{"id":"https://openalex.org/W2883358227","doi":"https://doi.org/10.1126/science.aat5440","title":"Teaching an old carbocation new tricks: Intermolecular C\u2013H insertion reactions of vinyl cations","display_name":"Teaching an old carbocation new tricks: Intermolecular C\u2013H insertion reactions of vinyl cations","publication_year":2018,"publication_date":"2018-07-26","ids":{"openalex":"https://openalex.org/W2883358227","doi":"https://doi.org/10.1126/science.aat5440","mag":"2883358227","pmid":"https://pubmed.ncbi.nlm.nih.gov/30049877","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/6688626"},"language":"en","primary_location":{"id":"doi:10.1126/science.aat5440","doi":"https://doi.org/10.1126/science.aat5440","is_oa":false,"landing_page_url":"https://doi.org/10.1126/science.aat5440","pdf_url":null,"source":{"id":"https://openalex.org/S3880285","display_name":"Science","issn_l":"0036-8075","issn":["0036-8075","0193-4511","1095-9203"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","doyens","erih-plus","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310315823","host_organization_name":"American Association for the Advancement of Science","host_organization_lineage":["https://openalex.org/P4310315823"],"host_organization_lineage_names":["American Association for the Advancement of Science"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Science","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/6688626","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5080413657","display_name":"Stasik Popov","orcid":"https://orcid.org/0000-0002-8870-0807","observed_orcids":["https://orcid.org/0000-0002-8870-0807"]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Stasik Popov","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA"],"raw_orcid":"https://orcid.org/0000-0002-8870-0807","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA","institution_ids":["https://openalex.org/I161318765"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5014112876","display_name":"Brian Shao","orcid":"https://orcid.org/0000-0002-4259-9803","observed_orcids":["https://orcid.org/0000-0002-4259-9803"]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Brian Shao","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA"],"raw_orcid":"https://orcid.org/0000-0002-4259-9803","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA","institution_ids":["https://openalex.org/I161318765"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032620376","display_name":"Alex L. Bagdasarian","orcid":"https://orcid.org/0000-0003-2281-8068","observed_orcids":["https://orcid.org/0000-0003-2281-8068"]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Alex L. Bagdasarian","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA"],"raw_orcid":"https://orcid.org/0000-0003-2281-8068","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA","institution_ids":["https://openalex.org/I161318765"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070765490","display_name":"Tyler R. Benton","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Tyler R. Benton","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA","institution_ids":["https://openalex.org/I161318765"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101896064","display_name":"Lu-Yi Zou","orcid":"https://orcid.org/0000-0002-2875-5283","observed_orcids":["https://orcid.org/0000-0002-2875-5283"]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]},{"id":"https://openalex.org/I194450716","display_name":"Jilin University","ror":"https://ror.org/00js3aw79","country_code":"CN","type":"education","lineage":["https://openalex.org/I194450716"]}],"countries":["CN","US"],"is_corresponding":false,"raw_author_name":"Luyi Zou","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA","Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun 130023, People\u2019s Republic of China"],"raw_orcid":"https://orcid.org/0000-0002-2875-5283","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA","institution_ids":["https://openalex.org/I161318765"]},{"raw_affiliation_string":"Laboratory of Theoretical and Computational Chemistry, Institute of Theoretical Chemistry, Jilin University, Changchun 130023, People\u2019s Republic of China","institution_ids":["https://openalex.org/I194450716"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5055785990","display_name":"Zhongyue John Yang","orcid":"https://orcid.org/0000-0003-0395-6617","observed_orcids":["https://orcid.org/0000-0003-0395-6617"]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Zhongyue Yang","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA","institution_ids":["https://openalex.org/I161318765"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5042178740","display_name":"Kendall N. Houk","orcid":"https://orcid.org/0000-0002-8387-5261","observed_orcids":["https://orcid.org/0000-0002-8387-5261"]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"K. N. Houk","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA"],"raw_orcid":"https://orcid.org/0000-0002-8387-5261","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA","institution_ids":["https://openalex.org/I161318765"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5036989439","display_name":"Hosea M. Nelson","orcid":"https://orcid.org/0000-0002-4666-2793","observed_orcids":["https://orcid.org/0000-0002-4666-2793"]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Hosea M. Nelson","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA"],"raw_orcid":"https://orcid.org/0000-0002-4666-2793","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095, USA","institution_ids":["https://openalex.org/I161318765"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5036989439","https://openalex.org/A5042178740"],"corresponding_institution_ids":["https://openalex.org/I161318765"],"apc_list":null,"apc_paid":null,"fwci":7.2321,"has_fulltext":true,"cited_by_count":135,"citation_normalized_percentile":{"value":0.9896735,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":99,"max":100},"biblio":{"volume":"361","issue":"6400","first_page":"381","last_page":"387"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T14068","display_name":"Organic and Inorganic Chemical Reactions","score":0.44600000977516174,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T14068","display_name":"Organic and Inorganic Chemical Reactions","score":0.44600000977516174,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.20800000429153442,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11611","display_name":"Cyclopropane Reaction Mechanisms","score":0.08810000121593475,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/vinyl-cations","display_name":"vinyl cations","score":0.9869999885559082},{"id":"https://openalex.org/keywords/c-h-insertion","display_name":"C-H insertion","score":0.8629999756813049},{"id":"https://openalex.org/keywords/silicon-cations","display_name":"silicon cations","score":0.8040000200271606},{"id":"https://openalex.org/keywords/alkane-functionalization","display_name":"alkane functionalization","score":0.5989999771118164},{"id":"https://openalex.org/keywords/carbocation-reactivity","display_name":"carbocation reactivity","score":0.5490000247955322},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.4560000002384186}],"concepts":[{"id":"https://openalex.org/C109057382","wikidata":"https://www.wikidata.org/wiki/Q212270","display_name":"Carbocation","level":2,"score":0.9755712747573853},{"id":"https://openalex.org/C166950319","wikidata":"https://www.wikidata.org/wiki/Q245031","display_name":"Intermolecular force","level":3,"score":0.7348678708076477},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5708643198013306},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.358088880777359},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.33796340227127075},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2667365074157715},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.18572396039962769}],"mesh":[],"locations_count":6,"locations":[{"id":"doi:10.1126/science.aat5440","doi":"https://doi.org/10.1126/science.aat5440","is_oa":false,"landing_page_url":"https://doi.org/10.1126/science.aat5440","pdf_url":null,"source":{"id":"https://openalex.org/S3880285","display_name":"Science","issn_l":"0036-8075","issn":["0036-8075","0193-4511","1095-9203"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","dongbi-a","doyens","erih-plus","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310315823","host_organization_name":"American Association for the Advancement of Science","host_organization_lineage":["https://openalex.org/P4310315823"],"host_organization_lineage_names":["American Association for the Advancement of Science"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Science","raw_type":"journal-article"},{"id":"pmid:30049877","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/30049877","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Science (New York, N.Y.)","raw_type":"Journal Article"},{"id":"pmh:oai:europepmc.org:5637423","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/6688626","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"Text"},{"id":"pmh:oai:pubmedcentral.nih.gov:6688626","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/6688626","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"Science","raw_type":"Text"},{"id":"pmh:oai:authors.library.caltech.edu:110217","doi":null,"is_oa":true,"landing_page_url":"https://resolver.caltech.edu/CaltechAUTHORS:20210811-225351879","pdf_url":"https://authors.library.caltech.edu/110217/","source":{"id":"https://openalex.org/S4306402161","display_name":"CaltechAUTHORS (California Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I122411786","host_organization_name":"California Institute of Technology","host_organization_lineage":["https://openalex.org/I122411786"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Article"},{"id":"pmh:oai:escholarship.org:ark:/13030/qt8f97421d","doi":null,"is_oa":false,"landing_page_url":"https://escholarship.org/uc/item/8f97421d","pdf_url":null,"source":{"id":"https://openalex.org/S4306400115","display_name":"eScholarship (California Digital Library)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I2801248553","host_organization_name":"California Digital Library","host_organization_lineage":["https://openalex.org/I2801248553"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Science, vol 361, iss 6400","raw_type":"article"}],"best_oa_location":{"id":"pmh:oai:europepmc.org:5637423","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/6688626","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":null,"raw_type":"Text"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1455760090","display_name":null,"funder_award_id":"CHE- 1361104","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G2202643355","display_name":null,"funder_award_id":"51673164","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G3890010759","display_name":null,"funder_award_id":"1361104","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"},{"id":"https://openalex.org/G4587767063","display_name":"Experimental and Theoretical Investigations of Organic Reaction Rates and Mechanisms","funder_award_id":"1361104","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"},{"id":"https://openalex.org/G7040847368","display_name":null,"funder_award_id":"11504130","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G7130919341","display_name":"Kinetically-Persistent Carbocationsin C-H Insertion Reactions and Biomimetic Cyclization Cascades","funder_award_id":"R35GM128936","funder_id":"https://openalex.org/F4320337354","funder_display_name":"National Institute of General Medical Sciences"},{"id":"https://openalex.org/G7482864200","display_name":null,"funder_award_id":"21501169","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G9000914377","display_name":"Development and validation of a high-throughput MicroED-driven platform technology for natural product discovery","funder_award_id":"R01AT011990","funder_id":"https://openalex.org/F4320337593","funder_display_name":"National Center for Complementary and Integrative Health"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320306079","display_name":"David and Lucile Packard Foundation","ror":"https://ror.org/032atxq54"},{"id":"https://openalex.org/F4320306151","display_name":"Alfred P. Sloan Foundation","ror":"https://ror.org/052csg198"},{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320332688","display_name":"University of California, Irvine","ror":"https://ror.org/04gyf1771"},{"id":"https://openalex.org/F4320337354","display_name":"National Institute of General Medical Sciences","ror":"https://ror.org/04q48ey07"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"},{"id":"https://openalex.org/F4320337593","display_name":"National Center for Complementary and Integrative Health","ror":"https://ror.org/00190t495"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":62,"referenced_works":["https://openalex.org/W1084434155","https://openalex.org/W1484629226","https://openalex.org/W1536714494","https://openalex.org/W1897874172","https://openalex.org/W1969624425","https://openalex.org/W1971035670","https://openalex.org/W1972987648","https://openalex.org/W1974093531","https://openalex.org/W1974522628","https://openalex.org/W1976565443","https://openalex.org/W1986366112","https://openalex.org/W1996337464","https://openalex.org/W2004165521","https://openalex.org/W2007254623","https://openalex.org/W2007626157","https://openalex.org/W2013402008","https://openalex.org/W2020075120","https://openalex.org/W2024607144","https://openalex.org/W2027262205","https://openalex.org/W2039836847","https://openalex.org/W2046412723","https://openalex.org/W2049583796","https://openalex.org/W2057390396","https://openalex.org/W2058363175","https://openalex.org/W2062006076","https://openalex.org/W2064193117","https://openalex.org/W2066735593","https://openalex.org/W2066950857","https://openalex.org/W2067297910","https://openalex.org/W2073393693","https://openalex.org/W2079361308","https://openalex.org/W2081232073","https://openalex.org/W2081500791","https://openalex.org/W2086489367","https://openalex.org/W2087818437","https://openalex.org/W2092743359","https://openalex.org/W2094642658","https://openalex.org/W2114952031","https://openalex.org/W2116257507","https://openalex.org/W2119714092","https://openalex.org/W2135737651","https://openalex.org/W2150264254","https://openalex.org/W2150697053","https://openalex.org/W2156154591","https://openalex.org/W2156402921","https://openalex.org/W2309554254","https://openalex.org/W2321197587","https://openalex.org/W2323934468","https://openalex.org/W2327912449","https://openalex.org/W2329034474","https://openalex.org/W2336071343","https://openalex.org/W2483185930","https://openalex.org/W2562267179","https://openalex.org/W2563188391","https://openalex.org/W2584118507","https://openalex.org/W2603593421","https://openalex.org/W2618176530","https://openalex.org/W2741253869","https://openalex.org/W2949096956","https://openalex.org/W2950000457","https://openalex.org/W2950708584","https://openalex.org/W2951759626"],"related_works":["https://openalex.org/W2945952896","https://openalex.org/W3088499326","https://openalex.org/W4229702689","https://openalex.org/W2884967919","https://openalex.org/W4404164892","https://openalex.org/W2081723437","https://openalex.org/W2059812090","https://openalex.org/W4321611133","https://openalex.org/W1964767533","https://openalex.org/W4311887673"],"abstract_inverted_index":{"Silicon":[0],"smooths":[1],"the":[2,25,70,102],"way":[3],"to":[4,35],"vinyl":[5,78],"cations":[6,30,53,79],"Saturated":[7],"carbon":[8,26],"centers":[9],"often":[10],"undergo":[11],"substitution":[12],"reactions":[13,94],"by":[14,72],"initial":[15],"cleavage":[16],"of":[17],"a":[18],"carbon-halogen":[19],"or":[20],"carbon-oxygen":[21],"bond,":[22],"which":[23],"leaves":[24],"positively":[27],"charged.":[28],"Analogous":[29],"have":[31],"proven":[32],"much":[33],"harder":[34],"access":[36],"from":[37],"vinylic":[38,64],"carbons":[39,65],"that":[40,51,92,99],"are":[41],"engaged":[42],"in":[43],"double":[44],"bonds.":[45],"Popov":[46],"et":[47],"al.":[48],"now":[49],"show":[50],"silicon":[52],"paired":[54],"with":[55,81],"noncoordinating":[56],"anions":[57],"can":[58],"pull":[59],"triflate":[60],"groups":[61],"off":[62],"such":[63],"under":[66],"ambient":[67],"conditions":[68],"(see":[69],"Perspective":[71],"Kennedy":[73],"and":[74,88],"Klumpp).":[75],"The":[76],"resultant":[77],"react":[80],"simple":[82],"alkanes":[83],"through":[84,96],"C\u2013H":[85],"insertion.":[86],"Theoretical":[87],"mechanistic":[89],"studies":[90],"suggest":[91],"these":[93],"proceed":[95],"nonclassical":[97],"pathways":[98],"bifurcate":[100],"after":[101],"transition":[103],"state.":[104],"Science":[105],",":[106],"this":[107],"issue":[108],"p.":[109,114],"381":[110],";":[111],"see":[112],"also":[113],"331":[115]},"counts_by_year":[{"year":2026,"cited_by_count":11},{"year":2025,"cited_by_count":13},{"year":2024,"cited_by_count":17},{"year":2023,"cited_by_count":15},{"year":2022,"cited_by_count":12},{"year":2021,"cited_by_count":16},{"year":2020,"cited_by_count":17},{"year":2019,"cited_by_count":25},{"year":2018,"cited_by_count":9}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2018-08-03T00:00:00"}