{"id":"https://openalex.org/W239120302","doi":null,"title":"Synthesis of Biomimetic Systems for Proton and Electron Transfer Reactions in the Ground and Excited State","display_name":"Synthesis of Biomimetic Systems for Proton and Electron Transfer Reactions in the Ground and Excited State","publication_year":2015,"publication_date":"2015-01-01","ids":{"openalex":"https://openalex.org/W239120302","mag":"239120302"},"language":"en","primary_location":{"id":"pmh:oai:DiVA.org:uu-251471","doi":null,"is_oa":true,"landing_page_url":"http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-251471","pdf_url":null,"source":{"id":"https://openalex.org/S4306401559","display_name":"KTH Publication Database DiVA (KTH Royal Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I86987016","host_organization_name":"KTH Royal Institute of Technology","host_organization_lineage":["https://openalex.org/I86987016"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"info:eu-repo/semantics/doctoralThesis"},"volume":null,"type":"dissertation","is_traditional":true,"indexed_in":[],"open_access":{"is_oa":true,"oa_status":"green","oa_url":"http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-251471","any_repository_has_fulltext":true},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5054432947","display_name":"Giovanny A. Parada","orcid":"https://orcid.org/0000-0002-1669-8832","observed_orcids":["https://orcid.org/0000-0002-1669-8832"]},"institutions":[],"countries":[],"is_corresponding":true,"raw_author_name":"Giovanny A. Parada","raw_affiliation_strings":[],"raw_orcid":"https://orcid.org/0000-0002-1669-8832","affiliations":[]}],"institutions":[],"countries_distinct_count":0,"institutions_distinct_count":0,"corresponding_author_ids":["https://openalex.org/A5054432947"],"corresponding_institution_ids":[],"apc_list":null,"apc_paid":null,"fwci":null,"has_fulltext":false,"cited_by_count":0,"citation_normalized_percentile":null,"cited_by_percentile_year":null,"biblio":{"volume":null,"issue":null,"first_page":null,"last_page":null},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.9750999808311462,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.9750999808311462,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10303","display_name":"Photosynthetic Processes and Mechanisms","score":0.013399999588727951,"subfield":{"id":"https://openalex.org/subfields/1312","display_name":"Molecular Biology"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.004399999976158142,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/artificial-photosynthesis","display_name":"artificial photosynthesis","score":0.9950000047683716},{"id":"https://openalex.org/keywords/light-harvesting","display_name":"light harvesting","score":0.593999981880188},{"id":"https://openalex.org/keywords/ruthenium-polypyridyl-complexes","display_name":"ruthenium polypyridyl complexes","score":0.8849999904632568},{"id":"https://openalex.org/keywords/photoinduced-electron-transfer","display_name":"photoinduced electron transfer","score":0.7480000257492065},{"id":"https://openalex.org/keywords/vectorial-electron-transfer","display_name":"vectorial electron transfer","score":0.7590000033378601},{"id":"https://openalex.org/keywords/mlct-excited-states","display_name":"MLCT excited states","score":0.7850000262260437},{"id":"https://openalex.org/keywords/proton-coupled-electron-transfer","display_name":"proton-coupled electron transfer","score":0.9559999704360962},{"id":"https://openalex.org/keywords/intramolecular-hydrogen-bonding","display_name":"intramolecular hydrogen bonding","score":0.8529999852180481},{"id":"https://openalex.org/keywords/quinoline","display_name":"quinoline","score":0.843999981880188},{"id":"https://openalex.org/keywords/photosystem-ii","display_name":"photosystem II","score":0.8420000076293945},{"id":"https://openalex.org/keywords/charge-accumulation","display_name":"charge accumulation","score":0.8479999899864197},{"id":"https://openalex.org/keywords/excited-state-dynamics","display_name":"excited-state dynamics","score":0.8930000066757202},{"id":"https://openalex.org/keywords/esipt","display_name":"excited-state intramolecular proton transfer","score":0.9200000166893005}],"concepts":[{"id":"https://openalex.org/C69523127","wikidata":"https://www.wikidata.org/wiki/Q4480008","display_name":"Ground state","level":2,"score":0.7223193049430847},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.7180122137069702},{"id":"https://openalex.org/C54516573","wikidata":"https://www.wikidata.org/wiki/Q2294","display_name":"Proton","level":2,"score":0.5679494738578796},{"id":"https://openalex.org/C123669783","wikidata":"https://www.wikidata.org/wiki/Q902898","display_name":"Electron transfer","level":2,"score":0.4526046812534332},{"id":"https://openalex.org/C147120987","wikidata":"https://www.wikidata.org/wiki/Q2225","display_name":"Electron","level":2,"score":0.4304129481315613},{"id":"https://openalex.org/C48103436","wikidata":"https://www.wikidata.org/wiki/Q599031","display_name":"State (computer science)","level":2,"score":0.4131770133972168},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.40585342049598694},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.3699001669883728},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.3280220031738281},{"id":"https://openalex.org/C75473681","wikidata":"https://www.wikidata.org/wiki/Q188651","display_name":"Photochemistry","level":1,"score":0.2791064381599426},{"id":"https://openalex.org/C41008148","wikidata":"https://www.wikidata.org/wiki/Q21198","display_name":"Computer science","level":0,"score":0.19989228248596191},{"id":"https://openalex.org/C185544564","wikidata":"https://www.wikidata.org/wiki/Q81197","display_name":"Nuclear physics","level":1,"score":0.15898212790489197},{"id":"https://openalex.org/C11413529","wikidata":"https://www.wikidata.org/wiki/Q8366","display_name":"Algorithm","level":1,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"pmh:oai:DiVA.org:uu-251471","doi":null,"is_oa":true,"landing_page_url":"http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-251471","pdf_url":null,"source":{"id":"https://openalex.org/S4306401559","display_name":"KTH Publication Database DiVA (KTH Royal Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I86987016","host_organization_name":"KTH Royal Institute of Technology","host_organization_lineage":["https://openalex.org/I86987016"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"info:eu-repo/semantics/doctoralThesis"},{"id":"mag:239120302","doi":null,"is_oa":false,"landing_page_url":"http://uu.diva-portal.org/smash/get/diva2:806239/FULLTEXT01.pdf","pdf_url":null,"source":null,"license":null,"license_id":null,"version":null,"is_accepted":false,"is_published":false,"raw_source_name":null,"raw_type":null}],"best_oa_location":{"id":"pmh:oai:DiVA.org:uu-251471","doi":null,"is_oa":true,"landing_page_url":"http://urn.kb.se/resolve?urn=urn:nbn:se:uu:diva-251471","pdf_url":null,"source":{"id":"https://openalex.org/S4306401559","display_name":"KTH Publication Database DiVA (KTH Royal Institute of Technology)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I86987016","host_organization_name":"KTH Royal Institute of Technology","host_organization_lineage":["https://openalex.org/I86987016"],"host_organization_lineage_names":[],"type":"repository"},"license":"other-oa","license_id":"https://openalex.org/licenses/other-oa","version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"","raw_type":"info:eu-repo/semantics/doctoralThesis"},"sustainable_development_goals":[{"display_name":"Affordable and clean energy","id":"https://metadata.un.org/sdg/7","score":0.5690000057220459}],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":115,"referenced_works":["https://openalex.org/W123792427","https://openalex.org/W388378098","https://openalex.org/W1550691904","https://openalex.org/W1968276670","https://openalex.org/W1968963012","https://openalex.org/W1969924934","https://openalex.org/W1970327813","https://openalex.org/W1970393749","https://openalex.org/W1970453628","https://openalex.org/W1973721002","https://openalex.org/W1973924961","https://openalex.org/W1974077347","https://openalex.org/W1975570171","https://openalex.org/W1978461472","https://openalex.org/W1979776740","https://openalex.org/W1980638508","https://openalex.org/W1981356540","https://openalex.org/W1982785950","https://openalex.org/W1985086699","https://openalex.org/W1985748667","https://openalex.org/W1986670180","https://openalex.org/W1989917955","https://openalex.org/W1991530112","https://openalex.org/W1991974264","https://openalex.org/W1995399971","https://openalex.org/W1998504425","https://openalex.org/W1998686499","https://openalex.org/W1999087697","https://openalex.org/W1999108339","https://openalex.org/W1999602233","https://openalex.org/W2000231152","https://openalex.org/W2005351547","https://openalex.org/W2007062401","https://openalex.org/W2007849368","https://openalex.org/W2009442202","https://openalex.org/W2009542925","https://openalex.org/W2010363805","https://openalex.org/W2011859576","https://openalex.org/W2012661196","https://openalex.org/W2013596909","https://openalex.org/W2016738144","https://openalex.org/W2020765728","https://openalex.org/W2021792392","https://openalex.org/W2024744943","https://openalex.org/W2024893196","https://openalex.org/W2029011927","https://openalex.org/W2029615583","https://openalex.org/W2030109515","https://openalex.org/W2031745865","https://openalex.org/W2031904472","https://openalex.org/W2031973327","https://openalex.org/W2032150367","https://openalex.org/W2032471301","https://openalex.org/W2032948295","https://openalex.org/W2034445094","https://openalex.org/W2035238441","https://openalex.org/W2040031253","https://openalex.org/W2040575909","https://openalex.org/W2041500618","https://openalex.org/W2041930594","https://openalex.org/W2044100673","https://openalex.org/W2044918377","https://openalex.org/W2046679394","https://openalex.org/W2049960212","https://openalex.org/W2050393976","https://openalex.org/W2050638713","https://openalex.org/W2053662222","https://openalex.org/W2054033384","https://openalex.org/W2057833130","https://openalex.org/W2058156039","https://openalex.org/W2058925597","https://openalex.org/W2059929371","https://openalex.org/W2060790113","https://openalex.org/W2062778939","https://openalex.org/W2063104454","https://openalex.org/W2076859568","https://openalex.org/W2077016814","https://openalex.org/W2078171630","https://openalex.org/W2078270432","https://openalex.org/W2080821278","https://openalex.org/W2082015186","https://openalex.org/W2082275777","https://openalex.org/W2084017605","https://openalex.org/W2096239090","https://openalex.org/W2096415122","https://openalex.org/W2103830068","https://openalex.org/W2113018874","https://openalex.org/W2118204678","https://openalex.org/W2123243495","https://openalex.org/W2125191072","https://openalex.org/W2126669798","https://openalex.org/W2135433724","https://openalex.org/W2138879095","https://openalex.org/W2141538618","https://openalex.org/W2142244352","https://openalex.org/W2143219568","https://openalex.org/W2148635252","https://openalex.org/W2152513820","https://openalex.org/W2157729113","https://openalex.org/W2161324059","https://openalex.org/W2163275303","https://openalex.org/W2163920704","https://openalex.org/W2171093931","https://openalex.org/W2258820226","https://openalex.org/W2317762889","https://openalex.org/W2320291901","https://openalex.org/W2322417798","https://openalex.org/W2326350780","https://openalex.org/W2327366771","https://openalex.org/W2332245777","https://openalex.org/W2951885080","https://openalex.org/W2952137105","https://openalex.org/W2952926071","https://openalex.org/W3170999623","https://openalex.org/W4233828289"],"related_works":["https://openalex.org/W570252924","https://openalex.org/W2047636269","https://openalex.org/W594299523","https://openalex.org/W1998504425","https://openalex.org/W2000201304","https://openalex.org/W79873822","https://openalex.org/W4234109773","https://openalex.org/W2063925046","https://openalex.org/W302604339","https://openalex.org/W7018876791"],"abstract_inverted_index":{"A":[0],"detailed":[1],"understanding":[2],"of":[3,11,23,48,68,72,92,99,108,142,151,157,175,197,247,277,284,292,320],"natural":[4,160,198],"photosynthesis":[5,50,163],"provides":[6],"inspiration":[7],"for":[8,79,105,112,289,331],"the":[9,46,66,96,106,143,172,232,239,248,254,257,267,269,275,285,290,317,321],"development":[10,47,291],"sustainable":[12],"and":[13,128,161,177,189,200,260,308,340],"renewable":[14],"energy":[15,26],"sources,":[16],"i.e.":[17,238],"a":[18,63,90,147,228],"technology":[19],"that":[20,132,164,253],"is":[21,33,87,130,165,251,262],"capable":[22],"converting":[24],"solar":[25],"directly":[27],"into":[28],"chemical":[29],"fuels.":[30],"This":[31],"concept":[32],"called":[34],"artificial":[35,49,162,293],"photosynthesis.":[36,244],"The":[37,55,85,119,154,179,210,224,245,282],"work":[38],"described":[39],"in":[40,51,167,192,235,243,295,297],"this":[41,168,208],"thesis":[42,169],"contains":[43],"contributions":[44],"to":[45,59,77,159,171,205,222,231,313],"two":[52,184,315],"separate":[53],"areas.":[54],"first":[56],"one":[57],"relates":[58,170],"light":[60],"harvesting":[61],"with":[62,218,299],"focus":[64],"on":[65,89,214,266,274,335],"question":[67],"how":[69],"electronic":[70],"properties":[71,98],"photosensitizers":[73],"can":[74,137],"be":[75,138],"tuned":[76],"allow":[78],"efficient":[80,113],"photo-induced":[81,115],"electron":[82,116,279,307],"transfer":[83,117,271,280,339],"processes.":[84],"study":[86],"based":[88,213,334],"series":[91],"bis(tridentate)ruthenium(II)":[93],"polypyridyl":[94],"complexes,":[95],"geometric":[97],"which":[100],"make":[101],"them":[102],"highly":[103],"appealing":[104],"construction":[107],"linear":[109],"donor-photosensitizer-acceptor":[110],"arrangements":[111],"vectorial":[114],"reactions.":[118,281],"chromophores":[120],"possess":[121],"remarkably":[122,148],"long":[123],"lived":[124],"3MLCT":[125],"excited":[126],"states":[127],"it":[129],"shown":[131],"their":[133],"excited-state":[134,318,336],"oxidation":[135],"strength":[136],"altered":[139],"by":[140],"variations":[141],"ligand":[144],"scaffold":[145],"over":[146],"large":[149],"range":[150],"900":[152],"mV.":[153],"second":[155],"area":[156],"relevance":[158],"discussed":[166],"coupled":[173],"movement":[174],"protons":[176],"electrons.":[178],"delicate":[180],"interplay":[181],"between":[182,256],"these":[183,314],"charged":[185],"particles":[186],"regulates":[187],"thermodynamic":[188],"kinetic":[190],"aspects":[191],"many":[193],"key":[194],"elementary":[195],"steps":[196],"photosynthesis,":[199,294],"further":[201],"studies":[202,211,265,286],"are":[203,212],"needed":[204],"fully":[206],"understand":[207],"concept.":[209],"redox":[215,300],"active":[216],"phenols":[217,324],"intramolecular":[219,322,337],"hydrogen":[220],"bonds":[221],"quinolines.":[223],"compounds":[225],"thus":[226],"bear":[227],"strong":[229],"resemblance":[230],"tyrosine/histidine":[233],"couple":[234],"photosystem":[236],"II,":[237],"water-plastoquinone":[240],"oxidoreductase":[241],"enzyme":[242],"design":[246,329],"biomimetic":[249],"models":[250],"such":[252],"distance":[255,272],"proton":[258,270,309,338],"donor":[259],"acceptor":[261],"varied,":[263],"enabling":[264],"effect":[268],"has":[273],"rate":[276],"proton-coupled":[278],"results":[283],"have":[287],"implications":[288],"particular":[296],"connection":[298],"leveling,":[301],"charge":[302],"accumulation,":[303],"as":[304,306],"well":[305],"transfer.":[310],"In":[311],"addition":[312],"contributions,":[316],"dynamics":[319],"hydrogen-bonded":[323],"was":[325],"investigated,":[326],"thereby":[327],"revealing":[328],"principles":[330],"technological":[332],"applications":[333],"photoinduced":[341],"tautomerization.":[342]},"counts_by_year":[],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}
