{"id":"https://openalex.org/W2770355995","doi":"https://doi.org/10.1021/jacs.7b10817","title":"Molecular Scaffolding Strategy with Synergistic Active Centers To Facilitate Electrocatalytic CO 2 Reduction to Hydrocarbon/Alcohol","display_name":"Molecular Scaffolding Strategy with Synergistic Active Centers To Facilitate Electrocatalytic CO 2 Reduction to Hydrocarbon/Alcohol","publication_year":2017,"publication_date":"2017-11-19","ids":{"openalex":"https://openalex.org/W2770355995","doi":"https://doi.org/10.1021/jacs.7b10817","mag":"2770355995","pmid":"https://pubmed.ncbi.nlm.nih.gov/29151346"},"language":"en","primary_location":{"id":"doi:10.1021/jacs.7b10817","doi":"https://doi.org/10.1021/jacs.7b10817","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.7b10817","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5034195419","display_name":"Yan Jiao","orcid":"https://orcid.org/0000-0003-1329-4290","observed_orcids":["https://orcid.org/0000-0003-1329-4290"]},"institutions":[{"id":"https://openalex.org/I5681781","display_name":"The University of Adelaide","ror":"https://ror.org/00892tw58","country_code":"AU","type":"education","lineage":["https://openalex.org/I4405259444","https://openalex.org/I5681781"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Yan Jiao","raw_affiliation_strings":["School\rof Chemical Engineering, The University of Adelaide, Adelaide, South Australia 5005, Australia"],"raw_orcid":"https://orcid.org/0000-0003-1329-4290","affiliations":[{"raw_affiliation_string":"School\rof Chemical Engineering, The University of Adelaide, Adelaide, South Australia 5005, Australia","institution_ids":["https://openalex.org/I5681781"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5028236459","display_name":"Yao Zheng","orcid":"https://orcid.org/0000-0002-2411-8041","observed_orcids":["https://orcid.org/0000-0002-2411-8041"]},"institutions":[{"id":"https://openalex.org/I5681781","display_name":"The University of Adelaide","ror":"https://ror.org/00892tw58","country_code":"AU","type":"education","lineage":["https://openalex.org/I4405259444","https://openalex.org/I5681781"]}],"countries":["AU"],"is_corresponding":false,"raw_author_name":"Yao Zheng","raw_affiliation_strings":["School\rof Chemical Engineering, The University of Adelaide, Adelaide, South Australia 5005, Australia"],"raw_orcid":"https://orcid.org/0000-0002-2411-8041","affiliations":[{"raw_affiliation_string":"School\rof Chemical Engineering, The University of Adelaide, Adelaide, South Australia 5005, Australia","institution_ids":["https://openalex.org/I5681781"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100400321","display_name":"Ping Chen","orcid":"https://orcid.org/0000-0003-0274-5674","observed_orcids":["https://orcid.org/0000-0003-0274-5674","https://orcid.org/0000-0002-7646-2020"]},"institutions":[{"id":"https://openalex.org/I143868143","display_name":"Anhui University","ror":"https://ror.org/05th6yx34","country_code":"CN","type":"education","lineage":["https://openalex.org/I143868143"]},{"id":"https://openalex.org/I5681781","display_name":"The University of Adelaide","ror":"https://ror.org/00892tw58","country_code":"AU","type":"education","lineage":["https://openalex.org/I4405259444","https://openalex.org/I5681781"]}],"countries":["AU","CN"],"is_corresponding":false,"raw_author_name":"Ping Chen","raw_affiliation_strings":["School\rof Chemical Engineering, The University of Adelaide, Adelaide, South Australia 5005, Australia","School\rof Chemistry and Chemical Engineering, Anhui University, Hefei 230000, P. R. China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School\rof Chemical Engineering, The University of Adelaide, Adelaide, South Australia 5005, Australia","institution_ids":["https://openalex.org/I5681781"]},{"raw_affiliation_string":"School\rof Chemistry and Chemical Engineering, Anhui University, Hefei 230000, P. R. China","institution_ids":["https://openalex.org/I143868143"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5065693067","display_name":"Mietek Jaroniec","orcid":"https://orcid.org/0000-0002-1178-5611","observed_orcids":["https://orcid.org/0000-0002-1178-5611"]},"institutions":[{"id":"https://openalex.org/I149910238","display_name":"Kent State University","ror":"https://ror.org/049pfb863","country_code":"US","type":"education","lineage":["https://openalex.org/I149910238"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Mietek Jaroniec","raw_affiliation_strings":["Department\rof Chemistry and Biochemistry, Kent State University, Kent, Ohio 44242, United States"],"raw_orcid":"https://orcid.org/0000-0002-1178-5611","affiliations":[{"raw_affiliation_string":"Department\rof Chemistry and Biochemistry, Kent State University, Kent, Ohio 44242, United States","institution_ids":["https://openalex.org/I149910238"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5032628543","display_name":"Shi\u2010Zhang Qiao","orcid":"https://orcid.org/0000-0002-4568-8422","observed_orcids":["https://orcid.org/0000-0002-4568-8422","https://orcid.org/0000-0001-8748-7955"]},"institutions":[{"id":"https://openalex.org/I162868743","display_name":"Tianjin University","ror":"https://ror.org/012tb2g32","country_code":"CN","type":"education","lineage":["https://openalex.org/I162868743"]},{"id":"https://openalex.org/I5681781","display_name":"The University of Adelaide","ror":"https://ror.org/00892tw58","country_code":"AU","type":"education","lineage":["https://openalex.org/I4405259444","https://openalex.org/I5681781"]}],"countries":["AU","CN"],"is_corresponding":true,"raw_author_name":"Shi-Zhang Qiao","raw_affiliation_strings":["School\rof Chemical Engineering, The University of Adelaide, Adelaide, South Australia 5005, Australia","School\rof Materials Science and Engineering, Tianjin University, Tianjin 300072, P. R. China"],"raw_orcid":"https://orcid.org/0000-0002-4568-8422","affiliations":[{"raw_affiliation_string":"School\rof Chemical Engineering, The University of Adelaide, Adelaide, South Australia 5005, Australia","institution_ids":["https://openalex.org/I5681781"]},{"raw_affiliation_string":"School\rof Materials Science and Engineering, Tianjin University, Tianjin 300072, P. R. China","institution_ids":["https://openalex.org/I162868743"]}]}],"institutions":[],"countries_distinct_count":3,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5032628543"],"corresponding_institution_ids":["https://openalex.org/I162868743","https://openalex.org/I5681781"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":15.6182,"has_fulltext":false,"cited_by_count":532,"citation_normalized_percentile":{"value":0.99538212,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":99,"max":100},"biblio":{"volume":"139","issue":"49","first_page":"18093","last_page":"18100"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11784","display_name":"CO2 Reduction Techniques and Catalysts","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11784","display_name":"CO2 Reduction Techniques and Catalysts","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10030","display_name":"Electrocatalysts for Energy Conversion","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2105","display_name":"Renewable Energy, Sustainability and the Environment"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10495","display_name":"Catalysts for Methane Reforming","score":0.0,"subfield":{"id":"https://openalex.org/subfields/1503","display_name":"Catalysis"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/electrochemical-co2-reduction","display_name":"electrochemical CO2 reduction","score":0.9900000095367432},{"id":"https://openalex.org/keywords/graphitic-carbon-nitride","display_name":"graphitic carbon nitride","score":0.9409999847412109},{"id":"https://openalex.org/keywords/synergistic-catalysis","display_name":"synergistic catalysis","score":0.9269999861717224},{"id":"https://openalex.org/keywords/c2-products","display_name":"C2+ products","score":0.5799999833106995},{"id":"https://openalex.org/keywords/co2-adsorption","display_name":"CO2 adsorption","score":0.7170000076293945},{"id":"https://openalex.org/keywords/electronic-structure-tuning","display_name":"electronic structure modulation","score":0.7860000133514404},{"id":"https://openalex.org/keywords/nitrogen-doped-carbon","display_name":"nitrogen-doped carbon","score":0.7710000276565552},{"id":"https://openalex.org/keywords/cu-111-surface","display_name":"Cu(111) surface","score":0.7170000076293945}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9785259962081909},{"id":"https://openalex.org/C2777207669","wikidata":"https://www.wikidata.org/wiki/Q43648","display_name":"Hydrocarbon","level":2,"score":0.7181369066238403},{"id":"https://openalex.org/C2781066024","wikidata":"https://www.wikidata.org/wiki/Q156","display_name":"Alcohol","level":2,"score":0.6518616676330566},{"id":"https://openalex.org/C111335779","wikidata":"https://www.wikidata.org/wiki/Q3454686","display_name":"Reduction (mathematics)","level":2,"score":0.6325120329856873},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.4753803312778473},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.4556763768196106},{"id":"https://openalex.org/C89429830","wikidata":"https://www.wikidata.org/wiki/Q735710","display_name":"Scaffold","level":2,"score":0.4367571771144867},{"id":"https://openalex.org/C2781327392","wikidata":"https://www.wikidata.org/wiki/Q2832210","display_name":"Primary alcohol","level":3,"score":0.412034273147583},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.28832346200942993},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C2524010","wikidata":"https://www.wikidata.org/wiki/Q8087","display_name":"Geometry","level":1,"score":0.0},{"id":"https://openalex.org/C33923547","wikidata":"https://www.wikidata.org/wiki/Q395","display_name":"Mathematics","level":0,"score":0.0},{"id":"https://openalex.org/C136229726","wikidata":"https://www.wikidata.org/wiki/Q327092","display_name":"Biomedical engineering","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/jacs.7b10817","doi":"https://doi.org/10.1021/jacs.7b10817","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.7b10817","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:29151346","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/29151346","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"},{"id":"pmh:oai:digital.library.adelaide.edu.au:2440/110676","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/2440/110676","pdf_url":null,"source":{"id":"https://openalex.org/S4306401835","display_name":"Adelaide Research & Scholarship (AR&S) (University of Adelaide)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I5681781","host_organization_name":"The University of Adelaide","host_organization_lineage":["https://openalex.org/I5681781"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"https://doi.org/10.1021/jacs.7b10817","raw_type":"Journal article"}],"best_oa_location":null,"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/7","display_name":"Affordable and clean energy","score":0.75},{"id":"https://metadata.un.org/sdg/13","display_name":"Climate action","score":0.5351999998092651}],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G4337750347","display_name":"Nanostructured Electrocatalysts for Clean Fuels Production","funder_award_id":"DP160104866","funder_id":"https://openalex.org/F4320334704","funder_display_name":"Australian Research Council"},{"id":"https://openalex.org/G4442629036","display_name":"Development of functional dendrimer-like inorganic nanomaterials with hierarchical pores for biological applications","funder_award_id":"DP140104062","funder_id":"https://openalex.org/F4320334704","funder_display_name":"Australian Research Council"},{"id":"https://openalex.org/G4942170350","display_name":"Design of Nanostructured Electrocatalysts for Water Splitting","funder_award_id":"DE160101163","funder_id":"https://openalex.org/F4320334704","funder_display_name":"Australian Research Council"},{"id":"https://openalex.org/G6405890229","display_name":"Photocatalysts for solar hydrogen production","funder_award_id":"DP170104464","funder_id":"https://openalex.org/F4320334704","funder_display_name":"Australian Research Council"},{"id":"https://openalex.org/G7373356505","display_name":"Solar-driven sustainable production of fuels and chemicals","funder_award_id":"FL170100154","funder_id":"https://openalex.org/F4320334704","funder_display_name":"Australian Research Council"}],"funders":[{"id":"https://openalex.org/F4320312169","display_name":"National Computational Infrastructure","ror":"https://ror.org/04yx6dh41"},{"id":"https://openalex.org/F4320315885","display_name":"Australian Government","ror":"https://ror.org/0314h5y94"},{"id":"https://openalex.org/F4320320540","display_name":"Australian Synchrotron","ror":"https://ror.org/03vk18a84"},{"id":"https://openalex.org/F4320334704","display_name":"Australian Research Council","ror":"https://ror.org/05mmh0f86"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":64,"referenced_works":["https://openalex.org/W1899071315","https://openalex.org/W1973891115","https://openalex.org/W1976002844","https://openalex.org/W1979544533","https://openalex.org/W1981368803","https://openalex.org/W1991003106","https://openalex.org/W2006420601","https://openalex.org/W2014897468","https://openalex.org/W2052515101","https://openalex.org/W2054704030","https://openalex.org/W2059885388","https://openalex.org/W2060023027","https://openalex.org/W2070161787","https://openalex.org/W2070259209","https://openalex.org/W2076787222","https://openalex.org/W2079105963","https://openalex.org/W2082498048","https://openalex.org/W2083222334","https://openalex.org/W2085471965","https://openalex.org/W2090689053","https://openalex.org/W2093193003","https://openalex.org/W2126396070","https://openalex.org/W2135572171","https://openalex.org/W2147139866","https://openalex.org/W2154308826","https://openalex.org/W2170456486","https://openalex.org/W2171503883","https://openalex.org/W2202057872","https://openalex.org/W2225958871","https://openalex.org/W2241001655","https://openalex.org/W2257992222","https://openalex.org/W2292255513","https://openalex.org/W2297401062","https://openalex.org/W2319250790","https://openalex.org/W2323309348","https://openalex.org/W2323504704","https://openalex.org/W2330888951","https://openalex.org/W2339805231","https://openalex.org/W2340533519","https://openalex.org/W2438990463","https://openalex.org/W2513531240","https://openalex.org/W2521736035","https://openalex.org/W2529973511","https://openalex.org/W2554225655","https://openalex.org/W2560832335","https://openalex.org/W2569460474","https://openalex.org/W2579401689","https://openalex.org/W2582310832","https://openalex.org/W2584822254","https://openalex.org/W2586083027","https://openalex.org/W2586675271","https://openalex.org/W2591446277","https://openalex.org/W2596465153","https://openalex.org/W2602237473","https://openalex.org/W2613395675","https://openalex.org/W2619141030","https://openalex.org/W2619468913","https://openalex.org/W2624906538","https://openalex.org/W2734878332","https://openalex.org/W2737437113","https://openalex.org/W2738766279","https://openalex.org/W2745790361","https://openalex.org/W2750023029","https://openalex.org/W4232627022"],"related_works":["https://openalex.org/W4238611646","https://openalex.org/W2086122265","https://openalex.org/W2157457339","https://openalex.org/W2412724792","https://openalex.org/W2913103681","https://openalex.org/W2367857673","https://openalex.org/W2331057957","https://openalex.org/W1999101670","https://openalex.org/W2013151581","https://openalex.org/W1983080880"],"abstract_inverted_index":{"A":[0,235],"major":[1],"impediment":[2],"to":[3,39,42,66,166,173,230],"the":[4,12,33,44,68,78,89,101,122,128,138,150,159,181,197,213,218,242,246,252,255],"electrocatalytic":[5],"CO":[6,162,170],"2":[7,163,171,233],"reduction":[8,172],"reaction":[9,144],"(CRR)":[10],"is":[11],"lack":[13],"of":[14,35,54,63,80,103,121,125,141,161,187,245,254],"electrocatalysts":[15,36,81],"with":[16,82,178,207],"both":[17],"high":[18,83],"efficiency":[19],"and":[20,60,164,184,241,258],"good":[21,236],"selectivity":[22,85],"toward":[23,86],"liquid":[24],"fuels":[25],"or":[26],"other":[27,185],"valuable":[28],"chemicals.":[29],"Effective":[30],"strategies":[31],"for":[32,77,117,212],"design":[34],"are":[37],"yet":[38],"be":[40,147],"discovered":[41],"substitute":[43],"conventional":[45],"trial-and-error":[46],"approach.":[47],"This":[48],"work":[49],"shows":[50],"that":[51,100],"a":[52,73,95,113,136,167,227],"combination":[53],"density":[55],"functional":[56],"theory":[57],"(DFT)":[58],"computation":[59],"experimental":[61],"validation":[62],"molecular":[64,114],"scaffolding":[65],"coordinate":[67],"metal":[69,201],"active":[70,209],"centers":[71,210],"presents":[72],"new":[74],"molecular-level":[75],"strategy":[76],"development":[79],"CRR":[84,247],"hydrocarbon/alcohol.":[87],"Taking":[88],"most":[90,198],"widely":[91],"investigated":[92],"Cu":[93,126,188],"as":[94,112,176],"probe,":[96],"our":[97],"study":[98],"reveals":[99],"use":[102],"graphitic":[104],"carbon":[105],"nitride":[106],"(g-C":[107],"3":[108,131,152,220,261],"N":[109,132,153,221,262],"4":[110,133,154,222,263],")":[111],"scaffold":[115],"allows":[116],"an":[118,203],"appropriate":[119],"modification":[120],"electronic":[123],"structure":[124],"in":[127],"resultant":[129],"Cu\u2013C":[130,151,219,260],"complex.":[134],"As":[135],"result,":[137],"adsorption":[139],"behavior":[140],"some":[142],"key":[143],"intermediates":[145],"can":[146],"optimized":[148],"on":[149,180,191,217,251],"surface,":[155],"which":[156,225],"greatly":[157],"benefits":[158],"activation":[160],"leads":[165],"more":[168],"facile":[169],"desired":[174],"products":[175],"compared":[177],"those":[179],"Cu(111)":[182],"surface":[183],"kinds":[186],"complexes":[189],"formed":[190],"nitrogen-doped":[192],"carbons.":[193],"Remarkably,":[194],"different":[195],"from":[196],"studied":[199],"elementary":[200],"surfaces,":[202],"intramolecular":[204],"synergistic":[205],"catalysis":[206],"dual":[208],"was":[211],"first":[214],"time":[215],"observed":[216],"complex":[223],"model,":[224],"possesses":[226],"unique":[228],"capability":[229],"generate":[231],"C":[232],"products.":[234],"agreement":[237],"between":[238],"electrochemical":[239],"measurements":[240],"DFT":[243],"analysis":[244],"has":[248],"been":[249],"achieved":[250],"basis":[253],"newly":[256],"designed":[257],"synthesized":[259],"electrocatalyst.":[264]},"counts_by_year":[{"year":2026,"cited_by_count":17},{"year":2025,"cited_by_count":37},{"year":2024,"cited_by_count":51},{"year":2023,"cited_by_count":59},{"year":2022,"cited_by_count":64},{"year":2021,"cited_by_count":85},{"year":2020,"cited_by_count":82},{"year":2019,"cited_by_count":92},{"year":2018,"cited_by_count":45}],"updated_date":"2026-10-19T09:35:57.686232","created_date":"2025-10-10T00:00:00"}
