{"id":"https://openalex.org/W2462282937","doi":"https://doi.org/10.1002/chem.201601784","title":"Direct Structural Identification of Gas Induced Gate\u2010Opening Coupled with Commensurate Adsorption in a Microporous Metal\u2013Organic Framework","display_name":"Direct Structural Identification of Gas Induced Gate\u2010Opening Coupled with Commensurate Adsorption in a Microporous Metal\u2013Organic Framework","publication_year":2016,"publication_date":"2016-07-07","ids":{"openalex":"https://openalex.org/W2462282937","doi":"https://doi.org/10.1002/chem.201601784","mag":"2462282937","pmid":"https://pubmed.ncbi.nlm.nih.gov/27385527"},"language":"en","primary_location":{"id":"doi:10.1002/chem.201601784","doi":"https://doi.org/10.1002/chem.201601784","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chem.201601784","pdf_url":null,"source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry \u2013 A European Journal","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5021823749","display_name":"Debasis Banerjee","orcid":"https://orcid.org/0009-0004-5710-6663","observed_orcids":["https://orcid.org/0009-0004-5710-6663","https://orcid.org/0000-0001-8626-8742"]},"institutions":[{"id":"https://openalex.org/I102322142","display_name":"Rutgers, The State University of New Jersey","ror":"https://ror.org/05vt9qd57","country_code":"US","type":"education","lineage":["https://openalex.org/I102322142"]},{"id":"https://openalex.org/I142606810","display_name":"Pacific Northwest National Laboratory","ror":"https://ror.org/05h992307","country_code":"US","type":"facility","lineage":["https://openalex.org/I1325736334","https://openalex.org/I1330989302","https://openalex.org/I142606810","https://openalex.org/I39565521"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Debasis Banerjee","raw_affiliation_strings":["Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey, 08854 USA","Fundamental and Computational Science Directorate, Pacific Northwest National Laboratory, Richland, Washington, 99352 USA","These authors contributed equally to this work"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey, 08854 USA","institution_ids":["https://openalex.org/I102322142"]},{"raw_affiliation_string":"Fundamental and Computational Science Directorate, Pacific Northwest National Laboratory, Richland, Washington, 99352 USA","institution_ids":["https://openalex.org/I142606810"]},{"raw_affiliation_string":"These authors contributed equally to this work","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009431721","display_name":"Hao Wang","orcid":"https://orcid.org/0000-0001-7732-778X","observed_orcids":["https://orcid.org/0000-0001-7732-778X"]},"institutions":[{"id":"https://openalex.org/I102322142","display_name":"Rutgers, The State University of New Jersey","ror":"https://ror.org/05vt9qd57","country_code":"US","type":"education","lineage":["https://openalex.org/I102322142"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Hao Wang","raw_affiliation_strings":["Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey, 08854 USA","These authors contributed equally to this work"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey, 08854 USA","institution_ids":["https://openalex.org/I102322142"]},{"raw_affiliation_string":"These authors contributed equally to this work","institution_ids":[]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5040705794","display_name":"Anna M. P\u0142onka","orcid":"https://orcid.org/0000-0003-2606-0477","observed_orcids":["https://orcid.org/0000-0003-2606-0477"]},"institutions":[{"id":"https://openalex.org/I19772626","display_name":"Yeshiva University","ror":"https://ror.org/045x93337","country_code":"US","type":"education","lineage":["https://openalex.org/I19772626"]},{"id":"https://openalex.org/I59553526","display_name":"Stony Brook University","ror":"https://ror.org/05qghxh33","country_code":"US","type":"education","lineage":["https://openalex.org/I59553526"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Anna M. Plonka","raw_affiliation_strings":["Department of Geosciences, Stony Brook University, Stony Brook, New York, 11794 USA","Physics Department, Yeshiva University, New York, NY, 10016 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Geosciences, Stony Brook University, Stony Brook, New York, 11794 USA","institution_ids":["https://openalex.org/I59553526"]},{"raw_affiliation_string":"Physics Department, Yeshiva University, New York, NY, 10016 USA","institution_ids":["https://openalex.org/I19772626"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5077351386","display_name":"Thomas J. Emge","orcid":"https://orcid.org/0000-0002-5307-7250","observed_orcids":["https://orcid.org/0000-0002-5307-7250"]},"institutions":[{"id":"https://openalex.org/I102322142","display_name":"Rutgers, The State University of New Jersey","ror":"https://ror.org/05vt9qd57","country_code":"US","type":"education","lineage":["https://openalex.org/I102322142"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Thomas J. Emge","raw_affiliation_strings":["Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey, 08854 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey, 08854 USA","institution_ids":["https://openalex.org/I102322142"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5023871557","display_name":"John B. Parise","orcid":"https://orcid.org/0000-0002-1302-703X","observed_orcids":["https://orcid.org/0000-0002-1302-703X"]},"institutions":[{"id":"https://openalex.org/I59553526","display_name":"Stony Brook University","ror":"https://ror.org/05qghxh33","country_code":"US","type":"education","lineage":["https://openalex.org/I59553526"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"John B. Parise","raw_affiliation_strings":["Department of Geosciences, Stony Brook University, Stony Brook, New York, 11794 USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Geosciences, Stony Brook University, Stony Brook, New York, 11794 USA","institution_ids":["https://openalex.org/I59553526"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5100336796","display_name":"Jing Li","orcid":"https://orcid.org/0000-0001-7792-4322","observed_orcids":["https://orcid.org/0000-0001-7792-4322","https://orcid.org/0000-0003-1811-4586"]},"institutions":[{"id":"https://openalex.org/I102322142","display_name":"Rutgers, The State University of New Jersey","ror":"https://ror.org/05vt9qd57","country_code":"US","type":"education","lineage":["https://openalex.org/I102322142"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Jing Li","raw_affiliation_strings":["Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey, 08854 USA"],"raw_orcid":"https://orcid.org/0000-0001-7792-4322","affiliations":[{"raw_affiliation_string":"Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, New Jersey, 08854 USA","institution_ids":["https://openalex.org/I102322142"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5100336796"],"corresponding_institution_ids":["https://openalex.org/I102322142"],"apc_list":{"value":4640,"currency":"USD","value_usd":4640},"apc_paid":null,"fwci":2.115,"has_fulltext":false,"cited_by_count":35,"citation_normalized_percentile":{"value":0.86993725,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"22","issue":"33","first_page":"11816","last_page":"11825"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10096","display_name":"Metal-Organic Frameworks: Synthesis and Applications","score":0.9990000128746033,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12038","display_name":"Covalent Organic Framework Applications","score":0.00039999998989515007,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11362","display_name":"Membrane Separation and Gas Transport","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/1506","display_name":"Filtration and Separation"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/gate-opening","display_name":"gate opening","score":0.8159999847412109},{"id":"https://openalex.org/keywords/metal-organic-frameworks","display_name":"metal-organic frameworks","score":0.8920000195503235},{"id":"https://openalex.org/keywords/co2-adsorption","display_name":"CO2 adsorption","score":0.8450000286102295},{"id":"https://openalex.org/keywords/propane-adsorption","display_name":"propane adsorption","score":0.9919999837875366},{"id":"https://openalex.org/keywords/gas-separation","display_name":"gas separation","score":0.527999997138977}],"concepts":[{"id":"https://openalex.org/C86381522","wikidata":"https://www.wikidata.org/wiki/Q2752988","display_name":"Microporous material","level":2,"score":0.8376699686050415},{"id":"https://openalex.org/C150394285","wikidata":"https://www.wikidata.org/wiki/Q180254","display_name":"Adsorption","level":2,"score":0.7776823043823242},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.5445204377174377},{"id":"https://openalex.org/C179366358","wikidata":"https://www.wikidata.org/wiki/Q909212","display_name":"Metal-organic framework","level":3,"score":0.5258381962776184},{"id":"https://openalex.org/C162711632","wikidata":"https://www.wikidata.org/wiki/Q905514","display_name":"Desorption","level":3,"score":0.5149708390235901},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.48345670104026794},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.4590079188346863},{"id":"https://openalex.org/C39519442","wikidata":"https://www.wikidata.org/wiki/Q904893","display_name":"Differential scanning calorimetry","level":2,"score":0.41789495944976807},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.40538689494132996},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.4002978205680847},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.19426760077476501},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.17862042784690857},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.14251938462257385},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1002/chem.201601784","doi":"https://doi.org/10.1002/chem.201601784","is_oa":false,"landing_page_url":"https://doi.org/10.1002/chem.201601784","pdf_url":null,"source":{"id":"https://openalex.org/S68911691","display_name":"Chemistry - A European Journal","issn_l":"0947-6539","issn":["0947-6539","1521-3765"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-2","ki-jl-2","medline","norway-2","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320595","host_organization_name":"Wiley","host_organization_lineage":["https://openalex.org/P4310320595"],"host_organization_lineage_names":["Wiley"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry \u2013 A European Journal","raw_type":"journal-article"},{"id":"pmid:27385527","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/27385527","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Chemistry (Weinheim an der Bergstrasse, Germany)","raw_type":"Journal Article"},{"id":"pmh:oai:osti.gov:1400463","doi":null,"is_oa":false,"landing_page_url":"https://www.osti.gov/biblio/1400463","pdf_url":null,"source":{"id":"https://openalex.org/S4306402487","display_name":"OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I139351228","host_organization_name":"Office of Scientific and Technical Information","host_organization_lineage":["https://openalex.org/I139351228"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G2643097022","display_name":"NOVEL THEORETICAL AND EXPERIMENTAL APPROACHES FOR UNDERSTANDING AND OPTIMIZING HYDROGEN-SORBENT","funder_award_id":"DEFG0208ER46491","funder_id":"https://openalex.org/F4320306084","funder_display_name":"U.S. Department of Energy"}],"funders":[{"id":"https://openalex.org/F4320306084","display_name":"U.S. Department of Energy","ror":"https://ror.org/01bj3aw27"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":64,"referenced_works":["https://openalex.org/W1972146469","https://openalex.org/W1973687047","https://openalex.org/W1974333979","https://openalex.org/W1982063727","https://openalex.org/W1985558127","https://openalex.org/W1987943700","https://openalex.org/W1989036019","https://openalex.org/W1989118706","https://openalex.org/W1990966816","https://openalex.org/W1992545229","https://openalex.org/W1993933512","https://openalex.org/W1995365123","https://openalex.org/W1999918445","https://openalex.org/W2002799357","https://openalex.org/W2005454218","https://openalex.org/W2007082361","https://openalex.org/W2010052854","https://openalex.org/W2015034050","https://openalex.org/W2021549741","https://openalex.org/W2028602669","https://openalex.org/W2030327355","https://openalex.org/W2030434872","https://openalex.org/W2038123723","https://openalex.org/W2040837069","https://openalex.org/W2041790717","https://openalex.org/W2042397184","https://openalex.org/W2051441149","https://openalex.org/W2061090028","https://openalex.org/W2062269633","https://openalex.org/W2062916427","https://openalex.org/W2066001826","https://openalex.org/W2066339511","https://openalex.org/W2069537362","https://openalex.org/W2094145140","https://openalex.org/W2094774149","https://openalex.org/W2099486431","https://openalex.org/W2102457549","https://openalex.org/W2105631122","https://openalex.org/W2110899146","https://openalex.org/W2115328740","https://openalex.org/W2115735355","https://openalex.org/W2134094254","https://openalex.org/W2145538332","https://openalex.org/W2148860836","https://openalex.org/W2154854306","https://openalex.org/W2156440952","https://openalex.org/W2168431088","https://openalex.org/W2170669177","https://openalex.org/W2314599426","https://openalex.org/W2315315313","https://openalex.org/W2316124489","https://openalex.org/W2316651128","https://openalex.org/W2319032468","https://openalex.org/W2319066054","https://openalex.org/W2321596778","https://openalex.org/W2322759533","https://openalex.org/W2737396643","https://openalex.org/W3143879557","https://openalex.org/W4232142777","https://openalex.org/W4238771099","https://openalex.org/W4249290975","https://openalex.org/W4249594919","https://openalex.org/W4254807473","https://openalex.org/W4299130266"],"related_works":["https://openalex.org/W3149477275","https://openalex.org/W2888178072","https://openalex.org/W2020171897","https://openalex.org/W4221090872","https://openalex.org/W7009878115","https://openalex.org/W2809854799","https://openalex.org/W2066001826","https://openalex.org/W4400318523","https://openalex.org/W2332973748","https://openalex.org/W4402971802"],"abstract_inverted_index":{"Gate-opening":[0],"is":[1,36,67],"a":[2,58,96,104,116,160,172],"unique":[3],"and":[4,138,148,186],"interesting":[5],"phenomenon":[6,66],"commonly":[7],"observed":[8,153],"in":[9,21,127,154],"flexible":[10],"porous":[11],"frameworks,":[12],"where":[13],"the":[14,41,72,85,146,167,177,193,197],"pore":[15],"characteristics":[16],"and/or":[17],"crystal":[18,124],"structures":[19],"change":[20],"response":[22],"to":[23,55,71,84,191],"external":[24],"stimuli":[25],"such":[26,92,200],"as":[27,171],"adding":[28],"or":[29],"removing":[30],"guest":[31],"molecules.":[32],"For":[33],"gate-opening":[34,101],"that":[35,145,163],"induced":[37],"by":[38,115],"gas":[39,59,139,181],"adsorption,":[40,114],"pore-opening":[42],"pressure":[43,190],"often":[44],"varies":[45],"for":[46,91],"different":[47],"adsorbate":[48],"molecules":[49,170,182],"and,":[50],"thus,":[51],"can":[52],"be":[53],"applied":[54],"selectively":[56],"separate":[57],"mixture.":[60],"The":[61,188],"detailed":[62],"understanding":[63],"of":[64,68,74,87,99,103,118,166,174,176,199],"this":[65],"fundamental":[69],"importance":[70],"design":[73],"industrially":[75],"applicable":[76],"gas-selective":[77],"sorbents,":[78],"which":[79],"remains":[80],"under":[81],"investigated":[82],"due":[83],"lack":[86],"direct":[88],"structural":[89,161],"evidence":[90],"systems.":[93],"We":[94],"report":[95],"mechanistic":[97],"study":[98,143],"gas-induced":[100],"process":[102],"microporous":[105],"metal-organic":[106],"framework,":[107],"[Mn(ina)2":[108,155],"]":[109,156],"(ina=isonicotinate)":[110],"associated":[111],"with":[112,133,159,179,196],"commensurate":[113],"combination":[117],"several":[119],"analytical":[120],"techniques":[121],"including":[122,183],"single":[123],"X-ray":[125,130],"diffraction,":[126],"situ":[128],"powder":[129],"diffraction":[131],"coupled":[132,158],"differential":[134],"scanning":[135],"calorimetry":[136],"(XRD-DSC),":[137],"adsorption-desorption":[140],"methods.":[141],"Our":[142],"reveals":[144],"pronounced":[147],"reversible":[149],"gate":[150,194],"opening/closing":[151],"phenomena":[152],"are":[157],"transition":[162],"involves":[164],"rotation":[165],"organic":[168],"linker":[169],"result":[173],"interaction":[175],"framework":[178],"adsorbed":[180],"carbon":[184],"dioxide":[185],"propane.":[187],"onset":[189],"open":[192],"correlates":[195],"extent":[198],"interaction.":[201]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":5},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":3},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":8},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":6}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-07-22T00:00:00"}