{"id":"https://openalex.org/W2379994136","doi":"https://doi.org/10.1039/c6ob00734a","title":"Rhodium( i )-catalysed intermolecular alkyne insertion into (2-pyridylmethylene)cyclobutenes","display_name":"Rhodium( i )-catalysed intermolecular alkyne insertion into (2-pyridylmethylene)cyclobutenes","publication_year":2016,"publication_date":"2016-01-01","ids":{"openalex":"https://openalex.org/W2379994136","doi":"https://doi.org/10.1039/c6ob00734a","mag":"2379994136","pmid":"https://pubmed.ncbi.nlm.nih.gov/27193826"},"language":"en","primary_location":{"id":"doi:10.1039/c6ob00734a","doi":"https://doi.org/10.1039/c6ob00734a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c6ob00734a","pdf_url":null,"source":{"id":"https://openalex.org/S179810352","display_name":"Organic & Biomolecular Chemistry","issn_l":"1477-0520","issn":["1477-0520","1477-0539"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic &amp; Biomolecular Chemistry","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5041041689","display_name":"Takanori Matsuda","orcid":"https://orcid.org/0000-0002-9927-3599","observed_orcids":["https://orcid.org/0000-0002-9927-3599"]},"institutions":[{"id":"https://openalex.org/I161296585","display_name":"Tokyo University of Science","ror":"https://ror.org/05sj3n476","country_code":"JP","type":"education","lineage":["https://openalex.org/I161296585"]}],"countries":["JP"],"is_corresponding":true,"raw_author_name":"Takanori Matsuda","raw_affiliation_strings":["Department of Applied Chemistry","Japan","Tokyo 162-8601","Tokyo University of Science","Department of Applied Chemistry, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan"],"raw_orcid":"https://orcid.org/0000-0002-9927-3599","affiliations":[{"raw_affiliation_string":"Department of Applied Chemistry","institution_ids":[]},{"raw_affiliation_string":"Japan","institution_ids":[]},{"raw_affiliation_string":"Tokyo 162-8601","institution_ids":[]},{"raw_affiliation_string":"Tokyo University of Science","institution_ids":["https://openalex.org/I161296585"]},{"raw_affiliation_string":"Department of Applied Chemistry, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan","institution_ids":["https://openalex.org/I161296585"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5054079223","display_name":"Takeshi Matsumoto","orcid":"https://orcid.org/0000-0002-1517-0761","observed_orcids":["https://orcid.org/0000-0002-1517-0761"]},"institutions":[{"id":"https://openalex.org/I161296585","display_name":"Tokyo University of Science","ror":"https://ror.org/05sj3n476","country_code":"JP","type":"education","lineage":["https://openalex.org/I161296585"]}],"countries":["JP"],"is_corresponding":false,"raw_author_name":"Takeshi Matsumoto","raw_affiliation_strings":["Department of Applied Chemistry","Japan","Tokyo 162-8601","Tokyo University of Science","Department of Applied Chemistry, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Applied Chemistry","institution_ids":[]},{"raw_affiliation_string":"Japan","institution_ids":[]},{"raw_affiliation_string":"Tokyo 162-8601","institution_ids":[]},{"raw_affiliation_string":"Tokyo University of Science","institution_ids":["https://openalex.org/I161296585"]},{"raw_affiliation_string":"Department of Applied Chemistry, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan","institution_ids":["https://openalex.org/I161296585"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5041041689"],"corresponding_institution_ids":["https://openalex.org/I161296585"],"apc_list":null,"apc_paid":null,"fwci":1.7672,"has_fulltext":false,"cited_by_count":20,"citation_normalized_percentile":{"value":0.8202477,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":98},"biblio":{"volume":"14","issue":"22","first_page":"5023","last_page":"5027"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.8353999853134155,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10871","display_name":"Catalytic Alkyne Reactions","score":0.8353999853134155,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11611","display_name":"Cyclopropane Reaction Mechanisms","score":0.07890000194311142,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.027699999511241913,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/rhodium-i-catalysis","display_name":"rhodium(I) catalysis","score":0.9559999704360962},{"id":"https://openalex.org/keywords/cyclobutene","display_name":"cyclobutene","score":0.8809999823570251},{"id":"https://openalex.org/keywords/benzene-derivatives","display_name":"benzene derivatives","score":0.7369999885559082},{"id":"https://openalex.org/keywords/alkyne-coupling","display_name":"alkyne coupling","score":0.6549999713897705},{"id":"https://openalex.org/keywords/terminal-alkynes","display_name":"terminal alkynes","score":0.9020000100135803},{"id":"https://openalex.org/keywords/carbon-carbon-bond-formation","display_name":"C\u2013C bond formation","score":0.6499999761581421}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.95323646068573},{"id":"https://openalex.org/C521398313","wikidata":"https://www.wikidata.org/wiki/Q1087","display_name":"Rhodium","level":3,"score":0.8755205869674683},{"id":"https://openalex.org/C2779012754","wikidata":"https://www.wikidata.org/wiki/Q159226","display_name":"Alkyne","level":3,"score":0.8459923267364502},{"id":"https://openalex.org/C166950319","wikidata":"https://www.wikidata.org/wiki/Q245031","display_name":"Intermolecular force","level":3,"score":0.6904492378234863},{"id":"https://openalex.org/C137955730","wikidata":"https://www.wikidata.org/wiki/Q6844361","display_name":"Migratory insertion","level":3,"score":0.5150658488273621},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.4629775881767273},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.3804927468299866},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.3581811785697937},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3255079984664917},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.23293939232826233},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.21984940767288208}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1039/c6ob00734a","doi":"https://doi.org/10.1039/c6ob00734a","is_oa":false,"landing_page_url":"https://doi.org/10.1039/c6ob00734a","pdf_url":null,"source":{"id":"https://openalex.org/S179810352","display_name":"Organic & Biomolecular Chemistry","issn_l":"1477-0520","issn":["1477-0520","1477-0539"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","ki-jl-1","medline","norway-1","poland-100","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320556","host_organization_name":"Royal Society of Chemistry","host_organization_lineage":["https://openalex.org/P4310320556"],"host_organization_lineage_names":["Royal Society of Chemistry"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic &amp; Biomolecular Chemistry","raw_type":"journal-article"},{"id":"pmid:27193826","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/27193826","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organic & biomolecular chemistry","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G1373038747","display_name":null,"funder_award_id":"130325","funder_id":"https://openalex.org/F4320310657","funder_display_name":"Sumitomo Foundation"},{"id":"https://openalex.org/G1505334069","display_name":"Development of transformations of bicyclic compounds to monocyclic compounds through sequential bond cleavage","funder_award_id":"16K05783","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"},{"id":"https://openalex.org/G661982136","display_name":"Development of catalytic transformations that include multiple bond cleavages and formations","funder_award_id":"25410054","funder_id":"https://openalex.org/F4320334764","funder_display_name":"Japan Society for the Promotion of Science"}],"funders":[{"id":"https://openalex.org/F4320310657","display_name":"Sumitomo Foundation","ror":"https://ror.org/01nmpj461"},{"id":"https://openalex.org/F4320334764","display_name":"Japan Society for the Promotion of Science","ror":"https://ror.org/00hhkn466"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":60,"referenced_works":["https://openalex.org/W62426150","https://openalex.org/W613493951","https://openalex.org/W1971656728","https://openalex.org/W1971884956","https://openalex.org/W1979137328","https://openalex.org/W1988701476","https://openalex.org/W1995629871","https://openalex.org/W2002755075","https://openalex.org/W2004294181","https://openalex.org/W2007342550","https://openalex.org/W2010767475","https://openalex.org/W2037532624","https://openalex.org/W2037575112","https://openalex.org/W2039608253","https://openalex.org/W2040644059","https://openalex.org/W2048693503","https://openalex.org/W2049460578","https://openalex.org/W2051851250","https://openalex.org/W2054176108","https://openalex.org/W2058983966","https://openalex.org/W2068690726","https://openalex.org/W2073422424","https://openalex.org/W2073646664","https://openalex.org/W2086736534","https://openalex.org/W2090682299","https://openalex.org/W2094997568","https://openalex.org/W2097482736","https://openalex.org/W2098433872","https://openalex.org/W2104929472","https://openalex.org/W2105449367","https://openalex.org/W2109451713","https://openalex.org/W2117552559","https://openalex.org/W2118378996","https://openalex.org/W2120366110","https://openalex.org/W2130976192","https://openalex.org/W2131280431","https://openalex.org/W2137192161","https://openalex.org/W2139715583","https://openalex.org/W2141524036","https://openalex.org/W2151024923","https://openalex.org/W2153326597","https://openalex.org/W2158548796","https://openalex.org/W2168340781","https://openalex.org/W2170955562","https://openalex.org/W2178831676","https://openalex.org/W2260216711","https://openalex.org/W2273352752","https://openalex.org/W2316821379","https://openalex.org/W2320097457","https://openalex.org/W2321247683","https://openalex.org/W2322162786","https://openalex.org/W2949494321","https://openalex.org/W2949698965","https://openalex.org/W2949700121","https://openalex.org/W2950942420","https://openalex.org/W2950991425","https://openalex.org/W2951752244","https://openalex.org/W4232497120","https://openalex.org/W4249012482","https://openalex.org/W4298243380"],"related_works":["https://openalex.org/W2952509727","https://openalex.org/W2579773601","https://openalex.org/W2952471568","https://openalex.org/W2323381394","https://openalex.org/W4231889632","https://openalex.org/W2093262907","https://openalex.org/W2229982997","https://openalex.org/W2071579212","https://openalex.org/W2044192713","https://openalex.org/W2094939276"],"abstract_inverted_index":{"Cyclobutenes":[0],"with":[1,42],"2-pyridylmethylene":[2,31],"groups":[3,32],"at":[4,21],"the":[5,15,29],"3":[6],"position":[7],"underwent":[8],"an":[9],"intermolecular":[10],"alkyne":[11],"insertion":[12],"reaction":[13],"in":[14],"presence":[16],"of":[17],"a":[18],"rhodium(i)":[19],"catalyst":[20],"170":[22],"\u00b0C":[23],"to":[24],"afford":[25],"substituted":[26],"benzenes.":[27],"Among":[28],"different":[30],"examined,":[33],"3-methyl-2-pyridyl":[34],"derivatives":[35],"showed":[36],"superior":[37],"activity":[38],"and":[39,49],"readily":[40],"coupled":[41],"various":[43],"alkynes,":[44],"including":[45],"sterically":[46],"demanding,":[47],"heteroaromatic":[48],"terminal":[50],"alkynes.":[51]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":2},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":2},{"year":2018,"cited_by_count":3},{"year":2017,"cited_by_count":6},{"year":2016,"cited_by_count":2}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}
