{"id":"https://openalex.org/W2403949481","doi":"https://doi.org/10.1021/acs.organomet.6b00255","title":"Longer-Wavelength-Absorbing, Extended Chalcogenorhodamine Dyes","display_name":"Longer-Wavelength-Absorbing, Extended Chalcogenorhodamine Dyes","publication_year":2016,"publication_date":"2016-05-19","ids":{"openalex":"https://openalex.org/W2403949481","doi":"https://doi.org/10.1021/acs.organomet.6b00255","mag":"2403949481"},"language":"en","primary_location":{"id":"doi:10.1021/acs.organomet.6b00255","doi":"https://doi.org/10.1021/acs.organomet.6b00255","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.6b00255","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5076576298","display_name":"Mark W. Kryman","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I63190737","display_name":"University at Buffalo, State University of New York","ror":"https://ror.org/01y64my43","country_code":"US","type":"education","lineage":["https://openalex.org/I63190737"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Mark W. Kryman","raw_affiliation_strings":["Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, United States","institution_ids":["https://openalex.org/I63190737"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5003158752","display_name":"Theresa M. McCormick","orcid":"https://orcid.org/0000-0003-1745-2911","observed_orcids":["https://orcid.org/0000-0003-1745-2911"]},"institutions":[{"id":"https://openalex.org/I126345244","display_name":"Portland State University","ror":"https://ror.org/00yn2fy02","country_code":"US","type":"education","lineage":["https://openalex.org/I126345244"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Theresa M. McCormick","raw_affiliation_strings":["Department\rof Chemistry, Portland State University, Portland, Oregon 97207, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department\rof Chemistry, Portland State University, Portland, Oregon 97207, United States","institution_ids":["https://openalex.org/I126345244"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5039149956","display_name":"Michael R. Detty","orcid":"https://orcid.org/0000-0002-8815-1481","observed_orcids":["https://orcid.org/0000-0002-8815-1481"]},"institutions":[{"id":"https://openalex.org/I63190737","display_name":"University at Buffalo, State University of New York","ror":"https://ror.org/01y64my43","country_code":"US","type":"education","lineage":["https://openalex.org/I63190737"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Michael R. Detty","raw_affiliation_strings":["Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University at Buffalo, The State University of New York, Buffalo, New York 14260-3000, United States","institution_ids":["https://openalex.org/I63190737"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5003158752","https://openalex.org/A5039149956"],"corresponding_institution_ids":["https://openalex.org/I126345244","https://openalex.org/I63190737"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":1.485,"has_fulltext":false,"cited_by_count":25,"citation_normalized_percentile":{"value":0.80032885,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"35","issue":"11","first_page":"1944","last_page":"1955"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11240","display_name":"Luminescence and Fluorescent Materials","score":0.6230000257492065,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11240","display_name":"Luminescence and Fluorescent Materials","score":0.6230000257492065,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.19020000100135803,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10532","display_name":"Molecular Sensors and Ion Detection","score":0.08009999990463257,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/regioselective-lithiation","display_name":"regioselective lithiation","score":0.9509999752044678},{"id":"https://openalex.org/keywords/naphthamides","display_name":"naphthamides","score":0.515999972820282},{"id":"https://openalex.org/keywords/singlet-oxygen-generation","display_name":"singlet oxygen generation","score":0.8519999980926514},{"id":"https://openalex.org/keywords/fluorescence-quantum-yield","display_name":"fluorescence quantum yield","score":0.9290000200271606},{"id":"https://openalex.org/keywords/homo-lumo-transition","display_name":"HOMO-LUMO transition","score":0.8009999990463257},{"id":"https://openalex.org/keywords/dft-calculations","display_name":"DFT calculations","score":0.6970000267028809}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9491233229637146},{"id":"https://openalex.org/C6260449","wikidata":"https://www.wikidata.org/wiki/Q41364","display_name":"Wavelength","level":2,"score":0.6056776642799377},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.47814738750457764},{"id":"https://openalex.org/C49040817","wikidata":"https://www.wikidata.org/wiki/Q193091","display_name":"Optoelectronics","level":1,"score":0.3086359202861786},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/acs.organomet.6b00255","doi":"https://doi.org/10.1021/acs.organomet.6b00255","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acs.organomet.6b00255","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},{"id":"pmh:oai:pdxscholar.library.pdx.edu:chem_fac-1162","doi":null,"is_oa":false,"landing_page_url":"https://pdxscholar.library.pdx.edu/chem_fac/161","pdf_url":null,"source":{"id":"https://openalex.org/S4377196300","display_name":"PDXScholar  (Portland State University)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I126345244","host_organization_name":"Portland State University","host_organization_lineage":["https://openalex.org/I126345244"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Chemistry Faculty Publications and Presentations","raw_type":"text"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G6017941608","display_name":null,"funder_award_id":"CHE-1151379","funder_id":"https://openalex.org/F4320337393","funder_display_name":"Division of Chemistry"}],"funders":[{"id":"https://openalex.org/F4320309493","display_name":"Portland State University","ror":"https://ror.org/00yn2fy02"},{"id":"https://openalex.org/F4320337393","display_name":"Division of Chemistry","ror":"https://ror.org/01ar8dr59"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":49,"referenced_works":["https://openalex.org/W638557855","https://openalex.org/W1840377627","https://openalex.org/W1965930560","https://openalex.org/W1966132341","https://openalex.org/W1967036092","https://openalex.org/W1970874708","https://openalex.org/W1971957467","https://openalex.org/W1974371326","https://openalex.org/W1978912064","https://openalex.org/W1984614201","https://openalex.org/W1986084814","https://openalex.org/W1986724293","https://openalex.org/W1992511709","https://openalex.org/W1992769097","https://openalex.org/W1997588127","https://openalex.org/W1998875076","https://openalex.org/W2003535038","https://openalex.org/W2009803588","https://openalex.org/W2012748063","https://openalex.org/W2012852483","https://openalex.org/W2014234337","https://openalex.org/W2015602487","https://openalex.org/W2023271753","https://openalex.org/W2024956005","https://openalex.org/W2033990154","https://openalex.org/W2035247444","https://openalex.org/W2044747683","https://openalex.org/W2046412723","https://openalex.org/W2067011309","https://openalex.org/W2068228867","https://openalex.org/W2074703978","https://openalex.org/W2080628813","https://openalex.org/W2086871654","https://openalex.org/W2086957099","https://openalex.org/W2093447759","https://openalex.org/W2094128036","https://openalex.org/W2094642658","https://openalex.org/W2100030276","https://openalex.org/W2107729201","https://openalex.org/W2129788878","https://openalex.org/W2146561272","https://openalex.org/W2150331863","https://openalex.org/W2153085502","https://openalex.org/W2166019161","https://openalex.org/W2313239886","https://openalex.org/W2322418105","https://openalex.org/W2323735535","https://openalex.org/W2327452598","https://openalex.org/W2949384676"],"related_works":["https://openalex.org/W2740472112","https://openalex.org/W1986084814","https://openalex.org/W2892172665","https://openalex.org/W2081863872","https://openalex.org/W2058259546","https://openalex.org/W2586958956","https://openalex.org/W2528288611","https://openalex.org/W4405566454","https://openalex.org/W2025070412","https://openalex.org/W7096192718"],"abstract_inverted_index":{"Extended":[0],"rhodamines":[1],"were":[2,135],"prepared":[3],"by":[4,50,90],"inserting":[5],"an":[6],"additional":[7],"fused":[8],"benzene":[9],"ring":[10],"into":[11],"the":[12,32,72,104,138,144,147,155,161,175],"rhodamine":[13],"xanthylium":[14],"core.":[15],"The":[16,56],"synthesis":[17,57],"of":[18,31,34,52,58,71,74,92,128,168],"\u201cbent\u201d":[19],"dyes":[20,60,116,145,159],"4-E":[21,97,109,139],"(E":[22,62],"=":[23,63],"S,":[24,64],"Se,":[25,65],"Te)":[26,66],"began":[27,67],"with":[28,42,68,82,123],"regioselective":[29,69],"lithiation":[30,70],"1-position":[33],"N,":[35,75],"N":[36,76],"-diisopropyl":[37],"6-dimethylamino-2-naphthamide":[38,78],"(":[39,79],"11b":[40],")":[41,81],"n":[43],"-BuLi/TMEDA":[44],"(\u226525:1":[45],"1-":[46],"vs":[47,87],"3-lithiation)":[48],"followed":[49,89],"addition":[51,91],"a":[53,93,166],"dichalcogenide":[54,94],"electrophile.":[55,95],"\u201clinear\u201d":[59],"5-E":[61,99,141],"3-position":[73],"-diethyl":[77],"11a":[80],"lithium":[83],"tetramethylpiperidide":[84],"(\u226550:1":[85],"3-":[86],"1-lithiation)":[88],"Dyes":[96,108],"and":[98,118,130,140,179],"have":[100],"absorption":[101],"maxima":[102],"in":[103],"633\u2013700":[105],"nm":[106],"range.":[107],"generate":[110],"singlet":[111],"oxygen":[112],"upon":[113],"irradiation":[114],"while":[115],"4-S":[117],"5-S":[119],"are":[120],"highly":[121],"fluorescent,":[122],"quantum":[124],"yields":[125],"for":[126],"fluorescence":[127],"0.47":[129],"0.18,":[131],"respectively.":[132],"DFT":[133],"calculations":[134],"performed":[136],"on":[137],"chromophores.":[142],"For":[143,158],"4-E,":[146],"lowest":[148,162],"energy":[149,163],"excitation":[150,164],"is":[151,165],"due":[152],"solely":[153],"to":[154,177,181],"HOMO\u2013LUMO":[156],"transition.":[157],"5-E,":[160],"combination":[167],"two":[169],"excitations,":[170],"both":[171],"having":[172],"contributions":[173],"from":[174],"HOMO":[176],"LUMO":[178],"HOMO-1":[180],"LUMO.":[182]},"counts_by_year":[{"year":2026,"cited_by_count":3},{"year":2024,"cited_by_count":2},{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":2},{"year":2021,"cited_by_count":1},{"year":2020,"cited_by_count":5},{"year":2019,"cited_by_count":5},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":3}],"updated_date":"2026-10-14T16:39:01.820549","created_date":"2016-06-24T00:00:00"}