{"id":"https://openalex.org/W2805873531","doi":"https://doi.org/10.1021/acs.inorgchem.8b00582","title":"Bis(hydroxylamino)triazines: High Selectivity and Hydrolytic Stability of Hydroxylamine-Based Ligands for Uranyl Compared to Vanadium(V) and Iron(III)","display_name":"Bis(hydroxylamino)triazines: High Selectivity and Hydrolytic Stability of Hydroxylamine-Based Ligands for Uranyl Compared to Vanadium(V) and Iron(III)","publication_year":2018,"publication_date":"2018-06-08","ids":{"openalex":"https://openalex.org/W2805873531","doi":"https://doi.org/10.1021/acs.inorgchem.8b00582","mag":"2805873531","pmid":"https://pubmed.ncbi.nlm.nih.gov/29882661"},"language":"en","primary_location":{"id":"doi:10.1021/acs.inorgchem.8b00582","doi":"https://doi.org/10.1021/acs.inorgchem.8b00582","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.8b00582","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5018193164","display_name":"Sofia Hadjithoma","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I34771391","display_name":"University of Cyprus","ror":"https://ror.org/02qjrjx09","country_code":"CY","type":"education","lineage":["https://openalex.org/I34771391"]}],"countries":["CY"],"is_corresponding":false,"raw_author_name":"Sofia Hadjithoma","raw_affiliation_strings":["Department of Chemistry, University of Cyprus, 2109 Nicosia, Cyprus"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Cyprus, 2109 Nicosia, Cyprus","institution_ids":["https://openalex.org/I34771391"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5078742012","display_name":"Michael G. Papanikolaou","orcid":"https://orcid.org/0000-0002-0975-4429","observed_orcids":["https://orcid.org/0000-0002-0975-4429"]},"institutions":[{"id":"https://openalex.org/I194019607","display_name":"University of Ioannina","ror":"https://ror.org/01qg3j183","country_code":"GR","type":"education","lineage":["https://openalex.org/I194019607"]}],"countries":["GR"],"is_corresponding":false,"raw_author_name":"Michael G. Papanikolaou","raw_affiliation_strings":["Department of Chemistry, Section of Inorganic and Analytical Chemistry, University of Ioannina, 45110 Ioannina, Greece"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Section of Inorganic and Analytical Chemistry, University of Ioannina, 45110 Ioannina, Greece","institution_ids":["https://openalex.org/I194019607"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077409466","display_name":"Epameinondas Leontidis","orcid":"https://orcid.org/0000-0003-4427-0398","observed_orcids":["https://orcid.org/0000-0003-4427-0398"]},"institutions":[{"id":"https://openalex.org/I34771391","display_name":"University of Cyprus","ror":"https://ror.org/02qjrjx09","country_code":"CY","type":"education","lineage":["https://openalex.org/I34771391"]}],"countries":["CY"],"is_corresponding":false,"raw_author_name":"Epameinondas Leontidis","raw_affiliation_strings":["Department of Chemistry, University of Cyprus, 2109 Nicosia, Cyprus"],"raw_orcid":"https://orcid.org/0000-0003-4427-0398","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Cyprus, 2109 Nicosia, Cyprus","institution_ids":["https://openalex.org/I34771391"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5002881586","display_name":"Themistoklis A. Kabanos","orcid":"https://orcid.org/0000-0003-0357-2138","observed_orcids":["https://orcid.org/0000-0003-0357-2138"]},"institutions":[{"id":"https://openalex.org/I194019607","display_name":"University of Ioannina","ror":"https://ror.org/01qg3j183","country_code":"GR","type":"education","lineage":["https://openalex.org/I194019607"]}],"countries":["GR"],"is_corresponding":true,"raw_author_name":"Themistoklis A. Kabanos","raw_affiliation_strings":["Department of Chemistry, Section of Inorganic and Analytical Chemistry, University of Ioannina, 45110 Ioannina, Greece"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Section of Inorganic and Analytical Chemistry, University of Ioannina, 45110 Ioannina, Greece","institution_ids":["https://openalex.org/I194019607"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5045324658","display_name":"Anastasios D. Keramidas","orcid":"https://orcid.org/0000-0002-0446-8220","observed_orcids":["https://orcid.org/0000-0002-0446-8220"]},"institutions":[{"id":"https://openalex.org/I34771391","display_name":"University of Cyprus","ror":"https://ror.org/02qjrjx09","country_code":"CY","type":"education","lineage":["https://openalex.org/I34771391"]}],"countries":["CY"],"is_corresponding":true,"raw_author_name":"Anastasios D. Keramidas","raw_affiliation_strings":["Department of Chemistry, University of Cyprus, 2109 Nicosia, Cyprus"],"raw_orcid":"https://orcid.org/0000-0002-0446-8220","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Cyprus, 2109 Nicosia, Cyprus","institution_ids":["https://openalex.org/I34771391"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5002881586","https://openalex.org/A5045324658"],"corresponding_institution_ids":["https://openalex.org/I194019607","https://openalex.org/I34771391"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.622,"has_fulltext":false,"cited_by_count":18,"citation_normalized_percentile":{"value":0.59142857,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"57","issue":"13","first_page":"7631","last_page":"7643"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10973","display_name":"Radioactive element chemistry and processing","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10973","display_name":"Radioactive element chemistry and processing","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10578","display_name":"Supramolecular Chemistry and Complexes","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12524","display_name":"Chemical Synthesis and Characterization","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2311","display_name":"Waste Management and Disposal"},"field":{"id":"https://openalex.org/fields/23","display_name":"Environmental Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/uranyl-extraction","display_name":"uranyl extraction","score":0.6140000224113464},{"id":"https://openalex.org/keywords/ligand-selectivity","display_name":"ligand selectivity","score":0.8109999895095825},{"id":"https://openalex.org/keywords/uranyl-complexes","display_name":"uranyl complexes","score":0.5680000185966492},{"id":"https://openalex.org/keywords/vanadium-v-complexes","display_name":"vanadium(V) complexes","score":0.7559999823570251},{"id":"https://openalex.org/keywords/iron-iii-complexes","display_name":"iron(III) complexes","score":0.9940000176429749},{"id":"https://openalex.org/keywords/hydrolytic-stability","display_name":"hydrolytic stability","score":0.8019999861717224},{"id":"https://openalex.org/keywords/uranyl-coordination","display_name":"uranyl coordination chemistry","score":0.35600000619888306},{"id":"https://openalex.org/keywords/dipicolinic-acid","display_name":"dipicolinic acid","score":0.8500000238418579},{"id":"https://openalex.org/keywords/uranium-extraction-from-seawater","display_name":"seawater uranium extraction","score":0.47999998927116394}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.970839262008667},{"id":"https://openalex.org/C118792377","wikidata":"https://www.wikidata.org/wiki/Q108584245","display_name":"Selectivity","level":3,"score":0.7700843811035156},{"id":"https://openalex.org/C2778468930","wikidata":"https://www.wikidata.org/wiki/Q421141","display_name":"Uranyl","level":3,"score":0.7325595021247864},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.6919233798980713},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.6137353777885437},{"id":"https://openalex.org/C504678139","wikidata":"https://www.wikidata.org/wiki/Q722","display_name":"Vanadium","level":2,"score":0.5846526622772217},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.570636510848999},{"id":"https://openalex.org/C199164860","wikidata":"https://www.wikidata.org/wiki/Q6822745","display_name":"Metal ions in aqueous solution","level":3,"score":0.564647376537323},{"id":"https://openalex.org/C555451288","wikidata":"https://www.wikidata.org/wiki/Q1098","display_name":"Uranium","level":2,"score":0.45245417952537537},{"id":"https://openalex.org/C2776303721","wikidata":"https://www.wikidata.org/wiki/Q419563","display_name":"Triazine","level":2,"score":0.41414687037467957},{"id":"https://openalex.org/C2779485729","wikidata":"https://www.wikidata.org/wiki/Q210385","display_name":"Pyridine","level":2,"score":0.41126489639282227},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.3866053521633148},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.34797602891921997},{"id":"https://openalex.org/C13965031","wikidata":"https://www.wikidata.org/wiki/Q243545","display_name":"Nuclear chemistry","level":1,"score":0.3313438892364502},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.22992420196533203},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.20969811081886292},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.1304686963558197},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/acs.inorgchem.8b00582","doi":"https://doi.org/10.1021/acs.inorgchem.8b00582","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.inorgchem.8b00582","pdf_url":null,"source":{"id":"https://openalex.org/S171072222","display_name":"Inorganic Chemistry","issn_l":"0020-1669","issn":["0020-1669","1520-510X"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic Chemistry","raw_type":"journal-article"},{"id":"pmid:29882661","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/29882661","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Inorganic chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":63,"referenced_works":["https://openalex.org/W1146214064","https://openalex.org/W1835629181","https://openalex.org/W1959918093","https://openalex.org/W1966829246","https://openalex.org/W1977495874","https://openalex.org/W1978676646","https://openalex.org/W1983202946","https://openalex.org/W1992357109","https://openalex.org/W2003486680","https://openalex.org/W2003806691","https://openalex.org/W2005794085","https://openalex.org/W2008276930","https://openalex.org/W2009885280","https://openalex.org/W2014233512","https://openalex.org/W2018006375","https://openalex.org/W2018985418","https://openalex.org/W2019128055","https://openalex.org/W2022973164","https://openalex.org/W2023255509","https://openalex.org/W2026383611","https://openalex.org/W2034155026","https://openalex.org/W2040520553","https://openalex.org/W2042149117","https://openalex.org/W2043797348","https://openalex.org/W2067386402","https://openalex.org/W2069093221","https://openalex.org/W2077994026","https://openalex.org/W2082694267","https://openalex.org/W2083451051","https://openalex.org/W2083650938","https://openalex.org/W2097422001","https://openalex.org/W2117733462","https://openalex.org/W2137348109","https://openalex.org/W2152207101","https://openalex.org/W2161130537","https://openalex.org/W2235956054","https://openalex.org/W2312881842","https://openalex.org/W2314129795","https://openalex.org/W2316682496","https://openalex.org/W2316903107","https://openalex.org/W2320660569","https://openalex.org/W2332934910","https://openalex.org/W2332939050","https://openalex.org/W2338099354","https://openalex.org/W2339540635","https://openalex.org/W2471093548","https://openalex.org/W2512434287","https://openalex.org/W2531227530","https://openalex.org/W2565108180","https://openalex.org/W2585467355","https://openalex.org/W2586122873","https://openalex.org/W2739711172","https://openalex.org/W2741510292","https://openalex.org/W2742003177","https://openalex.org/W2746718297","https://openalex.org/W2754525610","https://openalex.org/W2767738902","https://openalex.org/W2767829541","https://openalex.org/W2770534062","https://openalex.org/W2777506985","https://openalex.org/W2784045435","https://openalex.org/W2793004311","https://openalex.org/W2795921549"],"related_works":["https://openalex.org/W4389137932","https://openalex.org/W7211881805","https://openalex.org/W2035369937","https://openalex.org/W2074857783","https://openalex.org/W2042324645","https://openalex.org/W2057901151","https://openalex.org/W2907110315","https://openalex.org/W4364378319","https://openalex.org/W4324311265","https://openalex.org/W6987882075"],"abstract_inverted_index":{"The":[0,73,220,319],"development":[1],"of":[2,16,31,34,59,122,165,173,246,268,357,365],"ligands":[3,47],"with":[4,48,98,162,177,336],"high":[5,67,337],"selectivity":[6,33,68,267,338],"and":[7,23,44,56,93,117,140,158,169,229,238,265,288,316,343,370,376],"affinity":[8],"for":[9,36,69,83,259,330],"uranium":[10,17,37,366],"is":[11,28,213,326],"critical":[12],"in":[13,114,119,153,155,193,217,236,280,291,362],"the":[14,29,32,54,60,70,120,123,163,170,198,214,223,230,242,247,266,269,363,368,374,377],"extraction":[15,364],"from":[18,367,373],"human":[19,378],"body,":[20],"radioactive":[21],"waste,":[22],"seawater.":[24],"A":[25],"scientific":[26],"challenge":[27],"improvement":[30],"chelators":[35],"over":[38,251],"other":[39],"heavy":[40],"metals,":[41],"including":[42],"iron":[43],"vanadium.":[45],"Flat":[46],"hard":[49,84],"donor":[50],"atoms":[51],"that":[52,322],"satisfy":[53],"geometric":[55],"electronic":[57],"requirements":[58],"U":[61,224,260,275,293,304,331],"VI":[62,95,100,126,133,142,179,202,225,261,276,294,305,332],"O":[63,101,113,127,134,143,180,192,204,226,262,277,285,295,300,306,333,346],"2":[64,78,102,106,108,110,112,128,130,135,137,144,146,167,175,181,185,187,189,191,207,209,227,234,249,255,263,271,278,296,307,324,334],"2+":[65,228,279,297,308,335],"exhibit":[66],"uranyl":[71],"moiety.":[72],"bis(hydroxylamino)(triazine)":[74],"ligand,":[75],"2,6-bis[hydroxy(methyl)amino]-4-morpholino-1,3,5-triazine":[76],"(H":[77,107,186,254],"bihyat),":[79],"a":[80,327],"strong":[81],"binder":[82],"metal":[85,243],"ions":[86],"(Fe":[87],"III,":[88],"Ti":[89],"IV,":[90],"V":[91,283,284,299,344,345],"V,":[92],"Mo":[94],"),":[96],"reacted":[97],"[U":[99,125,132,178,201],"(NO":[103,182],"3":[104,183,195,203],")":[105,184],"O)":[109,188],"]\u00b74H":[111,190],"aqueous":[115,156,237],"solution":[116],"resulted":[118],"isolation":[121],"complexes":[124],"(bihyat)(H":[129],"O)],":[131],"(bihyat)":[136,206],"]":[138,210],"2\u2013,":[139,211],"{[U":[141],"(bihyat)(\u03bc-OH)]}":[145],"2\u2013":[147],".":[148],"These":[149],"three":[150],"species":[151,216],"are":[152],"equilibrium":[154],"solution,":[157],"their":[159],"abundance":[160],"varies":[161],"concentration":[164],"H":[166,174,233,248,270,323],"bihyat":[168,176,235,250,272,325],"pH.":[171],"Reaction":[172],"CH":[194],"CN":[196],"gave":[197],"trinuclear":[199],"complex":[200],"6":[205],"(\u03bc-bihyat)":[208],"which":[212,349],"major":[215],"organic":[218],"solvents.":[219],"dynamics":[221],"between":[222],"free":[231],"ligand":[232,329,358],"dimethyl":[239],"sulfoxide":[240],"solutions;":[241],"binding":[244],"ability":[245],"pyridine-2,6-dicarboxylic":[252],"acid":[253],"dipic)":[256],"or":[257,303],"glutarimidedioxime":[258],"2+,":[264],"to":[273,282,340],"bind":[274],"comparison":[281],"4":[286,301,347],"3\u2013":[287,302],"Fe":[289,341],"III":[290,310,342],"either":[292],"/V":[298],"/Fe":[309],"solutions":[311],"were":[312],"examined":[313],"by":[314],"NMR":[315],"UV\u2013vis":[317],"spectroscopies.":[318],"results":[320],"revealed":[321],"superior":[328],"compared":[339],"3\u2013,":[348],"increases":[350],"at":[351],"higher":[352],"pHs.":[353],"Thus,":[354],"this":[355],"type":[356],"might":[359],"find":[360],"applications":[361],"sea":[369],"its":[371],"removal":[372],"environment":[375],"body.":[379]},"counts_by_year":[{"year":2026,"cited_by_count":5},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":3},{"year":2018,"cited_by_count":1}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2018-06-13T00:00:00"}