{"id":"https://openalex.org/W2575126329","doi":"https://doi.org/10.1063/1.4973827","title":"Lithium ion micrometer diffusion in a garnet-type cubic Li7La3Zr2O12 (LLZO) studied using 7Li NMR spectroscopy","display_name":"Lithium ion micrometer diffusion in a garnet-type cubic Li7La3Zr2O12 (LLZO) studied using 7Li NMR spectroscopy","publication_year":2017,"publication_date":"2017-01-13","ids":{"openalex":"https://openalex.org/W2575126329","doi":"https://doi.org/10.1063/1.4973827","mag":"2575126329","pmid":"https://pubmed.ncbi.nlm.nih.gov/28088148"},"language":"en","primary_location":{"id":"doi:10.1063/1.4973827","doi":"https://doi.org/10.1063/1.4973827","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.4973827","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5023529165","display_name":"Kikuko Hayamizu","orcid":"https://orcid.org/0000-0003-3042-8289","observed_orcids":["https://orcid.org/0000-0003-3042-8289"]},"institutions":[{"id":"https://openalex.org/I146399215","display_name":"University of Tsukuba","ror":"https://ror.org/02956yf07","country_code":"JP","type":"education","lineage":["https://openalex.org/I146399215"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Kikuko Hayamizu","raw_affiliation_strings":["University of Tsukuba 1 Institute of Applied Physics, , Tennodai, Tsukuba 305-8573, Japan"],"raw_orcid":"https://orcid.org/0000-0003-3042-8289","affiliations":[{"raw_affiliation_string":"University of Tsukuba 1 Institute of Applied Physics, , Tennodai, Tsukuba 305-8573, Japan","institution_ids":["https://openalex.org/I146399215"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5073451692","display_name":"Shiro Seki","orcid":"https://orcid.org/0000-0001-9717-2009","observed_orcids":["https://orcid.org/0000-0001-9717-2009"]},"institutions":[{"id":"https://openalex.org/I130416959","display_name":"Central Research Institute of Electric Power Industry","ror":"https://ror.org/041jswc25","country_code":"JP","type":"nonprofit","lineage":["https://openalex.org/I130416959"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Shiro Seki","raw_affiliation_strings":["Central Research Institute of Electric Power Industry 2 Material Science Laboratory, , Nagasaka, Yokosuka 240-0196, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Central Research Institute of Electric Power Industry 2 Material Science Laboratory, , Nagasaka, Yokosuka 240-0196, Japan","institution_ids":["https://openalex.org/I130416959"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5017521255","display_name":"Tomoyuki Haishi","orcid":"https://orcid.org/0000-0003-0989-615X","observed_orcids":["https://orcid.org/0000-0003-0989-615X"]},"institutions":[{"id":"https://openalex.org/I4405264306","display_name":"MR Technology, Inc. (Japan)","ror":"https://ror.org/01hfwpq02","country_code":"JP","type":"company","lineage":["https://openalex.org/I4405264306"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Tomoyuki Haishi","raw_affiliation_strings":["3MR Technology, Inc., Sengen, Tsukuba 300-0047, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"3MR Technology, Inc., Sengen, Tsukuba 300-0047, Japan","institution_ids":["https://openalex.org/I4405264306"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":3500,"currency":"USD","value_usd":3500},"apc_paid":null,"fwci":1.6731,"has_fulltext":false,"cited_by_count":41,"citation_normalized_percentile":{"value":0.83362864,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":99},"biblio":{"volume":"146","issue":"2","first_page":"024701","last_page":"024701"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.9653000235557556,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.9653000235557556,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11878","display_name":"Solid-state spectroscopy and crystallography","score":0.008500000461935997,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12603","display_name":"NMR spectroscopy and applications","score":0.006899999920278788,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/lithium-ion-diffusion","display_name":"lithium ion diffusion","score":0.8140000104904175},{"id":"https://openalex.org/keywords/li7la3zr2o12","display_name":"Li7La3Zr2O12","score":0.9390000104904175},{"id":"https://openalex.org/keywords/7li-nmr","display_name":"7Li NMR","score":0.8429999947547913},{"id":"https://openalex.org/keywords/pulsed-gradient-spin-echo","display_name":"pulsed gradient spin echo","score":0.8939999938011169},{"id":"https://openalex.org/keywords/apparent-diffusion-coefficient","display_name":"apparent diffusion coefficient","score":0.6869999766349792},{"id":"https://openalex.org/keywords/restricted-diffusion","display_name":"restricted diffusion","score":0.843999981880188},{"id":"https://openalex.org/keywords/temperature-dependence","display_name":"temperature dependence","score":0.4440000057220459},{"id":"https://openalex.org/keywords/ionic-conductivity","display_name":"ionic conductivity","score":0.8220000267028809},{"id":"https://openalex.org/keywords/solid-electrolyte-membranes","display_name":"solid electrolyte membranes","score":0.4580000042915344}],"concepts":[{"id":"https://openalex.org/C2778541603","wikidata":"https://www.wikidata.org/wiki/Q152763","display_name":"Lithium (medication)","level":2,"score":0.6722735166549683},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.6553801894187927},{"id":"https://openalex.org/C69357855","wikidata":"https://www.wikidata.org/wiki/Q163214","display_name":"Diffusion","level":2,"score":0.6287095546722412},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.6012714505195618},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5924752354621887},{"id":"https://openalex.org/C53403541","wikidata":"https://www.wikidata.org/wiki/Q856634","display_name":"Fick's laws of diffusion","level":3,"score":0.4931137263774872},{"id":"https://openalex.org/C138679309","wikidata":"https://www.wikidata.org/wiki/Q6063658","display_name":"Ionic conductivity","level":4,"score":0.48793503642082214},{"id":"https://openalex.org/C46141821","wikidata":"https://www.wikidata.org/wiki/Q209402","display_name":"Nuclear magnetic resonance","level":1,"score":0.33994486927986145},{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.08501389622688293},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.07704296708106995},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.07101008296012878},{"id":"https://openalex.org/C134018914","wikidata":"https://www.wikidata.org/wiki/Q162606","display_name":"Endocrinology","level":1,"score":0.0},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1063/1.4973827","doi":"https://doi.org/10.1063/1.4973827","is_oa":false,"landing_page_url":"https://doi.org/10.1063/1.4973827","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Chemical Physics","raw_type":"journal-article"},{"id":"pmid:28088148","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/28088148","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of chemical physics","raw_type":"Journal Article"},{"id":"mag:2745188348","doi":null,"is_oa":false,"landing_page_url":"http://jglobal.jst.go.jp/public/201702296066174168","pdf_url":null,"source":{"id":"https://openalex.org/S77047749","display_name":"The Journal of Chemical Physics","issn_l":"0021-9606","issn":["0021-9606","1089-7690","1520-9032"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-b","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320257","host_organization_name":"American Institute of Physics","host_organization_lineage":["https://openalex.org/P4310320257"],"host_organization_lineage_names":["American Institute of Physics"],"type":"journal"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":"The Journal of Chemical Physics","raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1788501188","display_name":"Research and development of molacular domain polymer electrolyte for next generation batteries","funder_award_id":"15K13767","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"}],"funders":[{"id":"https://openalex.org/F4320334764","display_name":"Japan Society for the Promotion of Science","ror":"https://ror.org/00hhkn466"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":66,"referenced_works":["https://openalex.org/W220670338","https://openalex.org/W973802317","https://openalex.org/W1552170748","https://openalex.org/W1872801038","https://openalex.org/W1964007977","https://openalex.org/W1965335922","https://openalex.org/W1967434586","https://openalex.org/W1968125847","https://openalex.org/W1976763852","https://openalex.org/W1981937098","https://openalex.org/W1984249237","https://openalex.org/W1986844457","https://openalex.org/W1988656097","https://openalex.org/W1990944523","https://openalex.org/W1998131795","https://openalex.org/W1999904740","https://openalex.org/W2014202794","https://openalex.org/W2014487639","https://openalex.org/W2016876155","https://openalex.org/W2017265410","https://openalex.org/W2019014489","https://openalex.org/W2019368249","https://openalex.org/W2025249109","https://openalex.org/W2035266770","https://openalex.org/W2038475538","https://openalex.org/W2039140542","https://openalex.org/W2044189396","https://openalex.org/W2049564501","https://openalex.org/W2050097483","https://openalex.org/W2051261532","https://openalex.org/W2054555463","https://openalex.org/W2069399508","https://openalex.org/W2069691371","https://openalex.org/W2070226172","https://openalex.org/W2071807730","https://openalex.org/W2071892892","https://openalex.org/W2076231936","https://openalex.org/W2084761689","https://openalex.org/W2102487231","https://openalex.org/W2108603273","https://openalex.org/W2109979025","https://openalex.org/W2113647284","https://openalex.org/W2142000498","https://openalex.org/W2143795526","https://openalex.org/W2152048732","https://openalex.org/W2166330692","https://openalex.org/W2177045798","https://openalex.org/W2188829545","https://openalex.org/W2210968952","https://openalex.org/W2220242780","https://openalex.org/W2267276271","https://openalex.org/W2281909103","https://openalex.org/W2301876101","https://openalex.org/W2313515426","https://openalex.org/W2317099826","https://openalex.org/W2318806540","https://openalex.org/W2319813822","https://openalex.org/W2320261085","https://openalex.org/W2323111737","https://openalex.org/W2324012744","https://openalex.org/W2325327503","https://openalex.org/W2334065408","https://openalex.org/W2498377240","https://openalex.org/W2512314861","https://openalex.org/W2512446787","https://openalex.org/W2554614436"],"related_works":["https://openalex.org/W2898199935","https://openalex.org/W2220242780","https://openalex.org/W2945293315","https://openalex.org/W6887300039","https://openalex.org/W2014202794","https://openalex.org/W2335568252","https://openalex.org/W2532462685","https://openalex.org/W2978501775","https://openalex.org/W3091865368","https://openalex.org/W3021873348"],"abstract_inverted_index":{"Mobile":[0],"lithium":[1,126,137,171],"ions":[2,127,195],"in":[3,31,180],"a":[4,32,97,187],"cubic":[5],"garnet":[6],"Li7La3Zr2O12":[7],"(Al-stabilized)":[8],"were":[9,156],"studied":[10],"using":[11,37],"7Li":[12,41],"NMR":[13,42],"spectroscopy":[14],"for":[15],"membrane":[16,150],"and":[17,46,113,136,139,144,163,201],"powder":[18],"samples,":[19],"the":[20,27,38,50,59,68,80,103,107,125,149,164,170,174,178,190,198,202,207],"latter":[21],"of":[22,82,148,152,192],"which":[23],"was":[24,35,54],"ground":[25],"from":[26,158,197],"membrane.":[28],"Lithium":[29],"diffusion":[30,84,99,204],"micrometer":[33],"space":[34,71],"measured":[36],"pulsed-gradient":[39],"spin-echo":[40],"method":[43],"between":[44],"70":[45],"130":[47],"\u00b0C.":[48],"When":[49],"observation":[51],"time":[52],"(\u0394)":[53],"shorter":[55],"than":[56],"20":[57],"ms,":[58],"echo":[60],"attenuation":[61],"showed":[62,186],"diffusive":[63],"diffraction":[64],"patterns,":[65],"indicating":[66],"that":[67,124],"Li+":[69,130,193],"diffusing":[70],"is":[72],"not":[73],"free":[74],"but":[75],"restricted.":[76],"For":[77],"longer":[78],"\u0394,":[79],"values":[81],"apparent":[83],"constant":[85,205],"(Dapparent)":[86],"became":[87,114,118],"gradually":[88],"smaller":[89,115],"to":[90,96,160,189],"approach":[91],"an":[92],"equilibrated":[93,203],"value":[94],"(close":[95],"tracer":[98],"constant).":[100],"In":[101],"addition,":[102],"Dapparent":[104],"depends":[105],"on":[106],"pulse":[108],"field":[109],"gradient":[110],"strength":[111],"(g)":[112],"as":[116,167,169],"g":[117],"larger.":[119],"These":[120],"experimental":[121],"results":[122],"suggest":[123],"diffuse":[128],"through":[129,206],"pathways":[131],"surrounded":[132],"by":[133,142],"stationary":[134],"anions":[135],"ions,":[138],"are":[140],"affected":[141],"collisions":[143],"diffractions.":[145],"One-dimensional":[146],"profiles":[147],"sample":[151],"thickness":[153],"0.5":[154],"mm":[155],"observed":[157],"65":[159],"110":[161],"\u00b0C":[162],"area":[165,184],"intensity,":[166],"well":[168],"occurrence":[172],"near":[173],"surface,":[175],"increased":[176],"with":[177],"increase":[179],"temperature.":[181],"The":[182],"temperature-dependent":[183],"intensity":[185],"correspondence":[188],"number":[191],"carrier":[194],"estimated":[196],"ionic":[199],"conductivity":[200],"Nernst-Einstein":[208],"relationship.":[209]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":11},{"year":2022,"cited_by_count":6},{"year":2021,"cited_by_count":5},{"year":2020,"cited_by_count":4},{"year":2019,"cited_by_count":5},{"year":2018,"cited_by_count":4},{"year":2017,"cited_by_count":2}],"updated_date":"2026-11-07T11:25:07.637180","created_date":"2017-01-26T00:00:00"}
