{"id":"https://openalex.org/W2883732016","doi":"https://doi.org/10.1021/acs.inorgchem.8b01643","title":"Backbone Dehydrogenation in Pyrrole-Based Pincer Ligands","display_name":"Backbone Dehydrogenation in Pyrrole-Based Pincer Ligands","publication_year":2018,"publication_date":"2018-07-24","ids":{"openalex":"https://openalex.org/W2883732016","doi":"https://doi.org/10.1021/acs.inorgchem.8b01643","mag":"2883732016","pmid":"https://pubmed.ncbi.nlm.nih.gov/30040391"},"language":"en","primary_location":{"id":"doi:10.1021/acs.inorgchem.8b01643","doi":"https://doi.org/10.1021/acs.inorgchem.8b01643","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.8b01643","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/6090532","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5043359790","display_name":"V. Mahesh Krishnan","orcid":"https://orcid.org/0000-0001-9642-5908","observed_orcids":["https://orcid.org/0000-0001-9642-5908"]},"institutions":[{"id":"https://openalex.org/I45438204","display_name":"The University of Texas at San Antonio","ror":"https://ror.org/01kd65564","country_code":"US","type":"education","lineage":["https://openalex.org/I45438204"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"V. Mahesh Krishnan","raw_affiliation_strings":["Department of Chemistry, University of Texas at San Antonio (UTSA), San Antonio, Texas 78249, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Texas at San Antonio (UTSA), San Antonio, Texas 78249, United States","institution_ids":["https://openalex.org/I45438204"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5061053575","display_name":"Ian Davis","orcid":"https://orcid.org/0000-0002-1566-4972","observed_orcids":["https://orcid.org/0000-0002-1566-4972"]},"institutions":[{"id":"https://openalex.org/I45438204","display_name":"The University of Texas at San Antonio","ror":"https://ror.org/01kd65564","country_code":"US","type":"education","lineage":["https://openalex.org/I45438204"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ian Davis","raw_affiliation_strings":["Department of Chemistry, University of Texas at San Antonio (UTSA), San Antonio, Texas 78249, United States"],"raw_orcid":"https://orcid.org/0000-0002-1566-4972","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Texas at San Antonio (UTSA), San Antonio, Texas 78249, United States","institution_ids":["https://openalex.org/I45438204"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009117561","display_name":"Tessa M. Baker","orcid":"https://orcid.org/0000-0003-3637-578X","observed_orcids":["https://orcid.org/0000-0003-3637-578X"]},"institutions":[{"id":"https://openalex.org/I5388228","display_name":"University of Rochester","ror":"https://ror.org/022kthw22","country_code":"US","type":"education","lineage":["https://openalex.org/I5388228"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Tessa M. Baker","raw_affiliation_strings":["Department of Chemistry, University of Rochester, Rochester, New York 14627, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Rochester, Rochester, New York 14627, United States","institution_ids":["https://openalex.org/I5388228"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5035585136","display_name":"Daniel J. Curran","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I5388228","display_name":"University of Rochester","ror":"https://ror.org/022kthw22","country_code":"US","type":"education","lineage":["https://openalex.org/I5388228"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Daniel J. Curran","raw_affiliation_strings":["Department of Chemistry, University of Rochester, Rochester, New York 14627, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Rochester, Rochester, New York 14627, United States","institution_ids":["https://openalex.org/I5388228"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067988249","display_name":"Hadi D. Arman","orcid":"https://orcid.org/0000-0002-9084-560X","observed_orcids":["https://orcid.org/0000-0002-9084-560X"]},"institutions":[{"id":"https://openalex.org/I45438204","display_name":"The University of Texas at San Antonio","ror":"https://ror.org/01kd65564","country_code":"US","type":"education","lineage":["https://openalex.org/I45438204"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Hadi D. Arman","raw_affiliation_strings":["Department of Chemistry, University of Texas at San Antonio (UTSA), San Antonio, Texas 78249, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Texas at San Antonio (UTSA), San Antonio, Texas 78249, United States","institution_ids":["https://openalex.org/I45438204"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5075864515","display_name":"Michael L. Neidig","orcid":"https://orcid.org/0000-0002-2300-3867","observed_orcids":["https://orcid.org/0000-0002-2300-3867"]},"institutions":[{"id":"https://openalex.org/I5388228","display_name":"University of Rochester","ror":"https://ror.org/022kthw22","country_code":"US","type":"education","lineage":["https://openalex.org/I5388228"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Michael L. Neidig","raw_affiliation_strings":["Department of Chemistry, University of Rochester, Rochester, New York 14627, United States"],"raw_orcid":"https://orcid.org/0000-0002-2300-3867","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Rochester, Rochester, New York 14627, United States","institution_ids":["https://openalex.org/I5388228"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5069795151","display_name":"Aimin Liu","orcid":"https://orcid.org/0000-0002-4182-8176","observed_orcids":["https://orcid.org/0000-0002-4182-8176"]},"institutions":[{"id":"https://openalex.org/I45438204","display_name":"The University of Texas at San Antonio","ror":"https://ror.org/01kd65564","country_code":"US","type":"education","lineage":["https://openalex.org/I45438204"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Aimin Liu","raw_affiliation_strings":["Department of Chemistry, University of Texas at San Antonio (UTSA), San Antonio, Texas 78249, United States"],"raw_orcid":"https://orcid.org/0000-0002-4182-8176","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Texas at San Antonio (UTSA), San Antonio, Texas 78249, United States","institution_ids":["https://openalex.org/I45438204"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5039366242","display_name":"Zachary J. Tonzetich","orcid":"https://orcid.org/0000-0001-7010-8007","observed_orcids":["https://orcid.org/0000-0001-7010-8007"]},"institutions":[{"id":"https://openalex.org/I45438204","display_name":"The University of Texas at San Antonio","ror":"https://ror.org/01kd65564","country_code":"US","type":"education","lineage":["https://openalex.org/I45438204"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Zachary J. Tonzetich","raw_affiliation_strings":["Department of Chemistry, University of Texas at San Antonio (UTSA), San Antonio, Texas 78249, United States"],"raw_orcid":"https://orcid.org/0000-0001-7010-8007","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Texas at San Antonio (UTSA), San Antonio, Texas 78249, United States","institution_ids":["https://openalex.org/I45438204"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5039366242"],"corresponding_institution_ids":["https://openalex.org/I45438204"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.1723,"has_fulltext":false,"cited_by_count":22,"citation_normalized_percentile":{"value":0.74093737,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":98},"biblio":{"volume":"57","issue":"15","first_page":"9544","last_page":"9553"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.7821999788284302,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.7821999788284302,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.08250000327825546,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.06239999830722809,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cobalt-complexes","display_name":"cobalt complexes","score":0.6380000114440918},{"id":"https://openalex.org/keywords/nickel-complexes","display_name":"nickel complexes","score":1.0},{"id":"https://openalex.org/keywords/redox-potential","display_name":"redox potential","score":0.7129999995231628},{"id":"https://openalex.org/keywords/electron-spin-resonance","display_name":"electron spin resonance","score":0.8669999837875366},{"id":"https://openalex.org/keywords/electronic-structure","display_name":"electronic structure","score":0.546999990940094},{"id":"https://openalex.org/keywords/dft-calculations","display_name":"DFT calculations","score":0.8090000152587891}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9445482492446899},{"id":"https://openalex.org/C119889771","wikidata":"https://www.wikidata.org/wiki/Q898262","display_name":"Dehydrogenation","level":3,"score":0.85198575258255},{"id":"https://openalex.org/C2778468751","wikidata":"https://www.wikidata.org/wiki/Q1332703","display_name":"Pincer ligand","level":4,"score":0.8175668120384216},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.7387266755104065},{"id":"https://openalex.org/C201194858","wikidata":"https://www.wikidata.org/wiki/Q898238","display_name":"Steric effects","level":2,"score":0.6721583604812622},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.6700403094291687},{"id":"https://openalex.org/C2779400197","wikidata":"https://www.wikidata.org/wiki/Q242627","display_name":"Pyrrole","level":2,"score":0.5483532547950745},{"id":"https://openalex.org/C46000676","wikidata":"https://www.wikidata.org/wiki/Q804644","display_name":"Lone pair","level":3,"score":0.5135445594787598},{"id":"https://openalex.org/C2777961443","wikidata":"https://www.wikidata.org/wiki/Q106520","display_name":"Hydride","level":3,"score":0.4606831669807434},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.45135557651519775},{"id":"https://openalex.org/C91819851","wikidata":"https://www.wikidata.org/wiki/Q146889","display_name":"Pincer movement","level":3,"score":0.44693219661712646},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.295329749584198},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.2258068025112152},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.18835562467575073},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.14074334502220154},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.08726155757904053},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":4,"locations":[{"id":"doi:10.1021/acs.inorgchem.8b01643","doi":"https://doi.org/10.1021/acs.inorgchem.8b01643","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.8b01643","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:30040391","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/30040391","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"},{"id":"pmh:oai:europepmc.org:5038331","doi":null,"is_oa":false,"landing_page_url":"http://europepmc.org/pmc/articles/PMC6090532","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Text"},{"id":"pmh:oai:pubmedcentral.nih.gov:6090532","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/6090532","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Inorg Chem","raw_type":"Text"}],"best_oa_location":{"id":"pmh:oai:pubmedcentral.nih.gov:6090532","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/6090532","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Inorg Chem","raw_type":"Text"},"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1134986084","display_name":null,"funder_award_id":"R01GM108988","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G1839915149","display_name":null,"funder_award_id":"R01 GM111480","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G2408389694","display_name":null,"funder_award_id":"GM107529","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G2961846298","display_name":null,"funder_award_id":"GM108988","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G3089808211","display_name":null,"funder_award_id":"CHE-1454370","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G3545267354","display_name":"Kynurenine metabolites and depression: An in vitro and ex vivo study","funder_award_id":"R21MH107985","funder_id":"https://openalex.org/F4320337346","funder_display_name":"National Institute of Mental Health"},{"id":"https://openalex.org/G5783718059","display_name":null,"funder_award_id":"R01 GM107529","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G7785917110","display_name":null,"funder_award_id":"AX-1772","funder_id":"https://openalex.org/F4320306196","funder_display_name":"Welch Foundation"},{"id":"https://openalex.org/G845876515","display_name":null,"funder_award_id":"MH107985","funder_id":"https://openalex.org/F4320337346","funder_display_name":"National Institute of Mental Health"}],"funders":[{"id":"https://openalex.org/F4320306196","display_name":"Welch Foundation","ror":"https://ror.org/00np6vq88"},{"id":"https://openalex.org/F4320337346","display_name":"National Institute of Mental Health","ror":"https://ror.org/04xeg9z08"},{"id":"https://openalex.org/F4320337354","display_name":"National Institute of General Medical Sciences","ror":"https://ror.org/04q48ey07"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":66,"referenced_works":["https://openalex.org/W607383982","https://openalex.org/W1534219584","https://openalex.org/W1779702343","https://openalex.org/W1964088841","https://openalex.org/W1964158385","https://openalex.org/W1970326168","https://openalex.org/W1977891840","https://openalex.org/W1981368803","https://openalex.org/W1988091937","https://openalex.org/W1991771670","https://openalex.org/W1996846370","https://openalex.org/W2010763248","https://openalex.org/W2010939069","https://openalex.org/W2020102842","https://openalex.org/W2022671939","https://openalex.org/W2037906407","https://openalex.org/W2038958650","https://openalex.org/W2045894490","https://openalex.org/W2046630863","https://openalex.org/W2054149576","https://openalex.org/W2058210956","https://openalex.org/W2059205366","https://openalex.org/W2104793811","https://openalex.org/W2107055594","https://openalex.org/W2118947524","https://openalex.org/W2131350133","https://openalex.org/W2132454074","https://openalex.org/W2133156121","https://openalex.org/W2133343430","https://openalex.org/W2151220474","https://openalex.org/W2163572838","https://openalex.org/W2179158778","https://openalex.org/W2290495632","https://openalex.org/W2293920058","https://openalex.org/W2316125765","https://openalex.org/W2317355752","https://openalex.org/W2317542525","https://openalex.org/W2323613567","https://openalex.org/W2327304277","https://openalex.org/W2330948654","https://openalex.org/W2330979774","https://openalex.org/W2340760970","https://openalex.org/W2499262475","https://openalex.org/W2504509099","https://openalex.org/W2512123891","https://openalex.org/W2512854279","https://openalex.org/W2530475862","https://openalex.org/W2567162937","https://openalex.org/W2578217578","https://openalex.org/W2603617872","https://openalex.org/W2608319895","https://openalex.org/W2731177544","https://openalex.org/W2743881703","https://openalex.org/W2751525459","https://openalex.org/W2763013166","https://openalex.org/W2765643447","https://openalex.org/W2765810971","https://openalex.org/W2765838832","https://openalex.org/W2773300977","https://openalex.org/W2773992718","https://openalex.org/W2781936076","https://openalex.org/W2785462468","https://openalex.org/W2786630066","https://openalex.org/W2792858395","https://openalex.org/W2803242450","https://openalex.org/W4212871526"],"related_works":["https://openalex.org/W2802479700","https://openalex.org/W2311521065","https://openalex.org/W2789939821","https://openalex.org/W2783815941","https://openalex.org/W2901101435","https://openalex.org/W2071139478","https://openalex.org/W2321417757","https://openalex.org/W2739095113","https://openalex.org/W3012011422","https://openalex.org/W2532464779"],"abstract_inverted_index":{"Treatment":[0],"of":[1,18,25,46,51,62,74,137,159,166,187,213,231,243,273],"both":[2,84,113,128],"[CoCl(":[3,167],"t":[4,9,13,37,41,86,91,168,182],"Bu":[5,10,14,38,42,87,92,169,183],"PNP)]":[6,11],"and":[7,89,116,131,149,209,221],"[NiCl(":[8],"(":[12,40],"PNP":[15,35,52,108,233],"=":[16,44],"anion":[17,45,198],"2,5-bis((di-":[19,47],"tert":[20,48],"-butylphosphino)methyl)pyrrole)":[21],"with":[22,105,112,152,171,216],"one":[23],"equivalent":[24],"benzoquinone":[26],"affords":[27],"the":[28,63,70,75,80,106,114,129,135,138,175,188,205,214,228,232,246,260,270,274],"corresponding":[29],"chloride":[30],"complexes":[31,262],"containing":[32],"a":[33,121,156,160,195,251],"dehydrogenated":[34],"ligand,":[36,248],"dPNP":[39,43,54,118],"-butylphosphino)methylene)-2,5-dihydropyrrole).":[49],"Dehydrogenation":[50],"to":[53,59,82,103,141,146,193,204,239,265],"results":[55],"in":[56,79,124,227,245,250],"minimal":[57],"change":[58],"steric":[60],"profile":[61],"ligand":[64,215,234],"but":[65],"has":[66],"important":[67],"consequences":[68],"for":[69,127],"resulting":[71,78,249],"redox":[72,125],"potentials":[73,126],"metal":[76],"complexes,":[77],"ability":[81],"isolate":[83],"[CoH(":[85],"dPNP)]":[88,170],"[CoEt(":[90],"dPNP)],":[93],"which":[94],"are":[95,237],"more":[96,252],"challenging":[97],"(hydride)":[98],"or":[99],"not":[100],"possible":[101],"(ethyl)":[102],"prepare":[104],"parent":[107],"ligand.":[109],"Electrochemical":[110],"measurements":[111],"Co":[115,143],"Ni":[117],"species":[119],"demonstrate":[120],"substantial":[122],"shift":[123],"M(II/III)":[130],"M(II/I)":[132],"couples.":[133],"In":[134],"case":[136],"former,":[139],"oxidation":[140],"trivalent":[142],"was":[144,191],"found":[145,192],"be":[147],"reversible,":[148],"subsequent":[150],"reaction":[151],"AgSbF":[153],"6":[154],"afforded":[155],"rare":[157],"example":[158],"square-planar":[161],"Co(III)":[162],"species.":[163],"Corresponding":[164],"reduction":[165,186],"KC":[172],"8":[173],"produced":[174],"diamagnetic":[176],"Co(I)":[177,189],"species,":[178],"[Co(N":[179],"2":[180,224],")(":[181],"dPNP)].":[184],"Further":[185],"complex":[190],"generate":[194],"pincer-based":[196],"\u03c0-radical":[197],"that":[199],"demonstrated":[200],"well-resolved":[201],"EPR":[202],"features":[203],"four":[206],"hydrogen":[207],"atoms":[208],"lone":[210],"nitrogen":[211],"atom":[212],"minor":[217],"contributions":[218],"from":[219,241],"cobalt":[220],"coordinated":[222],"N":[223],".":[225],"Changes":[226],"electronic":[229,271],"character":[230],"upon":[235],"dehydrogenation":[236],"proposed":[238],"result":[240],"loss":[242],"aromaticity":[244],"pyrrole":[247],"reducing":[253],"central":[254],"amido":[255],"donor.":[256],"DFT":[257],"calculations":[258],"on":[259],"Co(II)":[261],"were":[263],"performed":[264],"shed":[266],"further":[267],"insight":[268],"into":[269],"structure":[272],"pincer":[275],"complexes.":[276]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":3},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":5}],"updated_date":"2026-10-15T10:00:46.086208","created_date":"2025-10-10T00:00:00"}