{"id":"https://openalex.org/W2804395569","doi":"https://doi.org/10.1002/asia.201800591","title":"Sulfonylation of Benzylic C\u2212H Bonds through the Reaction of Aryl(o\u2010tolyl)methanones with Sulfonyl Hydrazides or Sulfonyl Chlorides","display_name":"Sulfonylation of Benzylic C\u2212H Bonds through the Reaction of Aryl(o\u2010tolyl)methanones with Sulfonyl Hydrazides or Sulfonyl Chlorides","publication_year":2018,"publication_date":"2018-05-23","ids":{"openalex":"https://openalex.org/W2804395569","doi":"https://doi.org/10.1002/asia.201800591","mag":"2804395569","pmid":"https://pubmed.ncbi.nlm.nih.gov/29791085"},"language":"en","primary_location":{"id":"doi:10.1002/asia.201800591","doi":"https://doi.org/10.1002/asia.201800591","is_oa":false,"landing_page_url":"https://doi.org/10.1002/asia.201800591","pdf_url":null,"source":{"id":"https://openalex.org/S188582317","display_name":"Chemistry - An Asian Journal","issn_l":"1861-471X","issn":["1861-471X","1861-4728"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry \u2013 An Asian Journal","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5102795690","display_name":"Xinxing Gong","orcid":"https://orcid.org/0000-0002-5536-3824","observed_orcids":["https://orcid.org/0000-0002-5536-3824"]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xinxing Gong","raw_affiliation_strings":["Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200438 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200438 P. R. China","institution_ids":["https://openalex.org/I24943067"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100434482","display_name":"Jiahao Chen","orcid":"https://orcid.org/0000-0003-2625-6656","observed_orcids":["https://orcid.org/0000-0003-2625-6656"]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jiahao Chen","raw_affiliation_strings":["Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200438 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200438 P. R. China","institution_ids":["https://openalex.org/I24943067"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100362425","display_name":"Xiaofang Li","orcid":"https://orcid.org/0000-0001-7501-9572","observed_orcids":["https://orcid.org/0000-0001-7501-9572"]},"institutions":[{"id":"https://openalex.org/I121296143","display_name":"Hunan University of Science and Technology","ror":"https://ror.org/02m9vrb24","country_code":"CN","type":"education","lineage":["https://openalex.org/I121296143"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Xiaofang Li","raw_affiliation_strings":["School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201 P. R. China","institution_ids":["https://openalex.org/I121296143"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5102346433","display_name":"Wenlin Xie","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I121296143","display_name":"Hunan University of Science and Technology","ror":"https://ror.org/02m9vrb24","country_code":"CN","type":"education","lineage":["https://openalex.org/I121296143"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Wenlin Xie","raw_affiliation_strings":["School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201 P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201 P. R. China","institution_ids":["https://openalex.org/I121296143"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5038839605","display_name":"Jie Wu","orcid":"https://orcid.org/0000-0002-0967-6360","observed_orcids":["https://orcid.org/0000-0002-0967-6360"]},"institutions":[{"id":"https://openalex.org/I19820366","display_name":"Chinese Academy of Sciences","ror":"https://ror.org/034t30j35","country_code":"CN","type":"government","lineage":["https://openalex.org/I19820366"]},{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]},{"id":"https://openalex.org/I4210112946","display_name":"Shanghai Institute of Organic Chemistry","ror":"https://ror.org/01y3hvq34","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210112946"]},{"id":"https://openalex.org/I4391767815","display_name":"State Key Laboratory of Organometallic Chemistry","ror":"https://ror.org/04kaae654","country_code":"CN","type":"facility","lineage":["https://openalex.org/I19820366","https://openalex.org/I4210112946","https://openalex.org/I4391767815"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Jie Wu","raw_affiliation_strings":["Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200438 P. R. China","State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032 P. R. China"],"raw_orcid":"https://orcid.org/0000-0002-0967-6360","affiliations":[{"raw_affiliation_string":"Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai, 200438 P. R. China","institution_ids":["https://openalex.org/I24943067"]},{"raw_affiliation_string":"State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, 200032 P. R. China","institution_ids":["https://openalex.org/I19820366","https://openalex.org/I4210112946","https://openalex.org/I4391767815"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":5,"corresponding_author_ids":["https://openalex.org/A5038839605","https://openalex.org/A5102346433"],"corresponding_institution_ids":["https://openalex.org/I121296143","https://openalex.org/I19820366","https://openalex.org/I24943067","https://openalex.org/I4210112946","https://openalex.org/I4391767815"],"apc_list":{"value":4520,"currency":"USD","value_usd":4520},"apc_paid":null,"fwci":4.2372,"has_fulltext":false,"cited_by_count":52,"citation_normalized_percentile":{"value":0.96043035,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":88,"max":100},"biblio":{"volume":"13","issue":"17","first_page":"2543","last_page":"2548"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12189","display_name":"Sulfur-Based Synthesis Techniques","score":0.9726999998092651,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12189","display_name":"Sulfur-Based Synthesis Techniques","score":0.9726999998092651,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.019700000062584877,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10354","display_name":"Catalytic C\u2013H Functionalization Methods","score":0.00570000009611249,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/benzylic-c-h-functionalization","display_name":"benzylic C\u2013H functionalization","score":0.8399999737739563},{"id":"https://openalex.org/keywords/sulfonylation","display_name":"sulfonylation","score":0.859000027179718},{"id":"https://openalex.org/keywords/arylsulfonyl-hydrazides","display_name":"arylsulfonyl hydrazides","score":0.9909999966621399},{"id":"https://openalex.org/keywords/arylsulfonyl-chlorides","display_name":"arylsulfonyl chlorides","score":0.9980000257492065},{"id":"https://openalex.org/keywords/uv-irradiation","display_name":"UV irradiation","score":0.875},{"id":"https://openalex.org/keywords/sulfonyl-radicals","display_name":"sulfonyl radicals","score":0.9480000138282776}],"concepts":[{"id":"https://openalex.org/C87906975","wikidata":"https://www.wikidata.org/wiki/Q899114","display_name":"Sulfonyl","level":3,"score":0.9390087127685547},{"id":"https://openalex.org/C2781076698","wikidata":"https://www.wikidata.org/wiki/Q718074","display_name":"Aryl","level":3,"score":0.8484039902687073},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8195965886116028},{"id":"https://openalex.org/C40875361","wikidata":"https://www.wikidata.org/wiki/Q2356542","display_name":"Reagent","level":2,"score":0.6826894283294678},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.4817831218242645},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.2588571608066559},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.04593488574028015}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1002/asia.201800591","doi":"https://doi.org/10.1002/asia.201800591","is_oa":false,"landing_page_url":"https://doi.org/10.1002/asia.201800591","pdf_url":null,"source":{"id":"https://openalex.org/S188582317","display_name":"Chemistry - An Asian Journal","issn_l":"1861-471X","issn":["1861-471X","1861-4728"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry \u2013 An Asian Journal","raw_type":"journal-article"},{"id":"pmid:29791085","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/29791085","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry, an Asian journal","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2609353879","display_name":"\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u7684\u65b0\u578b\u4e32\u8054\u73af\u5316\u53cd\u5e94\u8bbe\u8ba1\u7814\u7a76\u53ca\u5e94\u7528","funder_award_id":"21532001","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"},{"id":"https://openalex.org/G7111114318","display_name":null,"funder_award_id":"21672037","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":109,"referenced_works":["https://openalex.org/W86560810","https://openalex.org/W1496779265","https://openalex.org/W1769755720","https://openalex.org/W1794488607","https://openalex.org/W1823863301","https://openalex.org/W1862632885","https://openalex.org/W1970113297","https://openalex.org/W1979008877","https://openalex.org/W1982854153","https://openalex.org/W1986939463","https://openalex.org/W1988161686","https://openalex.org/W1988441603","https://openalex.org/W1990922735","https://openalex.org/W1995089537","https://openalex.org/W1996941025","https://openalex.org/W2013120927","https://openalex.org/W2017602598","https://openalex.org/W2022236530","https://openalex.org/W2024584544","https://openalex.org/W2027104358","https://openalex.org/W2030309694","https://openalex.org/W2033104547","https://openalex.org/W2039294512","https://openalex.org/W2050379798","https://openalex.org/W2052981545","https://openalex.org/W2054281584","https://openalex.org/W2064901199","https://openalex.org/W2066757175","https://openalex.org/W2071636393","https://openalex.org/W2075362249","https://openalex.org/W2080971524","https://openalex.org/W2082947289","https://openalex.org/W2085288928","https://openalex.org/W2089540058","https://openalex.org/W2099173380","https://openalex.org/W2105200196","https://openalex.org/W2106467930","https://openalex.org/W2118989336","https://openalex.org/W2130841503","https://openalex.org/W2145002461","https://openalex.org/W2156313419","https://openalex.org/W2159488977","https://openalex.org/W2165179223","https://openalex.org/W2187816675","https://openalex.org/W2221911656","https://openalex.org/W2255596973","https://openalex.org/W2267802694","https://openalex.org/W2271079307","https://openalex.org/W2290219888","https://openalex.org/W2319768892","https://openalex.org/W2333920637","https://openalex.org/W2335883000","https://openalex.org/W2342298857","https://openalex.org/W2344832573","https://openalex.org/W2346263393","https://openalex.org/W2411976440","https://openalex.org/W2424784302","https://openalex.org/W2439036034","https://openalex.org/W2461435401","https://openalex.org/W2476397298","https://openalex.org/W2483656054","https://openalex.org/W2504256884","https://openalex.org/W2507169805","https://openalex.org/W2510588682","https://openalex.org/W2511477429","https://openalex.org/W2520261199","https://openalex.org/W2521838363","https://openalex.org/W2534655537","https://openalex.org/W2553342480","https://openalex.org/W2557259823","https://openalex.org/W2558623433","https://openalex.org/W2566315748","https://openalex.org/W2579482172","https://openalex.org/W2587145846","https://openalex.org/W2587464474","https://openalex.org/W2588727370","https://openalex.org/W2594891443","https://openalex.org/W2604321286","https://openalex.org/W2604373508","https://openalex.org/W2604638607","https://openalex.org/W2604728757","https://openalex.org/W2604859344","https://openalex.org/W2606248540","https://openalex.org/W2609543801","https://openalex.org/W2613027685","https://openalex.org/W2618716906","https://openalex.org/W2671147448","https://openalex.org/W2739688203","https://openalex.org/W2742214997","https://openalex.org/W2745041424","https://openalex.org/W2749884090","https://openalex.org/W2752521684","https://openalex.org/W2755769665","https://openalex.org/W2765507450","https://openalex.org/W2765643936","https://openalex.org/W2766313329","https://openalex.org/W2766820130","https://openalex.org/W2767038194","https://openalex.org/W2770552137","https://openalex.org/W2770947283","https://openalex.org/W2773712305","https://openalex.org/W2784512770","https://openalex.org/W2785981148","https://openalex.org/W2949638220","https://openalex.org/W2951292786","https://openalex.org/W2951443891","https://openalex.org/W2952097337","https://openalex.org/W2952807175","https://openalex.org/W4253404718"],"related_works":["https://openalex.org/W2891533868","https://openalex.org/W3198102604","https://openalex.org/W2342298857","https://openalex.org/W3102780322","https://openalex.org/W3194373790","https://openalex.org/W2904188640","https://openalex.org/W2301043393","https://openalex.org/W2951908545","https://openalex.org/W4391660211","https://openalex.org/W4385564688"],"abstract_inverted_index":{"A":[0],"sulfonylation":[1],"of":[2,6,55],"benzylic":[3],"C-H":[4],"bonds":[5],"aryl(o-tolyl)methanones":[7,41],"with":[8,48],"arylsulfonyl":[9,12,20],"hydrazides":[10,18],"or":[11],"chlorides":[13,21],"has":[14],"been":[15],"developed.":[16],"Arylsulfonyl":[17],"and":[19,45],"were":[22,36],"employed":[23],"as":[24],"sulfonylating":[25],"reagents":[26],"respectively":[27],"to":[28,51],"complete":[29],"this":[30],"transformation.":[31],"During":[32],"the":[33],"reaction,":[34],"enols":[35],"generated":[37],"in":[38],"situ":[39],"from":[40],"under":[42],"UV":[43],"irradiation,":[44],"subsequently":[46],"reacted":[47],"sulfonyl":[49],"radicals":[50],"provide":[52],"a":[53],"range":[54],"aryl(2-(arylsulfonylmethyl)aryl)methanones.":[56]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":5},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":9},{"year":2019,"cited_by_count":26},{"year":2018,"cited_by_count":5}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2018-06-01T00:00:00"}