[1,41],"protection":[2],"reactions":[3,42],"of":[4,38,73,90,124],"alcohols":[5],"(primary":[6],"and":[7,25,59,99,119,134],"secondary)":[8],"were":[9],"efficiently":[10],"performed":[11],"applying":[12],"silyl":[13],"chlorides":[14],"(Me":[15],"3":[16,19],"SiCl,":[17,20],"Et":[18],"t":[21,26],"\u2010BuMe":[22],"2":[23,28],"SiCl":[24],"\u2010BuPh":[27],"SiCl)":[29],"as":[30,147],"protecting":[31,56],"source,":[32],"on":[33,54],"grinding,":[34],"without":[35],"the":[36,55,66,74,88,127,138,141],"use":[37],"a":[39,130,148],"catalyst.":[40],"proceeded":[43],"smoothly,":[44],"either":[45],"at":[46,50,111],"room":[47],"temperature":[48],"or":[49,81,140],"40":[51],"\u00b0C,":[52],"depending":[53],"group":[57],"applied,":[58],"under":[60],"solvent\u2010free":[61],"conditions.":[62],"In":[63],"comparison":[64],"with":[65],"classical":[67],"reaction":[68,92,95,113],"conditions,":[69,96],"which":[70],"employ,":[71],"most":[72],"times,":[75,93],"solvent":[76],"in":[77,151],"anhydrous":[78],"conditions":[79],"(tetrahydrofuran":[80],"N,N":[82],"\u2010dimethylformamide),":[83],"this":[84,104],"synthetic":[85],"protocol":[86],"exhibits":[87],"advantages":[89],"shorter":[91],"milder":[94],"higher":[97],"yields":[98],"simpler":[100],"purification":[101],"steps.":[102],"Under":[103],"method":[105],"21":[106],"examples":[107],"could":[108,144],"be":[109,145],"obtained":[110,146],"short":[112],"times":[114],"(5":[115],"\u2013":[116],"10":[117],"min)":[118],"presenting":[120],"up":[121],"to":[122],"98%":[123],"yields.":[125,153],"When":[126],"substrate":[128],"was":[129],"diol":[131],"bearing":[132],"primary":[133],"phenolic":[135],"hydroxyl":[136],"moieties,":[137],"monoprotected":[139],"diprotected":[142],"product":[143],"sole":[149],"product,":[150],"excellent":[152]},"counts_by_year":[{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":1}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2018-10-26T00:00:00"}