{"id":"https://openalex.org/W2494540049","doi":"https://doi.org/10.14279/depositonce-1212","title":"Beitr\u00e4ge zur Synthese neuer Liganden f\u00fcr \u00dcbergangsmetalle und deren Anwendung in der Katalyse","display_name":"Beitr\u00e4ge zur Synthese neuer Liganden f\u00fcr \u00dcbergangsmetalle und deren Anwendung in der Katalyse","publication_year":2005,"publication_date":"2005-10-25","ids":{"openalex":"https://openalex.org/W2494540049","doi":"https://doi.org/10.14279/depositonce-1212","mag":"2494540049"},"language":"de","primary_location":{"id":"pmh:oai:depositonce.tu-berlin.de:11303/1509","doi":null,"is_oa":true,"landing_page_url":"https://depositonce.tu-berlin.de/handle/11303/1509","pdf_url":"http://depositonce.tu-berlin.de/handle/11303/1509","source":{"id":"https://openalex.org/S4406922277","display_name":"DepositOnce","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"public-domain","license_id":"https://openalex.org/licenses/public-domain","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Doctoral Thesis"},"volume":null,"type":"dissertation","indexed_in":["datacite"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"http://depositonce.tu-berlin.de/handle/11303/1509","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5063867419","display_name":"Marko Eck","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Eck, Marko","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5063867419"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":true,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.4772999882698059,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11790","display_name":"N-Heterocyclic Carbenes in Organic and Inorganic Chemistry","score":0.4772999882698059,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.2660999894142151,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11281","display_name":"Asymmetric Hydrogenation and Catalysis","score":0.12129999697208405,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/transition-metal-ligands","display_name":"transition metal ligands","score":0.7289999723434448},{"id":"https://openalex.org/keywords/n-heterocyclic-carbene-ligands","display_name":"N-heterocyclic carbene ligands","score":0.9089999794960022},{"id":"https://openalex.org/keywords/grubbs-catalyst","display_name":"Grubbs catalyst","score":0.6809999942779541},{"id":"https://openalex.org/keywords/palladium-catalysis","display_name":"palladium catalysis","score":0.5090000033378601},{"id":"https://openalex.org/keywords/imidazolium-salts","display_name":"imidazolium salts","score":0.7739999890327454},{"id":"https://openalex.org/keywords/ring-opening-metathesis-polymerization","display_name":"ring-opening metathesis polymerization","score":0.5049999952316284}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.42456528544425964},{"id":"https://openalex.org/C138885662","wikidata":"https://www.wikidata.org/wiki/Q5891","display_name":"Philosophy","level":0,"score":0.33647775650024414}],"mesh":[],"locations_count":4,"locations":[{"id":"pmh:oai:depositonce.tu-berlin.de:11303/1509","doi":null,"is_oa":true,"landing_page_url":"https://depositonce.tu-berlin.de/handle/11303/1509","pdf_url":"http://depositonce.tu-berlin.de/handle/11303/1509","source":{"id":"https://openalex.org/S4406922277","display_name":"DepositOnce","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"public-domain","license_id":"https://openalex.org/licenses/public-domain","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Doctoral Thesis"},{"id":"pmh:oai:aleph.bib-bvb.de:BVB01-018581314","doi":null,"is_oa":false,"landing_page_url":"https://nbn-resolving.org/urn:nbn:de:kobv:83-opus-11182","pdf_url":null,"source":null,"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Hochschulschrift"},{"id":"doi:10.14279/depositonce-1212","doi":"https://doi.org/10.14279/depositonce-1212","is_oa":true,"landing_page_url":"https://doi.org/10.14279/depositonce-1212","pdf_url":null,"source":{"id":"https://openalex.org/S7407052985","display_name":"Technische Universit\u00e4t Berlin \u2013 Universit\u00e4tsbibliothek","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4577782","host_organization_name":"Technische Universit\u00e4t Berlin","host_organization_lineage":["https://openalex.org/I4577782"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"article-journal"},{"id":"mag:2494540049","doi":null,"is_oa":false,"landing_page_url":"https://depositonce.tu-berlin.de/bitstream/11303/1509/1/Dokument_19.pdf","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":{"id":"pmh:oai:depositonce.tu-berlin.de:11303/1509","doi":null,"is_oa":true,"landing_page_url":"https://depositonce.tu-berlin.de/handle/11303/1509","pdf_url":"http://depositonce.tu-berlin.de/handle/11303/1509","source":{"id":"https://openalex.org/S4406922277","display_name":"DepositOnce","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"public-domain","license_id":"https://openalex.org/licenses/public-domain","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"Doctoral Thesis"},"sustainable_development_goals":[],"sustainable_development_goals_aurora":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":true,"pdf":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2494540049.pdf","grobid_xml":"https://content.openalex.org/works/W2494540049.grobid-xml"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W2296829013","https://openalex.org/W3046827258","https://openalex.org/W2499902503","https://openalex.org/W2998387622","https://openalex.org/W1699320052","https://openalex.org/W2290496834","https://openalex.org/W2483778169","https://openalex.org/W2491723148","https://openalex.org/W7038378806","https://openalex.org/W139617686"],"abstract_inverted_index":{"Im":[0,155],"ersten":[1],"Teil":[2,60,180],"der":[3,21,61,90,157,181],"Arbeit":[4,62,182],"wurde":[5,37,206],"die":[6,25,126,163,184],"Synthese":[7,127,185],"von":[8],"2,7-disubstituierten":[9],"Indenen":[10],"(als":[11],"Vorl\u00e4ufer":[12,197],"f\u00fcr":[13],"\u03b75-Liganden)":[14],"realisiert.":[15],"Dar\u00fcber":[16,84,123],"hinaus":[17,85,124],"konnte":[18,47,86,125,141,162,183],"das":[19,142],"Einbringen":[20],"chiralen":[22],"Information":[23],"in":[24,118],"7-Position":[26],"des":[27,52],"Indens":[28],"via":[29],"Nickel-katalysierter":[30],"Kumada-Kupplung":[31],"realisiert":[32,68,138,191],"werden.":[33,56,69,101,139,146,192],"Als":[34],"chirales":[35],"Grignard-Reagenz":[36],"(-)-Menthylmagnesiumchlorid":[38],"eingesetzt,":[39],"welches":[40],"aus":[41],"(-)-Menthylchlorid":[42],"generiert":[43],"wurde.":[44],"Die":[45,147,212],"Reaktion":[46],"jedoch":[48],"nicht":[49],"selektiv":[50],"hinsichtlich":[51],"gew\u00fcnschten":[53],"Produktes":[54],"gef\u00fchrt":[55],"In":[57,177],"einem":[58,76,166,178],"weiteren":[59,179],"konnten":[63,194],"neue":[64],"NHC-Liganden":[65,79],"und":[66,80,203,210],"Metathese-Katalysatorsysteme":[67],"Es":[70],"gelang":[71],"einen":[72],"Grubbs-II-homologen":[73],"Katalysator":[74],"mit":[75,97,108,149,159],"unsymmetrisch":[77,94,129],"substituierten":[78,95,130],"ges\u00e4ttigtem":[81],"R\u00fcckgrat":[82,99],"darzustellen.":[83],"ein":[87],"Nolan-Typ-Katalysator":[88],"auf":[89,216],"Basis":[91],"eines":[92,128],"achiralen":[93],"Oxazolin-NHC-Liganden":[96],"unges\u00e4ttigtem":[98],"synthetisiert":[100],"Derartige":[102],"Ligandensysteme":[103],"wurden":[104,116,215],"bis":[105],"dato":[106],"ausschlie\u00dflich":[107],"Pd-Quellen":[109],"zu":[110,165],"entsprechenden":[111,119,134],"Komplexen":[112],"umgesetzt.":[113],"Beide":[114],"Katalysatorsysteme":[115],"erfolgreich":[117,190],"Benchmark-Systemen":[120],"Aktivit\u00e4tsstudien":[121],"unterworfen.":[122],"non-NHC-Liganden":[131],"(ausgehend":[132],"vom":[133,188],"Iminiumsalz":[135],"als":[136,172,195,219],"Vorl\u00e4ufer)":[137],"Hier":[140],"freie":[143],"Carben":[144],"nachgewiesen":[145],"Umsetzung":[148,158,164],"div.":[150],"Rutheniumkomplexen":[151],"verlief":[152],"weitestgehend":[153],"erfolglos.":[154],"Falle":[156],"dem":[160],"p-Cymol(RuCl2)-Dimer":[161],"einkernigen":[167],"\u03b76-Ruthenium-Komplex":[168],"beobachtet":[169],"werden,":[170],"welcher":[171],"Rohprodukt":[173],"erhalten":[174],"werden":[175,202],"konnte.":[176],"ROMPgel-getr\u00e4gerter":[186],"Imidazoliumsalze":[187],"Arduendo-Typ":[189],"Hierzu":[193],"monomere":[196],"entsprechend":[198],"funktionalisierte":[199],"Norbonenderivate":[200],"genutzt":[201],"deren":[204],"ROMP":[205],"mittels":[207],"Grubbs-II":[208],"initiiert":[209],"untersucht.":[211],"erhaltenen":[213],"Verbindungen":[214],"Ihre":[217],"Eignung":[218],"Umpolungskatalysatoren":[220],"getestet.":[221]},"counts_by_year":[],"updated_date":"2026-08-30T07:30:35.949966","created_date":"2016-08-23T00:00:00"}