{"id":"https://openalex.org/W2510420518","doi":"https://doi.org/10.1021/acs.macromol.5b02174","title":"In Situ Characterization of the Self-Assembly of a Polystyrene\u2013Polydimethylsiloxane Block Copolymer during Solvent Vapor Annealing","display_name":"In Situ Characterization of the Self-Assembly of a Polystyrene\u2013Polydimethylsiloxane Block Copolymer during Solvent Vapor Annealing","publication_year":2015,"publication_date":"2015-11-18","ids":{"openalex":"https://openalex.org/W2510420518","doi":"https://doi.org/10.1021/acs.macromol.5b02174","mag":"2510420518"},"language":"en","primary_location":{"id":"doi:10.1021/acs.macromol.5b02174","doi":"https://doi.org/10.1021/acs.macromol.5b02174","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.macromol.5b02174","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5030073571","display_name":"Wubin Bai","orcid":"https://orcid.org/0000-0003-2872-5559","observed_orcids":["https://orcid.org/0000-0003-2872-5559"]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"W. Bai","raw_affiliation_strings":["Department\rof Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States","institution_ids":["https://openalex.org/I63966007"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5062034448","display_name":"Kevin G. Yager","orcid":"https://orcid.org/0000-0001-7745-2513","observed_orcids":["https://orcid.org/0000-0001-7745-2513"]},"institutions":[{"id":"https://openalex.org/I200870766","display_name":"Brookhaven National Laboratory","ror":"https://ror.org/02ex6cf31","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I200870766","https://openalex.org/I39565521","https://openalex.org/I4210142672"]},{"id":"https://openalex.org/I4390039222","display_name":"Center for Functional Nanomaterials","ror":"https://ror.org/035xqz322","country_code":"US","type":"facility","lineage":["https://openalex.org/I1330989302","https://openalex.org/I200870766","https://openalex.org/I39565521","https://openalex.org/I4210142672","https://openalex.org/I4390039222"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"K. G. Yager","raw_affiliation_strings":["Center\rfor Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Center\rfor Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, United States","institution_ids":["https://openalex.org/I200870766","https://openalex.org/I4390039222"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5108673945","display_name":"Caroline A. Ross","orcid":"https://orcid.org/0000-0003-2262-1249","observed_orcids":["https://orcid.org/0000-0003-2262-1249"]},"institutions":[{"id":"https://openalex.org/I63966007","display_name":"Massachusetts Institute of Technology","ror":"https://ror.org/042nb2s44","country_code":"US","type":"education","lineage":["https://openalex.org/I63966007"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"C. A. Ross","raw_affiliation_strings":["Department\rof Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States","institution_ids":["https://openalex.org/I63966007"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5108673945"],"corresponding_institution_ids":["https://openalex.org/I63966007"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":3.151,"has_fulltext":false,"cited_by_count":56,"citation_normalized_percentile":{"value":0.92961568,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":93,"max":99},"biblio":{"volume":"48","issue":"23","first_page":"8574","last_page":"8584"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11471","display_name":"Block Copolymer Self-Assembly","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11471","display_name":"Block Copolymer Self-Assembly","score":1.0,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10389","display_name":"Polymer crystallization and properties","score":0.0,"subfield":{"id":"https://openalex.org/subfields/2507","display_name":"Polymers and Plastics"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/microphase-separation","display_name":"microphase separation","score":0.878000020980835},{"id":"https://openalex.org/keywords/solvent-vapor-annealing","display_name":"solvent vapor annealing","score":0.906000018119812},{"id":"https://openalex.org/keywords/swelling-ratio","display_name":"swelling ratio","score":0.48500001430511475},{"id":"https://openalex.org/keywords/surface-interactions","display_name":"surface interactions","score":0.5699999928474426},{"id":"https://openalex.org/keywords/drying-kinetics","display_name":"drying kinetics","score":0.47099998593330383}],"concepts":[{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.7814904451370239},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.7547550797462463},{"id":"https://openalex.org/C2777855556","wikidata":"https://www.wikidata.org/wiki/Q4339544","display_name":"Annealing (glass)","level":2,"score":0.6865133047103882},{"id":"https://openalex.org/C2777922577","wikidata":"https://www.wikidata.org/wiki/Q146243","display_name":"Polystyrene","level":3,"score":0.6862133741378784},{"id":"https://openalex.org/C2778540859","wikidata":"https://www.wikidata.org/wiki/Q152234","display_name":"Swelling","level":2,"score":0.6814364194869995},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.671366810798645},{"id":"https://openalex.org/C2779849746","wikidata":"https://www.wikidata.org/wiki/Q411955","display_name":"Polydimethylsiloxane","level":2,"score":0.669204592704773},{"id":"https://openalex.org/C176443586","wikidata":"https://www.wikidata.org/wiki/Q5598487","display_name":"Grazing-incidence small-angle scattering","level":5,"score":0.66419517993927},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.5262693166732788},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.45876047015190125},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.42053452134132385},{"id":"https://openalex.org/C191486275","wikidata":"https://www.wikidata.org/wiki/Q210028","display_name":"Scattering","level":2,"score":0.35617148876190186},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.2268458604812622},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.21043619513511658},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.16662228107452393},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.11921581625938416},{"id":"https://openalex.org/C132841051","wikidata":"https://www.wikidata.org/wiki/Q4165337","display_name":"Small-angle neutron scattering","level":4,"score":0.07876881957054138},{"id":"https://openalex.org/C104015590","wikidata":"https://www.wikidata.org/wiki/Q1451740","display_name":"Neutron scattering","level":3,"score":0.06839960813522339},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/acs.macromol.5b02174","doi":"https://doi.org/10.1021/acs.macromol.5b02174","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.macromol.5b02174","pdf_url":null,"source":{"id":"https://openalex.org/S177196338","display_name":"Macromolecules","issn_l":"0024-9297","issn":["0024-9297","1520-5835"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-3","ki-jl-1","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Macromolecules","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1572106353","display_name":null,"funder_award_id":"DE-AC02- 98CH10886","funder_id":"https://openalex.org/F4320338289","funder_display_name":"Brookhaven National Laboratory"},{"id":"https://openalex.org/G3202401936","display_name":null,"funder_award_id":"DMR-14-19807","funder_id":"https://openalex.org/F4320337367","funder_display_name":"Division of Materials Research"}],"funders":[{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"},{"id":"https://openalex.org/F4320306087","display_name":"Semiconductor Research Corporation","ror":"https://ror.org/047z4n946"},{"id":"https://openalex.org/F4320315610","display_name":"Tokyo Electron","ror":"https://ror.org/05gd76j39"},{"id":"https://openalex.org/F4320322589","display_name":"Taiwan Semiconductor Manufacturing Company","ror":"https://ror.org/02wx79d08"},{"id":"https://openalex.org/F4320332180","display_name":"Defense Advanced Research Projects Agency","ror":"https://ror.org/02caytj08"},{"id":"https://openalex.org/F4320337367","display_name":"Division of Materials Research","ror":"https://ror.org/01pc7k308"},{"id":"https://openalex.org/F4320337480","display_name":"Basic Energy Sciences","ror":"https://ror.org/05mg91w61"},{"id":"https://openalex.org/F4320338289","display_name":"Brookhaven National Laboratory","ror":"https://ror.org/02ex6cf31"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":65,"referenced_works":["https://openalex.org/W1755024698","https://openalex.org/W1965155859","https://openalex.org/W1965960968","https://openalex.org/W1968514087","https://openalex.org/W1976055919","https://openalex.org/W1981118741","https://openalex.org/W1983309921","https://openalex.org/W1984954526","https://openalex.org/W1985366763","https://openalex.org/W1985599292","https://openalex.org/W1994699551","https://openalex.org/W1998725668","https://openalex.org/W2000272319","https://openalex.org/W2001299122","https://openalex.org/W2004928586","https://openalex.org/W2009808055","https://openalex.org/W2012843602","https://openalex.org/W2012903599","https://openalex.org/W2020337437","https://openalex.org/W2026132129","https://openalex.org/W2029374792","https://openalex.org/W2029707199","https://openalex.org/W2033007776","https://openalex.org/W2034961678","https://openalex.org/W2035526073","https://openalex.org/W2037596856","https://openalex.org/W2038672133","https://openalex.org/W2049357274","https://openalex.org/W2050463716","https://openalex.org/W2056318467","https://openalex.org/W2069675856","https://openalex.org/W2070887631","https://openalex.org/W2071233541","https://openalex.org/W2071752715","https://openalex.org/W2073912476","https://openalex.org/W2074386577","https://openalex.org/W2076224938","https://openalex.org/W2077379822","https://openalex.org/W2085103899","https://openalex.org/W2089930307","https://openalex.org/W2094629353","https://openalex.org/W2101591539","https://openalex.org/W2105000358","https://openalex.org/W2121117675","https://openalex.org/W2130704140","https://openalex.org/W2138437804","https://openalex.org/W2139823618","https://openalex.org/W2142595344","https://openalex.org/W2156750041","https://openalex.org/W2160037102","https://openalex.org/W2247029839","https://openalex.org/W2315360587","https://openalex.org/W2315362640","https://openalex.org/W2317340398","https://openalex.org/W2319621006","https://openalex.org/W2325858222","https://openalex.org/W2326306619","https://openalex.org/W2326758686","https://openalex.org/W2326787051","https://openalex.org/W2327227196","https://openalex.org/W2328357150","https://openalex.org/W2332773319","https://openalex.org/W2332782644","https://openalex.org/W2518375234","https://openalex.org/W4206882262"],"related_works":["https://openalex.org/W2513342322","https://openalex.org/W2070887631","https://openalex.org/W3094471375","https://openalex.org/W2325249492","https://openalex.org/W2108295984","https://openalex.org/W2790131146","https://openalex.org/W2342704130","https://openalex.org/W2004928586","https://openalex.org/W3035123628","https://openalex.org/W7097705980"],"abstract_inverted_index":{"Grazing":[0],"incidence":[1],"X-ray":[2],"scattering":[3],"was":[4,37],"used":[5],"to":[6,52,70,83,95],"follow":[7],"the":[8,50,64,87,102],"microphase":[9],"separation":[10,36],"during":[11,61],"room-temperature":[12],"solvent":[13,33],"annealing":[14],"of":[15,17,77,101],"films":[16,51,55],"high":[18],"interaction":[19],"parameter":[20],"cylinder-forming":[21],"16":[22],"kg/mol":[23],"polystyrene-":[24],"b":[25],"-polydimethylsiloxane":[26],"block":[27],"copolymer":[28],"in":[29,86],"a":[30,57,75,84],"toluene\u2013heptane":[31],"mixed":[32],"vapor.":[34],"Microphase":[35],"observed":[38],"for":[39],"swelling":[40,45],"ratios":[41,46],"above":[42,47],"1.2,":[43],"but":[44],"1.9":[48],"caused":[49],"disorder.":[53],"The":[54],"exhibited":[56],"thickness-dependent":[58],"microdomain":[59],"reorientation":[60],"annealing,":[62],"with":[63,91],"initial":[65],"out-of-plane":[66,88],"cylinder":[67,89],"orientation":[68,73],"converting":[69],"an":[71],"in-plane":[72],"as":[74],"result":[76],"preferential":[78],"surface":[79],"interactions.":[80],"Drying":[81],"led":[82],"reduction":[85],"spacing,":[90],"slower":[92],"drying":[93],"leading":[94],"greater":[96],"deswelling":[97],"and":[98],"larger":[99],"distortion":[100],"hexagonal":[103],"lattice.":[104]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":4},{"year":2024,"cited_by_count":4},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":8},{"year":2019,"cited_by_count":5},{"year":2018,"cited_by_count":9},{"year":2017,"cited_by_count":7},{"year":2016,"cited_by_count":10}],"updated_date":"2026-11-06T12:05:46.655746","created_date":"2016-09-16T00:00:00"}