{"id":"https://openalex.org/W2809735358","doi":"https://doi.org/10.1021/acs.organomet.8b00064","title":"Diversified Aggregation States of Phospholyl Lithiums","display_name":"Diversified Aggregation States of Phospholyl Lithiums","publication_year":2018,"publication_date":"2018-06-25","ids":{"openalex":"https://openalex.org/W2809735358","doi":"https://doi.org/10.1021/acs.organomet.8b00064","mag":"2809735358"},"language":"en","primary_location":{"id":"doi:10.1021/acs.organomet.8b00064","doi":"https://doi.org/10.1021/acs.organomet.8b00064","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.8b00064","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5101642361","display_name":"Shanshan Du","orcid":"https://orcid.org/0000-0001-7655-9765","observed_orcids":["https://orcid.org/0000-0001-7655-9765"]},"institutions":[{"id":"https://openalex.org/I20231570","display_name":"Peking University","ror":"https://ror.org/02v51f717","country_code":"CN","type":"education","lineage":["https://openalex.org/I20231570"]},{"id":"https://openalex.org/I4210116048","display_name":"Beijing National Laboratory for Molecular Sciences","ror":"https://ror.org/02601yx74","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210116048"]},{"id":"https://openalex.org/I4405271629","display_name":"Key Laboratory of Bioorganic Chemistry and Molecular Engineering, Ministry of Education","ror":"https://ror.org/02rmypw07","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4405271629"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Shanshan Du","raw_affiliation_strings":["Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, People\u2019s Republic of China","institution_ids":["https://openalex.org/I20231570","https://openalex.org/I4210116048","https://openalex.org/I4405271629"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029642484","display_name":"Wen\u2010Xiong Zhang","orcid":"https://orcid.org/0000-0003-0744-2832","observed_orcids":["https://orcid.org/0000-0003-0744-2832"]},"institutions":[{"id":"https://openalex.org/I20231570","display_name":"Peking University","ror":"https://ror.org/02v51f717","country_code":"CN","type":"education","lineage":["https://openalex.org/I20231570"]},{"id":"https://openalex.org/I205237279","display_name":"Nankai University","ror":"https://ror.org/01y1kjr75","country_code":"CN","type":"education","lineage":["https://openalex.org/I205237279"]},{"id":"https://openalex.org/I4210116048","display_name":"Beijing National Laboratory for Molecular Sciences","ror":"https://ror.org/02601yx74","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210116048"]},{"id":"https://openalex.org/I4405271629","display_name":"Key Laboratory of Bioorganic Chemistry and Molecular Engineering, Ministry of Education","ror":"https://ror.org/02rmypw07","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4405271629"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Wen-Xiong Zhang","raw_affiliation_strings":["Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, People\u2019s Republic of China","State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, People\u2019s Republic of China"],"raw_orcid":"https://orcid.org/0000-0003-0744-2832","affiliations":[{"raw_affiliation_string":"Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, People\u2019s Republic of China","institution_ids":["https://openalex.org/I20231570","https://openalex.org/I4210116048","https://openalex.org/I4405271629"]},{"raw_affiliation_string":"State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, People\u2019s Republic of China","institution_ids":["https://openalex.org/I205237279"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5100652045","display_name":"Zhenfeng Xi","orcid":"https://orcid.org/0000-0003-1124-5380","observed_orcids":["https://orcid.org/0000-0003-1124-5380"]},"institutions":[{"id":"https://openalex.org/I20231570","display_name":"Peking University","ror":"https://ror.org/02v51f717","country_code":"CN","type":"education","lineage":["https://openalex.org/I20231570"]},{"id":"https://openalex.org/I4210116048","display_name":"Beijing National Laboratory for Molecular Sciences","ror":"https://ror.org/02601yx74","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4210116048"]},{"id":"https://openalex.org/I4405271629","display_name":"Key Laboratory of Bioorganic Chemistry and Molecular Engineering, Ministry of Education","ror":"https://ror.org/02rmypw07","country_code":"CN","type":"facility","lineage":["https://openalex.org/I4405271629"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhenfeng Xi","raw_affiliation_strings":["Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, People\u2019s Republic of China"],"raw_orcid":"https://orcid.org/0000-0003-1124-5380","affiliations":[{"raw_affiliation_string":"Beijing National Laboratory for Molecular Sciences (BNLMS), Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, People\u2019s Republic of China","institution_ids":["https://openalex.org/I20231570","https://openalex.org/I4210116048","https://openalex.org/I4405271629"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5029642484"],"corresponding_institution_ids":["https://openalex.org/I20231570","https://openalex.org/I205237279","https://openalex.org/I4210116048","https://openalex.org/I4405271629"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.2441,"has_fulltext":false,"cited_by_count":22,"citation_normalized_percentile":{"value":0.76591042,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"37","issue":"13","first_page":"2018","last_page":"2022"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.6977999806404114,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.6977999806404114,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.11259999871253967,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.06939999759197235,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/state-of-aggregation","display_name":"aggregation state","score":0.9279999732971191},{"id":"https://openalex.org/keywords/solid-state-structure","display_name":"solid-state structure","score":0.777999997138977},{"id":"https://openalex.org/keywords/coordination-polymers","display_name":"coordination polymers","score":0.8180000185966492},{"id":"https://openalex.org/keywords/dimeric-structure","display_name":"dimeric structure","score":0.5690000057220459},{"id":"https://openalex.org/keywords/monomeric-structure","display_name":"monomeric structure","score":0.871999979019165},{"id":"https://openalex.org/keywords/12-crown-4","display_name":"12-crown-4","score":0.9039999842643738},{"id":"https://openalex.org/keywords/chelation","display_name":"chelation","score":0.625},{"id":"https://openalex.org/keywords/substituent-effects","display_name":"substituent effects","score":0.6650000214576721},{"id":"https://openalex.org/keywords/phosphine-ligands","display_name":"phosphine ligands","score":0.6200000047683716}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9615082740783691},{"id":"https://openalex.org/C166940927","wikidata":"https://www.wikidata.org/wiki/Q178827","display_name":"Monomer","level":3,"score":0.7470167875289917},{"id":"https://openalex.org/C2779546866","wikidata":"https://www.wikidata.org/wiki/Q531306","display_name":"Dimer","level":2,"score":0.7416120767593384},{"id":"https://openalex.org/C2778541603","wikidata":"https://www.wikidata.org/wiki/Q152763","display_name":"Lithium (medication)","level":2,"score":0.5150604248046875},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3593079447746277},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3366513252258301},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.21262341737747192},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.12013405561447144},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C134018914","wikidata":"https://www.wikidata.org/wiki/Q162606","display_name":"Endocrinology","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.organomet.8b00064","doi":"https://doi.org/10.1021/acs.organomet.8b00064","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.8b00064","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G6111847204","display_name":null,"funder_award_id":"21725201","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G7445656749","display_name":null,"funder_award_id":"21572005","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":63,"referenced_works":["https://openalex.org/W942313901","https://openalex.org/W1542490233","https://openalex.org/W1543800107","https://openalex.org/W1965094523","https://openalex.org/W1969657397","https://openalex.org/W1981836794","https://openalex.org/W1988777595","https://openalex.org/W1990975129","https://openalex.org/W1994431233","https://openalex.org/W1994766712","https://openalex.org/W1996551682","https://openalex.org/W2000519300","https://openalex.org/W2007630437","https://openalex.org/W2012574678","https://openalex.org/W2025238416","https://openalex.org/W2027322234","https://openalex.org/W2032763738","https://openalex.org/W2038871458","https://openalex.org/W2044485440","https://openalex.org/W2045990695","https://openalex.org/W2046298939","https://openalex.org/W2048885640","https://openalex.org/W2048990493","https://openalex.org/W2058683842","https://openalex.org/W2059205366","https://openalex.org/W2059688190","https://openalex.org/W2060517082","https://openalex.org/W2061851313","https://openalex.org/W2062039189","https://openalex.org/W2064661036","https://openalex.org/W2067022916","https://openalex.org/W2067290420","https://openalex.org/W2067656763","https://openalex.org/W2068532292","https://openalex.org/W2115641172","https://openalex.org/W2118112288","https://openalex.org/W2119040714","https://openalex.org/W2126982282","https://openalex.org/W2139881842","https://openalex.org/W2148856425","https://openalex.org/W2153709401","https://openalex.org/W2154263290","https://openalex.org/W2156415512","https://openalex.org/W2159308679","https://openalex.org/W2165528549","https://openalex.org/W2167101520","https://openalex.org/W2168693083","https://openalex.org/W2324166434","https://openalex.org/W2331465554","https://openalex.org/W2422729348","https://openalex.org/W2489381240","https://openalex.org/W2500320488","https://openalex.org/W2531336356","https://openalex.org/W2533361180","https://openalex.org/W2579328165","https://openalex.org/W2583489514","https://openalex.org/W2612089951","https://openalex.org/W2762643678","https://openalex.org/W2949374789","https://openalex.org/W2951415722","https://openalex.org/W2951974881","https://openalex.org/W2952969764","https://openalex.org/W2970108190"],"related_works":["https://openalex.org/W2074677312","https://openalex.org/W1967247005","https://openalex.org/W2110013361","https://openalex.org/W2315029993","https://openalex.org/W19953774","https://openalex.org/W1985050358","https://openalex.org/W2012966465","https://openalex.org/W1983131361","https://openalex.org/W2042693311","https://openalex.org/W1970538710"],"abstract_inverted_index":{"Studies":[0],"on":[1],"the":[2,29,70,116],"aggregation":[3],"states":[4],"of":[5,9,32,72],"phospholyl":[6,33,81],"lithiums":[7,34,82],"are":[8,119],"great":[10],"importance":[11],"and":[12,76],"demand":[13],"due":[14],"to":[15,85],"their":[16],"applications":[17],"as":[18],"ligands":[19],"in":[20,69],"coordination":[21,77],"chemistry.":[22],"In":[23],"this":[24],"paper,":[25],"we":[26],"report":[27],"that":[28],"solid-state":[30],"structures":[31,87],"with":[35],"different":[36],"substituents":[37],"(":[38,88],"2a,":[39],"b,":[40,50],"R":[41,45,51,55,60,63,90,94,99,103,108,111],"1":[42,52,61,91,100,109],"=":[43,47,53,57,62,65,92,96,101,105,110,113],"Ph,":[44,93],"2":[46,56,64,95,104,112],"TMS;":[48,58,97,106],"3a,":[49],"Me,":[54,102],"4,":[59],"Et)":[66,114],"could":[67],"be":[68],"form":[71],"a":[73],"monomer,":[74],"dimer,":[75],"polymer,":[78],"respectively.":[79],"These":[80],"can":[83],"change":[84],"monomeric":[86],"5,":[89],"6,":[98],"7,":[107],"when":[115],"lithium":[117],"cations":[118],"chelated":[120],"by":[121],"12-crown-4.":[122]},"counts_by_year":[{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":4},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":9},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2018-07-10T00:00:00"}
