{"id":"https://openalex.org/W2519185331","doi":"https://doi.org/10.1021/acs.langmuir.6b03289","title":"Destabilization of Oil-in-Water Emulsions Stabilized by Non-ionic Surfactants: Effect of Particle Hydrophilicity","display_name":"Destabilization of Oil-in-Water Emulsions Stabilized by Non-ionic Surfactants: Effect of Particle Hydrophilicity","publication_year":2016,"publication_date":"2016-09-15","ids":{"openalex":"https://openalex.org/W2519185331","doi":"https://doi.org/10.1021/acs.langmuir.6b03289","mag":"2519185331","pmid":"https://pubmed.ncbi.nlm.nih.gov/27632428"},"language":"en","primary_location":{"id":"doi:10.1021/acs.langmuir.6b03289","doi":"https://doi.org/10.1021/acs.langmuir.6b03289","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.langmuir.6b03289","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://digitalcommons.uri.edu/che_facpubs/443","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5036091430","display_name":"Hari Katepalli","orcid":"https://orcid.org/0000-0002-4297-217X","observed_orcids":["https://orcid.org/0000-0002-4297-217X"]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Hari Katepalli","raw_affiliation_strings":["Department\rof Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States","institution_ids":["https://openalex.org/I63966007"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5051716291","display_name":"Arijit Bose","orcid":"https://orcid.org/0000-0002-2309-5087","observed_orcids":["https://orcid.org/0000-0002-2309-5087"]},"institutions":[{"id":"https://openalex.org/I17626003","display_name":"University of Rhode Island","ror":"https://ror.org/013ckk937","country_code":"US","type":"education","lineage":["https://openalex.org/I17626003"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Arijit Bose","raw_affiliation_strings":["Department\rof Chemical Engineering, University of Rhode Island, Kingston, Rhode Island 02881, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemical Engineering, University of Rhode Island, Kingston, Rhode Island 02881, United States","institution_ids":["https://openalex.org/I17626003"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5046348268","display_name":"T. Alan Hatton","orcid":"https://orcid.org/0000-0002-4558-245X","observed_orcids":["https://orcid.org/0000-0002-4558-245X"]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"T. Alan Hatton","raw_affiliation_strings":["Department\rof Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States","institution_ids":["https://openalex.org/I63966007"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5029267851","display_name":"Daniel Blankschtein","orcid":"https://orcid.org/0000-0002-7836-415X","observed_orcids":["https://orcid.org/0000-0002-7836-415X"]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Daniel Blankschtein","raw_affiliation_strings":["Department\rof Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemical Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States","institution_ids":["https://openalex.org/I63966007"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5029267851","https://openalex.org/A5046348268"],"corresponding_institution_ids":["https://openalex.org/I63966007"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.079,"has_fulltext":false,"cited_by_count":44,"citation_normalized_percentile":{"value":0.86234714,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":93,"max":99},"biblio":{"volume":"32","issue":"41","first_page":"10694","last_page":"10698"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11915","display_name":"Pickering emulsions and particle stabilization","score":0.8398000001907349,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11915","display_name":"Pickering emulsions and particle stabilization","score":0.8398000001907349,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10721","display_name":"Surfactants and Colloidal Systems","score":0.15549999475479126,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10411","display_name":"Proteins in Food Systems","score":0.0013000000035390258,"subfield":{"id":"https://openalex.org/subfields/1106","display_name":"Food Science"},"field":{"id":"https://openalex.org/fields/11","display_name":"Agricultural and Biological Sciences"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/emulsion-destabilization","display_name":"emulsion destabilization","score":0.972000002861023},{"id":"https://openalex.org/keywords/oil-in-water-emulsions","display_name":"oil-in-water emulsions","score":0.9300000071525574},{"id":"https://openalex.org/keywords/triton-x-100","display_name":"Triton X-100","score":0.9190000295639038},{"id":"https://openalex.org/keywords/nonionic-surfactants","display_name":"nonionic surfactants","score":0.9829999804496765},{"id":"https://openalex.org/keywords/droplet-coarsening","display_name":"droplet coarsening","score":0.9020000100135803},{"id":"https://openalex.org/keywords/droplet-flocculation","display_name":"droplet flocculation","score":0.968999981880188},{"id":"https://openalex.org/keywords/phase-separation","display_name":"phase separation","score":0.8529999852180481},{"id":"https://openalex.org/keywords/surfactant-depletion","display_name":"surfactant depletion","score":0.9190000295639038},{"id":"https://openalex.org/keywords/surfactant-adsorption","display_name":"surfactant adsorption","score":0.8709999918937683},{"id":"https://openalex.org/keywords/hydrogen-bonding","display_name":"hydrogen bonding","score":0.9169999957084656},{"id":"https://openalex.org/keywords/hydrophobic-interactions","display_name":"hydrophobic interactions","score":0.9919999837875366},{"id":"https://openalex.org/keywords/antagonistic-effect","display_name":"antagonistic effect","score":0.6129999756813049},{"id":"https://openalex.org/keywords/emulsion-stability","display_name":"emulsion stability","score":0.671999990940094}],"concepts":[{"id":"https://openalex.org/C2778123984","wikidata":"https://www.wikidata.org/wiki/Q187634","display_name":"Emulsion","level":2,"score":0.7831020951271057},{"id":"https://openalex.org/C58226133","wikidata":"https://www.wikidata.org/wiki/Q1324199","display_name":"Pulmonary surfactant","level":2,"score":0.7322937250137329},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.7248443961143494},{"id":"https://openalex.org/C148328677","wikidata":"https://www.wikidata.org/wiki/Q3918778","display_name":"Fumed silica","level":2,"score":0.6698814630508423},{"id":"https://openalex.org/C8892853","wikidata":"https://www.wikidata.org/wiki/Q170749","display_name":"Surface tension","level":2,"score":0.6556958556175232},{"id":"https://openalex.org/C2778517922","wikidata":"https://www.wikidata.org/wiki/Q7140482","display_name":"Particle (ecology)","level":2,"score":0.6497544050216675},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.5873923897743225},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.562414288520813},{"id":"https://openalex.org/C90260826","wikidata":"https://www.wikidata.org/wiki/Q899157","display_name":"Hydrophobic effect","level":2,"score":0.5548099279403687},{"id":"https://openalex.org/C149556010","wikidata":"https://www.wikidata.org/wiki/Q4782870","display_name":"Aqueous two-phase system","level":3,"score":0.5417161583900452},{"id":"https://openalex.org/C148815931","wikidata":"https://www.wikidata.org/wiki/Q900689","display_name":"Flocculation","level":2,"score":0.5169350504875183},{"id":"https://openalex.org/C118129440","wikidata":"https://www.wikidata.org/wiki/Q5948930","display_name":"Hydrophobic silica","level":2,"score":0.4967942535877228},{"id":"https://openalex.org/C2780768339","wikidata":"https://www.wikidata.org/wiki/Q150843","display_name":"Hexadecane","level":2,"score":0.49366578459739685},{"id":"https://openalex.org/C44280652","wikidata":"https://www.wikidata.org/wiki/Q104837","display_name":"Phase (matter)","level":2,"score":0.4933909475803375},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.45069533586502075},{"id":"https://openalex.org/C6556556","wikidata":"https://www.wikidata.org/wiki/Q899239","display_name":"Contact angle","level":2,"score":0.42143112421035767},{"id":"https://openalex.org/C187530423","wikidata":"https://www.wikidata.org/wiki/Q7140503","display_name":"Particle size","level":2,"score":0.4200502932071686},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.36336976289749146},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.24120214581489563},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.057343870401382446},{"id":"https://openalex.org/C127313418","wikidata":"https://www.wikidata.org/wiki/Q1069","display_name":"Geology","level":0,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C111368507","wikidata":"https://www.wikidata.org/wiki/Q43518","display_name":"Oceanography","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/acs.langmuir.6b03289","doi":"https://doi.org/10.1021/acs.langmuir.6b03289","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.langmuir.6b03289","pdf_url":null,"source":{"id":"https://openalex.org/S75741262","display_name":"Langmuir","issn_l":"0743-7463","issn":["0743-7463","1520-5827"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-d","doyens","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir","raw_type":"journal-article"},{"id":"pmid:27632428","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/27632428","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Langmuir : the ACS journal of surfaces and colloids","raw_type":"Journal Article"},{"id":"pmh:oai:digitalcommons.uri.edu:che_facpubs-1445","doi":null,"is_oa":true,"landing_page_url":"https://digitalcommons.uri.edu/che_facpubs/443","pdf_url":null,"source":{"id":"https://openalex.org/S2764761010","display_name":"Journal of Media Literacy Education","issn_l":"2167-8715","issn":["2167-8715"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","doaj","jufo-1","norway-1","poland-20","russia-white-list-4","vabb-shw"],"host_organization":"https://openalex.org/P4310316378","host_organization_name":"National Association for Media Literacy Education","host_organization_lineage":["https://openalex.org/P4310316378"],"host_organization_lineage_names":["National Association for Media Literacy Education"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Chemical, Biomolecular, and Materials Engineering Faculty Publications","raw_type":"text"}],"best_oa_location":{"id":"pmh:oai:digitalcommons.uri.edu:che_facpubs-1445","doi":null,"is_oa":true,"landing_page_url":"https://digitalcommons.uri.edu/che_facpubs/443","pdf_url":null,"source":{"id":"https://openalex.org/S2764761010","display_name":"Journal of Media Literacy Education","issn_l":"2167-8715","issn":["2167-8715"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["anvur-class-a","anvur-scientific","cwts-core","doaj","jufo-1","norway-1","poland-20","russia-white-list-4","vabb-shw"],"host_organization":"https://openalex.org/P4310316378","host_organization_name":"National Association for Media Literacy Education","host_organization_lineage":["https://openalex.org/P4310316378"],"host_organization_lineage_names":["National Association for Media Literacy Education"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Chemical, Biomolecular, and Materials Engineering Faculty Publications","raw_type":"text"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":35,"referenced_works":["https://openalex.org/W1966845939","https://openalex.org/W1969050083","https://openalex.org/W1969300838","https://openalex.org/W1974374891","https://openalex.org/W1978580387","https://openalex.org/W1982354962","https://openalex.org/W1989669689","https://openalex.org/W1994012737","https://openalex.org/W2001964174","https://openalex.org/W2004966264","https://openalex.org/W2016598506","https://openalex.org/W2025621512","https://openalex.org/W2026758031","https://openalex.org/W2040947330","https://openalex.org/W2049123957","https://openalex.org/W2050976786","https://openalex.org/W2063968019","https://openalex.org/W2068921391","https://openalex.org/W2070318740","https://openalex.org/W2071864807","https://openalex.org/W2073120193","https://openalex.org/W2073428630","https://openalex.org/W2079030785","https://openalex.org/W2079245584","https://openalex.org/W2086667902","https://openalex.org/W2090049652","https://openalex.org/W2091039730","https://openalex.org/W2324399789","https://openalex.org/W2335017492","https://openalex.org/W2415187379","https://openalex.org/W2485020436","https://openalex.org/W2503348119","https://openalex.org/W2503576964","https://openalex.org/W2520236143","https://openalex.org/W3021256586"],"related_works":["https://openalex.org/W2335017492","https://openalex.org/W1978580387","https://openalex.org/W2016022042","https://openalex.org/W2564774406","https://openalex.org/W2980383473","https://openalex.org/W2924421454","https://openalex.org/W2808034016","https://openalex.org/W2323033468","https://openalex.org/W2091039730","https://openalex.org/W1969300838"],"abstract_inverted_index":{"We":[0],"investigate":[1],"the":[2,20,24,35,38,41,49,56,68,80,85,117,120,124,127,135,138,141,144,154,158,185],"use":[3],"of":[4,19,37,43,55,84,97,116,126,137,143,151,157,191,197],"particle":[5,65,92,105],"hydrophilicity":[6,18],"as":[7],"a":[8,31,202],"tool":[9],"for":[10,184],"emulsion":[11,57,86,139],"destabilization":[12],"in":[13,53,123,134,149,153,195,207],"Triton-X-100-stabilized":[14],"hexadecane-in-water":[15],"emulsions.":[16],"The":[17,131],"particles":[21,47,76,169,200],"added":[22,78],"to":[23,29,48,79,170],"aqueous":[25,50,81,121],"phase":[26,51,95,122],"was":[27,88,101],"found":[28],"have":[30],"pronounced":[32],"effect":[33],"on":[34,167,176],"stability":[36,136],"emulsion.":[39],"Specifically,":[40],"addition":[42],"hydrophilic":[44,168],"fumed":[45,74],"silica":[46,75],"resulted":[52],"coarsening":[54,83],"droplets,":[58],"with":[59],"droplet":[60],"flocculation":[61],"observed":[62,89,102,132],"at":[63,90,103],"higher":[64,104],"concentrations.":[66,106],"On":[67],"other":[69],"hand,":[70],"when":[71],"partially":[72,128,177,198],"hydrophobic":[73,129,174,178,199],"were":[77],"phase,":[82],"droplets":[87],"low":[91],"concentrations":[93],"and":[94,99,109,140,201],"separation":[96],"oil":[98],"water":[100],"Surface":[107],"tension":[108,111],"interfacial":[110],"measurements":[112],"showed":[113],"significant":[114],"depletion":[115,142],"surfactant":[118,145,159,204],"from":[119,161],"presence":[125],"particles.":[130,179],"changes":[133,152],"can":[146],"be":[147],"rationalized":[148],"terms":[150],"adsorption":[155],"behavior":[156],"molecules,":[160],"one":[162,171],"dominated":[163,172],"by":[164,173],"hydrogen":[165],"bonding":[166],"interactions":[175],"Our":[180],"findings":[181],"also":[182],"provide,":[183],"first":[186],"time,":[187],"an":[188],"in-depth":[189],"understanding":[190],"antagonistic":[192],"(destabilizing)":[193],"effects":[194],"mixtures":[196],"non-ionic":[203],"(Triton":[205],"X-100)":[206],"water.":[208]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":2},{"year":2024,"cited_by_count":8},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":5},{"year":2021,"cited_by_count":4},{"year":2020,"cited_by_count":7},{"year":2019,"cited_by_count":6},{"year":2018,"cited_by_count":6},{"year":2017,"cited_by_count":2}],"updated_date":"2026-10-01T08:54:57.152042","created_date":"2016-09-23T00:00:00"}