{"id":"https://openalex.org/W2800190044","doi":"https://doi.org/10.32657/10356/73859","title":"N-heterocyclic carbene-catalyzed single-electron-transfer radical processes for reductive coupling reactions","display_name":"N-heterocyclic carbene-catalyzed single-electron-transfer radical processes for reductive coupling reactions","publication_year":2018,"publication_date":"2018-01-01","ids":{"openalex":"https://openalex.org/W2800190044","doi":"https://doi.org/10.32657/10356/73859","mag":"2800190044"},"language":"en","primary_location":{"id":"doi:10.32657/10356/73859","doi":"https://doi.org/10.32657/10356/73859","is_oa":true,"landing_page_url":"https://doi.org/10.32657/10356/73859","pdf_url":"https://dr.ntu.edu.sg/bitstream/10356/73859/1/WangYuhuang_2017.pdf","source":null,"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nanyang Technological University","raw_type":"dissertation"},"volume":null,"type":"dissertation","indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"https://dr.ntu.edu.sg/bitstream/10356/73859/1/WangYuhuang_2017.pdf","any_repository_has_fulltext":null},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5008767601","display_name":"YuHuang Wang","orcid":"https://orcid.org/0000-0002-5664-1849","observed_orcids":["https://orcid.org/0000-0002-5664-1849"]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Wang, Yuhuang","raw_affiliation_strings":["School of Physical and Mathematical Sciences"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Physical and Mathematical Sciences","institution_ids":[]}]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5008767601"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.9980000257492065,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.0006000000284984708,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10548","display_name":"Catalytic Cross-Coupling Reactions","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/n-heterocyclic-carbene-catalysis","display_name":"N-heterocyclic carbene catalysis","score":0.953000009059906},{"id":"https://openalex.org/keywords/single-electron-transfer","display_name":"single electron transfer","score":0.9340000152587891},{"id":"https://openalex.org/keywords/reductive-coupling","display_name":"reductive coupling","score":0.8029999732971191},{"id":"https://openalex.org/keywords/reductive-cross-coupling","display_name":"reductive cross-coupling","score":0.8659999966621399},{"id":"https://openalex.org/keywords/breslow-intermediate","display_name":"Breslow intermediate","score":0.8429999947547913},{"id":"https://openalex.org/keywords/imines","display_name":"imines","score":0.6430000066757202},{"id":"https://openalex.org/keywords/leaving-group-activation","display_name":"leaving group activation","score":0.5960000157356262},{"id":"https://openalex.org/keywords/thiamine-pyrophosphate","display_name":"thiamine pyrophosphate","score":0.8920000195503235}],"concepts":[{"id":"https://openalex.org/C2777164566","wikidata":"https://www.wikidata.org/wiki/Q419257","display_name":"Carbene","level":3,"score":0.8378593921661377},{"id":"https://openalex.org/C2778815869","wikidata":"https://www.wikidata.org/wiki/Q25325213","display_name":"Reductive elimination","level":3,"score":0.8191322088241577},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.755452036857605},{"id":"https://openalex.org/C2776300020","wikidata":"https://www.wikidata.org/wiki/Q422423","display_name":"Bromide","level":2,"score":0.6450437307357788},{"id":"https://openalex.org/C2780183160","wikidata":"https://www.wikidata.org/wiki/Q10337058","display_name":"Nitroalkene","level":4,"score":0.6095942854881287},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.5676183104515076},{"id":"https://openalex.org/C94882840","wikidata":"https://www.wikidata.org/wiki/Q2123471","display_name":"Oxidative addition","level":3,"score":0.4700794517993927},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.45348164439201355},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.4374787211418152},{"id":"https://openalex.org/C48424934","wikidata":"https://www.wikidata.org/wiki/Q898912","display_name":"Coupling reaction","level":3,"score":0.4286264479160309},{"id":"https://openalex.org/C163638829","wikidata":"https://www.wikidata.org/wiki/Q900337","display_name":"Lewis acids and bases","level":3,"score":0.41183581948280334},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.3697679042816162},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.26188692450523376},{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.2167537808418274}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.32657/10356/73859","doi":"https://doi.org/10.32657/10356/73859","is_oa":true,"landing_page_url":"https://doi.org/10.32657/10356/73859","pdf_url":"https://dr.ntu.edu.sg/bitstream/10356/73859/1/WangYuhuang_2017.pdf","source":null,"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nanyang Technological University","raw_type":"dissertation"},{"id":"pmh:oai:dr.ntu.edu.sg:10356/73859","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/10356/73859","pdf_url":null,"source":{"id":"https://openalex.org/S4306402609","display_name":"DR-NTU (Nanyang Technological University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I172675005","host_organization_name":"Nanyang Technological University","host_organization_lineage":["https://openalex.org/I172675005"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Thesis"}],"best_oa_location":{"id":"doi:10.32657/10356/73859","doi":"https://doi.org/10.32657/10356/73859","is_oa":true,"landing_page_url":"https://doi.org/10.32657/10356/73859","pdf_url":"https://dr.ntu.edu.sg/bitstream/10356/73859/1/WangYuhuang_2017.pdf","source":null,"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Nanyang Technological University","raw_type":"dissertation"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2800190044.pdf","grobid_xml":"https://content.openalex.org/works/W2800190044.grobid-xml"},"referenced_works_count":5,"referenced_works":["https://openalex.org/W658534291","https://openalex.org/W2487413726","https://openalex.org/W2798992920","https://openalex.org/W6600062020","https://openalex.org/W6600756316"],"related_works":["https://openalex.org/W2525167161","https://openalex.org/W3092301630","https://openalex.org/W2582748086","https://openalex.org/W2625317081","https://openalex.org/W3075119080","https://openalex.org/W4319867071","https://openalex.org/W4407930779","https://openalex.org/W2048122722","https://openalex.org/W2952444533","https://openalex.org/W3091483831"],"abstract_inverted_index":{"This":[0],"thesis":[1],"focuses":[2],"on":[3,37],"exploring":[4],"single-electron-transfer":[5],"(SET)":[6],"reductive":[7,48,108,185],"coupling":[8,49],"reactions":[9,29],"catalyzed":[10],"by":[11],"N-heterocyclic":[12],"carbene":[13],"(NHC)":[14],"organocatalysts.It":[15],"contained":[16],"five":[17],"chapters:":[18],"Chapter":[19],"1":[20],"gives":[21],"a":[22,46,106,166,175,183],"brief":[23],"introduction":[24],"to":[25,78,87,218],"NHC-catalyzed":[26,38],"electron-pair":[27],"transfer":[28],"involving":[30],"different":[31],"key":[32],"intermediates,":[33],"and":[34,41,118,134,143,197,214],"recent":[35],"discoveries":[36],"SET":[39,56,70,116,129,195],"process":[40,57,71,117,130,196],"relating":[42],"reactions.Chapter":[43],"2":[44],"describes":[45,182],"carbene-catalyzed":[47,107,184],"reaction":[50,53,125,172,200],"for":[51,84,159],"\u03b2-nitroalkenes.The":[52],"pathway":[54,173],"includes":[55],"mimicking":[58],"the":[59,90,93,124,128,144,151,202],"thiamine":[60],"pyrophosphate":[61],"(TPP)catalyzed":[62],"oxidative":[63],"decarboxylation":[64],"of":[65,76,95,110,146,154,187,211,216],"pyruvate":[66],"in":[67,99,169,179],"living":[68],"systems.The":[69],"starts":[72],"from":[73,127],"Breslow":[74,135],"intermediate":[75,98,158],"nitroalkene":[77,81],"generate":[79],"corresponding":[80,155],"radical":[82,96,157,204],"anion":[83,97],"further":[85,160],"transforming":[86],"homocoupling":[88],"product.For":[89],"first":[91,139],"time,":[92],"presence":[94],"NHC-organocatalytic":[100],"system":[101],"is":[102],"revealed.Chapter":[103],"3":[104],"introduces":[105],"cross-coupling":[109,186],"nitrobenzyl":[111,132,137,156,188,203,212],"bromides":[112,189],"with":[113,190,220],"nitroalkenes":[114],"via":[115,194,208],"formal":[119,198],"1,4-addition.Control":[120],"experiments":[121],"prove":[122],"that":[123],"initiates":[126],"between":[131],"bromide":[133,138,147,213],"intermediate.The":[136],"obtains":[140],"one":[141],"electron,":[142],"elimination":[145,215],"takes":[148],"place":[149],"during":[150],"following":[152],"generation":[153],"transformation.The":[161],"bromo":[162],"group":[163,168],"serves":[164],"as":[165],"leaving":[167],"this":[170],"reaction.The":[171],"shows":[174],"new":[176],"activation":[177],"mode":[178],"NHCorganocatalysis.Chapter":[180],"4":[181],"ketones":[191],"or":[192],"imines":[193],"1,2-addition.This":[199],"utilizes":[201],"intermediate,":[205],"which":[206],"generates":[207],"single-electron":[209],"reduction":[210],"bromide,":[217],"react":[219],"\u03b1,\u03b2-unsaturated":[221],"ketoesters,":[222]},"counts_by_year":[],"updated_date":"2026-09-07T09:17:50.787605","created_date":"2018-05-17T00:00:00"}
