{"id":"https://openalex.org/W2792425607","doi":"https://doi.org/10.1002/cphc.201800102","title":"Effect of Magnesium Bond on the Competition Between Hydrogen and Halogen Bonds and the Induction of Proton and Halogen Transfer","display_name":"Effect of Magnesium Bond on the Competition Between Hydrogen and Halogen Bonds and the Induction of Proton and Halogen Transfer","publication_year":2018,"publication_date":"2018-03-15","ids":{"openalex":"https://openalex.org/W2792425607","doi":"https://doi.org/10.1002/cphc.201800102","mag":"2792425607","pmid":"https://pubmed.ncbi.nlm.nih.gov/29544030"},"language":"en","primary_location":{"id":"doi:10.1002/cphc.201800102","doi":"https://doi.org/10.1002/cphc.201800102","is_oa":false,"landing_page_url":"https://doi.org/10.1002/cphc.201800102","pdf_url":null,"source":{"id":"https://openalex.org/S169445072","display_name":"ChemPhysChem","issn_l":"1439-4235","issn":["1439-4235","1439-7641"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","medline","norway-2","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemPhysChem","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5072621033","display_name":"Huili Xu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I18452120","display_name":"Yantai University","ror":"https://ror.org/01rp41m56","country_code":"CN","type":"education","lineage":["https://openalex.org/I18452120"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Hui\u2010Li Xu","raw_affiliation_strings":["Laboratory of Theoretical and Computational Chemistry and School of Chemistry and Chemical Engineering, Yantai University, Yantai, 264005 China"],"raw_orcid":"https://orcid.org/0000-0003-1486-6772","affiliations":[{"raw_affiliation_string":"Laboratory of Theoretical and Computational Chemistry and School of Chemistry and Chemical Engineering, Yantai University, Yantai, 264005 China","institution_ids":["https://openalex.org/I18452120"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100746646","display_name":"Qingzhong Li","orcid":"https://orcid.org/0000-0003-1486-6772","observed_orcids":["https://orcid.org/0000-0003-1486-6772"]},"institutions":[{"id":"https://openalex.org/I18452120","display_name":"Yantai University","ror":"https://ror.org/01rp41m56","country_code":"CN","type":"education","lineage":["https://openalex.org/I18452120"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Qing\u2010Zhong Li","raw_affiliation_strings":["Laboratory of Theoretical and Computational Chemistry and School of Chemistry and Chemical Engineering, Yantai University, Yantai, 264005 China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratory of Theoretical and Computational Chemistry and School of Chemistry and Chemical Engineering, Yantai University, Yantai, 264005 China","institution_ids":["https://openalex.org/I18452120"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5085422555","display_name":"Steve Scheiner","orcid":"https://orcid.org/0000-0003-0793-0369","observed_orcids":["https://orcid.org/0000-0003-0793-0369"]},"institutions":[{"id":"https://openalex.org/I121980950","display_name":"Utah State University","ror":"https://ror.org/00h6set76","country_code":"US","type":"education","lineage":["https://openalex.org/I121980950"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Steve Scheiner","raw_affiliation_strings":["Department of Chemistry and Biochemistry, Utah State University, Logan, UT, 84322-0300 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, Utah State University, Logan, UT, 84322-0300 USA","institution_ids":["https://openalex.org/I121980950"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5085422555","https://openalex.org/A5100746646"],"corresponding_institution_ids":["https://openalex.org/I121980950","https://openalex.org/I18452120"],"apc_list":{"value":4550,"currency":"USD","value_usd":4550},"apc_paid":null,"fwci":1.4065,"has_fulltext":false,"cited_by_count":15,"citation_normalized_percentile":{"value":0.77128063,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"19","issue":"12","first_page":"1456","last_page":"1464"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":0.9916999936103821,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10798","display_name":"Crystallography and molecular interactions","score":0.9916999936103821,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10002","display_name":"Advanced Chemical Physics Studies","score":0.0020000000949949026,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.000699999975040555,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/halogen-bonding","display_name":"halogen bonding","score":0.6600000262260437},{"id":"https://openalex.org/keywords/hydrogen-bonding","display_name":"hydrogen bonding","score":0.9700000286102295},{"id":"https://openalex.org/keywords/halogen-transfer","display_name":"halogen transfer","score":0.44200000166893005},{"id":"https://openalex.org/keywords/proton-transfer","display_name":"proton transfer","score":0.9869999885559082},{"id":"https://openalex.org/keywords/hydrogen-cyanide","display_name":"hydrogen cyanide","score":0.5950000286102295},{"id":"https://openalex.org/keywords/ammonia","display_name":"ammonia","score":0.781000018119812},{"id":"https://openalex.org/keywords/imidazole","display_name":"imidazole","score":1.0}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8298579454421997},{"id":"https://openalex.org/C46062151","wikidata":"https://www.wikidata.org/wiki/Q19605","display_name":"Halogen","level":3,"score":0.7302209138870239},{"id":"https://openalex.org/C112887158","wikidata":"https://www.wikidata.org/wiki/Q169324","display_name":"Hydrogen bond","level":3,"score":0.659622311592102},{"id":"https://openalex.org/C23029723","wikidata":"https://www.wikidata.org/wiki/Q1193318","display_name":"Halogen bond","level":4,"score":0.5662733912467957},{"id":"https://openalex.org/C2779546866","wikidata":"https://www.wikidata.org/wiki/Q531306","display_name":"Dimer","level":2,"score":0.4978048801422119},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.4871968626976013},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.40178409218788147},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3842713534832001},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.088022381067276},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1002/cphc.201800102","doi":"https://doi.org/10.1002/cphc.201800102","is_oa":false,"landing_page_url":"https://doi.org/10.1002/cphc.201800102","pdf_url":null,"source":{"id":"https://openalex.org/S169445072","display_name":"ChemPhysChem","issn_l":"1439-4235","issn":["1439-4235","1439-7641"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","medline","norway-2","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ChemPhysChem","raw_type":"journal-article"},{"id":"pmid:29544030","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/29544030","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemphyschem : a European journal of chemical physics and physical chemistry","raw_type":"Journal Article"},{"id":"pmh:oai:digitalcommons.usu.edu:chem_facpub-1878","doi":null,"is_oa":false,"landing_page_url":"https://digitalcommons.usu.edu/chem_facpub/878","pdf_url":null,"source":{"id":"https://openalex.org/S4377196327","display_name":"Digital Commons - USU (Utah State University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I121980950","host_organization_name":"Utah State University","host_organization_lineage":["https://openalex.org/I121980950"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Chemistry and Biochemistry Faculty Publications","raw_type":"text"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G4700683438","display_name":"PhXF3\u5f62\u6210tetrel bond\u7684\u4f5c\u7528\u673a\u5236\u53ca\u5176\u5728\u6676\u4f53\u5de5\u7a0b\u4e2d\u7684\u5e94\u7528","funder_award_id":"21573188","funder_id":"https://openalex.org/F4320321001","funder_display_name":"National Natural Science Foundation of China"}],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":71,"referenced_works":["https://openalex.org/W1969734888","https://openalex.org/W1970875319","https://openalex.org/W1971885435","https://openalex.org/W1979462720","https://openalex.org/W1981111904","https://openalex.org/W1985074716","https://openalex.org/W1990885770","https://openalex.org/W1995958134","https://openalex.org/W1996724294","https://openalex.org/W1997737857","https://openalex.org/W1998205665","https://openalex.org/W2004988896","https://openalex.org/W2011430822","https://openalex.org/W2012257849","https://openalex.org/W2018813322","https://openalex.org/W2019808266","https://openalex.org/W2019849324","https://openalex.org/W2021987583","https://openalex.org/W2022564289","https://openalex.org/W2022950330","https://openalex.org/W2029320720","https://openalex.org/W2029667189","https://openalex.org/W2035573839","https://openalex.org/W2036767327","https://openalex.org/W2038767330","https://openalex.org/W2040757475","https://openalex.org/W2041310233","https://openalex.org/W2042400619","https://openalex.org/W2046004602","https://openalex.org/W2049768089","https://openalex.org/W2052117214","https://openalex.org/W2059922341","https://openalex.org/W2065132107","https://openalex.org/W2065524854","https://openalex.org/W2065611538","https://openalex.org/W2073297586","https://openalex.org/W2073473733","https://openalex.org/W2074947906","https://openalex.org/W2075648013","https://openalex.org/W2081887248","https://openalex.org/W2107276905","https://openalex.org/W2109791983","https://openalex.org/W2111659007","https://openalex.org/W2129614892","https://openalex.org/W2130918438","https://openalex.org/W2132525235","https://openalex.org/W2140631947","https://openalex.org/W2145506136","https://openalex.org/W2145609739","https://openalex.org/W2148941593","https://openalex.org/W2180760246","https://openalex.org/W2244945679","https://openalex.org/W2278804447","https://openalex.org/W2282700903","https://openalex.org/W2344838111","https://openalex.org/W2410103223","https://openalex.org/W2515356196","https://openalex.org/W2532226635","https://openalex.org/W2545209810","https://openalex.org/W2548889947","https://openalex.org/W2551597078","https://openalex.org/W2558880713","https://openalex.org/W2576491971","https://openalex.org/W2592462758","https://openalex.org/W2597727278","https://openalex.org/W2598072555","https://openalex.org/W2612228630","https://openalex.org/W2618442314","https://openalex.org/W2733230278","https://openalex.org/W2952921574","https://openalex.org/W4388166534"],"related_works":["https://openalex.org/W7155012624","https://openalex.org/W3110929395","https://openalex.org/W2325191220","https://openalex.org/W2161495803","https://openalex.org/W2994437033","https://openalex.org/W2070020905","https://openalex.org/W2187192897","https://openalex.org/W2006465483","https://openalex.org/W3144120984","https://openalex.org/W2158723118"],"abstract_inverted_index":{"Abstract":[0],"HOX":[1],"(X=Cl,":[2],"Br,":[3,34],"I,":[4],"and":[5,23,33,67,78],"At)":[6],"can":[7],"engage":[8],"in":[9,63,94,126],"either":[10],"a":[11,19,52,86,92,113,138],"H\u2010bond":[12],"(HB)":[13],"or":[14],"halogen":[15],"bond":[16],"(XB)":[17],"with":[18,45,54,134],"base\u2010like":[20],"HCN,":[21],"NH3,":[22],"imidazole.":[24],"Although":[25],"the":[26,37,55,64,76,79,95,98,104,108,123,127,135],"former":[27],"is":[28,36,40,131],"energetically":[29],"preferred":[30],"for":[31,43],"X=Cl":[32],"it":[35],"XB":[38],"that":[39],"more":[41],"stable":[42],"At,":[44],"I":[46],"showing":[47],"little":[48],"preference.":[49],"MgY2":[50],"forms":[51],"Mg\u2010bond":[53,99,111],"O":[56,119],"atom":[57,125],"of":[58,116,122,137],"HOX,":[59],"which":[60],"grows":[61],"stronger":[62],"order":[65],"X=Cl<Br<I<At":[66],"Y=F<Cl<Br.":[68],"When":[69],"all":[70],"three":[71],"molecules":[72],"are":[73,82],"combined,":[74],"both":[75],"Mg":[77],"H/X":[80,128],"bonds":[81],"cooperatively":[83],"strengthened":[84],"to":[85,102,120],"large":[87],"degree.":[88],"Rather":[89],"than":[90],"causing":[91],"reversal":[93],"HB/XB":[96],"competition,":[97],"acts":[100],"primarily":[101],"amplify":[103],"natural":[105],"preference":[106],"within":[107],"dimer.":[109],"The":[110],"induces":[112],"certain":[114],"degree":[115],"transfer":[117],"from":[118],"N":[121],"bridging":[124],"bond.":[129],"Comparison":[130],"also":[132],"made":[133],"effects":[136],"Be\u2010bond.":[139]},"counts_by_year":[{"year":2026,"cited_by_count":4},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":5},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":2}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2018-03-29T00:00:00"}