{"id":"https://openalex.org/W2789971996","doi":"https://doi.org/10.1021/acscatal.7b04337","title":"Catalyst-Controlled Stereoselective Synthesis of Atropisomers","display_name":"Catalyst-Controlled Stereoselective Synthesis of Atropisomers","publication_year":2018,"publication_date":"2018-03-07","ids":{"openalex":"https://openalex.org/W2789971996","doi":"https://doi.org/10.1021/acscatal.7b04337","mag":"2789971996"},"language":"en","primary_location":{"id":"doi:10.1021/acscatal.7b04337","doi":"https://doi.org/10.1021/acscatal.7b04337","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acscatal.7b04337","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://edoc.unibas.ch/68649/1/Perspective.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5067446129","display_name":"Bouthayna Zilate","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1850255","display_name":"University of Basel","ror":"https://ror.org/02s6k3f65","country_code":"CH","type":"education","lineage":["https://openalex.org/I1850255"]}],"countries":["CH"],"is_corresponding":false,"raw_author_name":"Bouthayna Zilate","raw_affiliation_strings":["Department of Chemistry, University of Basel, St. Johanns-Ring 19, CH-4056 Basel, Switzerland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Basel, St. Johanns-Ring 19, CH-4056 Basel, Switzerland","institution_ids":["https://openalex.org/I1850255"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5057006005","display_name":"Alessandro Castrogiovanni","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1850255","display_name":"University of Basel","ror":"https://ror.org/02s6k3f65","country_code":"CH","type":"education","lineage":["https://openalex.org/I1850255"]}],"countries":["CH"],"is_corresponding":false,"raw_author_name":"Alessandro Castrogiovanni","raw_affiliation_strings":["Department of Chemistry, University of Basel, St. Johanns-Ring 19, CH-4056 Basel, Switzerland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Basel, St. Johanns-Ring 19, CH-4056 Basel, Switzerland","institution_ids":["https://openalex.org/I1850255"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5008910219","display_name":"Christof Sparr","orcid":"https://orcid.org/0000-0002-4213-0941","observed_orcids":["https://orcid.org/0000-0002-4213-0941"]},"institutions":[{"id":"https://openalex.org/I1850255","display_name":"University of Basel","ror":"https://ror.org/02s6k3f65","country_code":"CH","type":"education","lineage":["https://openalex.org/I1850255"]}],"countries":["CH"],"is_corresponding":true,"raw_author_name":"Christof Sparr","raw_affiliation_strings":["Department of Chemistry, University of Basel, St. Johanns-Ring 19, CH-4056 Basel, Switzerland"],"raw_orcid":"https://orcid.org/0000-0002-4213-0941","affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Basel, St. Johanns-Ring 19, CH-4056 Basel, Switzerland","institution_ids":["https://openalex.org/I1850255"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5008910219"],"corresponding_institution_ids":["https://openalex.org/I1850255"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":14.5003,"has_fulltext":false,"cited_by_count":291,"citation_normalized_percentile":{"value":0.99849039,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":99,"max":100},"biblio":{"volume":"8","issue":"4","first_page":"2981","last_page":"2988"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T13115","display_name":"Axial and Atropisomeric Chirality Synthesis","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T13115","display_name":"Axial and Atropisomeric Chirality Synthesis","score":1.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11611","display_name":"Cyclopropane Reaction Mechanisms","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/atropisomers","display_name":"atropisomers","score":0.9950000047683716},{"id":"https://openalex.org/keywords/stereoselective-synthesis","display_name":"stereoselective synthesis","score":0.9070000052452087},{"id":"https://openalex.org/keywords/axially-chiral-compounds","display_name":"axially chiral compounds","score":0.8709999918937683},{"id":"https://openalex.org/keywords/chiral-scaffolds","display_name":"chiral scaffolds","score":0.8460000157356262},{"id":"https://openalex.org/keywords/transition-metal-catalysis","display_name":"transition metal catalysis","score":0.8659999966621399},{"id":"https://openalex.org/keywords/hydrogen-bond-catalysis","display_name":"hydrogen-bond catalysis","score":0.9419999718666077},{"id":"https://openalex.org/keywords/chiral-phosphoric-acid-catalysis","display_name":"chiral phosphoric acid catalysis","score":0.9769999980926514},{"id":"https://openalex.org/keywords/chiral-amine-catalysis","display_name":"chiral amine catalysis","score":0.9319999814033508},{"id":"https://openalex.org/keywords/isomeric-purity","display_name":"isomeric purity","score":0.6100000143051147}],"concepts":[{"id":"https://openalex.org/C167981757","wikidata":"https://www.wikidata.org/wiki/Q757764","display_name":"Atropisomer","level":2,"score":0.9070138335227966},{"id":"https://openalex.org/C134195300","wikidata":"https://www.wikidata.org/wiki/Q902071","display_name":"Stereocenter","level":4,"score":0.899544358253479},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6409187912940979},{"id":"https://openalex.org/C181647583","wikidata":"https://www.wikidata.org/wiki/Q903429","display_name":"Stereoselectivity","level":3,"score":0.6376625299453735},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.565454363822937},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.5512668490409851},{"id":"https://openalex.org/C201977512","wikidata":"https://www.wikidata.org/wiki/Q752152","display_name":"Axial chirality","level":4,"score":0.4865785837173462},{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.4714820384979248},{"id":"https://openalex.org/C66972969","wikidata":"https://www.wikidata.org/wiki/Q898995","display_name":"Organocatalysis","level":4,"score":0.4466175138950348},{"id":"https://openalex.org/C124668440","wikidata":"https://www.wikidata.org/wiki/Q2305173","display_name":"Chirality (physics)","level":5,"score":0.4434509575366974},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3725602626800537},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.11063507199287415},{"id":"https://openalex.org/C20621625","wikidata":"https://www.wikidata.org/wiki/Q6961432","display_name":"Nambu\u2013Jona-Lasinio model","level":4,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C7602139","wikidata":"https://www.wikidata.org/wiki/Q6718","display_name":"Quark","level":2,"score":0.0},{"id":"https://openalex.org/C52703039","wikidata":"https://www.wikidata.org/wiki/Q5101837","display_name":"Chiral symmetry breaking","level":3,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/acscatal.7b04337","doi":"https://doi.org/10.1021/acscatal.7b04337","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acscatal.7b04337","pdf_url":null,"source":{"id":"https://openalex.org/S37391459","display_name":"ACS Catalysis","issn_l":"2155-5435","issn":["2155-5435"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-2","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Catalysis","raw_type":"journal-article"},{"id":"pmh:oai:edoc.unibas.ch:68649","doi":null,"is_oa":true,"landing_page_url":"https://edoc.unibas.ch/68649/1/Perspective.pdf","pdf_url":"https://edoc.unibas.ch/68649/1/Perspective.pdf","source":{"id":"https://openalex.org/S4306401836","display_name":"edoc (University of Basel)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1850255","host_organization_name":"University of Basel","host_organization_lineage":["https://openalex.org/I1850255"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"","raw_type":"Article"}],"best_oa_location":{"id":"pmh:oai:edoc.unibas.ch:68649","doi":null,"is_oa":true,"landing_page_url":"https://edoc.unibas.ch/68649/1/Perspective.pdf","pdf_url":"https://edoc.unibas.ch/68649/1/Perspective.pdf","source":{"id":"https://openalex.org/S4306401836","display_name":"edoc (University of Basel)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1850255","host_organization_name":"University of Basel","host_organization_lineage":["https://openalex.org/I1850255"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"acceptedVersion","is_accepted":true,"is_published":false,"raw_source_name":"","raw_type":"Article"},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G6980370945","display_name":null,"funder_award_id":"BSSGI0-155902/1","funder_id":"https://openalex.org/F4320320924","funder_display_name":"Schweizerischer Nationalfonds zur F\u00f6rderung der Wissenschaftlichen Forschung"}],"funders":[{"id":"https://openalex.org/F4320310466","display_name":"Universit\u00e4t Basel","ror":"https://ror.org/02s6k3f65"},{"id":"https://openalex.org/F4320320924","display_name":"Schweizerischer Nationalfonds zur F\u00f6rderung der Wissenschaftlichen Forschung","ror":"https://ror.org/00yjd3n13"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":70,"referenced_works":["https://openalex.org/W1007187129","https://openalex.org/W1486981226","https://openalex.org/W1862339235","https://openalex.org/W1969899567","https://openalex.org/W1973464977","https://openalex.org/W1974087398","https://openalex.org/W1974992646","https://openalex.org/W1992520966","https://openalex.org/W2004083513","https://openalex.org/W2006655443","https://openalex.org/W2007029574","https://openalex.org/W2007683040","https://openalex.org/W2010055073","https://openalex.org/W2011912658","https://openalex.org/W2012306808","https://openalex.org/W2012988230","https://openalex.org/W2014233492","https://openalex.org/W2017592845","https://openalex.org/W2021237684","https://openalex.org/W2022389996","https://openalex.org/W2028356410","https://openalex.org/W2030764038","https://openalex.org/W2036927822","https://openalex.org/W2047247336","https://openalex.org/W2048829286","https://openalex.org/W2051686900","https://openalex.org/W2057600463","https://openalex.org/W2063544580","https://openalex.org/W2083955230","https://openalex.org/W2085834352","https://openalex.org/W2086933085","https://openalex.org/W2108108694","https://openalex.org/W2109537644","https://openalex.org/W2119711596","https://openalex.org/W2120736293","https://openalex.org/W2122839730","https://openalex.org/W2126982344","https://openalex.org/W2130383370","https://openalex.org/W2153800765","https://openalex.org/W2155701539","https://openalex.org/W2167901312","https://openalex.org/W2171650541","https://openalex.org/W2194615052","https://openalex.org/W2196945764","https://openalex.org/W2209292129","https://openalex.org/W2219722747","https://openalex.org/W2289935168","https://openalex.org/W2290518353","https://openalex.org/W2298078127","https://openalex.org/W2312772836","https://openalex.org/W2324783453","https://openalex.org/W2332470495","https://openalex.org/W2334339597","https://openalex.org/W2335442430","https://openalex.org/W2350898566","https://openalex.org/W2474436045","https://openalex.org/W2579530789","https://openalex.org/W2582703112","https://openalex.org/W2600928690","https://openalex.org/W2603726119","https://openalex.org/W2606061958","https://openalex.org/W2611267954","https://openalex.org/W2736830325","https://openalex.org/W2761110632","https://openalex.org/W2763229625","https://openalex.org/W2788101284","https://openalex.org/W2950014944","https://openalex.org/W2952236040","https://openalex.org/W4252698750","https://openalex.org/W4253833297"],"related_works":["https://openalex.org/W4399766526","https://openalex.org/W4396519532","https://openalex.org/W4387118653","https://openalex.org/W4229004273","https://openalex.org/W4403529022","https://openalex.org/W7204234037","https://openalex.org/W4380995130","https://openalex.org/W7203904023","https://openalex.org/W4213385974","https://openalex.org/W4303959131"],"abstract_inverted_index":{"Owing":[0],"to":[1,32,45],"their":[2],"favorable":[3],"molecular":[4],"topology,":[5],"atropisomers":[6],"represent":[7],"particularly":[8],"valuable":[9],"chiral":[10,35,69,90],"scaffolds":[11],"for":[12,57],"numerous":[13],"applications":[14],"throughout":[15],"academic":[16],"research":[17],"and":[18,93],"industry.":[19],"Nevertheless,":[20],"whereas":[21],"various":[22],"well-established":[23],"catalyst-controlled":[24],"methodologies":[25],"allow":[26],"addressing":[27],"stereocenter":[28],"configuration,":[29],"efficient":[30],"procedures":[31],"prepare":[33],"axially":[34,68],"compounds":[36],"in":[37,49,73],"high":[38],"isomeric":[39],"purity":[40],"are":[41,96],"still":[42],"scarce.":[43],"Complementary":[44],"the":[46,50,58],"comprehensive":[47],"reviews":[48],"area,":[51],"this":[52],"Perspective":[53],"features":[54],"representative":[55],"advances":[56],"catalyst-stereocontrolled":[59],"synthesis":[60],"of":[61],"atropisomeric":[62],"scaffolds.":[63],"With":[64],"a":[65],"focus":[66],"on":[67],"motifs":[70],"frequently":[71],"utilized":[72],"catalysis":[74,95],"or":[75],"medicinal":[76],"chemistry,":[77],"selected":[78],"recent":[79],"examples":[80],"encompassing":[81],"unique":[82],"stereoselective":[83],"transition":[84],"metal,":[85],"hydrogen":[86],"bond,":[87],"ion":[88],"pairing,":[89],"phosphoric":[91],"acid,":[92],"amine":[94],"highlighted.":[97]},"counts_by_year":[{"year":2026,"cited_by_count":15},{"year":2025,"cited_by_count":19},{"year":2024,"cited_by_count":33},{"year":2023,"cited_by_count":37},{"year":2022,"cited_by_count":39},{"year":2021,"cited_by_count":39},{"year":2020,"cited_by_count":37},{"year":2019,"cited_by_count":49},{"year":2018,"cited_by_count":23}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2018-03-29T00:00:00"}