{"id":"https://openalex.org/W2806317153","doi":"https://doi.org/10.1021/acs.organomet.8b00294","title":"Planar and Bent BN-Embedded p-Quinodimethanes Synthesized by Transmetalation of Bis(trimethylsilyl)-1,4-dihydropyrazines with Chloroborane","display_name":"Planar and Bent BN-Embedded p-Quinodimethanes Synthesized by Transmetalation of Bis(trimethylsilyl)-1,4-dihydropyrazines with Chloroborane","publication_year":2018,"publication_date":"2018-06-06","ids":{"openalex":"https://openalex.org/W2806317153","doi":"https://doi.org/10.1021/acs.organomet.8b00294","mag":"2806317153"},"language":"en","primary_location":{"id":"doi:10.1021/acs.organomet.8b00294","doi":"https://doi.org/10.1021/acs.organomet.8b00294","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.8b00294","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5110757303","display_name":"Mao Noguchi","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I96679780","display_name":"Chuo University","ror":"https://ror.org/03qvqb743","country_code":"JP","type":"education","lineage":["https://openalex.org/I96679780"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Mao Noguchi","raw_affiliation_strings":["Department of Applied Chemistry, Graduate School of Science and Engineering, Chuo University, 1-23-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Chemistry, Graduate School of Science and Engineering, Chuo University, 1-23-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan","institution_ids":["https://openalex.org/I96679780"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5050312260","display_name":"Katsunori Suzuki","orcid":"https://orcid.org/0000-0002-7971-5863","observed_orcids":["https://orcid.org/0000-0002-7971-5863"]},"institutions":[{"id":"https://openalex.org/I60134161","display_name":"Nagoya University","ror":"https://ror.org/04chrp450","country_code":"JP","type":"education","lineage":["https://openalex.org/I60134161"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Katsunori Suzuki","raw_affiliation_strings":["Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan"],"raw_orcid":"https://orcid.org/0000-0002-7971-5863","affiliations":[{"raw_affiliation_string":"Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan","institution_ids":["https://openalex.org/I60134161"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062888859","display_name":"Jun Kobayashi","orcid":"https://orcid.org/0000-0003-2798-1809","observed_orcids":["https://orcid.org/0000-0003-2798-1809"]},"institutions":[{"id":"https://openalex.org/I96679780","display_name":"Chuo University","ror":"https://ror.org/03qvqb743","country_code":"JP","type":"education","lineage":["https://openalex.org/I96679780"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Jun Kobayashi","raw_affiliation_strings":["Department of Applied Chemistry, Graduate School of Science and Engineering, Chuo University, 1-23-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Chemistry, Graduate School of Science and Engineering, Chuo University, 1-23-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan","institution_ids":["https://openalex.org/I96679780"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5017252681","display_name":"Taiga Yurino","orcid":"https://orcid.org/0000-0002-4158-3463","observed_orcids":["https://orcid.org/0000-0002-4158-3463"]},"institutions":[{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Taiga Yurino","raw_affiliation_strings":["Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan","institution_ids":["https://openalex.org/I98285908"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028694488","display_name":"Hayato Tsurugi","orcid":"https://orcid.org/0000-0003-2942-7705","observed_orcids":["https://orcid.org/0000-0003-2942-7705"]},"institutions":[{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Hayato Tsurugi","raw_affiliation_strings":["Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan"],"raw_orcid":"https://orcid.org/0000-0003-2942-7705","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan","institution_ids":["https://openalex.org/I98285908"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029903238","display_name":"Kazushi Mashima","orcid":"https://orcid.org/0000-0002-1316-2995","observed_orcids":["https://orcid.org/0000-0002-1316-2995"]},"institutions":[{"id":"https://openalex.org/I98285908","display_name":"The University of Osaka","ror":"https://ror.org/035t8zc32","country_code":"JP","type":"education","lineage":["https://openalex.org/I98285908"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Kazushi Mashima","raw_affiliation_strings":["Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan"],"raw_orcid":"https://orcid.org/0000-0002-1316-2995","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Osaka 560-8531, Japan","institution_ids":["https://openalex.org/I98285908"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5089502268","display_name":"Makoto Yamashita","orcid":"https://orcid.org/0000-0002-3665-5311","observed_orcids":["https://orcid.org/0000-0002-3665-5311"]},"institutions":[{"id":"https://openalex.org/I60134161","display_name":"Nagoya University","ror":"https://ror.org/04chrp450","country_code":"JP","type":"education","lineage":["https://openalex.org/I60134161"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Makoto Yamashita","raw_affiliation_strings":["Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan"],"raw_orcid":"https://orcid.org/0000-0002-3665-5311","affiliations":[{"raw_affiliation_string":"Department of Molecular and Macromolecular Chemistry, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan","institution_ids":["https://openalex.org/I60134161"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5050312260","https://openalex.org/A5089502268"],"corresponding_institution_ids":["https://openalex.org/I60134161"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.0233,"has_fulltext":false,"cited_by_count":20,"citation_normalized_percentile":{"value":0.69825894,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":97},"biblio":{"volume":"37","issue":"12","first_page":"1833","last_page":"1836"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.6187000274658203,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.6187000274658203,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11341","display_name":"Boron and Carbon Nanomaterials Research","score":0.23170000314712524,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.0885000005364418,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/p-quinodimethane","display_name":"p-quinodimethane","score":0.9129999876022339},{"id":"https://openalex.org/keywords/boron-nitride","display_name":"boron nitride","score":0.7559999823570251},{"id":"https://openalex.org/keywords/transmetalation","display_name":"transmetalation","score":0.9750000238418579},{"id":"https://openalex.org/keywords/pi-conjugated-molecules","display_name":"conjugated molecules","score":0.8550000190734863},{"id":"https://openalex.org/keywords/photophysical-properties","display_name":"photophysical properties","score":0.8510000109672546}],"concepts":[{"id":"https://openalex.org/C142653250","wikidata":"https://www.wikidata.org/wiki/Q900742","display_name":"Transmetalation","level":3,"score":0.9729967713356018},{"id":"https://openalex.org/C138211643","wikidata":"https://www.wikidata.org/wiki/Q675211","display_name":"Bent molecular geometry","level":2,"score":0.9102338552474976},{"id":"https://openalex.org/C2777000832","wikidata":"https://www.wikidata.org/wiki/Q419853","display_name":"Trimethylsilyl","level":2,"score":0.8597608208656311},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8550448417663574},{"id":"https://openalex.org/C134786449","wikidata":"https://www.wikidata.org/wiki/Q3391255","display_name":"Planar","level":2,"score":0.765844464302063},{"id":"https://openalex.org/C112613896","wikidata":"https://www.wikidata.org/wiki/Q898370","display_name":"Conjugated system","level":3,"score":0.6049854755401611},{"id":"https://openalex.org/C2776371256","wikidata":"https://www.wikidata.org/wiki/Q12370","display_name":"Salt (chemistry)","level":2,"score":0.5999224185943604},{"id":"https://openalex.org/C207114421","wikidata":"https://www.wikidata.org/wiki/Q133900","display_name":"Diffraction","level":2,"score":0.49826478958129883},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.3810873031616211},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.2615427076816559},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.18625399470329285},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.17136308550834656},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.14754724502563477},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.057950735092163086},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.05534210801124573},{"id":"https://openalex.org/C121684516","wikidata":"https://www.wikidata.org/wiki/Q7600677","display_name":"Computer graphics (images)","level":1,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.organomet.8b00294","doi":"https://doi.org/10.1021/acs.organomet.8b00294","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.8b00294","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2784668273","display_name":"Direct Transformation of Oxigen-Containing Compound through Electron Transfer from Organosilicon Species","funder_award_id":"16K17900","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G3872050418","display_name":null,"funder_award_id":"15H00762","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G5308116587","display_name":null,"funder_award_id":"14529307","funder_id":"https://openalex.org/F4320338075","funder_display_name":"Core Research for Evolutional Science and Technology"},{"id":"https://openalex.org/G7296830396","display_name":"Creation of highly reactive boron compounds by thorough utilization of vacant orbital","funder_award_id":"17H01191","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G8596961293","display_name":null,"funder_award_id":"15H00743","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G9000044970","display_name":"Synthesis of Bismuth-incorporated Conjugated Systems and Exploration of Their Function","funder_award_id":"17K19128","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"}],"funders":[{"id":"https://openalex.org/F4320309996","display_name":"Asahi Glass Foundation","ror":"https://ror.org/02nnhbq91"},{"id":"https://openalex.org/F4320334764","display_name":"Japan Society for the Promotion of Science","ror":"https://ror.org/00hhkn466"},{"id":"https://openalex.org/F4320338075","display_name":"Core Research for Evolutional Science and Technology","ror":"https://ror.org/00097mb19"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":42,"referenced_works":["https://openalex.org/W1517631572","https://openalex.org/W1964038229","https://openalex.org/W1973147090","https://openalex.org/W1973915134","https://openalex.org/W1981971775","https://openalex.org/W2000875788","https://openalex.org/W2012009864","https://openalex.org/W2015904059","https://openalex.org/W2022506367","https://openalex.org/W2041856975","https://openalex.org/W2055817552","https://openalex.org/W2069997331","https://openalex.org/W2084593168","https://openalex.org/W2084927277","https://openalex.org/W2092076977","https://openalex.org/W2095093761","https://openalex.org/W2101506060","https://openalex.org/W2109738234","https://openalex.org/W2122069250","https://openalex.org/W2125051738","https://openalex.org/W2129085471","https://openalex.org/W2130472598","https://openalex.org/W2142177578","https://openalex.org/W2144821086","https://openalex.org/W2163413179","https://openalex.org/W2163611813","https://openalex.org/W2170270338","https://openalex.org/W2313683552","https://openalex.org/W2324060579","https://openalex.org/W2331612036","https://openalex.org/W2332156034","https://openalex.org/W2334337789","https://openalex.org/W2506103069","https://openalex.org/W2513610235","https://openalex.org/W2520111051","https://openalex.org/W2594189123","https://openalex.org/W2601116900","https://openalex.org/W2730648392","https://openalex.org/W2744990868","https://openalex.org/W2775260265","https://openalex.org/W2786345646","https://openalex.org/W2793850669"],"related_works":["https://openalex.org/W2341548352","https://openalex.org/W2322940517","https://openalex.org/W4321748081","https://openalex.org/W2053589605","https://openalex.org/W1533394224","https://openalex.org/W1988348210","https://openalex.org/W2109738234","https://openalex.org/W2044672729","https://openalex.org/W1996036634","https://openalex.org/W1982182694"],"abstract_inverted_index":{"Two":[0],"BN-embedded":[1],"p":[2],"-quinodimethane":[3],"derivatives":[4],"were":[5,30],"synthesized":[6],"by":[7,32],"a":[8],"reaction":[9],"of":[10,25,53],"bis(trimethylsilyl)-1,4-dihydropyrazines,":[11],"which":[12],"are":[13],"known":[14],"as":[15],"inorganic-salt-free":[16],"reductants,":[17],"with":[18],"9-chloro-9-borafluorene.":[19],"The":[20],"planar":[21,42],"or":[22,43],"bent":[23,44],"structures":[24,45],"the":[26,48,51,54],"resulting":[27],"\u03c0-conjugated":[28],"compounds":[29],"revealed":[31],"X-ray":[33],"diffraction":[34],"analysis.":[35],"Their":[36],"photophysical":[37],"properties":[38],"relate":[39],"to":[40,47],"their":[41],"due":[46],"difference":[49],"in":[50],"distribution":[52],"HOMO.":[55]},"counts_by_year":[{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":3},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":4},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":2}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2018-06-13T00:00:00"}
