{"id":"https://openalex.org/W2773496854","doi":"https://doi.org/10.1021/jacs.7b11372","title":"Pd-Catalyzed Aerobic Oxidation Reactions: Strategies To Increase Catalyst Lifetimes","display_name":"Pd-Catalyzed Aerobic Oxidation Reactions: Strategies To Increase Catalyst Lifetimes","publication_year":2017,"publication_date":"2017-12-15","ids":{"openalex":"https://openalex.org/W2773496854","doi":"https://doi.org/10.1021/jacs.7b11372","mag":"2773496854","pmid":"https://pubmed.ncbi.nlm.nih.gov/29244945"},"language":"en","primary_location":{"id":"doi:10.1021/jacs.7b11372","doi":"https://doi.org/10.1021/jacs.7b11372","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.7b11372","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://www.osti.gov/servlets/purl/1594171","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5090577818","display_name":"Wilson C. Ho","orcid":"https://orcid.org/0000-0002-1322-7728","observed_orcids":["https://orcid.org/0000-0002-1322-7728"]},"institutions":[{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Wilson C. Ho","raw_affiliation_strings":["Department\rof Chemistry, Stanford University, Stanford, California 94305, United States"],"raw_orcid":"https://orcid.org/0000-0002-1322-7728","affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, Stanford University, Stanford, California 94305, United States","institution_ids":["https://openalex.org/I97018004"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Kevin Chung","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Kevin Chung","raw_affiliation_strings":["Department\rof Chemistry, Stanford University, Stanford, California 94305, United States","Formosa Plastics Corporation, 201 Formosa Drive, Point Comfort, Texas 77978, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, Stanford University, Stanford, California 94305, United States","institution_ids":["https://openalex.org/I97018004"]},{"raw_affiliation_string":"Formosa Plastics Corporation, 201 Formosa Drive, Point Comfort, Texas 77978, United States","institution_ids":[]}]},{"author_position":"middle","author":{"id":null,"display_name":"Andrew J. Ingram","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I74994324","display_name":"Archer Daniels Midland (United States)","ror":"https://ror.org/0499r1e09","country_code":"US","type":"company","lineage":["https://openalex.org/I74994324"]},{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Andrew J. Ingram","raw_affiliation_strings":["Department\rof Chemistry, Stanford University, Stanford, California 94305, United States","James\rR. Randall Research Center, Archer Daniels Midland Company, Decatur, Illinois 62521, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, Stanford University, Stanford, California 94305, United States","institution_ids":["https://openalex.org/I97018004"]},{"raw_affiliation_string":"James\rR. Randall Research Center, Archer Daniels Midland Company, Decatur, Illinois 62521, United States","institution_ids":["https://openalex.org/I74994324"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5009737401","display_name":"Robert M. Waymouth","orcid":"https://orcid.org/0000-0001-9862-9509","observed_orcids":["https://orcid.org/0000-0001-9862-9509"]},"institutions":[{"id":"https://openalex.org/I97018004","display_name":"Stanford University","ror":"https://ror.org/00f54p054","country_code":"US","type":"education","lineage":["https://openalex.org/I97018004"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Robert M. Waymouth","raw_affiliation_strings":["Department\rof Chemistry, Stanford University, Stanford, California 94305, United States"],"raw_orcid":"https://orcid.org/0000-0001-9862-9509","affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, Stanford University, Stanford, California 94305, United States","institution_ids":["https://openalex.org/I97018004"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5009737401"],"corresponding_institution_ids":["https://openalex.org/I97018004"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.0243,"has_fulltext":true,"cited_by_count":46,"citation_normalized_percentile":{"value":0.86324547,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":90,"max":99},"biblio":{"volume":"140","issue":"2","first_page":"748","last_page":"757"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.9970999956130981,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11989","display_name":"Oxidative Organic Chemistry Reactions","score":0.9970999956130981,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11747","display_name":"Metal-Catalyzed Oxygenation Mechanisms","score":0.00139999995008111,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12136","display_name":"Vanadium and Halogenation Chemistry","score":0.0006000000284984708,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/palladium-catalysis","display_name":"palladium catalysis","score":0.9369999766349792},{"id":"https://openalex.org/keywords/aerobic-oxidation","display_name":"aerobic oxidation","score":0.996999979019165},{"id":"https://openalex.org/keywords/neocuproine","display_name":"neocuproine","score":0.8209999799728394},{"id":"https://openalex.org/keywords/catalyst-lifetime","display_name":"catalyst lifetime","score":0.7749999761581421},{"id":"https://openalex.org/keywords/catalyst-deactivation","display_name":"catalyst deactivation","score":0.9039999842643738},{"id":"https://openalex.org/keywords/h-atom-abstraction","display_name":"H-atom abstraction","score":0.847000002861023},{"id":"https://openalex.org/keywords/styrene","display_name":"styrene","score":0.9480000138282776},{"id":"https://openalex.org/keywords/polyol-oxidation","display_name":"polyol oxidation","score":0.8550000190734863},{"id":"https://openalex.org/keywords/turnover-number","display_name":"turnover number","score":0.5950000286102295}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9587430357933044},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.8190302848815918},{"id":"https://openalex.org/C37329643","wikidata":"https://www.wikidata.org/wiki/Q789331","display_name":"Autoxidation","level":2,"score":0.7897369861602783},{"id":"https://openalex.org/C2777566558","wikidata":"https://www.wikidata.org/wiki/Q28917","display_name":"Styrene","level":4,"score":0.6447733044624329},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.6019548773765564},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4572870135307312},{"id":"https://openalex.org/C502130503","wikidata":"https://www.wikidata.org/wiki/Q1089","display_name":"Palladium","level":3,"score":0.41799864172935486},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.35739558935165405},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.28550809621810913},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.06970113515853882},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.0},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/jacs.7b11372","doi":"https://doi.org/10.1021/jacs.7b11372","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.7b11372","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:29244945","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/29244945","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"},{"id":"pmh:oai:osti.gov:1594171","doi":null,"is_oa":true,"landing_page_url":"https://www.osti.gov/biblio/1594171","pdf_url":"https://www.osti.gov/servlets/purl/1594171","source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":{"id":"pmh:oai:osti.gov:1594171","doi":null,"is_oa":true,"landing_page_url":"https://www.osti.gov/biblio/1594171","pdf_url":"https://www.osti.gov/servlets/purl/1594171","source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null},"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G4116929324","display_name":null,"funder_award_id":"DE-SC0018168","funder_id":"https://openalex.org/F4320337480","funder_display_name":"Basic Energy Sciences"},{"id":"https://openalex.org/G81725469","display_name":"SELECTIVE CATALYTIC OXIDATIONS: OPPORTUNITIES AND CHALLENGES FOR SELECTIVE CONVERSION OF RENEWABLE RESOURCE","funder_award_id":"DESC0018168","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"},{"id":"https://openalex.org/F4320308507","display_name":"Stanford University","ror":"https://ror.org/00f54p054"},{"id":"https://openalex.org/F4320337368","display_name":"Division of Graduate Education","ror":"https://ror.org/00whkrf32"},{"id":"https://openalex.org/F4320337480","display_name":"Basic Energy Sciences","ror":"https://ror.org/05mg91w61"}],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2773496854.pdf","grobid_xml":"https://content.openalex.org/works/W2773496854.grobid-xml"},"referenced_works_count":70,"referenced_works":["https://openalex.org/W96563269","https://openalex.org/W565854973","https://openalex.org/W1637643788","https://openalex.org/W1882683277","https://openalex.org/W1964323238","https://openalex.org/W1970863295","https://openalex.org/W1972978696","https://openalex.org/W1975382808","https://openalex.org/W1983329470","https://openalex.org/W1994258202","https://openalex.org/W2000573520","https://openalex.org/W2006231539","https://openalex.org/W2008836533","https://openalex.org/W2013464543","https://openalex.org/W2015222967","https://openalex.org/W2020357456","https://openalex.org/W2024337307","https://openalex.org/W2028823380","https://openalex.org/W2035911699","https://openalex.org/W2040264806","https://openalex.org/W2041930594","https://openalex.org/W2044671255","https://openalex.org/W2046786060","https://openalex.org/W2047171111","https://openalex.org/W2048088234","https://openalex.org/W2054722884","https://openalex.org/W2061774444","https://openalex.org/W2072554835","https://openalex.org/W2079743706","https://openalex.org/W2082697989","https://openalex.org/W2089719161","https://openalex.org/W2106116366","https://openalex.org/W2109324613","https://openalex.org/W2110852454","https://openalex.org/W2112441679","https://openalex.org/W2112989618","https://openalex.org/W2120415641","https://openalex.org/W2124278844","https://openalex.org/W2128466174","https://openalex.org/W2129417288","https://openalex.org/W2131027449","https://openalex.org/W2138813228","https://openalex.org/W2143562550","https://openalex.org/W2147899939","https://openalex.org/W2153134776","https://openalex.org/W2171065938","https://openalex.org/W2179651922","https://openalex.org/W2220687085","https://openalex.org/W2312405816","https://openalex.org/W2312499626","https://openalex.org/W2315498760","https://openalex.org/W2315885464","https://openalex.org/W2319023873","https://openalex.org/W2325672596","https://openalex.org/W2327847449","https://openalex.org/W2335269334","https://openalex.org/W2418285149","https://openalex.org/W2471368047","https://openalex.org/W2497677305","https://openalex.org/W2503149857","https://openalex.org/W2526470276","https://openalex.org/W2570278065","https://openalex.org/W2570354702","https://openalex.org/W2577227104","https://openalex.org/W2761892148","https://openalex.org/W2949290708","https://openalex.org/W2950639846","https://openalex.org/W2951109569","https://openalex.org/W3217536492","https://openalex.org/W4244822363"],"related_works":["https://openalex.org/W2319023873","https://openalex.org/W4317438691","https://openalex.org/W2044671255","https://openalex.org/W2950036878","https://openalex.org/W2138708846","https://openalex.org/W2056494928","https://openalex.org/W2062185297","https://openalex.org/W3143387953","https://openalex.org/W6981088998","https://openalex.org/W1990625436"],"abstract_inverted_index":{"(1,":[0],"neocuproine":[1,43,80],"=":[2],"2,9-dimethyl-1,10-phenanthroline)":[3],"is":[4,146],"an":[5],"effective":[6,147],"catalyst":[7,55,64,101],"precursor":[8],"for":[9],"the":[10,42,79,93,117,155],"selective":[11,156],"oxidation":[12,158],"of":[13,41,63,95,119,159,171],"primary":[14],"and":[15,21,25,103,143],"secondary":[16],"alcohols,":[17],"vicinal":[18],"diols,":[19],"polyols,":[20],"carbohydrates.":[22],"Both":[23],"air":[24],"benzoquinone":[26],"can":[27],"be":[28],"used":[29],"as":[30,90,92,130,139,165,167],"terminal":[31],"oxidants,":[32],"but":[33],"aerobic":[34,54,111,157],"oxidations":[35],"are":[36],"accompanied":[37],"by":[38,60,74],"oxidative":[39],"degradation":[40],"ligand,":[44],"thus":[45],"necessitating":[46],"high":[47],"Pd":[48,150],"loadings.":[49],"Several":[50],"strategies":[51,153],"to":[52,85,105,125],"improve":[53],"lifetimes":[56,102],"were":[57],"devised,":[58],"guided":[59],"mechanistic":[61],"studies":[62,67,133],"deactivation.":[65],"These":[66,152],"implicate":[68],"a":[69,173],"radical":[70],"autoxidation":[71],"mechanism":[72],"initiated":[73],"H":[75,87,97,140],"atom":[76,88,98,141],"abstraction":[77],"from":[78],"ligand.":[81],"Ligand":[82],"modifications":[83],"designed":[84],"retard":[86],"abstractions":[89],"well":[91],"addition":[94,118],"sacrificial":[96],"donors":[99,142],"increase":[100],"lead":[104],"higher":[106],"turnover":[107],"numbers":[108],"(TON)":[109],"under":[110],"conditions.":[112],"Additional":[113],"investigations":[114],"revealed":[115],"that":[116,135,144],"benzylic":[120,136],"hydroperoxides":[121,137],"or":[122],"styrene":[123,145],"leads":[124],"significant":[126],"increases":[127],"in":[128],"TON":[129],"well.":[131],"Mechanistic":[132],"suggest":[134],"function":[138],"at":[148],"intercepting":[149],"hydrides.":[151],"enabled":[154],"polyols":[160],"on":[161],"preparative":[162],"scales":[163],"using":[164],"little":[166],"0.25":[168],"mol":[169],"%":[170],"Pd,":[172],"major":[174],"improvement":[175],"over":[176],"previous":[177],"work.":[178]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":3},{"year":2023,"cited_by_count":5},{"year":2022,"cited_by_count":8},{"year":2021,"cited_by_count":8},{"year":2020,"cited_by_count":7},{"year":2019,"cited_by_count":7},{"year":2018,"cited_by_count":5}],"updated_date":"2026-11-03T10:50:19.383937","created_date":"2017-12-22T00:00:00"}
