{"id":"https://openalex.org/W2596931084","doi":null,"title":"The Zinc/Bromine Flow Battery: Fundamentals and Novel Materials for Technology Advancement","display_name":"The Zinc/Bromine Flow Battery: Fundamentals and Novel Materials for Technology Advancement","publication_year":2016,"publication_date":"2016-07-19","ids":{"openalex":"https://openalex.org/W2596931084","mag":"2596931084"},"language":"en","primary_location":{"id":"pmh:oai:ses.library.usyd.edu.au:2123/16394","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/2123/16394","pdf_url":null,"source":{"id":"https://openalex.org/S4306402414","display_name":"The Sydney eScholarship Repository (The University of Sydney)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I129604602","host_organization_name":"The University of Sydney","host_organization_lineage":["https://openalex.org/I129604602"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Thesis"},"volume":null,"type":"dissertation","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5076375148","display_name":"Gobinath Pillai Rajarathnam","orcid":"https://orcid.org/0000-0002-7838-0360","observed_orcids":["https://orcid.org/0000-0002-7838-0360"]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Gobinath Pillai Rajarathnam","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0002-7838-0360","affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5076375148"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":7,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11690","display_name":"Aqueous and Flow Batteries","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11690","display_name":"Aqueous and Flow Batteries","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T14444","display_name":"Power Systems and Renewable Energy","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2102","display_name":"Energy Engineering and Power Technology"},"field":{"id":"https://openalex.org/fields/21","display_name":"Energy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/zinc-bromine-flow-battery","display_name":"zinc-bromine flow battery","score":0.9789999723434448},{"id":"https://openalex.org/keywords/zinc-electrodeposition","display_name":"zinc electrodeposition","score":0.6669999957084656},{"id":"https://openalex.org/keywords/sulfate-electrolyte","display_name":"sulfate electrolyte","score":0.49000000953674316},{"id":"https://openalex.org/keywords/phosphate-electrolyte","display_name":"phosphate electrolyte","score":0.9089999794960022},{"id":"https://openalex.org/keywords/tetrahedral-zinc-complexes","display_name":"tetrahedral zinc complexes","score":0.8289999961853027},{"id":"https://openalex.org/keywords/ionic-liquid-additives","display_name":"ionic liquid additives","score":0.9509999752044678},{"id":"https://openalex.org/keywords/electrode-electrolyte-interface","display_name":"electrode-electrolyte interface","score":0.8870000243186951},{"id":"https://openalex.org/keywords/energy-storage","display_name":"energy storage","score":0.5289999842643738},{"id":"https://openalex.org/keywords/renewable-energy-intermittency","display_name":"renewable energy intermittency","score":0.7990000247955322}],"concepts":[{"id":"https://openalex.org/C517835270","wikidata":"https://www.wikidata.org/wiki/Q879","display_name":"Bromine","level":2,"score":0.6266970634460449},{"id":"https://openalex.org/C535196362","wikidata":"https://www.wikidata.org/wiki/Q758","display_name":"Zinc","level":2,"score":0.6118767261505127},{"id":"https://openalex.org/C555008776","wikidata":"https://www.wikidata.org/wiki/Q267298","display_name":"Battery (electricity)","level":3,"score":0.5192908644676208},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.4174792766571045},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.39123332500457764},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.34481287002563477},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.32649075984954834},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.3222922384738922},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.1342451274394989},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.07286745309829712},{"id":"https://openalex.org/C163258240","wikidata":"https://www.wikidata.org/wiki/Q25342","display_name":"Power (physics)","level":2,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"pmh:oai:ses.library.usyd.edu.au:2123/16394","doi":null,"is_oa":false,"landing_page_url":"http://hdl.handle.net/2123/16394","pdf_url":null,"source":{"id":"https://openalex.org/S4306402414","display_name":"The Sydney eScholarship Repository (The University of Sydney)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I129604602","host_organization_name":"The University of Sydney","host_organization_lineage":["https://openalex.org/I129604602"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Thesis"},{"id":"mag:2596931084","doi":null,"is_oa":false,"landing_page_url":"https://ses.library.usyd.edu.au/bitstream/2123/16394/2/rajarathnam_g_thesis.pdf","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[{"id":"https://metadata.un.org/sdg/7","display_name":"Affordable and clean energy","score":0.9853000044822693}],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":207,"referenced_works":["https://openalex.org/W37821655","https://openalex.org/W140850216","https://openalex.org/W350079331","https://openalex.org/W1503701659","https://openalex.org/W1521533637","https://openalex.org/W1538310988","https://openalex.org/W1598545088","https://openalex.org/W1599974001","https://openalex.org/W1630274445","https://openalex.org/W1656659695","https://openalex.org/W1720618126","https://openalex.org/W1941769491","https://openalex.org/W1945083283","https://openalex.org/W1963712116","https://openalex.org/W1963871309","https://openalex.org/W1964010261","https://openalex.org/W1964626537","https://openalex.org/W1965462413","https://openalex.org/W1965767049","https://openalex.org/W1966484515","https://openalex.org/W1966506074","https://openalex.org/W1967956939","https://openalex.org/W1969779271","https://openalex.org/W1969923259","https://openalex.org/W1970127494","https://openalex.org/W1972013448","https://openalex.org/W1972581659","https://openalex.org/W1973099745","https://openalex.org/W1977704619","https://openalex.org/W1978202905","https://openalex.org/W1978676310","https://openalex.org/W1978816969","https://openalex.org/W1979076727","https://openalex.org/W1979237037","https://openalex.org/W1979544533","https://openalex.org/W1980084338","https://openalex.org/W1981204912","https://openalex.org/W1981368803","https://openalex.org/W1981737501","https://openalex.org/W1983378088","https://openalex.org/W1983870505","https://openalex.org/W1985671991","https://openalex.org/W1987621685","https://openalex.org/W1988965030","https://openalex.org/W1989157562","https://openalex.org/W1989300822","https://openalex.org/W1989470795","https://openalex.org/W1990488730","https://openalex.org/W1990933886","https://openalex.org/W1991432121","https://openalex.org/W1994534915","https://openalex.org/W1995333963","https://openalex.org/W1995574399","https://openalex.org/W1996474075","https://openalex.org/W1998987022","https://openalex.org/W2002963147","https://openalex.org/W2007912531","https://openalex.org/W2008426812","https://openalex.org/W2009775084","https://openalex.org/W2011107695","https://openalex.org/W2011994005","https://openalex.org/W2013190587","https://openalex.org/W2014016413","https://openalex.org/W2014403137","https://openalex.org/W2014997883","https://openalex.org/W2015199069","https://openalex.org/W2015463672","https://openalex.org/W2015534088","https://openalex.org/W2016300982","https://openalex.org/W2019530426","https://openalex.org/W2019553243","https://openalex.org/W2019627895","https://openalex.org/W2020124388","https://openalex.org/W2022957353","https://openalex.org/W2023376100","https://openalex.org/W2023600771","https://openalex.org/W2023863575","https://openalex.org/W2023898515","https://openalex.org/W2025710788","https://openalex.org/W2025888962","https://openalex.org/W2027135746","https://openalex.org/W2028010755","https://openalex.org/W2028056984","https://openalex.org/W2028099529","https://openalex.org/W2030428021","https://openalex.org/W2031175889","https://openalex.org/W2031618898","https://openalex.org/W2032662310","https://openalex.org/W2033283554","https://openalex.org/W2034370794","https://openalex.org/W2035963096","https://openalex.org/W2036153622","https://openalex.org/W2036683950","https://openalex.org/W2037957514","https://openalex.org/W2038102635","https://openalex.org/W2040432202","https://openalex.org/W2041564711","https://openalex.org/W2041920621","https://openalex.org/W2042026874","https://openalex.org/W2043162120","https://openalex.org/W2043954057","https://openalex.org/W2045954641","https://openalex.org/W2046052287","https://openalex.org/W2046464001","https://openalex.org/W2046503796","https://openalex.org/W2047475093","https://openalex.org/W2047730985","https://openalex.org/W2047924371","https://openalex.org/W2049001178","https://openalex.org/W2049339655","https://openalex.org/W2049673314","https://openalex.org/W2050550472","https://openalex.org/W2050591158","https://openalex.org/W2050957889","https://openalex.org/W2052182876","https://openalex.org/W2052774831","https://openalex.org/W2052818396","https://openalex.org/W2055076027","https://openalex.org/W2055128695","https://openalex.org/W2055655412","https://openalex.org/W2056228485","https://openalex.org/W2057605757","https://openalex.org/W2059631240","https://openalex.org/W2060013835","https://openalex.org/W2062401185","https://openalex.org/W2063780005","https://openalex.org/W2063866856","https://openalex.org/W2064807075","https://openalex.org/W2065926973","https://openalex.org/W2066274620","https://openalex.org/W2066880706","https://openalex.org/W2067205503","https://openalex.org/W2067293340","https://openalex.org/W2069825095","https://openalex.org/W2070352690","https://openalex.org/W2072455224","https://openalex.org/W2073070517","https://openalex.org/W2074568034","https://openalex.org/W2075008956","https://openalex.org/W2075853414","https://openalex.org/W2076283824","https://openalex.org/W2078538117","https://openalex.org/W2080551469","https://openalex.org/W2081371965","https://openalex.org/W2081892385","https://openalex.org/W2083222334","https://openalex.org/W2083760881","https://openalex.org/W2083856893","https://openalex.org/W2084990590","https://openalex.org/W2085794129","https://openalex.org/W2086168389","https://openalex.org/W2086611821","https://openalex.org/W2087455100","https://openalex.org/W2087522681","https://openalex.org/W2089525884","https://openalex.org/W2091875228","https://openalex.org/W2092289648","https://openalex.org/W2093413593","https://openalex.org/W2097807619","https://openalex.org/W2100002658","https://openalex.org/W2101226854","https://openalex.org/W2103954978","https://openalex.org/W2108084892","https://openalex.org/W2110088947","https://openalex.org/W2111003787","https://openalex.org/W2114234026","https://openalex.org/W2115234257","https://openalex.org/W2115258833","https://openalex.org/W2116276018","https://openalex.org/W2119732846","https://openalex.org/W2120089208","https://openalex.org/W2122408573","https://openalex.org/W2122427541","https://openalex.org/W2123405170","https://openalex.org/W2124744931","https://openalex.org/W2124767684","https://openalex.org/W2124988295","https://openalex.org/W2126539454","https://openalex.org/W2126910559","https://openalex.org/W2133707082","https://openalex.org/W2135337656","https://openalex.org/W2141235977","https://openalex.org/W2147440227","https://openalex.org/W2147708819","https://openalex.org/W2150126492","https://openalex.org/W2151473996","https://openalex.org/W2152121108","https://openalex.org/W2155991654","https://openalex.org/W2161138491","https://openalex.org/W2163367894","https://openalex.org/W2166618387","https://openalex.org/W2167503549","https://openalex.org/W2169127840","https://openalex.org/W2169133444","https://openalex.org/W2171167960","https://openalex.org/W2217639061","https://openalex.org/W2237493828","https://openalex.org/W2239947795","https://openalex.org/W2255599823","https://openalex.org/W2262095900","https://openalex.org/W2293363603","https://openalex.org/W2322354531","https://openalex.org/W2332777419","https://openalex.org/W2335651008","https://openalex.org/W2951908097","https://openalex.org/W2998157670","https://openalex.org/W3013446035"],"related_works":["https://openalex.org/W4248682736","https://openalex.org/W4285398693","https://openalex.org/W7115943979","https://openalex.org/W4384929259","https://openalex.org/W4404120923","https://openalex.org/W4389836186","https://openalex.org/W2237493828","https://openalex.org/W2811335311","https://openalex.org/W4239824049","https://openalex.org/W2605793770"],"abstract_inverted_index":{"Flow":[0],"batteries":[1,25],"are":[2,26,108,163,195],"a":[3,158,177],"promising":[4],"solution":[5],"for":[6,30,251],"solving":[7],"intermittency":[8],"challenges":[9],"and":[10,20,44,64,87,96,115,176,237,246],"increasing":[11],"uptake":[12],"of":[13,41,49,56,61,83,130,139,161,210,228],"renewable":[14],"power":[15,66],"sources":[16],"such":[17],"as":[18],"wind":[19],"solar.":[21],"In":[22],"particular,":[23],"zinc/bromine":[24],"an":[27,81],"attractive":[28],"option":[29],"large-scale":[31],"electrical":[32],"energy":[33,48],"storage":[34],"due":[35,206],"to":[36,75,104,188,198,207,254],"their":[37,211],"relatively":[38],"low":[39],"cost":[40],"primary":[42],"electrolyte":[43,95],"high":[45],"theoretical":[46],"specific":[47],"440":[50],"Wh":[51],"kg-1.":[52],"However,":[53],"inefficient":[54],"materials":[55,103,253],"construction":[57],"hinder":[58],"practical":[59],"utilization":[60],"this":[62,72,241],"capability":[63],"reduce":[65],"delivery.":[67],"The":[68],"work":[69],"presented":[70,239],"in":[71,147,173,202,240],"thesis":[73,242],"aims":[74],"overcome":[76],"these":[77],"limitations":[78],"by":[79],"providing":[80],"understanding":[82],"the":[84,93,98,128,142,148,189,203,208,226,235,248],"fundamental":[85],"physical":[86,113],"electrochemical":[88,111],"processes":[89],"governing":[90],"interactions":[91],"within":[92],"bulk":[94],"at":[97,183],"electrode\u2013electrolyte":[99],"interface.":[100],"Suitable":[101],"alternative":[102],"improve":[105,256],"system":[106],"performance":[107],"developed":[109],"via":[110],"investigations,":[112],"characterization":[114],"molecular":[116],"modelling.":[117],"It":[118,150,231],"is":[119,151,186,232],"shown":[120,152],"that":[121,153,221,234],"conventional":[122,174],"chloride-based":[123],"supporting":[124],"electrolytes":[125],"significantly":[126],"influence":[127],"morphology":[129],"zinc":[131,140,170,204],"electrodeposits":[132],"generated.":[133],"High":[134],"chloride":[135],"concentration":[136],"causes":[137],"removal":[138],"from":[141,225],"bulk,":[143],"causing":[144],"coulombic":[145],"losses":[146],"system.":[149],"sulfates,":[154],"phosphates":[155],"or":[156],"even":[157],"higher":[159],"proportion":[160],"bromides,":[162],"potentially":[164],"suitable":[165],"alternatives.":[166],"Single-halide":[167],"type":[168],"tetrahedral":[169],"complexes":[171],"exist":[172],"electrolytes,":[175],"previously":[178],"unreported":[179],"Raman":[180],"vibrational":[181],"band":[182],"220":[184],"cm-1":[185],"assigned":[187],"[ZnBr2Cl(H2O)]\u2013":[190],"complex.":[191],"Ionic":[192],"liquid":[193,218],"additives":[194],"proven":[196],"not":[197],"be":[199],"merely":[200],"spectators":[201],"half-cell,":[205],"effects":[209],"chemical":[212],"structures.":[213],"Studies":[214],"using":[215],"hybrid":[216],"ionic":[217],"mixtures":[219],"indicate":[220],"each":[222],"half-cell":[223],"benefits":[224],"use":[227],"different":[229],"compounds.":[230],"expected":[233],"approaches":[236],"findings":[238],"contribute":[243],"towards":[244],"aiding":[245],"guiding":[247],"future":[249],"search":[250],"novel":[252],"further":[255],"Zn/Br":[257],"battery":[258],"technology.":[259]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2018,"cited_by_count":2}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2017-03-23T00:00:00"}
