{"id":"https://openalex.org/W2332817277","doi":"https://doi.org/10.1021/om4006802","title":"On the Rapid Oxidation of Allene-Containing Phosphines","display_name":"On the Rapid Oxidation of Allene-Containing Phosphines","publication_year":2013,"publication_date":"2013-09-17","ids":{"openalex":"https://openalex.org/W2332817277","doi":"https://doi.org/10.1021/om4006802","mag":"2332817277"},"language":"en","primary_location":{"id":"doi:10.1021/om4006802","doi":"https://doi.org/10.1021/om4006802","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om4006802","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5086244750","display_name":"Feng Cai","orcid":"https://orcid.org/0000-0001-5192-9520","observed_orcids":["https://orcid.org/0000-0001-5192-9520"]},"institutions":[{"id":"https://openalex.org/I867280407","display_name":"The University of Texas Southwestern Medical Center","ror":"https://ror.org/05byvp690","country_code":"US","type":"healthcare","lineage":["https://openalex.org/I867280407"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Feng Cai","raw_affiliation_strings":["Department of Biochemistry, University of Texas Southwestern Medical Center, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biochemistry, University of Texas Southwestern Medical Center, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038, United States","institution_ids":["https://openalex.org/I867280407"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5059161638","display_name":"Neela D. Thangada","orcid":"https://orcid.org/0000-0001-8973-7508","observed_orcids":["https://orcid.org/0000-0001-8973-7508"]},"institutions":[{"id":"https://openalex.org/I867280407","display_name":"The University of Texas Southwestern Medical Center","ror":"https://ror.org/05byvp690","country_code":"US","type":"healthcare","lineage":["https://openalex.org/I867280407"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Neela D. Thangada","raw_affiliation_strings":["Department of Biochemistry, University of Texas Southwestern Medical Center, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biochemistry, University of Texas Southwestern Medical Center, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038, United States","institution_ids":["https://openalex.org/I867280407"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113513762","display_name":"Ende Pan","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I867280407","display_name":"The University of Texas Southwestern Medical Center","ror":"https://ror.org/05byvp690","country_code":"US","type":"healthcare","lineage":["https://openalex.org/I867280407"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Ende Pan","raw_affiliation_strings":["Department of Biochemistry, University of Texas Southwestern Medical Center, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biochemistry, University of Texas Southwestern Medical Center, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038, United States","institution_ids":["https://openalex.org/I867280407"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5088196532","display_name":"Joseph M. Ready","orcid":"https://orcid.org/0000-0003-1305-9581","observed_orcids":["https://orcid.org/0000-0003-1305-9581"]},"institutions":[{"id":"https://openalex.org/I867280407","display_name":"The University of Texas Southwestern Medical Center","ror":"https://ror.org/05byvp690","country_code":"US","type":"healthcare","lineage":["https://openalex.org/I867280407"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Joseph M. Ready","raw_affiliation_strings":["Department of Biochemistry, University of Texas Southwestern Medical Center, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Biochemistry, University of Texas Southwestern Medical Center, 5323 Harry Hines Boulevard, Dallas, Texas 75390-9038, United States","institution_ids":["https://openalex.org/I867280407"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5088196532"],"corresponding_institution_ids":["https://openalex.org/I867280407"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":0.0,"has_fulltext":false,"cited_by_count":2,"citation_normalized_percentile":{"value":0.17048636,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":94},"biblio":{"volume":"32","issue":"19","first_page":"5619","last_page":"5622"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.5067999958992004,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11748","display_name":"Organophosphorus compounds synthesis","score":0.5067999958992004,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T13239","display_name":"Phosphorus compounds and reactions","score":0.25780001282691956,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.09220000356435776,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/rapid-oxidation","display_name":"rapid oxidation","score":0.5860000252723694},{"id":"https://openalex.org/keywords/zwitterion","display_name":"zwitterion","score":0.7369999885559082},{"id":"https://openalex.org/keywords/molecular-oxygen-oxidation","display_name":"molecular oxygen oxidation","score":0.8019999861717224},{"id":"https://openalex.org/keywords/ligand-stability","display_name":"ligand stability","score":0.6710000038146973},{"id":"https://openalex.org/keywords/asymmetric-catalysis","display_name":"asymmetric catalysis","score":0.8140000104904175}],"concepts":[{"id":"https://openalex.org/C2778652500","wikidata":"https://www.wikidata.org/wiki/Q411369","display_name":"Allene","level":3,"score":0.9776217341423035},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9718011617660522},{"id":"https://openalex.org/C2780707935","wikidata":"https://www.wikidata.org/wiki/Q907718","display_name":"Phosphonium","level":2,"score":0.9066286087036133},{"id":"https://openalex.org/C2778743342","wikidata":"https://www.wikidata.org/wiki/Q245115","display_name":"Zwitterion","level":3,"score":0.7239395976066589},{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.5264250040054321},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.45645803213119507},{"id":"https://openalex.org/C2992086430","wikidata":"https://www.wikidata.org/wiki/Q428653","display_name":"Molecular oxygen","level":3,"score":0.45564138889312744},{"id":"https://openalex.org/C106773901","wikidata":"https://www.wikidata.org/wiki/Q19588","display_name":"Transition metal","level":3,"score":0.4351505637168884},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3249000310897827},{"id":"https://openalex.org/C21951064","wikidata":"https://www.wikidata.org/wiki/Q899212","display_name":"Combinatorial chemistry","level":1,"score":0.3244592547416687},{"id":"https://openalex.org/C32909587","wikidata":"https://www.wikidata.org/wiki/Q11369","display_name":"Molecule","level":2,"score":0.19218343496322632}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/om4006802","doi":"https://doi.org/10.1021/om4006802","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om4006802","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320306196","display_name":"Welch Foundation","ror":"https://ror.org/00np6vq88"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":15,"referenced_works":["https://openalex.org/W1977706373","https://openalex.org/W1987635290","https://openalex.org/W2015577073","https://openalex.org/W2015790021","https://openalex.org/W2017280600","https://openalex.org/W2023182333","https://openalex.org/W2035554577","https://openalex.org/W2052114811","https://openalex.org/W2061089512","https://openalex.org/W2068871883","https://openalex.org/W2092126337","https://openalex.org/W2334918491","https://openalex.org/W2950671789","https://openalex.org/W2952311977","https://openalex.org/W3146143345"],"related_works":["https://openalex.org/W2466821932","https://openalex.org/W1709502500","https://openalex.org/W341026186","https://openalex.org/W4412077080","https://openalex.org/W7023994715","https://openalex.org/W2790694394","https://openalex.org/W4309235838","https://openalex.org/W2950625444","https://openalex.org/W2790608115","https://openalex.org/W4247545421"],"abstract_inverted_index":{"Allene-containing":[0],"phosphines":[1,18,29,58],"have":[2],"recently":[3],"been":[4],"shown":[5],"to":[6,23,40],"serve":[7],"as":[8],"effective":[9],"ligands":[10],"in":[11],"transition":[12],"metal-catalyzed":[13],"enantioselective":[14],"reactions.":[15],"Surprisingly,":[16],"(2-allenylphenyl)diphenyl":[17],"rapidly":[19],"oxidize":[20],"when":[21],"exposed":[22],"air,":[24],"whereas":[25],"many":[26],"other":[27],"triaryl":[28],"are":[30],"stable":[31],"under":[32],"ambient":[33],"conditions.":[34],"Here":[35],"we":[36],"describe":[37],"experiments":[38],"designed":[39],"understand":[41],"the":[42,55,66],"origin":[43],"of":[44],"this":[45],"behavior.":[46],"Stereochemical":[47],"probes":[48],"and":[49,64],"an":[50],"isolated":[51],"phosphonium":[52],"complex":[53],"support":[54],"hypothesis":[56],"that":[57,65],"can":[59],"cyclize":[60],"onto":[61],"pendant":[62],"allenes":[63],"resultant":[67],"zwitterion":[68],"undergoes":[69],"rapid":[70],"oxidation":[71],"with":[72],"molecular":[73],"oxygen.":[74]},"counts_by_year":[{"year":2021,"cited_by_count":1},{"year":2017,"cited_by_count":1}],"updated_date":"2026-10-02T10:15:12.560889","created_date":"2016-06-24T00:00:00"}
