{"id":"https://openalex.org/W2404889840","doi":"https://doi.org/10.1134/s0022476616020189","title":"ION PAIRING IN H2O AND D2O SOLUTIONS OF LEAD NITRATE, AS DETERMINED WITH 207Pb NMR SPECTROSCOPY","display_name":"ION PAIRING IN H2O AND D2O SOLUTIONS OF LEAD NITRATE, AS DETERMINED WITH 207Pb NMR SPECTROSCOPY","publication_year":2016,"publication_date":"2016-01-01","ids":{"openalex":"https://openalex.org/W2404889840","doi":"https://doi.org/10.1134/s0022476616020189","mag":"2404889840"},"language":"en","primary_location":{"id":"doi:10.1134/s0022476616020189","doi":"https://doi.org/10.1134/s0022476616020189","is_oa":false,"landing_page_url":"https://doi.org/10.1134/s0022476616020189","pdf_url":null,"source":{"id":"https://openalex.org/S111479809","display_name":"Journal of Structural Chemistry","issn_l":"0022-4766","issn":["0022-4766","1573-8779"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320267","host_organization_name":"Pleiades Publishing","host_organization_lineage":["https://openalex.org/P4310320267","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Pleiades Publishing","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Structural Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5059764233","display_name":"Fahri Alkan","orcid":"https://orcid.org/0000-0002-4046-9044","observed_orcids":["https://orcid.org/0000-0002-4046-9044"]},"institutions":[{"id":"https://openalex.org/I86501945","display_name":"University of Delaware","ror":"https://ror.org/01sbq1a82","country_code":"US","type":"education","lineage":["https://openalex.org/I86501945"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"F. Alkan","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, 19716, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, 19716, USA","institution_ids":["https://openalex.org/I86501945"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5007479297","display_name":"Thomas D. Small","orcid":"https://orcid.org/0000-0001-9978-5490","observed_orcids":["https://orcid.org/0000-0001-9978-5490"]},"institutions":[{"id":"https://openalex.org/I86501945","display_name":"University of Delaware","ror":"https://ror.org/01sbq1a82","country_code":"US","type":"education","lineage":["https://openalex.org/I86501945"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"T. Small","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, 19716, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, 19716, USA","institution_ids":["https://openalex.org/I86501945"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5042345600","display_name":"Shi Bai","orcid":"https://orcid.org/0000-0003-2126-450X","observed_orcids":["https://orcid.org/0000-0003-2126-450X"]},"institutions":[{"id":"https://openalex.org/I86501945","display_name":"University of Delaware","ror":"https://ror.org/01sbq1a82","country_code":"US","type":"education","lineage":["https://openalex.org/I86501945"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"S. Bai","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, 19716, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, 19716, USA","institution_ids":["https://openalex.org/I86501945"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000282981","display_name":"A. Dominowski","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I86501945","display_name":"University of Delaware","ror":"https://ror.org/01sbq1a82","country_code":"US","type":"education","lineage":["https://openalex.org/I86501945"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"A. Dominowski","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, 19716, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, 19716, USA","institution_ids":["https://openalex.org/I86501945"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5014890796","display_name":"Cecil R. Dybowski","orcid":"https://orcid.org/0000-0002-0557-8915","observed_orcids":["https://orcid.org/0000-0002-0557-8915"]},"institutions":[{"id":"https://openalex.org/I86501945","display_name":"University of Delaware","ror":"https://ror.org/01sbq1a82","country_code":"US","type":"education","lineage":["https://openalex.org/I86501945"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"C. Dybowski","raw_affiliation_strings":["Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, 19716, USA"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware, 19716, USA","institution_ids":["https://openalex.org/I86501945"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5014890796"],"corresponding_institution_ids":["https://openalex.org/I86501945"],"apc_list":null,"apc_paid":null,"fwci":0.2999,"has_fulltext":false,"cited_by_count":11,"citation_normalized_percentile":{"value":0.51237164,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":96},"biblio":{"volume":"57","issue":"2","first_page":"369","last_page":"375"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11809","display_name":"Advanced NMR Techniques and Applications","score":0.28369998931884766,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11809","display_name":"Advanced NMR Techniques and Applications","score":0.28369998931884766,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.2549000084400177,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10962","display_name":"Thermodynamic properties of mixtures","score":0.05389999970793724,"subfield":{"id":"https://openalex.org/subfields/1507","display_name":"Fluid Flow and Transfer Processes"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/ion-pairing","display_name":"ion pairing","score":0.8140000104904175},{"id":"https://openalex.org/keywords/lead-nitrate","display_name":"lead nitrate","score":0.9589999914169312},{"id":"https://openalex.org/keywords/contact-ion-pairs","display_name":"contact ion pairs","score":0.7549999952316284},{"id":"https://openalex.org/keywords/enthalpy-of-dissociation","display_name":"dissociation enthalpy","score":0.7070000171661377},{"id":"https://openalex.org/keywords/heavy-water","display_name":"heavy water","score":0.6050000190734863},{"id":"https://openalex.org/keywords/dft-calculations","display_name":"DFT calculations","score":0.5910000205039978},{"id":"https://openalex.org/keywords/temperature-dependence","display_name":"temperature dependence","score":0.4740000069141388},{"id":"https://openalex.org/keywords/concentration-dependence","display_name":"concentration dependence","score":0.984000027179718}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.7704188823699951},{"id":"https://openalex.org/C111429119","wikidata":"https://www.wikidata.org/wiki/Q899127","display_name":"Chemical shift","level":2,"score":0.6670676469802856},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.6601366400718689},{"id":"https://openalex.org/C102931765","wikidata":"https://www.wikidata.org/wiki/Q189673","display_name":"Dissociation (chemistry)","level":2,"score":0.6585954427719116},{"id":"https://openalex.org/C3288061","wikidata":"https://www.wikidata.org/wiki/Q161064","display_name":"Enthalpy","level":2,"score":0.60763019323349},{"id":"https://openalex.org/C66974803","wikidata":"https://www.wikidata.org/wiki/Q10359898","display_name":"Nuclear magnetic resonance spectroscopy","level":2,"score":0.5115566849708557},{"id":"https://openalex.org/C32891209","wikidata":"https://www.wikidata.org/wiki/Q483666","display_name":"Spectroscopy","level":2,"score":0.41750919818878174},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.38905590772628784},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.3791401982307434},{"id":"https://openalex.org/C147597530","wikidata":"https://www.wikidata.org/wiki/Q369472","display_name":"Computational chemistry","level":1,"score":0.33119073510169983},{"id":"https://openalex.org/C179104552","wikidata":"https://www.wikidata.org/wiki/Q11165","display_name":"Inorganic chemistry","level":1,"score":0.33105364441871643},{"id":"https://openalex.org/C97355855","wikidata":"https://www.wikidata.org/wiki/Q11473","display_name":"Thermodynamics","level":1,"score":0.1355321705341339},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.12332677841186523},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.11394014954566956},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C62520636","wikidata":"https://www.wikidata.org/wiki/Q944","display_name":"Quantum mechanics","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1134/s0022476616020189","doi":"https://doi.org/10.1134/s0022476616020189","is_oa":false,"landing_page_url":"https://doi.org/10.1134/s0022476616020189","pdf_url":null,"source":{"id":"https://openalex.org/S111479809","display_name":"Journal of Structural Chemistry","issn_l":"0022-4766","issn":["0022-4766","1573-8779"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-d","jufo-1","norway-1","poland-40","russia-white-list-3"],"host_organization":"https://openalex.org/P4310320267","host_organization_name":"Pleiades Publishing","host_organization_lineage":["https://openalex.org/P4310320267","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Pleiades Publishing","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Journal of Structural Chemistry","raw_type":"journal-article"},{"id":"doi:10.15372/jsc20160218","doi":"https://doi.org/10.15372/jsc20160218","is_oa":false,"landing_page_url":"https://doi.org/10.15372/jsc20160218","pdf_url":null,"source":{"id":"https://openalex.org/S4210204189","display_name":"\u0416\u0443\u0440\u043d\u0430\u043b \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u043d\u043e\u0439 \u0445\u0438\u043c\u0438\u0438","issn_l":"0136-7463","issn":["0136-7463","2542-0976"],"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":["russia-white-list-1"],"host_organization":"https://openalex.org/P4310319900","host_organization_name":"Springer Science+Business Media","host_organization_lineage":["https://openalex.org/P4310319900","https://openalex.org/P4310319965"],"host_organization_lineage_names":["Springer Science+Business Media","Springer Nature"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"\u0416\u0443\u0440\u043d\u0430\u043b \u0441\u0442\u0440\u0443\u043a\u0442\u0443\u0440\u043d\u043e\u0439 \u0445\u0438\u043c\u0438\u0438","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":28,"referenced_works":["https://openalex.org/W320268486","https://openalex.org/W1974711152","https://openalex.org/W1991061109","https://openalex.org/W1991683341","https://openalex.org/W1994716177","https://openalex.org/W1996559917","https://openalex.org/W2007130787","https://openalex.org/W2010729449","https://openalex.org/W2018283522","https://openalex.org/W2019066397","https://openalex.org/W2020073730","https://openalex.org/W2024683579","https://openalex.org/W2030687437","https://openalex.org/W2032696321","https://openalex.org/W2035347540","https://openalex.org/W2038533471","https://openalex.org/W2043285876","https://openalex.org/W2055563809","https://openalex.org/W2060254067","https://openalex.org/W2067978347","https://openalex.org/W2086941245","https://openalex.org/W2086957099","https://openalex.org/W2092329440","https://openalex.org/W2095374362","https://openalex.org/W2098368527","https://openalex.org/W2107577558","https://openalex.org/W2108446403","https://openalex.org/W2184590258"],"related_works":["https://openalex.org/W2067978347","https://openalex.org/W1973092828","https://openalex.org/W2419615020","https://openalex.org/W2107577558","https://openalex.org/W1981594693","https://openalex.org/W1891914160","https://openalex.org/W1964381269","https://openalex.org/W1999186142","https://openalex.org/W2319250157","https://openalex.org/W2043285876"],"abstract_inverted_index":{"The":[0,22],"temperature":[1],"and":[2,35,53,63],"concentration":[3],"dependences":[4],"of":[5,11,28,44,81,97,99],"207":[6,76],"Pb":[7,77],"NMR":[8,78],"chemical":[9,46,79],"shifts":[10,80],"Pb(NO":[12,37,82],"3":[13,38,83],")":[14,39,84],"2":[15,18,85,88],"in":[16,26,86],"D":[17],"O":[19,89],"are":[20,24,56,90],"reported.":[21],"results":[23],"analyzed":[25],"terms":[27],"exchange":[29],"between":[30,49],"a":[31,69],"solvated":[32,66],"lead":[33],"ion":[34,52],"the":[36,45,50,60,65,93,95,100],"+":[40],"contact-ion":[41,54,101],"pair.":[42],"Predictions":[43],"shift":[47],"difference":[48],"aquated":[51],"pair":[55,102],"carried":[57],"out":[58],"for":[59,64],"gas-phase":[61],"entities":[62],"species":[67],"with":[68],"DFT":[70],"calculation.":[71],"Previously":[72],"reported":[73],"data":[74],"on":[75],"H":[87],"reevaluated.":[91],"From":[92],"analysis,":[94],"enthalpy":[96],"dissociation":[98],"is":[103],"found":[104],"to":[105],"be\u201342.3\u00b11.0":[106],"kJ/mol.":[107]},"counts_by_year":[{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":3},{"year":2019,"cited_by_count":1},{"year":2017,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}