{"id":"https://openalex.org/W243569686","doi":"https://doi.org/10.1021/ja00051a025","title":"A hydrogen atom in an organoplatinum-amine system. 1. Synthesis and spectroscopic and crystallographic characterization of novel zwitterionic complexes with a Pt(II)-.cntdot..cntdot..cntdot.H-N+ unit","display_name":"A hydrogen atom in an organoplatinum-amine system. 1. Synthesis and spectroscopic and crystallographic characterization of novel zwitterionic complexes with a Pt(II)-.cntdot..cntdot..cntdot.H-N+ unit","publication_year":1992,"publication_date":"1992-12-01","ids":{"openalex":"https://openalex.org/W243569686","doi":"https://doi.org/10.1021/ja00051a025","mag":"243569686"},"language":"en","primary_location":{"id":"doi:10.1021/ja00051a025","doi":"https://doi.org/10.1021/ja00051a025","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00051a025","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"https://dspace.library.uu.nl/handle/1874/6044","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5079479992","display_name":"Ingrid C. M. Wehman\u2010Ooyevaar","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Ingrid C. M. Wehman-Ooyevaar","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110000821","display_name":"David M. Grove","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"David M. Grove","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032467416","display_name":"H. Kooijman","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Huub Kooijman","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5110080671","display_name":"P. van der Sluis","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Paul Van der Sluis","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"middle","author":{"id":"https://openalex.org/A5082910131","display_name":"Anton L. Spek","orcid":null,"observed_orcids":[]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Anthony L. Spek","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]},{"author_position":"last","author":{"id":"https://openalex.org/A5089521767","display_name":"Gerard van Koten","orcid":"https://orcid.org/0000-0003-3293-8370","observed_orcids":["https://orcid.org/0000-0003-3293-8370"]},"institutions":[],"countries":[],"is_corresponding":false,"raw_author_name":"Gerard Van Koten","raw_affiliation_strings":[],"raw_orcid":null,"affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":[],"corresponding_institution_ids":[],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.2352,"has_fulltext":true,"cited_by_count":94,"citation_normalized_percentile":{"value":0.86002575,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":87,"max":98},"biblio":{"volume":"114","issue":"25","first_page":"9916","last_page":"9924"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9740999937057495,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.9740999937057495,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11746","display_name":"Inorganic and Organometallic Chemistry","score":0.010700000450015068,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.006200000178068876,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/organotin-reagents","display_name":"organotin reagents","score":0.5400000214576721},{"id":"https://openalex.org/keywords/electrostatic-interactions","display_name":"electrostatic interactions","score":0.4749999940395355},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.5799999833106995},{"id":"https://openalex.org/keywords/195pt-nmr","display_name":"195Pt NMR","score":0.6520000100135803},{"id":"https://openalex.org/keywords/chiral-ligands","display_name":"chiral ligands","score":0.5509999990463257}],"concepts":[{"id":"https://openalex.org/C2778805511","wikidata":"https://www.wikidata.org/wiki/Q1713","display_name":"Citation","level":2,"score":0.6747965812683105},{"id":"https://openalex.org/C58312451","wikidata":"https://www.wikidata.org/wiki/Q4817200","display_name":"Atom (system on chip)","level":2,"score":0.45906761288642883},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.4323884844779968},{"id":"https://openalex.org/C518677369","wikidata":"https://www.wikidata.org/wiki/Q202833","display_name":"Social media","level":2,"score":0.4220190942287445},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.40301674604415894},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.3918454051017761},{"id":"https://openalex.org/C23123220","wikidata":"https://www.wikidata.org/wiki/Q816826","display_name":"Information retrieval","level":1,"score":0.36774933338165283},{"id":"https://openalex.org/C171250308","wikidata":"https://www.wikidata.org/wiki/Q11468","display_name":"Nanotechnology","level":1,"score":0.3298821449279785},{"id":"https://openalex.org/C161191863","wikidata":"https://www.wikidata.org/wiki/Q199655","display_name":"Library science","level":1,"score":0.3102383017539978},{"id":"https://openalex.org/C136764020","wikidata":"https://www.wikidata.org/wiki/Q466","display_name":"World Wide Web","level":1,"score":0.24423518776893616},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.20893576741218567},{"id":"https://openalex.org/C149635348","wikidata":"https://www.wikidata.org/wiki/Q193040","display_name":"Embedded system","level":1,"score":0.0}],"mesh":[],"locations_count":3,"locations":[{"id":"doi:10.1021/ja00051a025","doi":"https://doi.org/10.1021/ja00051a025","is_oa":false,"landing_page_url":"https://doi.org/10.1021/ja00051a025","pdf_url":null,"source":{"id":"https://openalex.org/S111155417","display_name":"Journal of the American Chemical Society","issn_l":"0002-7863","issn":["0002-7863","1520-5126","1943-2984"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-a","jufo-3","ki-jl-3","medline","norway-2","poland-200","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of the American Chemical Society","raw_type":"journal-article"},{"id":"pmh:uu:oai:dspace.library.uu.nl:1874/6044","doi":null,"is_oa":true,"landing_page_url":"https://dspace.library.uu.nl/handle/1874/6044","pdf_url":"https://dspace.library.uu.nl/handle/1874/6044","source":{"id":"https://openalex.org/S4306401649","display_name":"Utrecht University Repository (Utrecht University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I193662353","host_organization_name":"Utrecht University","host_organization_lineage":["https://openalex.org/I193662353"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal of the American Chemical Society, 114(25), 9916. American Chemical Society","raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:oai:dspace.library.uu.nl:1874/6044","doi":null,"is_oa":true,"landing_page_url":"http://dspace.library.uu.nl:8080/handle/1874/6044","pdf_url":null,"source":{"id":"https://openalex.org/S4306401649","display_name":"Utrecht University Repository (Utrecht University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I193662353","host_organization_name":"Utrecht University","host_organization_lineage":["https://openalex.org/I193662353"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"Article"}],"best_oa_location":{"id":"pmh:uu:oai:dspace.library.uu.nl:1874/6044","doi":null,"is_oa":true,"landing_page_url":"https://dspace.library.uu.nl/handle/1874/6044","pdf_url":"https://dspace.library.uu.nl/handle/1874/6044","source":{"id":"https://openalex.org/S4306401649","display_name":"Utrecht University Repository (Utrecht University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I193662353","host_organization_name":"Utrecht University","host_organization_lineage":["https://openalex.org/I193662353"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Journal of the American Chemical Society, 114(25), 9916. American Chemical Society","raw_type":"info:eu-repo/semantics/article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W243569686.pdf","grobid_xml":"https://content.openalex.org/works/W243569686.grobid-xml"},"referenced_works_count":0,"referenced_works":[],"related_works":["https://openalex.org/W7029004886","https://openalex.org/W2167418293","https://openalex.org/W2003464534","https://openalex.org/W2012598281","https://openalex.org/W2800968255","https://openalex.org/W2076639849","https://openalex.org/W2073947554","https://openalex.org/W3120755978","https://openalex.org/W2951786762","https://openalex.org/W2017249125"],"abstract_inverted_index":{"The":[0],"unusual":[1],"bridging-hydrogen":[2],"complexes":[3],"PtX(L-C,N)(LH-C,H)":[4,102],"containing":[5],"a":[6,14,29,75,85,113,127,144,149,193,231],"zwitterionic":[7,71],"Pt(II)--.H-N+":[8,72],"moiety":[9,73,99,176],"have":[10],"been":[11],"obtained":[12,57],"in":[13,28,41,126],"reaction":[15,43,59,128],"of":[16,31,60,69,87,100,106,116,142,173],"cis-Pt(L-C,N),":[17,124],"with":[18,64,84,93,112,129],"R2SnX,":[19],"(R":[20],"=":[21,25,194,200,204,210,213,216,232,236,241,245],"Me,":[22],"Ph;":[23],"X":[24],"C1,":[26],"Br)":[27],"mixture":[30],"CH2C12":[32],"and":[33,48,148,221,251],"MeOH.The":[34],"chelating":[35],"amine":[36],"ligand":[37,95],"systems":[38],"L":[39,120],"used":[40],"this":[42],"are":[44,153],"[":[45],"1-Cl&6NMe2-8]-,":[46],"[C6H4CH2NMq-2]-,":[47],"[C6H4CH2NEt2-2]-.The":[49],"complex":[50,133],"PtC1(":[51],"l-CloH6NMe2-8-C,N)(":[52],"l-CloH6NHMe2-8-C,H)":[53],"can":[54],"also":[55],"be":[56],"by":[58],"cis-Pt(":[61],"1-":[62],"CloH6NMe,-8-C,N),":[63],"dry":[65],"HC1.The":[66],"bridging":[67,145,162,175],"proton":[68],"the":[70,90,97,101,107,117,131,136,155,161,171,174,183],"shows":[74,157],"characteristic":[76],"'H":[77],"NMR":[78],"resonance":[79],"at":[80,190,228],"ca.":[81],"11-16":[82],"ppm":[83],"1J('95Pt,'H)":[86],"ca.65-180":[88],"Hz;":[89],"latter":[91,156],"decreases":[92],"increasing":[94],"flexibility.In":[96],"Pts-H-N":[98],"complexes,":[103],"an":[104],"increase":[105],"Pt-H":[108],"interaction":[109,163],"is":[110,121,164],"associated":[111],"simultaneous":[114],"decrease":[115],"H-N":[118],"interaction.When":[119],"chiral":[122],"[C6H4CH(Me)NMe2-(R)-2]-,":[123],"affords":[125],"Me2SnBr2":[130],"nonbridging":[132,150],"PtBr(C6H4CH(Me)NMe2-(R)-2-C,N)(C6H4CH(Me)NHMe2-(R)-2-C)":[134,227],"as":[135],"major":[137],"product.The":[138],"X-ray":[139],"crystal":[140],"structures":[141],"both":[143],"complex,":[146,151],"i.e.PtBr(l-CloH6NMe2-8-C,N)(l-ClOH6NHMe2-8-C,H),":[147],"i.e.PtBr(C6H4CH(Me)NMe2-(R)-2-C,N)(C6H4CH(Me)NHMe2-(R)-2-C),":[152],"described.Especially":[154],"good":[158],"evidence":[159],"that":[160],"largely":[165],"electrostatic.Internal":[166],"steric":[167],"influences":[168],"only":[169],"affect":[170],"stability":[172],"when":[177],"they":[178],"arise":[179],"from":[180],"groups":[181],"on":[182],"benzylic":[184],"carbon":[185],"atom.Crystal":[186],"data":[187,225],"for":[188,226],"PtBr(l-C,oH6NMe2-8-C,N)(l-C,oH6NHMe2-8-C,H)":[189],"100":[191],"K:":[192,230],"9.469":[195],"(":[196],"1)":[197],"A,":[198,202,207,234,239,243],"b":[199,235],"30.481(1)":[201],"c":[203,240],"7.298":[205],"(1)":[206],"/":[208],"3":[209],"91.81(1)O,":[211],"Z":[212,244],"4,":[214,246],"Dcalcd":[215],"1.945":[217],"g":[218,249],"~m":[219],"-~,":[220],"space":[222,252],"group":[223,253],"Cc.Crystal":[224],"298":[229],"11.136(1)":[233],"12.0577":[237],"(8)":[238],"15.378(1)":[242],"Dmld":[247],"=1.841":[248],"cm-j,":[250],"P2,2,2,.":[254]},"counts_by_year":[{"year":2026,"cited_by_count":1},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":1},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":1},{"year":2014,"cited_by_count":2},{"year":2013,"cited_by_count":5},{"year":2012,"cited_by_count":2}],"updated_date":"2026-11-08T12:12:28.789561","created_date":"2016-06-24T00:00:00"}