{"id":"https://openalex.org/W2803344931","doi":"https://doi.org/10.1002/ange.201804445","title":"Enolkatalyse erm\u00f6glicht eine unerwartete \u03b1\u2010Oxidation zyklischer Ketone mit 1,4\u2010Benzochinonen","display_name":"Enolkatalyse erm\u00f6glicht eine unerwartete \u03b1\u2010Oxidation zyklischer Ketone mit 1,4\u2010Benzochinonen","publication_year":2018,"publication_date":"2018-05-22","ids":{"openalex":"https://openalex.org/W2803344931","doi":"https://doi.org/10.1002/ange.201804445","mag":"2803344931"},"language":"de","primary_location":{"id":"doi:10.1002/ange.201804445","doi":"https://doi.org/10.1002/ange.201804445","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.201804445","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5014143318","display_name":"Grigory Andr\u00e9 Shevchenko","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Grigory A. Shevchenko","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz 1 45470 M\u00fclheim an der Ruhr Deutschland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz 1 45470 M\u00fclheim an der Ruhr Deutschland","institution_ids":["https://openalex.org/I4210090782"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5067767593","display_name":"Barry Oppelaar","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":false,"raw_author_name":"Barry Oppelaar","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz 1 45470 M\u00fclheim an der Ruhr Deutschland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz 1 45470 M\u00fclheim an der Ruhr Deutschland","institution_ids":["https://openalex.org/I4210090782"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5040055598","display_name":"Benjamin List","orcid":"https://orcid.org/0000-0002-9804-599X","observed_orcids":["https://orcid.org/0000-0002-9804-599X"]},"institutions":[{"id":"https://openalex.org/I4210090782","display_name":"Max-Planck-Institut f\u00fcr Kohlenforschung","ror":"https://ror.org/00a7vgh58","country_code":"DE","type":"facility","lineage":["https://openalex.org/I149899117","https://openalex.org/I4210090782"]}],"countries":["DE"],"is_corresponding":true,"raw_author_name":"Benjamin List","raw_affiliation_strings":["Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz 1 45470 M\u00fclheim an der Ruhr Deutschland"],"raw_orcid":"https://orcid.org/0000-0002-9804-599X","affiliations":[{"raw_affiliation_string":"Max-Planck-Institut f\u00fcr Kohlenforschung  Kaiser-Wilhelm-Platz 1 45470 M\u00fclheim an der Ruhr Deutschland","institution_ids":["https://openalex.org/I4210090782"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5040055598"],"corresponding_institution_ids":["https://openalex.org/I4210090782"],"apc_list":{"value":5790,"currency":"USD","value_usd":5790},"apc_paid":null,"fwci":0.7171,"has_fulltext":false,"cited_by_count":9,"citation_normalized_percentile":{"value":0.60356089,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":97},"biblio":{"volume":"130","issue":"33","first_page":"10916","last_page":"10919"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.5770999789237976,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.5770999789237976,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.23890000581741333,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.09669999778270721,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/alpha-oxidation","display_name":"alpha-oxidation","score":0.8149999976158142},{"id":"https://openalex.org/keywords/cyclic-ketones","display_name":"cyclic ketones","score":0.9860000014305115},{"id":"https://openalex.org/keywords/p-benzoquinone","display_name":"p-benzoquinone","score":0.9559999704360962},{"id":"https://openalex.org/keywords/phosphoric-acid","display_name":"phosphoric acid","score":0.7360000014305115},{"id":"https://openalex.org/keywords/enantioselectivity","display_name":"enantioselectivity","score":0.8999999761581421},{"id":"https://openalex.org/keywords/proton-coupled-electron-transfer","display_name":"proton-coupled electron transfer","score":0.9819999933242798},{"id":"https://openalex.org/keywords/radical-recombination","display_name":"radical recombination","score":0.8799999952316284},{"id":"https://openalex.org/keywords/reaction-mechanism","display_name":"reaction mechanism","score":0.8629999756813049}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7730538845062256},{"id":"https://openalex.org/C2777738585","wikidata":"https://www.wikidata.org/wiki/Q170744","display_name":"Ketone","level":2,"score":0.6198466420173645},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.6132480502128601},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.08770200610160828}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1002/ange.201804445","doi":"https://doi.org/10.1002/ange.201804445","is_oa":false,"landing_page_url":"https://doi.org/10.1002/ange.201804445","pdf_url":null,"source":{"id":"https://openalex.org/S4210200754","display_name":"Angewandte Chemie","issn_l":"0044-8249","issn":["0044-8249","0932-2140","1521-3757"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","norway-1"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Angewandte Chemie","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320320879","display_name":"Deutsche Forschungsgemeinschaft","ror":"https://ror.org/018mejw64"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":52,"referenced_works":["https://openalex.org/W21827199","https://openalex.org/W1967445507","https://openalex.org/W1969568153","https://openalex.org/W1971237428","https://openalex.org/W1971698650","https://openalex.org/W1974687743","https://openalex.org/W1984348178","https://openalex.org/W1995162404","https://openalex.org/W2000500107","https://openalex.org/W2011811302","https://openalex.org/W2015078430","https://openalex.org/W2019248116","https://openalex.org/W2041930594","https://openalex.org/W2087807642","https://openalex.org/W2107044826","https://openalex.org/W2108182680","https://openalex.org/W2109821697","https://openalex.org/W2125838376","https://openalex.org/W2140779374","https://openalex.org/W2152470891","https://openalex.org/W2158596207","https://openalex.org/W2167133058","https://openalex.org/W2168941067","https://openalex.org/W2169215414","https://openalex.org/W2219722747","https://openalex.org/W2253871590","https://openalex.org/W2288178375","https://openalex.org/W2320361128","https://openalex.org/W2322631918","https://openalex.org/W2326143445","https://openalex.org/W2327985527","https://openalex.org/W2332470495","https://openalex.org/W2336126891","https://openalex.org/W2336915847","https://openalex.org/W2340585673","https://openalex.org/W2343564673","https://openalex.org/W2344923007","https://openalex.org/W2345777662","https://openalex.org/W2488628364","https://openalex.org/W2527370541","https://openalex.org/W2601606867","https://openalex.org/W2614822064","https://openalex.org/W2625978817","https://openalex.org/W2739273819","https://openalex.org/W2776616985","https://openalex.org/W2788466870","https://openalex.org/W2952402616","https://openalex.org/W4233501926","https://openalex.org/W4234927837","https://openalex.org/W4238100063","https://openalex.org/W4243402467","https://openalex.org/W4246677265"],"related_works":["https://openalex.org/W2809984965","https://openalex.org/W2076501064","https://openalex.org/W4232779299","https://openalex.org/W6890139306","https://openalex.org/W2167133058","https://openalex.org/W3160541529","https://openalex.org/W4381334531","https://openalex.org/W7018323981","https://openalex.org/W2145147115","https://openalex.org/W2952925404"],"abstract_inverted_index":{"Abstract":[0],"In":[1],"der":[2],"vorliegenden":[3],"Zuschrift":[4],"berichten":[5],"wir":[6],"nun":[7],"\u00fcber":[8,60],"eine,":[9],"durch":[10],"die":[11,36,58],"Enolkatalyse":[12],"erm\u00f6glichte,":[13],"direkte":[14],"und":[15,43],"asymmetrische":[16],"\u03b1\u2010Aryloxylierung":[17],"zyklischer":[18],"Ketone":[19,39],"mit":[20,65],"Chinonen":[21],"als":[22],"Reaktionspartnern.":[23],"Ausgehend":[24],"von":[25],"\u03b1\u2010verzweigten":[26],"Ketonen":[27],"k\u00f6nnen":[28],"unter":[29],"zur":[30],"Hilfenahme":[31],"katalytischer":[32],"Mengen":[33],"einer":[34],"Phosphors\u00e4ure":[35],"entsprechenden":[37],"\u03b1,\u03b1\u2010disubstituierten":[38],"in":[40],"guten":[41],"Ausbeuten":[42],"Enantioselektivit\u00e4ten":[44],"(bis":[45],"zu":[46],"96.5:3.5":[47],"er)":[48],"erhalten":[49],"werden.":[50],"Vorl\u00e4ufige":[51],"mechanistische":[52],"Experimente":[53],"deuten":[54],"darauf":[55],"hin,":[56],"dass":[57],"Reaktion":[59],"einen":[61],"protonengekoppelten":[62],"Elektronentransfer":[63],"(PCET)":[64],"anschlie\u00dfender":[66],"Radikalrekombination":[67],"abl\u00e4uft.":[68]},"counts_by_year":[{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":2}],"updated_date":"2026-09-22T06:50:58.402377","created_date":"2018-06-01T00:00:00"}
