{"id":"https://openalex.org/W2340432140","doi":"https://doi.org/10.1021/acsmacrolett.5b00876","title":"Influence of Dipole Orientation on Solution Properties of Polyzwitterions","display_name":"Influence of Dipole Orientation on Solution Properties of Polyzwitterions","publication_year":2016,"publication_date":"2016-01-04","ids":{"openalex":"https://openalex.org/W2340432140","doi":"https://doi.org/10.1021/acsmacrolett.5b00876","mag":"2340432140","pmid":"https://pubmed.ncbi.nlm.nih.gov/35668586"},"language":"en","primary_location":{"id":"doi:10.1021/acsmacrolett.5b00876","doi":"https://doi.org/10.1021/acsmacrolett.5b00876","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsmacrolett.5b00876","pdf_url":null,"source":{"id":"https://openalex.org/S75495113","display_name":"ACS Macro Letters","issn_l":"2161-1653","issn":["2161-1653"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Macro Letters","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5084201091","display_name":"Svetlana Morozova","orcid":"https://orcid.org/0000-0002-1002-7413","observed_orcids":["https://orcid.org/0000-0002-1002-7413"]},"institutions":[{"id":"https://openalex.org/I24603500","display_name":"University of Massachusetts Amherst","ror":"https://ror.org/0072zz521","country_code":"US","type":"education","lineage":["https://openalex.org/I24603500"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"S. Morozova","raw_affiliation_strings":["Polymer Science and Engineering, University of Massachusetts, Amherst, Massachusetts 01003, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Polymer Science and Engineering, University of Massachusetts, Amherst, Massachusetts 01003, United States","institution_ids":["https://openalex.org/I24603500"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5037304379","display_name":"Gaojie Hu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I24603500","display_name":"University of Massachusetts Amherst","ror":"https://ror.org/0072zz521","country_code":"US","type":"education","lineage":["https://openalex.org/I24603500"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"G. Hu","raw_affiliation_strings":["Polymer Science and Engineering, University of Massachusetts, Amherst, Massachusetts 01003, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Polymer Science and Engineering, University of Massachusetts, Amherst, Massachusetts 01003, United States","institution_ids":["https://openalex.org/I24603500"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5030195131","display_name":"Todd S. Emrick","orcid":"https://orcid.org/0000-0003-0460-1797","observed_orcids":["https://orcid.org/0000-0003-0460-1797"]},"institutions":[{"id":"https://openalex.org/I24603500","display_name":"University of Massachusetts Amherst","ror":"https://ror.org/0072zz521","country_code":"US","type":"education","lineage":["https://openalex.org/I24603500"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"T. Emrick","raw_affiliation_strings":["Polymer Science and Engineering, University of Massachusetts, Amherst, Massachusetts 01003, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Polymer Science and Engineering, University of Massachusetts, Amherst, Massachusetts 01003, United States","institution_ids":["https://openalex.org/I24603500"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5047715090","display_name":"Murugappan Muthukumar","orcid":"https://orcid.org/0000-0001-7872-4883","observed_orcids":["https://orcid.org/0000-0001-7872-4883"]},"institutions":[{"id":"https://openalex.org/I24603500","display_name":"University of Massachusetts Amherst","ror":"https://ror.org/0072zz521","country_code":"US","type":"education","lineage":["https://openalex.org/I24603500"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"M. Muthukumar","raw_affiliation_strings":["Polymer Science and Engineering, University of Massachusetts, Amherst, Massachusetts 01003, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Polymer Science and Engineering, University of Massachusetts, Amherst, Massachusetts 01003, United States","institution_ids":["https://openalex.org/I24603500"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5047715090"],"corresponding_institution_ids":["https://openalex.org/I24603500"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":5.4781,"has_fulltext":false,"cited_by_count":63,"citation_normalized_percentile":{"value":0.96600598,"is_in_top_1_percent":false,"is_in_top_10_percent":true},"cited_by_percentile_year":{"min":96,"max":99},"biblio":{"volume":"5","issue":"1","first_page":"118","last_page":"122"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T12274","display_name":"Electrostatics and Colloid Interactions","score":0.6919000148773193,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T12274","display_name":"Electrostatics and Colloid Interactions","score":0.6919000148773193,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10405","display_name":"Advanced Polymer Synthesis and Characterization","score":0.2833999991416931,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11471","display_name":"Block Copolymer Self-Assembly","score":0.015799999237060547,"subfield":{"id":"https://openalex.org/subfields/2505","display_name":"Materials Chemistry"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/polyzwitterions","display_name":"polyzwitterions","score":0.9729999899864197},{"id":"https://openalex.org/keywords/dipole-dipole-interaction","display_name":"dipole-dipole interaction","score":0.8500000238418579},{"id":"https://openalex.org/keywords/polymer-self-assembly","display_name":"polymer self-assembly","score":0.7239999771118164},{"id":"https://openalex.org/keywords/aggregation-behavior","display_name":"aggregation behavior","score":0.6019999980926514},{"id":"https://openalex.org/keywords/poly-2-methacryloyloxyethyl-phosphorylcholine","display_name":"poly(2-methacryloyloxyethyl phosphorylcholine)","score":0.9049999713897705},{"id":"https://openalex.org/keywords/diblock-copolymers","display_name":"diblock copolymers","score":0.9860000014305115},{"id":"https://openalex.org/keywords/ionic-strength-dependence","display_name":"ionic strength dependence","score":0.7540000081062317},{"id":"https://openalex.org/keywords/electrostatic-interactions","display_name":"electrostatic interactions","score":0.7110000252723694},{"id":"https://openalex.org/keywords/polymer-solutions","display_name":"polymer solutions","score":0.40400001406669617}],"concepts":[{"id":"https://openalex.org/C173523689","wikidata":"https://www.wikidata.org/wiki/Q215589","display_name":"Dipole","level":2,"score":0.7516534924507141},{"id":"https://openalex.org/C2776833585","wikidata":"https://www.wikidata.org/wiki/Q7187582","display_name":"Phosphorylcholine","level":2,"score":0.6569774746894836},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.6330113410949707},{"id":"https://openalex.org/C521977710","wikidata":"https://www.wikidata.org/wiki/Q81163","display_name":"Polymer","level":2,"score":0.6264433264732361},{"id":"https://openalex.org/C15920480","wikidata":"https://www.wikidata.org/wiki/Q421281","display_name":"Copolymer","level":3,"score":0.5984377861022949},{"id":"https://openalex.org/C187428577","wikidata":"https://www.wikidata.org/wiki/Q898396","display_name":"Ionic strength","level":3,"score":0.5736238360404968},{"id":"https://openalex.org/C159467904","wikidata":"https://www.wikidata.org/wiki/Q2001702","display_name":"Chemical physics","level":1,"score":0.5081608295440674},{"id":"https://openalex.org/C2776371256","wikidata":"https://www.wikidata.org/wiki/Q12370","display_name":"Salt (chemistry)","level":2,"score":0.456748366355896},{"id":"https://openalex.org/C2182769","wikidata":"https://www.wikidata.org/wiki/Q62500","display_name":"Ionic bonding","level":3,"score":0.45425087213516235},{"id":"https://openalex.org/C120456961","wikidata":"https://www.wikidata.org/wiki/Q210028","display_name":"Light scattering","level":3,"score":0.4274858832359314},{"id":"https://openalex.org/C191486275","wikidata":"https://www.wikidata.org/wiki/Q210028","display_name":"Scattering","level":2,"score":0.38994234800338745},{"id":"https://openalex.org/C42360764","wikidata":"https://www.wikidata.org/wiki/Q83588","display_name":"Chemical engineering","level":1,"score":0.36451154947280884},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.3583521842956543},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.231560617685318},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.19015073776245117},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.15755674242973328},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.14473411440849304},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.1329963505268097},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.11517482995986938},{"id":"https://openalex.org/C159985019","wikidata":"https://www.wikidata.org/wiki/Q181790","display_name":"Composite material","level":1,"score":0.0958544909954071},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0922604501247406},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0}],"mesh":[],"locations_count":2,"locations":[{"id":"doi:10.1021/acsmacrolett.5b00876","doi":"https://doi.org/10.1021/acsmacrolett.5b00876","is_oa":false,"landing_page_url":"https://doi.org/10.1021/acsmacrolett.5b00876","pdf_url":null,"source":{"id":"https://openalex.org/S75495113","display_name":"ACS Macro Letters","issn_l":"2161-1653","issn":["2161-1653"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["cwts-core","dongbi-b","jufo-2","medline","norway-1","poland-140","russia-white-list-1","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS Macro Letters","raw_type":"journal-article"},{"id":"pmid:35668586","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/35668586","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"ACS macro letters","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G4497213747","display_name":null,"funder_award_id":"FA9550-14-1-0164","funder_id":"https://openalex.org/F4320338279","funder_display_name":"Air Force Office of Scientific Research"},{"id":"https://openalex.org/G5463563179","display_name":null,"funder_award_id":"0820506","funder_id":"https://openalex.org/F4320337367","funder_display_name":"Division of Materials Research"},{"id":"https://openalex.org/G974325792","display_name":null,"funder_award_id":"1504265","funder_id":"https://openalex.org/F4320337367","funder_display_name":"Division of Materials Research"}],"funders":[{"id":"https://openalex.org/F4320306076","display_name":"National Science Foundation","ror":"https://ror.org/021nxhr62"},{"id":"https://openalex.org/F4320332749","display_name":"University of Massachusetts Amherst","ror":"https://ror.org/0072zz521"},{"id":"https://openalex.org/F4320337367","display_name":"Division of Materials Research","ror":"https://ror.org/01pc7k308"},{"id":"https://openalex.org/F4320338279","display_name":"Air Force Office of Scientific Research","ror":"https://ror.org/011e9bt93"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":39,"referenced_works":["https://openalex.org/W1474147165","https://openalex.org/W1535870925","https://openalex.org/W1966304945","https://openalex.org/W1970049909","https://openalex.org/W1972539574","https://openalex.org/W1976282694","https://openalex.org/W1985595538","https://openalex.org/W1985794519","https://openalex.org/W1988466810","https://openalex.org/W1990493019","https://openalex.org/W2005133176","https://openalex.org/W2005845821","https://openalex.org/W2012698158","https://openalex.org/W2015026657","https://openalex.org/W2018007768","https://openalex.org/W2022565868","https://openalex.org/W2025095543","https://openalex.org/W2027994242","https://openalex.org/W2035522666","https://openalex.org/W2042018405","https://openalex.org/W2060221873","https://openalex.org/W2064788332","https://openalex.org/W2076961195","https://openalex.org/W2077640238","https://openalex.org/W2089112628","https://openalex.org/W2092991884","https://openalex.org/W2094116425","https://openalex.org/W2106334513","https://openalex.org/W2155932727","https://openalex.org/W2163833492","https://openalex.org/W2312662255","https://openalex.org/W2321129318","https://openalex.org/W2335158450","https://openalex.org/W2972445658","https://openalex.org/W4205700093","https://openalex.org/W4211203577","https://openalex.org/W4243772029","https://openalex.org/W4252472885","https://openalex.org/W4388247015"],"related_works":["https://openalex.org/W2570820243","https://openalex.org/W4408535152","https://openalex.org/W2036970648","https://openalex.org/W1966304945","https://openalex.org/W3103561772","https://openalex.org/W4283363905","https://openalex.org/W1932969839","https://openalex.org/W2346062661","https://openalex.org/W2617130277","https://openalex.org/W4206530560"],"abstract_inverted_index":{"We":[0,44],"have":[1],"studied":[2],"the":[3,10,56,76,81,85,111,133],"influence":[4],"of":[5,13,21,40,70,78,84,104,135,137],"segmental":[6],"dipole":[7],"orientation":[8],"on":[9],"solution":[11,140],"properties":[12],"polyzwitterions":[14,138],"using":[15],"dynamic":[16],"and":[17,31,141,148],"static":[18],"light":[19],"scattering":[20],"poly(2-methacryloyloxyethyl":[22],"phosphorylcholine)":[23],"(PMPC),":[24],"n":[25],"-butyl-substituted":[26],"choline":[27],"phosphate":[28],"polymers":[29],"(PMBP),":[30],"their":[32],"diblock":[33,112],"(PMPC-":[34],"b":[35,115],"-PMBP)":[36],"copolymers":[37],"in":[38,58,94,110,124,139],"solutions":[39],"different":[41,52],"salt":[42],"concentration.":[43],"find":[45],"that":[46],"these":[47,105],"three":[48],"structures":[49,93],"exhibit":[50],"dramatically":[51],"aggregation":[53],"behaviors.":[54],"For":[55],"conditions":[57],"our":[59],"study,":[60],"PMPC":[61],"is":[62,107],"a":[63,143],"swollen":[64],"excluded-volume":[65],"chain":[66],"without":[67],"significant":[68],"presence":[69],"dipolar":[71],"correlations":[72],"as":[73],"evident":[74],"from":[75],"lack":[77],"sensitivity":[79],"to":[80,126,132],"ionic":[82],"strength":[83],"solution.":[86],"In":[87],"contrast,":[88],"PMBP":[89],"self-assembles":[90,118],"into":[91,119],"finite-sized":[92],"solution,":[95],"which":[96,117],"are":[97],"stabilized":[98],"by":[99],"electrostatic":[100],"dipole\u2013dipole":[101],"interactions.":[102],"Evidence":[103],"interactions":[106],"also":[108],"present":[109],"polymer,":[113],"PMPB-":[114],"-PMPC,":[116],"two":[120],"distinct,":[121],"stable":[122],"aggregates":[123],"addition":[125],"unaggregated":[127],"chains.":[128],"These":[129],"results":[130],"contribute":[131],"breadth":[134],"understanding":[136],"provide":[142],"platform":[144],"for":[145],"future":[146],"simulation":[147],"experimental":[149],"explorations.":[150]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":6},{"year":2024,"cited_by_count":5},{"year":2023,"cited_by_count":6},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":7},{"year":2020,"cited_by_count":9},{"year":2019,"cited_by_count":4},{"year":2018,"cited_by_count":7},{"year":2017,"cited_by_count":8},{"year":2016,"cited_by_count":5}],"updated_date":"2026-10-02T10:15:12.560889","created_date":"2016-06-24T00:00:00"}