{"id":"https://openalex.org/W2431096574","doi":"https://doi.org/10.1107/s2056989016009269","title":"Crystal structure of an unknown solvate of (piperazine-\u03ba N ){5,10,15,20-tetrakis[4-(benzoyloxy)phenyl]porphyrinato-\u03ba 4 N }zinc","display_name":"Crystal structure of an unknown solvate of (piperazine-\u03ba N ){5,10,15,20-tetrakis[4-(benzoyloxy)phenyl]porphyrinato-\u03ba 4 N }zinc","publication_year":2016,"publication_date":"2016-06-14","ids":{"openalex":"https://openalex.org/W2431096574","doi":"https://doi.org/10.1107/s2056989016009269","mag":"2431096574","pmid":"https://pubmed.ncbi.nlm.nih.gov/27555935","pmcid":"https://www.ncbi.nlm.nih.gov/pmc/articles/4992910"},"language":"en","primary_location":{"id":"doi:10.1107/s2056989016009269","doi":"https://doi.org/10.1107/s2056989016009269","is_oa":true,"landing_page_url":"https://doi.org/10.1107/s2056989016009269","pdf_url":"http://journals.iucr.org/e/issues/2016/07/00/lh5815/lh5815.pdf","source":{"id":"https://openalex.org/S2739106167","display_name":"Acta Crystallographica Section E Crystallographic Communications","issn_l":"2056-9890","issn":["2056-9890"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-c","jufo-1","norway-1","oarl","poland-20","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320555","host_organization_name":"International Union of Crystallography","host_organization_lineage":["https://openalex.org/P4310320555"],"host_organization_lineage_names":["International Union of Crystallography"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallographica Section E Crystallographic Communications","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","datacite","doaj","pubmed"],"open_access":{"is_oa":true,"oa_status":"gold","oa_url":"http://journals.iucr.org/e/issues/2016/07/00/lh5815/lh5815.pdf","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5083866440","display_name":"Soumaya Nasri","orcid":"https://orcid.org/0000-0002-7753-8306","observed_orcids":["https://orcid.org/0000-0002-7753-8306"]},"institutions":[{"id":"https://openalex.org/I166928557","display_name":"University of Monastir","ror":"https://ror.org/00nhtcg76","country_code":"TN","type":"education","lineage":["https://openalex.org/I166928557"]}],"countries":["TN"],"is_corresponding":true,"raw_author_name":"Soumaya Nasri","raw_affiliation_strings":["Laboratoire de Physico-chimie des Mat\u00e9riaux, Facult\u00e9 des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Physico-chimie des Mat\u00e9riaux, Facult\u00e9 des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia","institution_ids":["https://openalex.org/I166928557"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5035908266","display_name":"Khaireddine Ezzayani","orcid":"https://orcid.org/0000-0001-9334-6788","observed_orcids":["https://orcid.org/0000-0001-9334-6788"]},"institutions":[{"id":"https://openalex.org/I166928557","display_name":"University of Monastir","ror":"https://ror.org/00nhtcg76","country_code":"TN","type":"education","lineage":["https://openalex.org/I166928557"]}],"countries":["TN"],"is_corresponding":false,"raw_author_name":"Khaireddine Ezzayani","raw_affiliation_strings":["Laboratoire de Physico-chimie des Mat\u00e9riaux, Facult\u00e9 des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Physico-chimie des Mat\u00e9riaux, Facult\u00e9 des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia","institution_ids":["https://openalex.org/I166928557"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5036875838","display_name":"Ilona Turowska\u2010Tyrk","orcid":"https://orcid.org/0000-0001-8534-1944","observed_orcids":["https://orcid.org/0000-0001-8534-1944","https://orcid.org/0009-0004-3598-6401"]},"institutions":[{"id":"https://openalex.org/I11923345","display_name":"Wroc\u0142aw University of Science and Technology","ror":"https://ror.org/008fyn775","country_code":"PL","type":"education","lineage":["https://openalex.org/I11923345"]}],"countries":["PL"],"is_corresponding":false,"raw_author_name":"Ilona Turowska-Tyrk","raw_affiliation_strings":["Faculty of Chemistry, Wro\u0142aw University of Technology, Wybrze\u017ce Wyspia\u0144skiego 27, 50-370 Wro\u0142aw, Poland"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Faculty of Chemistry, Wro\u0142aw University of Technology, Wybrze\u017ce Wyspia\u0144skiego 27, 50-370 Wro\u0142aw, Poland","institution_ids":["https://openalex.org/I11923345"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5049143428","display_name":"Thierry Roisnel","orcid":"https://orcid.org/0000-0002-6088-4472","observed_orcids":["https://orcid.org/0000-0002-6088-4472"]},"institutions":[{"id":"https://openalex.org/I1294671590","display_name":"Centre National de la Recherche Scientifique","ror":"https://ror.org/02feahw73","country_code":"FR","type":"government","lineage":["https://openalex.org/I1294671590"]},{"id":"https://openalex.org/I4210090783","display_name":"Institut des Sciences Chimiques de Rennes","ror":"https://ror.org/00adwkx90","country_code":"FR","type":"facility","lineage":["https://openalex.org/I1294671590","https://openalex.org/I28221208","https://openalex.org/I4210090783","https://openalex.org/I4210115835","https://openalex.org/I4210128300","https://openalex.org/I56067802"]},{"id":"https://openalex.org/I56067802","display_name":"Universit\u00e9 de Rennes","ror":"https://ror.org/015m7wh34","country_code":"FR","type":"education","lineage":["https://openalex.org/I56067802"]}],"countries":["FR"],"is_corresponding":false,"raw_author_name":"Thierry Roisnel","raw_affiliation_strings":["Centre de Diffractom\u00e9trie X, Institut des Sciences Chimiques de Rennes, UMR 6226, CNRS-Universit\u00e9 de, Rennes, 1, Campus de Beaulieu, 35042 Rennes Cedex, France"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Centre de Diffractom\u00e9trie X, Institut des Sciences Chimiques de Rennes, UMR 6226, CNRS-Universit\u00e9 de, Rennes, 1, Campus de Beaulieu, 35042 Rennes Cedex, France","institution_ids":["https://openalex.org/I1294671590","https://openalex.org/I4210090783","https://openalex.org/I56067802"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5014522854","display_name":"Habib Nasri","orcid":"https://orcid.org/0000-0002-7565-8240","observed_orcids":["https://orcid.org/0000-0002-7565-8240"]},"institutions":[{"id":"https://openalex.org/I166928557","display_name":"University of Monastir","ror":"https://ror.org/00nhtcg76","country_code":"TN","type":"education","lineage":["https://openalex.org/I166928557"]}],"countries":["TN"],"is_corresponding":false,"raw_author_name":"Habib Nasri","raw_affiliation_strings":["Laboratoire de Physico-chimie des Mat\u00e9riaux, Facult\u00e9 des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Laboratoire de Physico-chimie des Mat\u00e9riaux, Facult\u00e9 des Sciences de Monastir, Avenue de l'environnement, 5019 Monastir, University of Monastir, Tunisia","institution_ids":["https://openalex.org/I166928557"]}]}],"institutions":[],"countries_distinct_count":3,"institutions_distinct_count":5,"corresponding_author_ids":["https://openalex.org/A5083866440"],"corresponding_institution_ids":["https://openalex.org/I166928557"],"apc_list":{"value":500,"currency":"USD","value_usd":500},"apc_paid":{"value":500,"currency":"USD","value_usd":500},"fwci":0.0,"has_fulltext":true,"cited_by_count":1,"citation_normalized_percentile":{"value":0.04034189,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":91,"max":95},"biblio":{"volume":"72","issue":"7","first_page":"937","last_page":"942"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.8032000064849854,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10903","display_name":"Porphyrin and Phthalocyanine Chemistry","score":0.8032000064849854,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10464","display_name":"Crystal structures of chemical compounds","score":0.19290000200271606,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12441","display_name":"Porphyrin Metabolism and Disorders","score":0.0008999999845400453,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/zinc-porphyrin","display_name":"zinc porphyrin","score":0.871999979019165},{"id":"https://openalex.org/keywords/piperazine-ligands","display_name":"piperazine ligands","score":0.7540000081062317},{"id":"https://openalex.org/keywords/solvates","display_name":"solvates","score":0.6110000014305115},{"id":"https://openalex.org/keywords/distorted-square-pyramidal-coordination","display_name":"distorted square pyramidal coordination","score":0.8759999871253967},{"id":"https://openalex.org/keywords/solvent-disorder","display_name":"solvent disorder","score":0.32600000500679016}],"concepts":[{"id":"https://openalex.org/C2776201271","wikidata":"https://www.wikidata.org/wiki/Q409292","display_name":"Piperazine","level":2,"score":0.8100979328155518},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7660103440284729},{"id":"https://openalex.org/C8010536","wikidata":"https://www.wikidata.org/wiki/Q160398","display_name":"Crystallography","level":1,"score":0.7536945343017578},{"id":"https://openalex.org/C116569031","wikidata":"https://www.wikidata.org/wiki/Q899107","display_name":"Ligand (biochemistry)","level":3,"score":0.670829176902771},{"id":"https://openalex.org/C115624301","wikidata":"https://www.wikidata.org/wiki/Q895901","display_name":"Crystal structure","level":2,"score":0.6555386781692505},{"id":"https://openalex.org/C535196362","wikidata":"https://www.wikidata.org/wiki/Q758","display_name":"Zinc","level":2,"score":0.6247345209121704},{"id":"https://openalex.org/C155860418","wikidata":"https://www.wikidata.org/wiki/Q863695","display_name":"Bond length","level":3,"score":0.5050237774848938},{"id":"https://openalex.org/C58312451","wikidata":"https://www.wikidata.org/wiki/Q4817200","display_name":"Atom (system on chip)","level":2,"score":0.5001542568206787},{"id":"https://openalex.org/C2781285689","wikidata":"https://www.wikidata.org/wiki/Q21921428","display_name":"Crystal (programming language)","level":2,"score":0.49365100264549255},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.4447771906852722},{"id":"https://openalex.org/C2780378348","wikidata":"https://www.wikidata.org/wiki/Q25351438","display_name":"Ring (chemistry)","level":2,"score":0.4309470057487488},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3708292841911316},{"id":"https://openalex.org/C170493617","wikidata":"https://www.wikidata.org/wiki/Q208467","display_name":"Receptor","level":2,"score":0.09778830409049988},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C199360897","wikidata":"https://www.wikidata.org/wiki/Q9143","display_name":"Programming language","level":1,"score":0.0},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.0},{"id":"https://openalex.org/C149635348","wikidata":"https://www.wikidata.org/wiki/Q193040","display_name":"Embedded system","level":1,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0}],"mesh":[],"locations_count":8,"locations":[{"id":"doi:10.1107/s2056989016009269","doi":"https://doi.org/10.1107/s2056989016009269","is_oa":true,"landing_page_url":"https://doi.org/10.1107/s2056989016009269","pdf_url":"http://journals.iucr.org/e/issues/2016/07/00/lh5815/lh5815.pdf","source":{"id":"https://openalex.org/S2739106167","display_name":"Acta Crystallographica Section E Crystallographic Communications","issn_l":"2056-9890","issn":["2056-9890"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-c","jufo-1","norway-1","oarl","poland-20","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320555","host_organization_name":"International Union of Crystallography","host_organization_lineage":["https://openalex.org/P4310320555"],"host_organization_lineage_names":["International Union of Crystallography"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallographica Section E Crystallographic Communications","raw_type":"journal-article"},{"id":"pmh:oai:europepmc.org:3953722","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/4992910","pdf_url":null,"source":{"id":"https://openalex.org/S4306400806","display_name":"Europe PMC (PubMed Central)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1303153112","host_organization_name":"European Bioinformatics Institute","host_organization_lineage":["https://openalex.org/I1303153112"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":null,"raw_type":"Text"},{"id":"pmh:oai:pubmedcentral.nih.gov:4992910","doi":null,"is_oa":true,"landing_page_url":"https://www.ncbi.nlm.nih.gov/pmc/articles/4992910","pdf_url":null,"source":{"id":"https://openalex.org/S2764455111","display_name":"PubMed Central","issn_l":null,"issn":null,"is_oa":true,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallogr E Crystallogr Commun","raw_type":"Text"},{"id":"pmid:27555935","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/27555935","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta crystallographica. Section E, Crystallographic communications","raw_type":"Journal Article"},{"id":"pmh:oai:HAL:hal-01357415v1","doi":null,"is_oa":false,"landing_page_url":"https://univ-rennes.hal.science/hal-01357415","pdf_url":null,"source":{"id":"https://openalex.org/S4306402512","display_name":"HAL","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I4405252976","host_organization_name":"Centre pour la Communication Scientifique Directe","host_organization_lineage":["https://openalex.org/I4405252976"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Acta crystallographica Section E : Crystallographic communications [2015-..], 2016, 72 (7), pp.937--+. ⟨10.1107/S2056989016009269⟩","raw_type":"info:eu-repo/semantics/article"},{"id":"pmh:oai:doaj.org/article:71642dd74b4d43bab277b5050b3b6daf","doi":null,"is_oa":true,"landing_page_url":"https://doaj.org/article/71642dd74b4d43bab277b5050b3b6daf","pdf_url":null,"source":{"id":"https://openalex.org/S4306401280","display_name":"DOAJ (DOAJ: Directory of Open Access Journals)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":"cc-by-sa","license_id":"https://openalex.org/licenses/cc-by-sa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Acta Crystallographica Section E: Crystallographic Communications, Vol 72, Iss 7, Pp 937-942 (2016)","raw_type":"article"},{"id":"doi:10.60692/a9mtg-jz563","doi":"https://doi.org/10.60692/a9mtg-jz563","is_oa":true,"landing_page_url":"https://doi.org/10.60692/a9mtg-jz563","pdf_url":null,"source":{"id":"https://openalex.org/S7407051682","display_name":"Greater South Information System","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"article-journal"},{"id":"doi:10.60692/gv7av-8pc97","doi":"https://doi.org/10.60692/gv7av-8pc97","is_oa":true,"landing_page_url":"https://doi.org/10.60692/gv7av-8pc97","pdf_url":null,"source":{"id":"https://openalex.org/S7407051682","display_name":"Greater South Information System","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":null,"host_organization_name":null,"host_organization_lineage":[],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":"article-journal"}],"best_oa_location":{"id":"doi:10.1107/s2056989016009269","doi":"https://doi.org/10.1107/s2056989016009269","is_oa":true,"landing_page_url":"https://doi.org/10.1107/s2056989016009269","pdf_url":"http://journals.iucr.org/e/issues/2016/07/00/lh5815/lh5815.pdf","source":{"id":"https://openalex.org/S2739106167","display_name":"Acta Crystallographica Section E Crystallographic Communications","issn_l":"2056-9890","issn":["2056-9890"],"is_oa":true,"is_in_doaj":true,"is_core":true,"listed_in":["cwts-core","doaj","dongbi-c","jufo-1","norway-1","oarl","poland-20","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320555","host_organization_name":"International Union of Crystallography","host_organization_lineage":["https://openalex.org/P4310320555"],"host_organization_lineage_names":["International Union of Crystallography"],"type":"journal"},"license":"cc-by","license_id":"https://openalex.org/licenses/cc-by","version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Acta Crystallographica Section E Crystallographic Communications","raw_type":"journal-article"},"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"pdf":true,"grobid_xml":true},"content_urls":{"pdf":"https://content.openalex.org/works/W2431096574.pdf","grobid_xml":"https://content.openalex.org/works/W2431096574.grobid-xml"},"referenced_works_count":21,"referenced_works":["https://openalex.org/W137362595","https://openalex.org/W1615343110","https://openalex.org/W1965718476","https://openalex.org/W1969360633","https://openalex.org/W1971590970","https://openalex.org/W1975217371","https://openalex.org/W1981926142","https://openalex.org/W1990170643","https://openalex.org/W1996878271","https://openalex.org/W2024175762","https://openalex.org/W2039902205","https://openalex.org/W2040807307","https://openalex.org/W2076075589","https://openalex.org/W2076888725","https://openalex.org/W2086511371","https://openalex.org/W2094791399","https://openalex.org/W2131350133","https://openalex.org/W2138676933","https://openalex.org/W2145538332","https://openalex.org/W2333065922","https://openalex.org/W3203162623"],"related_works":["https://openalex.org/W2237961725","https://openalex.org/W3003615110","https://openalex.org/W2605046777","https://openalex.org/W1983831924","https://openalex.org/W2077262711","https://openalex.org/W2083728751","https://openalex.org/W2895835950","https://openalex.org/W989743043","https://openalex.org/W2376026603","https://openalex.org/W2065601989"],"abstract_inverted_index":{"The":[0,58,77,179],"title":[1],"compound,":[2],"[Zn(C72H44N4O8)(C4H10N2)]":[3],"or":[4],"[Zn(TPBP)(pipz]":[5],"(where":[6],"TPBP":[7],"and":[8,12,41,67,106,176,183],"pipz":[9],"are":[10],"5,10,15,20-tetra-kis-[4-(benzo-yloxy)phen-yl]porphyrinato":[11],"piperazine":[13,50,97],"ligands":[14],"respectively),":[15],"features":[16],"a":[17,45,55],"distorted":[18],"square-pyramidal":[19],"coordin-ation":[20],"geometry":[21],"about":[22],"the":[23,33,38,49,68,87,92,96,111,113,133,151],"central":[24,28],"Zn(II)":[25],"atom.":[26],"This":[27,100],"atom":[29,47],"is":[30,63,73,80,116,140],"chelated":[31],"by":[32,44,82,118],"four":[34],"N":[35],"atoms":[36],"of":[37,48,91,121,129,138,145,172],"porphyrinate":[39,93,101],"anion":[40,94],"further":[42],"coordinated":[43],"nitro-gen":[46],"axial":[51,98],"ligand,":[52],"which":[53],"adopts":[54],"chair":[56],"confirmation.":[57],"average":[59],"Zn-N(pyrrole)":[60],"bond":[61,71],"length":[62,72],"2.078":[64],"(7)":[65],"\u00c5":[66,85,131],"Zn-":[69],"N(pipz)":[70],"2.1274":[74],"(19)":[75],"\u00c5.":[76,142],"zinc":[78],"cation":[79],"displaced":[81],"0.4365":[83],"(4)":[84],"from":[86],"N4C20":[88],"mean":[89],"plane":[90],"toward":[95],"ligand.":[99],"macrocycle":[102],"exhibits":[103],"major":[104],"saddle":[105],"moderate":[107],"ruffling":[108],"deformations.":[109],"In":[110],"crystal,":[112],"supra-molecular":[114],"structure":[115],"made":[117],"parallel":[119],"pairs":[120,137],"layers":[122,139],"along":[123],"(100),":[124],"with":[125,150],"an":[126],"inter-layer":[127],"distance":[128,134],"4.100":[130],"while":[132],"between":[135],"two":[136],"4.047":[141],"A":[143],"region":[144],"electron":[146],"density":[147],"was":[148],"treated":[149],"SQUEEZE":[152],"[Spek":[153],"(2015":[154],"\u25b8).":[155],"Acta":[156],"Cryst.":[157],"C71,":[158],"9-18]":[159],"procedure":[160],"in":[161],"PLATON":[162],"following":[163],"unsuccessful":[164],"attempts":[165],"to":[166],"model":[167],"it":[168],"as":[169],"being":[170],"part":[171],"disordered":[173],"n-hexane":[174],"solvent":[175,193],"water":[177],"mol-ecules.":[178,194],"given":[180],"chemical":[181],"formula":[182],"other":[184],"crystal":[185],"data":[186],"do":[187],"not":[188],"take":[189],"into":[190],"account":[191],"these":[192]},"counts_by_year":[{"year":2026,"cited_by_count":1}],"updated_date":"2026-10-30T12:39:25.321706","created_date":"2016-06-24T00:00:00"}