{"id":"https://openalex.org/W2486042218","doi":"https://doi.org/10.1246/cl.1990.381","title":"Reaction of Tris(\u03b2-diketonato)ruthenium(III) Complexes with Strong Acids in Acetonitrile. Formation of Bis(acetonitrile)bis(\u03b2-diketonato)ruthenium(III) Complexes","display_name":"Reaction of Tris(\u03b2-diketonato)ruthenium(III) Complexes with Strong Acids in Acetonitrile. Formation of Bis(acetonitrile)bis(\u03b2-diketonato)ruthenium(III) Complexes","publication_year":1990,"publication_date":"1990-03-01","ids":{"openalex":"https://openalex.org/W2486042218","doi":"https://doi.org/10.1246/cl.1990.381","mag":"2486042218"},"language":"en","primary_location":{"id":"doi:10.1246/cl.1990.381","doi":"https://doi.org/10.1246/cl.1990.381","is_oa":false,"landing_page_url":"https://doi.org/10.1246/cl.1990.381","pdf_url":null,"source":{"id":"https://openalex.org/S90825563","display_name":"Chemistry Letters","issn_l":"0366-7022","issn":["0366-7022","1348-0715"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310311648","host_organization_name":"Oxford University Press","host_organization_lineage":["https://openalex.org/P4310311648","https://openalex.org/P4310311647"],"host_organization_lineage_names":["Oxford University Press","University of Oxford"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry Letters","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5005352275","display_name":"Yuko Kasahara","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I42999171","display_name":"Sophia University","ror":"https://ror.org/01nckkm68","country_code":"JP","type":"education","lineage":["https://openalex.org/I42999171"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yuko Kasahara","raw_affiliation_strings":["Department of Chemistry, Faculty of Science and Technology, Sophia University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Faculty of Science and Technology, Sophia University","institution_ids":["https://openalex.org/I42999171"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5051989999","display_name":"Yoshimasa Hoshino","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I42999171","display_name":"Sophia University","ror":"https://ror.org/01nckkm68","country_code":"JP","type":"education","lineage":["https://openalex.org/I42999171"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Yoshimasa Hoshino","raw_affiliation_strings":["Department of Chemistry, Faculty of Science and Technology, Sophia University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Faculty of Science and Technology, Sophia University","institution_ids":["https://openalex.org/I42999171"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5018565784","display_name":"Kunio Shimizu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I42999171","display_name":"Sophia University","ror":"https://ror.org/01nckkm68","country_code":"JP","type":"education","lineage":["https://openalex.org/I42999171"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Kunio Shimizu","raw_affiliation_strings":["Department of Chemistry, Faculty of Science and Technology, Sophia University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Faculty of Science and Technology, Sophia University","institution_ids":["https://openalex.org/I42999171"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5030670734","display_name":"Gen P. Sat\u00f4","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I42999171","display_name":"Sophia University","ror":"https://ror.org/01nckkm68","country_code":"JP","type":"education","lineage":["https://openalex.org/I42999171"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Gen P Sat\u00f4","raw_affiliation_strings":["Department of Chemistry, Faculty of Science and Technology, Sophia University"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, Faculty of Science and Technology, Sophia University","institution_ids":["https://openalex.org/I42999171"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":[],"corresponding_institution_ids":["https://openalex.org/I42999171"],"apc_list":{"value":150000,"currency":"JPY","value_usd":1003},"apc_paid":null,"fwci":0.8267,"has_fulltext":false,"cited_by_count":43,"citation_normalized_percentile":{"value":0.71337911,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":96},"biblio":{"volume":"19","issue":"3","first_page":"381","last_page":"384"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.8237000107765198,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.8237000107765198,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.12330000102519989,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10163","display_name":"Metal complexes synthesis and properties","score":0.038100000470876694,"subfield":{"id":"https://openalex.org/subfields/2730","display_name":"Oncology"},"field":{"id":"https://openalex.org/fields/27","display_name":"Medicine"},"domain":{"id":"https://openalex.org/domains/4","display_name":"Health Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/perchloric-acid","display_name":"perchloric acid","score":0.9369999766349792},{"id":"https://openalex.org/keywords/sulfuric-acid","display_name":"sulfuric acid","score":0.9980000257492065},{"id":"https://openalex.org/keywords/hydrochloric-acid","display_name":"hydrochloric acid","score":1.0},{"id":"https://openalex.org/keywords/acetonitrile","display_name":"acetonitrile","score":0.8450000286102295},{"id":"https://openalex.org/keywords/beta-diketonate-ligands","display_name":"\u03b2-diketonate ligands","score":0.8320000171661377}],"concepts":[{"id":"https://openalex.org/C555196967","wikidata":"https://www.wikidata.org/wiki/Q1086","display_name":"Ruthenium","level":3,"score":0.9816292524337769},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9738517999649048},{"id":"https://openalex.org/C2777463227","wikidata":"https://www.wikidata.org/wiki/Q408047","display_name":"Acetonitrile","level":2,"score":0.9566309452056885},{"id":"https://openalex.org/C2781014771","wikidata":"https://www.wikidata.org/wiki/Q413961","display_name":"Tris","level":2,"score":0.7553259134292603},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.445998877286911},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.4014533758163452},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.33498236536979675},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.26942697167396545},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.18276086449623108},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1246/cl.1990.381","doi":"https://doi.org/10.1246/cl.1990.381","is_oa":false,"landing_page_url":"https://doi.org/10.1246/cl.1990.381","pdf_url":null,"source":{"id":"https://openalex.org/S90825563","display_name":"Chemistry Letters","issn_l":"0366-7022","issn":["0366-7022","1348-0715"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","ki-jl-1","norway-1","poland-70","russia-white-list-2"],"host_organization":"https://openalex.org/P4310311648","host_organization_name":"Oxford University Press","host_organization_lineage":["https://openalex.org/P4310311648","https://openalex.org/P4310311647"],"host_organization_lineage_names":["Oxford University Press","University of Oxford"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry Letters","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":4,"referenced_works":["https://openalex.org/W1973493883","https://openalex.org/W1990422899","https://openalex.org/W1993888749","https://openalex.org/W2142971171"],"related_works":["https://openalex.org/W1999832496","https://openalex.org/W1964317503","https://openalex.org/W2111810842","https://openalex.org/W2952741717","https://openalex.org/W2029517840","https://openalex.org/W2295409733","https://openalex.org/W2034062471","https://openalex.org/W2040714131","https://openalex.org/W2619604142","https://openalex.org/W2952487073"],"abstract_inverted_index":{"Abstract":[0],"Bis(acetonitrile)bis(\u03b2-diketonato)ruthenium(III)":[1],"was":[2,22,26,36],"readily":[3],"formed":[4],"through":[5],"the":[6,9,24,50,58],"reaction":[7,21,35],"of":[8,52,57],"corresponding":[10],"tris(\u03b2-diketonato)ruthenium(III)":[11],"with":[12],"perchloric,":[13],"sulfuric,":[14],"or":[15],"hydrochloric":[16],"acid":[17,31],"in":[18],"acetonitrile.":[19],"The":[20],"quantitative;":[23],"stoichiometry":[25],"1:1":[27],"for":[28,49],"each":[29],"strong":[30],"studied":[32],"here.":[33],"This":[34],"employed":[37],"to":[38,45],"prepare":[39],"several":[40],"bis(acetonitrile)bis(\u03b2-diketonato)ruthenium(III)":[41],"complexes,":[42],"which":[43],"proved":[44],"be":[46],"convenient":[47],"intermediates":[48],"synthesis":[51],"mixed-ligand":[53],"\u03b2-diketonato":[54],"ruthenium(III)":[55],"complexes":[56],"[RuIIIL2L\u2032]":[59],"type.":[60]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":3},{"year":2021,"cited_by_count":1},{"year":2019,"cited_by_count":1},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":2},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":2},{"year":2012,"cited_by_count":2}],"updated_date":"2026-08-21T09:56:20.448147","created_date":"2016-08-23T00:00:00"}