{"id":"https://openalex.org/W2894636715","doi":"https://doi.org/10.29333/ejac/97267","title":"Synthesis, Spectral and Biological Studies of Ni(II), Pd(II), and Pt(IV) Complexes with New Heterocyclic ligand Derived from Azo-Schiff Bases Dye","display_name":"Synthesis, Spectral and Biological Studies of Ni(II), Pd(II), and Pt(IV) Complexes with New Heterocyclic ligand Derived from Azo-Schiff Bases Dye","publication_year":2018,"publication_date":"2018-10-02","ids":{"openalex":"https://openalex.org/W2894636715","doi":"https://doi.org/10.29333/ejac/97267","mag":"2894636715"},"language":"en","primary_location":{"id":"doi:10.29333/ejac/97267","doi":"https://doi.org/10.29333/ejac/97267","is_oa":true,"landing_page_url":"https://doi.org/10.29333/ejac/97267","pdf_url":null,"source":{"id":"https://openalex.org/S2764829743","display_name":"Eurasian Journal of Analytical Chemistry","issn_l":"1306-3057","issn":["1306-3057"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1","poland-40"],"host_organization":"https://openalex.org/P4328143497","host_organization_name":"Modestum Limited","host_organization_lineage":["https://openalex.org/P4328143497"],"host_organization_lineage_names":["Modestum Limited"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Eurasian Journal of Analytical Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"diamond","oa_url":"https://doi.org/10.29333/ejac/97267","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5012685028","display_name":"Khalid Jawad Al-Adilee","orcid":"https://orcid.org/0000-0002-7382-9739","observed_orcids":["https://orcid.org/0000-0002-7382-9739"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Khalid Al-Adilee","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5034625478","display_name":"Haitham Dakheel","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Haitham Dakheel","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.5282,"has_fulltext":true,"cited_by_count":12,"citation_normalized_percentile":{"value":0.68302403,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":97},"biblio":{"volume":"13","issue":"6","first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.9833999872207642,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},"topics":[{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.9833999872207642,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.013700000010430813,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.0008999999845400453,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/nickel-ii-complexes","display_name":"nickel(II) complexes","score":0.9139999747276306},{"id":"https://openalex.org/keywords/palladium-ii-complexes","display_name":"palladium(II) complexes","score":1.0},{"id":"https://openalex.org/keywords/platinum-iv-complexes","display_name":"platinum(IV) complexes","score":0.9990000128746033},{"id":"https://openalex.org/keywords/heterocyclic-ligands","display_name":"heterocyclic ligands","score":0.8889999985694885},{"id":"https://openalex.org/keywords/azo-schiff-base","display_name":"azo Schiff base","score":0.9150000214576721},{"id":"https://openalex.org/keywords/coordination-chemistry","display_name":"coordination chemistry","score":0.5950000286102295},{"id":"https://openalex.org/keywords/spectroscopic-characterization","display_name":"spectroscopic characterization","score":0.6119999885559082},{"id":"https://openalex.org/keywords/bioactivity","display_name":"biological activity","score":0.9710000157356262}],"concepts":[{"id":"https://openalex.org/C2776428424","wikidata":"https://www.wikidata.org/wiki/Q2602701","display_name":"Schiff base","level":2,"score":0.6727246642112732},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.643576979637146},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.544011116027832},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.4276289641857147},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.37591609358787537},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.35149824619293213},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.09584596753120422},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0645303726196289}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.29333/ejac/97267","doi":"https://doi.org/10.29333/ejac/97267","is_oa":true,"landing_page_url":"https://doi.org/10.29333/ejac/97267","pdf_url":null,"source":{"id":"https://openalex.org/S2764829743","display_name":"Eurasian Journal of Analytical Chemistry","issn_l":"1306-3057","issn":["1306-3057"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1","poland-40"],"host_organization":"https://openalex.org/P4328143497","host_organization_name":"Modestum Limited","host_organization_lineage":["https://openalex.org/P4328143497"],"host_organization_lineage_names":["Modestum Limited"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Eurasian Journal of Analytical Chemistry","raw_type":"journal-article"},{"id":"pmh:oai:eurasianjournals.com:article/1008","doi":null,"is_oa":true,"landing_page_url":"https://eurasianjournals.com/ej/article/view/1008","pdf_url":"https://eurasianjournals.com/ej/article/download/1008/1008","source":{"id":"https://openalex.org/S2764829743","display_name":"Eurasian Journal of Analytical Chemistry","issn_l":"1306-3057","issn":["1306-3057"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1","poland-40"],"host_organization":"https://openalex.org/P4328143497","host_organization_name":"Modestum Limited","host_organization_lineage":["https://openalex.org/P4328143497"],"host_organization_lineage_names":["Modestum Limited"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"1306-3057","raw_type":"info:eu-repo/semantics/article"}],"best_oa_location":{"id":"doi:10.29333/ejac/97267","doi":"https://doi.org/10.29333/ejac/97267","is_oa":true,"landing_page_url":"https://doi.org/10.29333/ejac/97267","pdf_url":null,"source":{"id":"https://openalex.org/S2764829743","display_name":"Eurasian Journal of Analytical Chemistry","issn_l":"1306-3057","issn":["1306-3057"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1","poland-40"],"host_organization":"https://openalex.org/P4328143497","host_organization_name":"Modestum Limited","host_organization_lineage":["https://openalex.org/P4328143497"],"host_organization_lineage_names":["Modestum Limited"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Eurasian Journal of Analytical Chemistry","raw_type":"journal-article"},"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/3","score":0.46810001134872437,"display_name":"Good health and well-being"}],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2894636715.pdf","grobid_xml":"https://content.openalex.org/works/W2894636715.grobid-xml"},"referenced_works_count":2,"referenced_works":["https://openalex.org/W1979900426","https://openalex.org/W2305106015"],"related_works":["https://openalex.org/W4389205038","https://openalex.org/W4390064819","https://openalex.org/W3174320412","https://openalex.org/W3033899790","https://openalex.org/W4394860606","https://openalex.org/W2054739960","https://openalex.org/W3091949787","https://openalex.org/W7167358258","https://openalex.org/W4405873820","https://openalex.org/W7171424192"],"abstract_inverted_index":{"New":[0],"heterocyclic":[1],"azo-schiff":[2,157],"base":[3,31,158],"dye":[4],"(L2)":[5],"have":[6],"been":[7],"synthesized":[8],"from":[9],"a":[10],"reaction":[11],"of":[12,23,32,99,106,155,170,183,231,240],"4-(dimethylamino)benzaldehyde":[13],"with":[14,203,217],"(E)-5-((1H-benzo[d]imidazol-2-yl)":[15],"diazenyl)":[16],"-2-amine-4,6-dimethylpyridin":[17],"(L1)":[18],".":[19],"A":[20],"new":[21],"class":[22],"Ni(II),":[24],"Pd(II),":[25],"and":[26,39,47,55,68,87,121,123,136,147,159,189,242],"Pt(IV)":[27,88],"complexes":[28,50,115,139,161,172],"ofazo-":[29],"schiff":[30],"the":[33,53,80,104,110,112,119,128,134,153,156,163,171,181,238],"type":[34],"[Ni(L2)2Cl2],":[35],"[Pd(L2)":[36],"Cl2]":[37],",":[38],"[Pt(L2)2Cl2]Cl2":[40],"where":[41],"L2=(E)-5-((E)-(1H-benzo[d]imidazol-2-yl)diazenyl)-N-(4-(dimethylamino)benzylidene)":[42],"-2-amine-":[43],"4,6-dimethylpyridin.":[44],"Both":[45],"ligand":[46,135],"its":[48],"metal":[49,89,95,114,138,160],"were":[51,101],"characterizedby":[52],"spectroscopic":[54],"analytical":[56],"methods":[57],"such":[58],"as":[59,234],"mass":[60],"spectral,":[61],"1H-":[62],"NMR,":[63],"FT-":[64],"IR,UV-Visb.,X-":[65],"ray,":[66],"TGA":[67],"SEM,":[69],"elemental":[70],"analysis,":[71],"molar":[72],"conductance":[73],"measurementsand":[74],"magnetic":[75],"susceptibility.,":[76],"spectral":[77],"studies":[78],"suggest":[79,109],"mole":[81],"ratio":[82],"[M:L]":[83],"was":[84,140,210],"[1:2]":[85],"forNi(II)":[86],"ions,":[90],"but":[91],"[1:1]":[92],"for":[93,118,127,223],"Pd(II)":[94,129],"ion.":[96],"The":[97,131],"structures":[98],"thesescomplexes":[100],"elucidated":[102],"on":[103,185,213],"basis":[105],"different":[107],"techniques":[108],"structuresof":[111],"prepared":[113,137],"octahedral":[116],"geometry":[117,126],"Ni(II)":[120],"Pt(IV)complexes":[122],"square":[124],"planar":[125],"complex.":[130],"antibacterial":[132],"activityof":[133],"also":[141],"studied":[142],"against":[143,162,176,200],"gram":[144,148],"positiveStaphylococcus":[145],"aureus":[146],"negative":[149],"bacteria":[150],"Escherichia":[151],"coli,":[152],"antifungalactivity":[154],"fungi":[164,177],"Alternaria.":[165,178],"It":[166],"isfound":[167],"that":[168],"some":[169],"are":[173],"quite":[174],"effective":[175],"In":[179],"thisstudy":[180],"cytotoxicity":[182,199],"Pd(II)-complex":[184,196],"human":[186,224],"(PC3)":[187],"cancer":[188],"normal":[190,214],"cells":[191,215,225],"werestudied":[192],"using":[193,232],"MTT":[194],"assay.":[195],"showed":[197],"selective":[198],"cancercell":[201],"line":[202,216],"IC50":[204,218],"=":[205],"450":[206],"\u03bcg/ml,":[207],"while":[208],"it":[209],"very":[211],"safe":[212],"=14554885":[219],"\u03bcg":[220],"/ml,":[221],"respectively":[222],".The":[226],"results":[227],"indicate":[228],"undoubtedly":[229],"thepossibility":[230],"them":[233],"antitumor":[235],"drugs":[236],"in":[237],"field":[239],"medicine":[241],"Pharmacyagainst":[243],"prostate":[244],"cancer.":[245]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2018-10-12T00:00:00"}