{"id":"https://openalex.org/W2852595232","doi":"https://doi.org/10.1063/1.5028524","title":"Polyelectrolyte complex coacervation: Effects of concentration asymmetry","display_name":"Polyelectrolyte complex coacervation: Effects of concentration asymmetry","publication_year":2018,"publication_date":"2018-07-06","ids":{"openalex":"https://openalex.org/W2852595232","doi":"https://doi.org/10.1063/1.5028524","mag":"2852595232","pmid":"https://pubmed.ncbi.nlm.nih.gov/30384721"},"language":"en","primary_location":{"id":"doi:10.1063/1.5028524","doi":"https://doi.org/10.1063/1.5028524","is_oa":true,"landing_page_url":"https://doi.org/10.1063/1.5028524","pdf_url":"https://aip.scitation.org/doi/pdf/10.1063/1.5028524","source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"bronze","oa_url":"https://aip.scitation.org/doi/pdf/10.1063/1.5028524","any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5029804956","display_name":"Pengfei Zhang","orcid":"https://orcid.org/0000-0002-4226-1394","observed_orcids":["https://orcid.org/0000-0002-4226-1394","https://orcid.org/0000-0003-2914-7332"]},"institutions":[{"id":"https://openalex.org/I122411786","display_name":"California Institute of Technology","ror":"https://ror.org/05dxps055","country_code":"US","type":"education","lineage":["https://openalex.org/I122411786"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Pengfei Zhang","raw_affiliation_strings":["Division of Chemistry and Chemical Engineering, California Institute of Technology 1 , Pasadena, California 91125, USA"],"raw_orcid":"https://orcid.org/0000-0002-4226-1394","affiliations":[{"raw_affiliation_string":"Division of Chemistry and Chemical Engineering, California Institute of Technology 1 , Pasadena, California 91125, USA","institution_ids":["https://openalex.org/I122411786"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000060200","display_name":"Nayef M. Alsaifi","orcid":"https://orcid.org/0000-0003-3232-6411","observed_orcids":["https://orcid.org/0000-0003-3232-6411"]},"institutions":[{"id":"https://openalex.org/I122411786","display_name":"California Institute of Technology","ror":"https://ror.org/05dxps055","country_code":"US","type":"education","lineage":["https://openalex.org/I122411786"]},{"id":"https://openalex.org/I134085113","display_name":"King Fahd University of Petroleum and Minerals","ror":"https://ror.org/03yez3163","country_code":"SA","type":"education","lineage":["https://openalex.org/I134085113"]}],"countries":["SA","US"],"is_corresponding":false,"raw_author_name":"Nayef M. Alsaifi","raw_affiliation_strings":["Chemical Engineering Department, King Fahd University of Petroleum and Minerals 2 , Dhahran, Saudi Arabia","Division of Chemistry and Chemical Engineering, California Institute of Technology 1 , Pasadena, California 91125, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Chemical Engineering Department, King Fahd University of Petroleum and Minerals 2 , Dhahran, Saudi Arabia","institution_ids":["https://openalex.org/I134085113"]},{"raw_affiliation_string":"Division of Chemistry and Chemical Engineering, California Institute of Technology 1 , Pasadena, California 91125, USA","institution_ids":["https://openalex.org/I122411786"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5088942752","display_name":"Jianzhong Wu","orcid":"https://orcid.org/0000-0002-4582-5941","observed_orcids":["https://orcid.org/0000-0002-4582-5941"]},"institutions":[{"id":"https://openalex.org/I103635307","display_name":"University of California, Riverside","ror":"https://ror.org/03nawhv43","country_code":"US","type":"education","lineage":["https://openalex.org/I103635307"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Jianzhong Wu","raw_affiliation_strings":["Department of Chemical and Environmental Engineering, University of California 3 , Riverside, California 92521, USA"],"raw_orcid":"https://orcid.org/0000-0002-4582-5941","affiliations":[{"raw_affiliation_string":"Department of Chemical and Environmental Engineering, University of California 3 , Riverside, California 92521, USA","institution_ids":["https://openalex.org/I103635307"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5015108167","display_name":"Zhen\u2010Gang Wang","orcid":"https://orcid.org/0000-0002-3361-6114","observed_orcids":["https://orcid.org/0000-0002-3361-6114","https://orcid.org/0009-0004-5482-8732"]},"institutions":[{"id":"https://openalex.org/I122411786","display_name":"California Institute of Technology","ror":"https://ror.org/05dxps055","country_code":"US","type":"education","lineage":["https://openalex.org/I122411786"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Zhen-Gang Wang","raw_affiliation_strings":["Division of Chemistry and Chemical Engineering, California Institute of Technology 1 , Pasadena, California 91125, USA"],"raw_orcid":"https://orcid.org/0000-0002-3361-6114","affiliations":[{"raw_affiliation_string":"Division of Chemistry and Chemical Engineering, California Institute of Technology 1 , Pasadena, California 91125, USA","institution_ids":["https://openalex.org/I122411786"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":6.8633,"has_fulltext":true,"cited_by_count":110,"citation_normalized_percentile":{"value":0.98071348,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":89,"max":100},"biblio":{"volume":"149","issue":"16","first_page":"163303","last_page":"163303"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12274","display_name":"Electrostatics and Colloid Interactions","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12274","display_name":"Electrostatics and Colloid Interactions","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11936","display_name":"Chemical and Physical Properties in Aqueous Solutions","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1506","display_name":"Filtration and Separation"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10721","display_name":"Surfactants and Colloidal Systems","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/liquid-state-theory","display_name":"liquid state theory","score":0.824999988079071},{"id":"https://openalex.org/keywords/phase-separation","display_name":"phase separation","score":0.6669999957084656},{"id":"https://openalex.org/keywords/phase-diagram","display_name":"phase diagram","score":0.7139999866485596},{"id":"https://openalex.org/keywords/galvani-potential","display_name":"Galvani potential","score":0.8289999961853027},{"id":"https://openalex.org/keywords/bjerrum-length","display_name":"Bjerrum length","score":0.8999999761581421},{"id":"https://openalex.org/keywords/small-ions","display_name":"small ions","score":0.4440000057220459},{"id":"https://openalex.org/keywords/translational-entropy","display_name":"translational entropy","score":0.7699999809265137},{"id":"https://openalex.org/keywords/charge-neutrality","display_name":"charge neutrality","score":0.9509999752044678},{"id":"https://openalex.org/keywords/coacervation","display_name":"coacervation","score":0.4569999873638153}],"concepts":[{"id":"https://openalex.org/C83029808","wikidata":"https://www.wikidata.org/wiki/Q1154463","display_name":"Coacervate","level":2,"score":0.9500775337219238},{"id":"https://openalex.org/C38976095","wikidata":"https://www.wikidata.org/wiki/Q752641","display_name":"Asymmetry","level":2,"score":0.7323806285858154},{"id":"https://openalex.org/C153356533","wikidata":"https://www.wikidata.org/wiki/Q901016","display_name":"Polyelectrolyte","level":3,"score":0.7280253171920776},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.3546600639820099},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3210522532463074},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.24343600869178772},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.19168856739997864},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.08341950178146362},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.08093434572219849},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1063/1.5028524","doi":"https://doi.org/10.1063/1.5028524","is_oa":true,"landing_page_url":"https://doi.org/10.1063/1.5028524","pdf_url":"https://aip.scitation.org/doi/pdf/10.1063/1.5028524","source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},{"id":"pmid:30384721","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/30384721","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of chemical physics","raw_type":"Journal Article"},{"id":"pmh:oai:authors.library.caltech.edu:87604","doi":null,"is_oa":false,"landing_page_url":"https://resolver.caltech.edu/CaltechAUTHORS:20180706-133157000","pdf_url":null,"source":{"id":"https://openalex.org/S4306402161","display_name":"CaltechAUTHORS (California Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I122411786","host_organization_name":"California Institute of Technology","host_organization_lineage":["https://openalex.org/I122411786"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Article"}],"best_oa_location":{"id":"doi:10.1063/1.5028524","doi":"https://doi.org/10.1063/1.5028524","is_oa":true,"landing_page_url":"https://doi.org/10.1063/1.5028524","pdf_url":"https://aip.scitation.org/doi/pdf/10.1063/1.5028524","source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G5245795092","display_name":null,"funder_award_id":"NSF-CBET-8200852353","funder_id":"https://openalex.org/F4320306076","funder_display_name":"National Science Foundation"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320309398","display_name":"California Institute of Technology","ror":"https://ror.org/05dxps055"},{"id":"https://openalex.org/F4320322323","display_name":"King Fahd University of Petroleum and Minerals","ror":"https://ror.org/03yez3163"},{"id":"https://openalex.org/F4320337390","display_name":"Division of Chemical, Bioengineering, Environmental, and Transport Systems","ror":"https://ror.org/0471zv972"}],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2852595232.pdf","grobid_xml":"https://content.openalex.org/works/W2852595232.grobid-xml"},"referenced_works_count":72,"referenced_works":["https://openalex.org/W1495680657","https://openalex.org/W1570946407","https://openalex.org/W1601171111","https://openalex.org/W1669004436","https://openalex.org/W1739629851","https://openalex.org/W1943197010","https://openalex.org/W1964996781","https://openalex.org/W1965592125","https://openalex.org/W1973743903","https://openalex.org/W1986202665","https://openalex.org/W1987328734","https://openalex.org/W1990380551","https://openalex.org/W1991572399","https://openalex.org/W2000037505","https://openalex.org/W2005229258","https://openalex.org/W2006712306","https://openalex.org/W2010632420","https://openalex.org/W2015903310","https://openalex.org/W2022138623","https://openalex.org/W2022283214","https://openalex.org/W2028602090","https://openalex.org/W2036203264","https://openalex.org/W2037194041","https://openalex.org/W2037929372","https://openalex.org/W2038494990","https://openalex.org/W2040405251","https://openalex.org/W2046377044","https://openalex.org/W2048478116","https://openalex.org/W2066195845","https://openalex.org/W2068318214","https://openalex.org/W2073841669","https://openalex.org/W2074113536","https://openalex.org/W2076770928","https://openalex.org/W2078041358","https://openalex.org/W2079203105","https://openalex.org/W2081697714","https://openalex.org/W2084041890","https://openalex.org/W2087569661","https://openalex.org/W2090227171","https://openalex.org/W2095350613","https://openalex.org/W2111764017","https://openalex.org/W2112597123","https://openalex.org/W2116103155","https://openalex.org/W2117208350","https://openalex.org/W2127374274","https://openalex.org/W2139851370","https://openalex.org/W2144633240","https://openalex.org/W2157997035","https://openalex.org/W2159044575","https://openalex.org/W2167589723","https://openalex.org/W2259596804","https://openalex.org/W2294282556","https://openalex.org/W2302551836","https://openalex.org/W2312232330","https://openalex.org/W2320321388","https://openalex.org/W2321501796","https://openalex.org/W2324423543","https://openalex.org/W2335336849","https://openalex.org/W2343295012","https://openalex.org/W2548037804","https://openalex.org/W2562137968","https://openalex.org/W2566070701","https://openalex.org/W2590404863","https://openalex.org/W2601253845","https://openalex.org/W2732832733","https://openalex.org/W2745595887","https://openalex.org/W2755445391","https://openalex.org/W2765863229","https://openalex.org/W2789293763","https://openalex.org/W2795682970","https://openalex.org/W4206379292","https://openalex.org/W4211028110"],"related_works":["https://openalex.org/W4312082370","https://openalex.org/W2786899008","https://openalex.org/W2037194041","https://openalex.org/W1973743903","https://openalex.org/W4378173225","https://openalex.org/W1985431287","https://openalex.org/W4388860226","https://openalex.org/W4280624229","https://openalex.org/W3186778229","https://openalex.org/W2075214092"],"abstract_inverted_index":{"Using":[0],"a":[1,20,43,71],"simple":[2],"liquid-state":[3],"theory,":[4],"we":[5,58],"study":[6],"the":[7,28,31,61,95,98,112,118,137,146,149,153,158,167,185,190,194,197,202],"phase":[8,23,48,100,134],"behaviors":[9],"of":[10,13,27,30,80,90,124,148,152,157,173,184,193],"concentration-asymmetric":[11],"mixtures":[12],"polycation":[14],"and":[15,38,52,83,117,140,144,160,166,201],"polyanion":[16],"solutions.":[17],"We":[18,93,130,178],"construct":[19,131],"three-dimensional":[21],"(3D)":[22],"diagram":[24,49,101],"in":[25,97,136,163,182],"terms":[26,183],"concentrations":[29],"three":[32,63,103,132],"independent":[33],"charged":[34],"components:":[35],"polycation,":[36],"polyanion,":[37],"small":[39,81,91,195],"cation":[40],"(\u03c1p+\u2212\u03c1p\u2212\u2212\u03c1+),":[41],"for":[42,204],"given":[44],"Bjerrum":[45],"length.":[46],"This":[47],"yields":[50],"rich":[51],"complex":[53],"phase-separation":[54],"scenarios.":[55],"To":[56],"illustrate,":[57],"sequentially":[59],"examine":[60,145],"following":[62],"systems":[64],"that":[65],"are":[66],"directly":[67],"relevant":[68],"to":[69,128],"experiments:":[70],"symmetric":[72],"mixture,":[73],"an":[74,84],"asymmetric":[75,85],"mixture":[76,86],"with":[77,87],"one":[78],"type":[79],"ions,":[82,196],"both":[88,125],"types":[89],"ions.":[92],"re-express":[94],"information":[96],"3D":[99],"using":[102],"experimentally":[104],"more":[105],"easily":[106],"controllable":[107],"parameters\u2014the":[108],"asymmetry":[109],"factor":[110],"r,":[111],"initial":[113,119],"extra-salt":[114],"concentration":[115,122,156],"\u03c1s,0,":[116],"polyelectrolyte":[120],"(PE)":[121],"\u03c1p,0":[123],"solutions":[126],"prior":[127],"mixing.":[129],"reduced":[133],"diagrams":[135],"\u03c1p,0\u2212r,":[138],"r\u2212\u03c1s,0,":[139],"\u03c1s,0\u2212\u03c1p,0":[141],"planes,":[142],"respectively,":[143],"evolution":[147],"volume":[150],"fraction":[151],"coexisting":[154],"phases,":[155],"PE":[159],"small-ion":[161],"species":[162],"each":[164],"phase,":[165],"Galvani":[168],"potential":[169],"\u03a8G,":[170],"as":[171],"functions":[172],"these":[174],"experimental":[175],"controlling":[176],"parameters.":[177],"rationalize":[179],"our":[180],"findings":[181],"key":[186],"thermodynamic":[187],"factors,":[188],"namely,":[189],"translational":[191],"entropy":[192],"electrostatic":[198],"correlation":[199],"energy,":[200],"requirement":[203],"charge":[205],"neutrality.":[206]},"counts_by_year":[{"year":2026,"cited_by_count":18},{"year":2025,"cited_by_count":10},{"year":2024,"cited_by_count":11},{"year":2023,"cited_by_count":13},{"year":2022,"cited_by_count":19},{"year":2021,"cited_by_count":16},{"year":2020,"cited_by_count":12},{"year":2019,"cited_by_count":10},{"year":2018,"cited_by_count":1}],"updated_date":"2026-10-22T09:42:04.148104","created_date":"2018-07-19T00:00:00"}