{"id":"https://openalex.org/W2469245192","doi":"https://doi.org/10.1021/jacs.6b05568","title":"Mechanically Shaped Two-Dimensional Covalent Organic Frameworks Reveal Crystallographic Alignment and Fast Li-Ion Conductivity","display_name":"Mechanically Shaped Two-Dimensional Covalent Organic Frameworks Reveal Crystallographic Alignment and Fast Li-Ion Conductivity","publication_year":2016,"publication_date":"2016-07-14","ids":{"openalex":"https://openalex.org/W2469245192","doi":"https://doi.org/10.1021/jacs.6b05568","mag":"2469245192","pmid":"https://pubmed.ncbi.nlm.nih.gov/27414065"},"language":"en","primary_location":{"id":"doi:10.1021/jacs.6b05568","doi":"https://doi.org/10.1021/jacs.6b05568","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.6b05568","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://stars.library.ucf.edu/scopus2015/3698","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5009885283","display_name":"Demetrius A. Vazquez-Molina","orcid":"https://orcid.org/0000-0003-1986-3028","observed_orcids":["https://orcid.org/0000-0003-1986-3028"]},"institutions":[{"id":"https://openalex.org/I106165777","display_name":"University of Central Florida","ror":"https://ror.org/036nfer12","country_code":"US","type":"education","lineage":["https://openalex.org/I106165777"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Demetrius A. Vazquez-Molina","raw_affiliation_strings":["Department\rof Chemistry, University of Central Florida, 4111 Libra Drive, Orlando, Florida 32816, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, University of Central Florida, 4111 Libra Drive, Orlando, Florida 32816, United States","institution_ids":["https://openalex.org/I106165777"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5050505741","display_name":"Gavin S. Mohammad-Pour","orcid":"https://orcid.org/0000-0002-3157-8644","observed_orcids":["https://orcid.org/0000-0002-3157-8644"]},"institutions":[{"id":"https://openalex.org/I106165777","display_name":"University of Central Florida","ror":"https://ror.org/036nfer12","country_code":"US","type":"education","lineage":["https://openalex.org/I106165777"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Gavin S. Mohammad-Pour","raw_affiliation_strings":["Department\rof Chemistry, University of Central Florida, 4111 Libra Drive, Orlando, Florida 32816, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, University of Central Florida, 4111 Libra Drive, Orlando, Florida 32816, United States","institution_ids":["https://openalex.org/I106165777"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5031385934","display_name":"Chain Lee","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Chain Lee","raw_affiliation_strings":["Department\rof Chemistry and Biochemistry, University of California\u2014Los Angeles, 607 Charles E. Young Drive East, Los Angeles, California 90095, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry and Biochemistry, University of California\u2014Los Angeles, 607 Charles E. Young Drive East, Los Angeles, California 90095, United States","institution_ids":["https://openalex.org/I161318765"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5057597878","display_name":"Matthew W. Logan","orcid":"https://orcid.org/0000-0002-8641-2043","observed_orcids":["https://orcid.org/0000-0002-8641-2043"]},"institutions":[{"id":"https://openalex.org/I106165777","display_name":"University of Central Florida","ror":"https://ror.org/036nfer12","country_code":"US","type":"education","lineage":["https://openalex.org/I106165777"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Matthew W. Logan","raw_affiliation_strings":["Department\rof Chemistry, University of Central Florida, 4111 Libra Drive, Orlando, Florida 32816, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, University of Central Florida, 4111 Libra Drive, Orlando, Florida 32816, United States","institution_ids":["https://openalex.org/I106165777"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5019924793","display_name":"Xiangfeng Duan","orcid":"https://orcid.org/0000-0002-4321-6288","observed_orcids":["https://orcid.org/0000-0002-4321-6288"]},"institutions":[{"id":"https://openalex.org/I161318765","display_name":"University of California, Los Angeles","ror":"https://ror.org/046rm7j60","country_code":"US","type":"education","lineage":["https://openalex.org/I161318765"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Xiangfeng Duan","raw_affiliation_strings":["Department\rof Chemistry and Biochemistry, University of California\u2014Los Angeles, 607 Charles E. Young Drive East, Los Angeles, California 90095, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry and Biochemistry, University of California\u2014Los Angeles, 607 Charles E. Young Drive East, Los Angeles, California 90095, United States","institution_ids":["https://openalex.org/I161318765"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5005680364","display_name":"James K. Harper","orcid":"https://orcid.org/0000-0001-8363-2019","observed_orcids":["https://orcid.org/0000-0001-8363-2019"]},"institutions":[{"id":"https://openalex.org/I106165777","display_name":"University of Central Florida","ror":"https://ror.org/036nfer12","country_code":"US","type":"education","lineage":["https://openalex.org/I106165777"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"James K. Harper","raw_affiliation_strings":["Department\rof Chemistry, University of Central Florida, 4111 Libra Drive, Orlando, Florida 32816, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, University of Central Florida, 4111 Libra Drive, Orlando, Florida 32816, United States","institution_ids":["https://openalex.org/I106165777"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5020320447","display_name":"Fernando J. Uribe\u2010Romo","orcid":"https://orcid.org/0000-0003-0212-0295","observed_orcids":["https://orcid.org/0000-0003-0212-0295"]},"institutions":[{"id":"https://openalex.org/I106165777","display_name":"University of Central Florida","ror":"https://ror.org/036nfer12","country_code":"US","type":"education","lineage":["https://openalex.org/I106165777"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Fernando J. Uribe-Romo","raw_affiliation_strings":["Department\rof Chemistry, University of Central Florida, 4111 Libra Drive, Orlando, Florida 32816, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, University of Central Florida, 4111 Libra Drive, Orlando, Florida 32816, United States","institution_ids":["https://openalex.org/I106165777"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5020320447"],"corresponding_institution_ids":["https://openalex.org/I106165777"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":11.5831,"has_fulltext":false,"cited_by_count":291,"citation_normalized_percentile":{"value":0.99173603,"is_in_top_1_percent":true,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":99,"max":100},"biblio":{"volume":"138","issue":"31","first_page":"9767","last_page":"9770"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12038","display_name":"Covalent Organic Framework Applications","score":0.9951000213623047,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12038","display_name":"Covalent Organic Framework Applications","score":0.9951000213623047,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10281","display_name":"Advanced Battery Materials and Technologies","score":0.003700000001117587,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10018","display_name":"Advancements in Battery Materials","score":0.0003000000142492354,"subfield":{"id":"https://openalex.org/subfields/2208","display_name":"Electrical and Electronic Engineering"},"field":{"id":"https://openalex.org/fields/22","display_name":"Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/covalent-organic-frameworks","display_name":"covalent organic frameworks","score":0.9990000128746033},{"id":"https://openalex.org/keywords/mechanical-pressing","display_name":"mechanical pressing","score":0.5189999938011169},{"id":"https://openalex.org/keywords/crystal-orientation","display_name":"crystal orientation","score":0.796999990940094},{"id":"https://openalex.org/keywords/lithium-ion-conductivity","display_name":"lithium ion conductivity","score":0.7289999723434448},{"id":"https://openalex.org/keywords/solid-electrolytes","display_name":"solid electrolytes","score":0.9440000057220459},{"id":"https://openalex.org/keywords/electrochemical-stability","display_name":"electrochemical stability","score":0.953000009059906}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7684322595596313},{"id":"https://openalex.org/C180577832","wikidata":"https://www.wikidata.org/wiki/Q127920","display_name":"Covalent bond","level":2,"score":0.7648763656616211},{"id":"https://openalex.org/C131540310","wikidata":"https://www.wikidata.org/wiki/Q907564","display_name":"Conductivity","level":2,"score":0.5584097504615784},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.5324018597602844},{"id":"https://openalex.org/C52859227","wikidata":"https://www.wikidata.org/wiki/Q7877","display_name":"Electrochemistry","level":3,"score":0.5292548537254333},{"id":"https://openalex.org/C68801617","wikidata":"https://www.wikidata.org/wiki/Q162908","display_name":"Electrolyte","level":3,"score":0.521863579750061},{"id":"https://openalex.org/C2780584874","wikidata":"https://www.wikidata.org/wiki/Q575866","display_name":"Pellets","level":2,"score":0.4721282422542572},{"id":"https://openalex.org/C85725439","wikidata":"https://www.wikidata.org/wiki/Q466686","display_name":"Anisotropy","level":2,"score":0.46027278900146484},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.41058850288391113},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.37439751625061035},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.34018397331237793},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.1782359480857849},{"id":"https://openalex.org/C17525397","wikidata":"https://www.wikidata.org/wiki/Q176140","display_name":"Electrode","level":2,"score":0.16527828574180603},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.1454707682132721},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.11384090781211853},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.08589202165603638},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/jacs.6b05568","doi":"https://doi.org/10.1021/jacs.6b05568","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jacs.6b05568","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmid:27414065","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/27414065","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"Journal Article"},{"id":"pmh:oai:stars.library.ucf.edu:scopus2015-4697","doi":null,"is_oa":true,"landing_page_url":"https://stars.library.ucf.edu/scopus2015/3698","pdf_url":null,"source":{"id":"https://openalex.org/S4210172555","display_name":"Journal of International Crisis and Risk Communication Research","issn_l":"2576-0017","issn":["2576-0017","2576-0025"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","vabb-shw"],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Scopus Export 2015-2019","raw_type":"text"}],"best_oa_location":{"id":"pmh:oai:stars.library.ucf.edu:scopus2015-4697","doi":null,"is_oa":true,"landing_page_url":"https://stars.library.ucf.edu/scopus2015/3698","pdf_url":null,"source":{"id":"https://openalex.org/S4210172555","display_name":"Journal of International Crisis and Risk Communication Research","issn_l":"2576-0017","issn":["2576-0017","2576-0025"],"is_oa":true,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","vabb-shw"],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"journal"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Scopus Export 2015-2019","raw_type":"text"},"sustainable_development_goals":[{"display_name":"Affordable and clean energy","score":0.75,"id":"https://metadata.un.org/sdg/7"}],"study_designs":[],"awards":[{"id":"https://openalex.org/G6349810329","display_name":null,"funder_award_id":"CHE-1255159","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320310161","display_name":"University of Central Florida","ror":"https://ror.org/036nfer12"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":43,"referenced_works":["https://openalex.org/W1499303660","https://openalex.org/W1846545360","https://openalex.org/W1989896216","https://openalex.org/W1994692711","https://openalex.org/W1998010272","https://openalex.org/W2012037219","https://openalex.org/W2023429066","https://openalex.org/W2024540372","https://openalex.org/W2025286111","https://openalex.org/W2028478923","https://openalex.org/W2048435598","https://openalex.org/W2049145344","https://openalex.org/W2050571756","https://openalex.org/W2055880283","https://openalex.org/W2066470151","https://openalex.org/W2066704330","https://openalex.org/W2071253878","https://openalex.org/W2076625553","https://openalex.org/W2081643155","https://openalex.org/W2104015519","https://openalex.org/W2108510319","https://openalex.org/W2119741446","https://openalex.org/W2125117436","https://openalex.org/W2130351060","https://openalex.org/W2142269054","https://openalex.org/W2153511586","https://openalex.org/W2197550433","https://openalex.org/W2202012423","https://openalex.org/W2253548549","https://openalex.org/W2283475756","https://openalex.org/W2284687880","https://openalex.org/W2314803279","https://openalex.org/W2315309588","https://openalex.org/W2321930235","https://openalex.org/W2323852127","https://openalex.org/W2327311573","https://openalex.org/W2329311393","https://openalex.org/W2330915705","https://openalex.org/W2332785792","https://openalex.org/W2341179493","https://openalex.org/W2487723089","https://openalex.org/W2512613154","https://openalex.org/W3023435578"],"related_works":["https://openalex.org/W4324091702","https://openalex.org/W2965408278","https://openalex.org/W3001554634","https://openalex.org/W4384626189","https://openalex.org/W4307353661","https://openalex.org/W3212232617","https://openalex.org/W3210283923","https://openalex.org/W3185777363","https://openalex.org/W3048892518","https://openalex.org/W4281490327"],"abstract_inverted_index":{"Covalent":[0],"organic":[1],"frameworks":[2],"(COFs)":[3],"usually":[4],"crystallize":[5],"as":[6,91],"insoluble":[7],"powders,":[8],"and":[9,39,48,54,81],"their":[10],"processing":[11],"for":[12],"suitable":[13],"devices":[14],"is":[15],"thought":[16],"to":[17,77],"be":[18,25],"limited.":[19],"We":[20],"demonstrate":[21],"that":[22],"COFs":[23,44,90],"can":[24],"mechanically":[26],"pressed":[27],"into":[28],"shaped":[29],"objects":[30],"having":[31],"anisotropic":[32],"ordering":[33],"with":[34,45,70],"preferred":[35],"orientation":[36],"between":[37],"hk0":[38],"00l":[40],"crystallographic":[41,52],"planes.":[42],"Five":[43],"different":[46],"functionality":[47],"symmetry":[49],"exhibited":[50],"similar":[51],"behavior":[53],"remarkable":[55],"stability,":[56],"indicating":[57],"the":[58],"generality":[59],"of":[60,89],"this":[61],"processing.":[62],"Pellets":[63],"prepared":[64],"from":[65],"bulk":[66],"COF":[67],"powders":[68],"impregnated":[69],"LiClO4":[71],"displayed":[72],"room":[73],"temperature":[74],"conductivity":[75],"up":[76],"0.26":[78],"mS":[79],"cm(-1)":[80],"high":[82],"electrochemical":[83],"stability.":[84],"This":[85],"outcome":[86],"portends":[87],"use":[88],"solid-state":[92],"electrolytes":[93],"in":[94],"batteries.":[95]},"counts_by_year":[{"year":2026,"cited_by_count":15},{"year":2025,"cited_by_count":21},{"year":2024,"cited_by_count":37},{"year":2023,"cited_by_count":31},{"year":2022,"cited_by_count":28},{"year":2021,"cited_by_count":37},{"year":2020,"cited_by_count":43},{"year":2019,"cited_by_count":32},{"year":2018,"cited_by_count":22},{"year":2017,"cited_by_count":24}],"updated_date":"2026-10-12T09:40:04.860316","created_date":"2016-07-22T00:00:00"}