{"id":"https://openalex.org/W2887964706","doi":null,"title":"Interactions at the mineral - organic interface : the DMSO-nacrite thermal deintercalation.","display_name":"Interactions at the mineral - organic interface : the DMSO-nacrite thermal deintercalation.","publication_year":2006,"publication_date":"2006-01-01","ids":{"openalex":"https://openalex.org/W2887964706","mag":"2887964706"},"language":"en","primary_location":{"id":"pmh:oai:HAL:hal-00091428v1","doi":null,"is_oa":false,"landing_page_url":"https://insu.hal.science/hal-00091428","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"4\u00e8me Colloque du GFA (Groupe Fran\u00e7ais des Argiles) et 43\u00e8me Annual Meeting of the CMS (Clay Minerals Society), 2006, Ol\u00e9ron, France","raw_type":"info:eu-repo/semantics/conferenceObject"},"volume":null,"type":"conference-paper","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5110939485","display_name":"Fabrice Muller","orcid":"https://orcid.org/0000-0003-0887-651X","observed_orcids":["https://orcid.org/0000-0003-0887-651X"]},"institutions":[{"id":"https://openalex.org/I4387155497","display_name":"Institut des Sciences de la Terre d'Orl\u00e9ans","ror":"https://ror.org/02t2hg116","country_code":"FR","type":"facility","lineage":["https://openalex.org/I12449238","https://openalex.org/I1294671590","https://openalex.org/I4210148025","https://openalex.org/I4210158893","https://openalex.org/I4387155497"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Muller, Fabrice","raw_affiliation_strings":["ISTO - Institut des Sciences de la Terre d'Orl\u00e9ans (Projet I.S.T.E. 1A, rue de la F\u00e9rollerie 45071 ORLEANS CEDEX 2 - France)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"ISTO - Institut des Sciences de la Terre d'Orl\u00e9ans (Projet I.S.T.E. 1A, rue de la F\u00e9rollerie 45071 ORLEANS CEDEX 2 - France)","institution_ids":["https://openalex.org/I4387155497"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110721260","display_name":"Jean\u2010Michel B\u00e9ny","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4387155497","display_name":"Institut des Sciences de la Terre d'Orl\u00e9ans","ror":"https://ror.org/02t2hg116","country_code":"FR","type":"facility","lineage":["https://openalex.org/I12449238","https://openalex.org/I1294671590","https://openalex.org/I4210148025","https://openalex.org/I4210158893","https://openalex.org/I4387155497"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"B\u00e9ny, Jean-Michel","raw_affiliation_strings":["ISTO - Institut des Sciences de la Terre d'Orl\u00e9ans (Projet I.S.T.E. 1A, rue de la F\u00e9rollerie 45071 ORLEANS CEDEX 2 - France)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"ISTO - Institut des Sciences de la Terre d'Orl\u00e9ans (Projet I.S.T.E. 1A, rue de la F\u00e9rollerie 45071 ORLEANS CEDEX 2 - France)","institution_ids":["https://openalex.org/I4387155497"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5076116153","display_name":"Sonia Naamen","orcid":"https://orcid.org/0009-0004-4137-4188","observed_orcids":["https://orcid.org/0009-0004-4137-4188"]},"institutions":[{"id":"https://openalex.org/I179097149","display_name":"University of Carthage","ror":"https://ror.org/057x6za15","country_code":"TN","type":"education","lineage":["https://openalex.org/I179097149"]}],"countries":["TN"],"is_corresponding":false,"raw_author_name":"Naamen, S.","raw_affiliation_strings":["Facult\u00e9 des Sciences de Bizerte [Universit\u00e9 de Carthage] (7021 jarzouna - bizerte - Tunisia)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Facult\u00e9 des Sciences de Bizerte [Universit\u00e9 de Carthage] (7021 jarzouna - bizerte - Tunisia)","institution_ids":["https://openalex.org/I179097149"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5111085654","display_name":"A. Ben Haj Amara","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I179097149","display_name":"University of Carthage","ror":"https://ror.org/057x6za15","country_code":"TN","type":"education","lineage":["https://openalex.org/I179097149"]}],"countries":["TN"],"is_corresponding":false,"raw_author_name":"Ben Haj Amara, A.","raw_affiliation_strings":["Facult\u00e9 des Sciences de Bizerte [Universit\u00e9 de Carthage] (7021 jarzouna - bizerte - Tunisia)"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Facult\u00e9 des Sciences de Bizerte [Universit\u00e9 de Carthage] (7021 jarzouna - bizerte - Tunisia)","institution_ids":["https://openalex.org/I179097149"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":{"value":0.26353276,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11852","display_name":"Clay minerals and soil interactions","score":0.9984999895095825,"subfield":{"id":"https://openalex.org/subfields/1906","display_name":"Geochemistry and Petrology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11852","display_name":"Clay minerals and soil interactions","score":0.9984999895095825,"subfield":{"id":"https://openalex.org/subfields/1906","display_name":"Geochemistry and Petrology"},"field":{"id":"https://openalex.org/fields/19","display_name":"Earth and Planetary Sciences"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11940","display_name":"Layered Double Hydroxides Synthesis and Applications","score":0.0005000000237487257,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10501","display_name":"Polymer Nanocomposites and Properties","score":0.00039999998989515007,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/nacrite","display_name":"nacrite","score":0.9430000185966492},{"id":"https://openalex.org/keywords/phyllosilicates","display_name":"phyllosilicates","score":0.7559999823570251},{"id":"https://openalex.org/keywords/hydrogen-bonding","display_name":"hydrogen bonding","score":0.6899999976158142},{"id":"https://openalex.org/keywords/interlayer-spacing","display_name":"interlayer spacing","score":0.48899999260902405},{"id":"https://openalex.org/keywords/structural-change","display_name":"structural change","score":0.4320000112056732},{"id":"https://openalex.org/keywords/clay-mineral-stability","display_name":"clay mineral stability","score":0.8050000071525574},{"id":"https://openalex.org/keywords/clay-mineral-reactivity","display_name":"clay mineral reactivity","score":0.4569999873638153}],"concepts":[{"id":"https://openalex.org/C137824038","wikidata":"https://www.wikidata.org/wiki/Q175562","display_name":"Intercalation (chemistry)","level":2,"score":0.8434184789657593},{"id":"https://openalex.org/C153642686","wikidata":"https://www.wikidata.org/wiki/Q70906","display_name":"Infrared spectroscopy","level":2,"score":0.6150916814804077},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.614190399646759},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5950369238853455},{"id":"https://openalex.org/C160892712","wikidata":"https://www.wikidata.org/wiki/Q901559","display_name":"Fourier transform infrared spectroscopy","level":2,"score":0.5418878197669983},{"id":"https://openalex.org/C2776432453","wikidata":"https://www.wikidata.org/wiki/Q7946","display_name":"Mineral","level":2,"score":0.4873417317867279},{"id":"https://openalex.org/C40212044","wikidata":"https://www.wikidata.org/wiki/Q1799034","display_name":"Clay minerals","level":2,"score":0.4401317834854126},{"id":"https://openalex.org/C112887158","wikidata":"https://www.wikidata.org/wiki/Q169324","display_name":"Hydrogen bond","level":3,"score":0.4348514974117279},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.43255817890167236},{"id":"https://openalex.org/C125287762","wikidata":"https://www.wikidata.org/wiki/Q1758948","display_name":"Absorption (acoustics)","level":2,"score":0.4148067235946655},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.3747153878211975},{"id":"https://openalex.org/C199289684","wikidata":"https://www.wikidata.org/wiki/Q83353","display_name":"Mineralogy","level":1,"score":0.27046239376068115},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.26374903321266174},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.2312932312488556},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.189243346452713},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"pmh:oai:HAL:hal-00091428v1","doi":null,"is_oa":false,"landing_page_url":"https://insu.hal.science/hal-00091428","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"4\u00e8me Colloque du GFA (Groupe Fran\u00e7ais des Argiles) et 43\u00e8me Annual Meeting of the CMS (Clay Minerals Society), 2006, Ol\u00e9ron, France","raw_type":"info:eu-repo/semantics/conferenceObject"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2160742272","https://openalex.org/W2371922426","https://openalex.org/W2042008188","https://openalex.org/W2019744061","https://openalex.org/W7098716895","https://openalex.org/W3116158573","https://openalex.org/W2084514981","https://openalex.org/W2004432567","https://openalex.org/W2042133102","https://openalex.org/W2121092184"],"abstract_inverted_index":{"Intercalation":[0],"and":[1,33,51,71,93,133,151,182,200,257,273,282,332,364,378,458,467,491],"deintercalation":[2,101,248],"of":[3,11,20,57,75,82,90,103,144,163,177,239,303,344,394,402,411,420,429,439,455],"neutral":[4],"organic":[5,78,190,463],"molecules":[6,191],"in":[7,17,30,68,115,158,261,368,389,446],"the":[8,18,52,73,88,100,104,128,134,159,178,224,247,253,262,292,301,307,312,328,357,365,386,390,403,430,453,462,481,495],"interlayer":[9,456],"space":[10],"phyllosilicates":[12,70],"represent":[13],"an":[14],"important":[15],"interest":[16,89,445],"development":[19],"new":[21],"materials":[22],"with":[23,235,340,356,385,407,444],"desirable":[24],"properties":[25],"(catalysts,":[26],"sorbents,":[27],"...)":[28],"or":[29,483],"environmental":[31],"protection":[32],"rehabilitation":[34],"(waste":[35],"deposits,":[36],"polluted":[37],"soils,...).":[38],"To":[39,310,479],"analyse":[40],"these":[41],"mechanisms":[42],"several":[43],"approaches":[44],"are":[45,192,259,295,405],"usually":[46],"profitable.":[47],"The":[48,80,107,156,212,241,323,336,392,437],"small":[49],"dimensions":[50],"high":[53,63],"dipolar":[54],"momentum":[55],"value":[56],"dimethylsulfoxide":[58],"(DMSO)":[59],"give":[60],"it":[61],"a":[62,116,197,201,236,271,283,317,341,351,373],"ability":[64],"to":[65,86,98,126,187,222,233,350,398,452,475],"be":[66],"intercalated":[67,213,362,406,412],"1:1":[69],"initialize":[72],"intercalation":[74,482],"other":[76],"larger":[77],"molecules.":[79],"aim":[81],"this":[83,290,395],"work":[84],"is":[85,175,325,338,381,448],"show":[87],"FTIR":[91,477],"spectroscopy":[92,139],"X-ray":[94,220],"powder":[95],"diffraction":[96,221],"(XRD)":[97],"characterise":[99],"process":[102],"DMSO-nacrite":[105,108,149],"complex.":[106],"complex":[109,153,162,363,413],"was":[110],"prepared":[111,148,161],"by":[112,194,218],"heating":[113,209,237],"nacrite":[114,202,422],"92/8":[117],"wt":[118],"%":[119],"DMSO/H2O":[120],"solution":[121],"at":[122,166,210,250,383],"60\u00b0C.":[123],"In":[124,289],"order":[125],"localize":[127],"interaction":[129,179,465],"between":[130,180,196,330,376],"DMSO":[131,181,198],"molecule":[132],"clay":[135],"mineral,":[136],"infrared":[137],"absorption":[138],"has":[140,215,320],"been":[141,216,228,321],"performed.":[142],"Spectra":[143],"pure":[145],"nacrite,":[146],"freshly":[147,160],"complex,":[150],"thermally-treated":[152],"were":[154],"recorded.":[155],"presence":[157,302,454],"OH":[164],"bands":[165,206],"about":[167],"3400":[168],"cm-1,":[169],"3500":[170],"cm-1":[171,174],"et":[172],"3580":[173],"characteristic":[176],"nacrite.":[183],"These":[184,205],"results":[185],"allow":[186],"conclude":[188,399],"that":[189,245,400],"fixed":[193],"H-bonding":[195],"oxygen":[199],"surface":[203],"hydrogen.":[204],"disappear":[207],"after":[208],"360\u00b0C.":[211],"sample":[214],"studied":[217],"high-temperature":[219],"follow":[223],"deintercalation.":[225],"Samples":[226],"have":[227],"heated":[229],"from":[230,267],"room":[231],"temperature":[232,296],"360\u00b0C,":[234],"rate":[238],"100\u00b0C/hour.":[240],"XRD":[242,334,496],"patterns":[243],"showed":[244],"(i)":[246],"occurs":[249],"120\u00b0C,":[251],"(ii)":[252],"reticular":[254],"distances":[255],"(001)":[256],"(002)":[258],"not":[260],"expected":[263],"2/1":[264],"ratio,":[265],"(iii)":[266],"T":[268],"=":[269],"200\u00b0C":[270],"strong":[272],"sharp":[274],"reflection":[275],"near":[276],"25\u00b0":[277],"(in":[278],"2\u0398":[279],"Cu":[280],"K\u0391)":[281],"broad":[284],"one":[285],"around":[286],"12\u00b0":[287],"appear.":[288],"range,":[291],"peak":[293],"intensities":[294,380],"dependent.":[297],"This":[298],"analysis":[299,487],"indicates":[300],"non-homogenous":[304],"phases":[305,360],"during":[306],"structural":[308,313],"transformations.":[309],"quantify":[311,480],"evolution":[314],"upon":[315],"heating,":[316],"simulation":[318,396],"method":[319],"used.":[322],"model":[324,337],"based":[326],"on":[327],"comparison":[329],"experimental":[331,377],"calculated":[333,379],"patterns.":[335],"obtained":[339,382],"weighted":[342],"sum":[343],"different":[345],"contributions.":[346],"Each":[347],"contribution":[348,431],"corresponds":[349],"random":[352],"interstratified":[353],"phase":[354],"formed":[355],"two":[358],"end-member":[359],"(the":[361],"deintercalated":[366,421],"nacrite)":[367],"variable":[369],"proportion.":[370],"For":[371,461],"example,":[372],"fair":[374],"agreement":[375],"300\u00b0C":[384],"parameters":[387],"given":[388],"table.":[391],"result":[393],"allows":[397],"87.7%":[401],"layers":[404],"DMSO.":[408],"Contribution":[409],"Proportion":[410,419,428],"100":[414],"90":[415],"80":[416],"70":[417],"60":[418],"0":[423],"10":[424],"20":[425],"30":[426],"40":[427],"39":[432],"19":[433],"27":[434],"7":[435],"8":[436],"case":[438],"2:1":[440],"phyllosilicates,":[441],"like":[442,489],"smectites,":[443],"applications":[447],"more":[449],"complicated":[450],"due":[451],"water":[457],"stacking":[459],"faults.":[460],"molecules-clay":[464],"study,13C":[466],"1H":[468],"RMN":[469],"spectroscopies":[470],"should":[471],"provide":[472],"additional":[473],"informations":[474],"complete":[476,494],"analyses.":[478],"desintercalation":[484],"process,":[485],"chemical":[486],"techniques":[488],"CNS":[490],"HPLC":[492],"could":[493],"study.":[497]},"counts_by_year":[],"updated_date":"2026-10-25T09:29:13.331239","created_date":"2018-08-22T00:00:00"}