{"id":"https://openalex.org/W2883846574","doi":"https://doi.org/10.1055/s-0036-1591597","title":"Synthesis of (Z)-2-[(tert-Butyldimethylsilyl)oxy]-3-(phenylthio) acrylaldehyde","display_name":"Synthesis of (Z)-2-[(tert-Butyldimethylsilyl)oxy]-3-(phenylthio) acrylaldehyde","publication_year":2018,"publication_date":"2018-07-17","ids":{"openalex":"https://openalex.org/W2883846574","doi":"https://doi.org/10.1055/s-0036-1591597","mag":"2883846574"},"language":"en","primary_location":{"id":"doi:10.1055/s-0036-1591597","doi":"https://doi.org/10.1055/s-0036-1591597","is_oa":false,"landing_page_url":"https://doi.org/10.1055/s-0036-1591597","pdf_url":null,"source":{"id":"https://openalex.org/S197964166","display_name":"Synthesis","issn_l":"0039-7881","issn":["0039-7881","1437-210X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320000","host_organization_name":"Thieme Medical Publishers (Germany)","host_organization_lineage":["https://openalex.org/P4310320000"],"host_organization_lineage_names":["Thieme Medical Publishers (Germany)"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Synthesis","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5043924849","display_name":"Michael A. Harmata","orcid":"https://orcid.org/0000-0003-3894-2899","observed_orcids":["https://orcid.org/0000-0003-3894-2899"]},"institutions":[{"id":"https://openalex.org/I76835614","display_name":"University of Missouri","ror":"https://ror.org/02ymw8z06","country_code":"US","type":"education","lineage":["https://openalex.org/I76835614"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Michael Harmata","raw_affiliation_strings":["Department of Chemistry, University of Missouri-Columbia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Missouri-Columbia","institution_ids":["https://openalex.org/I76835614"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5038088467","display_name":"Michael Topinka","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I76835614","display_name":"University of Missouri","ror":"https://ror.org/02ymw8z06","country_code":"US","type":"education","lineage":["https://openalex.org/I76835614"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Michael Topinka","raw_affiliation_strings":["Department of Chemistry, University of Missouri-Columbia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Missouri-Columbia","institution_ids":["https://openalex.org/I76835614"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5038088467","https://openalex.org/A5043924849"],"corresponding_institution_ids":["https://openalex.org/I76835614"],"apc_list":null,"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":2,"citation_normalized_percentile":{"value":0.0,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":95},"biblio":{"volume":"50","issue":"22","first_page":"4476","last_page":"4482"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13859","display_name":"Organic Chemistry Synthesis Methods","score":0.9678000211715698,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13859","display_name":"Organic Chemistry Synthesis Methods","score":0.9678000211715698,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13649","display_name":"Advanced Synthetic Organic Chemistry","score":0.004999999888241291,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.004600000102072954,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/organosilicon-compounds","display_name":"organosilicon compounds","score":0.6119999885559082},{"id":"https://openalex.org/keywords/silyl-ethers","display_name":"silyl ethers","score":0.6959999799728394},{"id":"https://openalex.org/keywords/organolithium-reagents","display_name":"organolithium reagents","score":0.7149999737739563},{"id":"https://openalex.org/keywords/organosulfur-compounds","display_name":"organosulfur compounds","score":0.5730000138282776},{"id":"https://openalex.org/keywords/2-5-dimethylfuran","display_name":"2,5-dimethylfuran","score":0.828000009059906},{"id":"https://openalex.org/keywords/4-3-cycloaddition","display_name":"[4+3] cycloaddition","score":0.8379999995231628},{"id":"https://openalex.org/keywords/scandium-triflate-catalysis","display_name":"scandium triflate catalysis","score":0.8450000286102295},{"id":"https://openalex.org/keywords/ethyl-acrylate","display_name":"ethyl acrylate","score":0.7730000019073486},{"id":"https://openalex.org/keywords/ketone-synthesis","display_name":"ketone synthesis","score":0.48899999260902405}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9693361520767212},{"id":"https://openalex.org/C2778839380","wikidata":"https://www.wikidata.org/wiki/Q278540","display_name":"Alkoxide","level":3,"score":0.815009593963623},{"id":"https://openalex.org/C2777738585","wikidata":"https://www.wikidata.org/wiki/Q170744","display_name":"Ketone","level":2,"score":0.7655055522918701},{"id":"https://openalex.org/C5304478","wikidata":"https://www.wikidata.org/wiki/Q502457","display_name":"Silylation","level":3,"score":0.7021667957305908},{"id":"https://openalex.org/C2779664164","wikidata":"https://www.wikidata.org/wiki/Q898648","display_name":"Cycloaddition","level":3,"score":0.6635371446609497},{"id":"https://openalex.org/C2779989194","wikidata":"https://www.wikidata.org/wiki/Q343016","display_name":"Acrylate","level":4,"score":0.6049243807792664},{"id":"https://openalex.org/C2775856024","wikidata":"https://www.wikidata.org/wiki/Q343014","display_name":"Ethyl acrylate","level":5,"score":0.5330172181129456},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.40638267993927},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.36533862352371216},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.2036193609237671},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.06471982598304749},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.045658618211746216}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1055/s-0036-1591597","doi":"https://doi.org/10.1055/s-0036-1591597","is_oa":false,"landing_page_url":"https://doi.org/10.1055/s-0036-1591597","pdf_url":null,"source":{"id":"https://openalex.org/S197964166","display_name":"Synthesis","issn_l":"0039-7881","issn":["0039-7881","1437-210X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320000","host_organization_name":"Thieme Medical Publishers (Germany)","host_organization_lineage":["https://openalex.org/P4310320000"],"host_organization_lineage_names":["Thieme Medical Publishers (Germany)"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Synthesis","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":3,"referenced_works":["https://openalex.org/W2004328696","https://openalex.org/W2949152151","https://openalex.org/W2952549654"],"related_works":["https://openalex.org/W2004911487","https://openalex.org/W2011121517","https://openalex.org/W1995563297","https://openalex.org/W2951052781","https://openalex.org/W2122392661","https://openalex.org/W2950770755","https://openalex.org/W2396254067","https://openalex.org/W2054635273","https://openalex.org/W4237585618","https://openalex.org/W2072194379"],"abstract_inverted_index":{"The":[0,31],"title":[1,32],"compound":[2,33],"was":[3,15],"prepared":[4,16],"from":[5],"ethyl":[6],"acrylate":[7],"over":[8],"seven":[9],"steps.":[10],"En":[11],"route,":[12],"an":[13,46],"ester":[14,47],"that":[17],"could":[18],"be":[19,43],"catalytically":[20],"activated":[21],"with":[22,29,35],"Sc(OTf)3":[23],"to":[24,50,55],"undergo":[25],"a":[26,52,57],"(4+3)":[27],"cycloaddition":[28],"2,5-dimethylfuran.":[30],"reacts":[34],"organolithium":[36],"species":[37],"and":[38],"the":[39],"resultant":[40],"alkoxide":[41],"can":[42],"trapped":[44],"as":[45],"or":[48],"allowed":[49],"experience":[51],"silyl":[53],"shift":[54],"produce":[56],"highly":[58],"functionalized":[59],"ketone.":[60]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":1}],"updated_date":"2026-10-08T09:06:37.294493","created_date":"2018-08-03T00:00:00"}