{"id":"https://openalex.org/W2789665441","doi":"https://doi.org/10.1021/acs.iecr.7b05397","title":"How Do Reaction and Reactor Conditions Affect Photoinduced Electron/Energy Transfer Reversible Addition\u2013Fragmentation Transfer Polymerization?","display_name":"How Do Reaction and Reactor Conditions Affect Photoinduced Electron/Energy Transfer Reversible Addition\u2013Fragmentation Transfer Polymerization?","publication_year":2018,"publication_date":"2018-03-13","ids":{"openalex":"https://openalex.org/W2789665441","doi":"https://doi.org/10.1021/acs.iecr.7b05397","mag":"2789665441"},"language":"en","primary_location":{"id":"doi:10.1021/acs.iecr.7b05397","doi":"https://doi.org/10.1021/acs.iecr.7b05397","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.iecr.7b05397","pdf_url":null,"source":{"id":"https://openalex.org/S202680183","display_name":"Industrial & Engineering Chemistry Research","issn_l":"0888-5885","issn":["0888-5885","1520-5045"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Industrial & Engineering Chemistry Research","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5009856358","display_name":"Pierce N. Kurek","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I83328450","display_name":"Miami University","ror":"https://ror.org/05nbqxr67","country_code":"US","type":"education","lineage":["https://openalex.org/I83328450"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Pierce N. Kurek","raw_affiliation_strings":["Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States","institution_ids":["https://openalex.org/I83328450"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5078808079","display_name":"Alex J. Kloster","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I83328450","display_name":"Miami University","ror":"https://ror.org/05nbqxr67","country_code":"US","type":"education","lineage":["https://openalex.org/I83328450"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Alex J. Kloster","raw_affiliation_strings":["Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States","institution_ids":["https://openalex.org/I83328450"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5070471888","display_name":"Kyle A. Weaver","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I83328450","display_name":"Miami University","ror":"https://ror.org/05nbqxr67","country_code":"US","type":"education","lineage":["https://openalex.org/I83328450"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Kyle A. Weaver","raw_affiliation_strings":["Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States","institution_ids":["https://openalex.org/I83328450"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5052787551","display_name":"Rodrigo Manahan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I31746571","display_name":"UNSW Sydney","ror":"https://ror.org/03r8z3t63","country_code":"AU","type":"education","lineage":["https://openalex.org/I31746571"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Rodrigo Manahan","raw_affiliation_strings":["Centre for Advanced Macromolecular Design and Australian Centre for NanoMedicine, School of Chemical Engineering, The University of New South Wales, Sydney, NSW 2052, Australia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre for Advanced Macromolecular Design and Australian Centre for NanoMedicine, School of Chemical Engineering, The University of New South Wales, Sydney, NSW 2052, Australia","institution_ids":["https://openalex.org/I31746571"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5078101720","display_name":"Michael L. Allegrezza","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I83328450","display_name":"Miami University","ror":"https://ror.org/05nbqxr67","country_code":"US","type":"education","lineage":["https://openalex.org/I83328450"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Michael L. Allegrezza","raw_affiliation_strings":["Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States","institution_ids":["https://openalex.org/I83328450"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5055649176","display_name":"Nethmi De Alwis Watuthanthrige","orcid":"https://orcid.org/0000-0001-7058-2438","observed_orcids":["https://orcid.org/0000-0001-7058-2438"]},"institutions":[{"id":"https://openalex.org/I83328450","display_name":"Miami University","ror":"https://ror.org/05nbqxr67","country_code":"US","type":"education","lineage":["https://openalex.org/I83328450"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Nethmi De Alwis Watuthanthrige","raw_affiliation_strings":["Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States","institution_ids":["https://openalex.org/I83328450"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5001395511","display_name":"Cyrille Andre Boyer","orcid":"https://orcid.org/0000-0002-4564-4702","observed_orcids":["https://orcid.org/0000-0002-4564-4702"]},"institutions":[{"id":"https://openalex.org/I31746571","display_name":"UNSW Sydney","ror":"https://ror.org/03r8z3t63","country_code":"AU","type":"education","lineage":["https://openalex.org/I31746571"]}],"countries":["AU"],"is_corresponding":true,"raw_author_name":"Cyrille Boyer","raw_affiliation_strings":["Centre for Advanced Macromolecular Design and Australian Centre for NanoMedicine, School of Chemical Engineering, The University of New South Wales, Sydney, NSW 2052, Australia"],"raw_orcid":"https://orcid.org/0000-0002-4564-4702","affiliations":[{"raw_affiliation_string":"Centre for Advanced Macromolecular Design and Australian Centre for NanoMedicine, School of Chemical Engineering, The University of New South Wales, Sydney, NSW 2052, Australia","institution_ids":["https://openalex.org/I31746571"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049862311","display_name":"Jennifer A. Reeves","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I83328450","display_name":"Miami University","ror":"https://ror.org/05nbqxr67","country_code":"US","type":"education","lineage":["https://openalex.org/I83328450"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Jennifer A. Reeves","raw_affiliation_strings":["Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States","institution_ids":["https://openalex.org/I83328450"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5074585419","display_name":"Dominik Konkolewicz","orcid":"https://orcid.org/0000-0002-3828-5481","observed_orcids":["https://orcid.org/0000-0002-3828-5481"]},"institutions":[{"id":"https://openalex.org/I83328450","display_name":"Miami University","ror":"https://ror.org/05nbqxr67","country_code":"US","type":"education","lineage":["https://openalex.org/I83328450"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Dominik Konkolewicz","raw_affiliation_strings":["Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States"],"raw_orcid":"https://orcid.org/0000-0002-3828-5481","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, Miami University, 651 E High St., Oxford, Ohio 45056, United States","institution_ids":["https://openalex.org/I83328450"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5001395511","https://openalex.org/A5049862311","https://openalex.org/A5074585419"],"corresponding_institution_ids":["https://openalex.org/I31746571","https://openalex.org/I83328450"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":3.3806,"has_fulltext":false,"cited_by_count":58,"citation_normalized_percentile":{"value":0.93704172,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":93,"max":99},"biblio":{"volume":"57","issue":"12","first_page":"4203","last_page":"4213"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.9907000064849854,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.9907000064849854,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12570","display_name":"Photopolymerization techniques and applications","score":0.008500000461935997,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10701","display_name":"Radical Photochemical Reactions","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/pet-raft-polymerization","display_name":"PET-RAFT polymerization","score":0.9490000009536743},{"id":"https://openalex.org/keywords/raft-polymerization","display_name":"RAFT polymerization","score":0.9120000004768372},{"id":"https://openalex.org/keywords/polymerization-kinetics","display_name":"polymerization kinetics","score":0.7580000162124634},{"id":"https://openalex.org/keywords/reactor-geometry","display_name":"reactor geometry","score":0.6899999976158142},{"id":"https://openalex.org/keywords/cylindrical-reactor","display_name":"cylindrical reactor","score":0.6710000038146973},{"id":"https://openalex.org/keywords/photocatalyst-loading","display_name":"photocatalyst loading","score":0.8080000281333923},{"id":"https://openalex.org/keywords/dilution-effect","display_name":"dilution effect","score":0.6679999828338623},{"id":"https://openalex.org/keywords/optical-density","display_name":"optical density","score":0.5619999766349792}],"concepts":[{"id":"https://openalex.org/C44228677","wikidata":"https://www.wikidata.org/wiki/Q181898","display_name":"Polymerization","level":3,"score":0.8038471341133118},{"id":"https://openalex.org/C121120078","wikidata":"https://www.wikidata.org/wiki/Q3737603","display_name":"Chain transfer","level":5,"score":0.7775419354438782},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5472660660743713},{"id":"https://openalex.org/C175113610","wikidata":"https://www.wikidata.org/wiki/Q3394849","display_name":"Reaction rate","level":3,"score":0.5129237174987793},{"id":"https://openalex.org/C96618451","wikidata":"https://www.wikidata.org/wiki/Q3028008","display_name":"Dilution","level":2,"score":0.4930886924266815},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4695490002632141},{"id":"https://openalex.org/C191015642","wikidata":"https://www.wikidata.org/wiki/Q1132459","display_name":"Fragmentation (computing)","level":2,"score":0.4270109534263611},{"id":"https://openalex.org/C111998727","wikidata":"https://www.wikidata.org/wiki/Q2620998","display_name":"Radical polymerization","level":4,"score":0.37758731842041016},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.35752108693122864},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.3362271785736084},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.309814989566803},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.1671026349067688},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.09157684445381165},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0},{"id":"https://openalex.org/C111919701","wikidata":"https://www.wikidata.org/wiki/Q9135","display_name":"Operating system","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.iecr.7b05397","doi":"https://doi.org/10.1021/acs.iecr.7b05397","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.iecr.7b05397","pdf_url":null,"source":{"id":"https://openalex.org/S202680183","display_name":"Industrial & Engineering Chemistry Research","issn_l":"0888-5885","issn":["0888-5885","1520-5045"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Industrial & Engineering Chemistry Research","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1500857221","display_name":null,"funder_award_id":"57243-DNI7","funder_id":"https://openalex.org/F4320332454","funder_display_name":"American Chemical Society Petroleum Research Fund"}],"funders":[{"id":"https://openalex.org/F4320309249","display_name":"University of Miami","ror":"https://ror.org/02dgjyy92"},{"id":"https://openalex.org/F4320332454","display_name":"American Chemical Society Petroleum Research Fund","ror":"https://ror.org/059dqb057"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":60,"referenced_works":["https://openalex.org/W1837456710","https://openalex.org/W1968614751","https://openalex.org/W1971943306","https://openalex.org/W1975588461","https://openalex.org/W1983234215","https://openalex.org/W2019734596","https://openalex.org/W2021965676","https://openalex.org/W2027521170","https://openalex.org/W2036333105","https://openalex.org/W2039045964","https://openalex.org/W2060571716","https://openalex.org/W2068416409","https://openalex.org/W2074554162","https://openalex.org/W2080896481","https://openalex.org/W2081361953","https://openalex.org/W2083930966","https://openalex.org/W2088890545","https://openalex.org/W2090568310","https://openalex.org/W2107335703","https://openalex.org/W2111469549","https://openalex.org/W2123092820","https://openalex.org/W2126413506","https://openalex.org/W2127982211","https://openalex.org/W2134124609","https://openalex.org/W2150184000","https://openalex.org/W2152941952","https://openalex.org/W2153249890","https://openalex.org/W2156003679","https://openalex.org/W2161457415","https://openalex.org/W2167539127","https://openalex.org/W2171023891","https://openalex.org/W2181001240","https://openalex.org/W2226518113","https://openalex.org/W2277042127","https://openalex.org/W2288335213","https://openalex.org/W2289007734","https://openalex.org/W2290956822","https://openalex.org/W2299481623","https://openalex.org/W2313595743","https://openalex.org/W2315584134","https://openalex.org/W2332285994","https://openalex.org/W2333025780","https://openalex.org/W2334798071","https://openalex.org/W2343904929","https://openalex.org/W2473432380","https://openalex.org/W2482784562","https://openalex.org/W2511854215","https://openalex.org/W2517143524","https://openalex.org/W2517743539","https://openalex.org/W2520218970","https://openalex.org/W2529854953","https://openalex.org/W2547132653","https://openalex.org/W2556159405","https://openalex.org/W2561386004","https://openalex.org/W2563814925","https://openalex.org/W2581850458","https://openalex.org/W2737509966","https://openalex.org/W2757228295","https://openalex.org/W2759655425","https://openalex.org/W2952659176"],"related_works":["https://openalex.org/W4313401636","https://openalex.org/W3208876831","https://openalex.org/W7133162834","https://openalex.org/W2520218970","https://openalex.org/W2887316024","https://openalex.org/W4364354110","https://openalex.org/W4408328657","https://openalex.org/W3137261543","https://openalex.org/W4389987917","https://openalex.org/W2265147219"],"abstract_inverted_index":{"The":[0,72],"impact":[1,31],"of":[2,32,47,74,91,108],"conditions":[3],"was":[4,38,77],"investigated":[5],"on":[6,41],"a":[7,78,134],"model":[8],"photoinduced":[9],"electron/energy":[10],"transfer":[11,15],"reversible":[12],"addition\u2013fragmentation":[13],"chain":[14],"(PET-RAFT)":[16],"polymerization.":[17,49],"Within":[18],"the":[19,30,42,48,75,92,109,113,127,146],"cylindrical":[20,68],"geometries":[21],"studied,":[22],"with":[23,85,95,103,112,126,139],"relatively":[24,39,56],"small":[25,40,59],"changes":[26,60],"in":[27,61,81],"path":[28],"length,":[29],"reaction":[33,65,83],"vessel":[34],"dimensions":[35],"and":[36,45,64,116],"dilution":[37],"polymerization":[43,123],"kinetics":[44],"control":[46],"This":[50],"suggests":[51],"that":[52],"PET-RAFT":[53],"can":[54],"be":[55],"insensitive":[57],"to":[58,136,145],"reactor":[62],"geometry":[63],"volume":[66],"when":[67],"systems":[69],"are":[70],"used.":[71],"intensity":[73],"photoreactor":[76],"key":[79],"factor":[80],"determining":[82],"rate,":[84],"an":[86,104,117],"approximate":[87,105,118],"1/2":[88,106],"order":[89,107,120],"scaling":[90,121],"apparent":[93,110,122],"rate":[94,111,124,137],"intensity.":[96],"Reactant":[97],"concentration":[98],"ratios":[99],"were":[100],"also":[101],"important,":[102],"photocatalyst":[114],"loading":[115],"\u22121/2":[119],"coefficient":[125],"RAFT":[128],"agent":[129],"concentration.":[130],"However,":[131],"there":[132],"is":[133],"limit":[135],"increases":[138],"higher":[140],"Ir":[141],"catalyst":[142],"loadings":[143],"due":[144],"optical":[147],"density.":[148]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":4},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":10},{"year":2022,"cited_by_count":7},{"year":2021,"cited_by_count":7},{"year":2020,"cited_by_count":11},{"year":2019,"cited_by_count":8},{"year":2018,"cited_by_count":7}],"updated_date":"2026-10-16T09:59:22.235173","created_date":"2018-03-29T00:00:00"}