{"id":"https://openalex.org/W2330514101","doi":"https://doi.org/10.1021/om4007246","title":"Synthesis and Reactivity of the CO2 Adducts of Amine/Bis(2,4,6-tris(trifluoromethyl)phenyl)borane Pairs","display_name":"Synthesis and Reactivity of the CO2 Adducts of Amine/Bis(2,4,6-tris(trifluoromethyl)phenyl)borane Pairs","publication_year":2013,"publication_date":"2013-09-12","ids":{"openalex":"https://openalex.org/W2330514101","doi":"https://doi.org/10.1021/om4007246","mag":"2330514101"},"language":"en","primary_location":{"id":"doi:10.1021/om4007246","doi":"https://doi.org/10.1021/om4007246","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om4007246","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"parent_works":[],"lineage":["https://openalex.org/W2330514101"],"child_works_count":0,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5016686594","display_name":"Zhenpin Lu","orcid":"https://orcid.org/0000-0003-0000-6026","observed_orcids":["https://orcid.org/0000-0003-0000-6026"]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhenpin Lu","raw_affiliation_strings":["Shanghai\rKey Laboratory of Molecular Catalysis and Innovative Material, Department\rof Chemistry, Fudan University, Shanghai 200433, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shanghai\rKey Laboratory of Molecular Catalysis and Innovative Material, Department\rof Chemistry, Fudan University, Shanghai 200433, People\u2019s Republic of China","institution_ids":["https://openalex.org/I24943067"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5100708201","display_name":"Yuwen Wang","orcid":"https://orcid.org/0000-0001-8781-3394","observed_orcids":["https://orcid.org/0000-0001-8781-3394"]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yuwen Wang","raw_affiliation_strings":["Shanghai\rKey Laboratory of Molecular Catalysis and Innovative Material, Department\rof Chemistry, Fudan University, Shanghai 200433, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shanghai\rKey Laboratory of Molecular Catalysis and Innovative Material, Department\rof Chemistry, Fudan University, Shanghai 200433, People\u2019s Republic of China","institution_ids":["https://openalex.org/I24943067"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Jia Liu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jia Liu","raw_affiliation_strings":["Shanghai\rKey Laboratory of Molecular Catalysis and Innovative Material, Department\rof Chemistry, Fudan University, Shanghai 200433, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shanghai\rKey Laboratory of Molecular Catalysis and Innovative Material, Department\rof Chemistry, Fudan University, Shanghai 200433, People\u2019s Republic of China","institution_ids":["https://openalex.org/I24943067"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101112331","display_name":"Yue\u2010Jian Lin","orcid":"https://orcid.org/0009-0006-6840-9197","observed_orcids":["https://orcid.org/0009-0006-6840-9197"]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Yue-jian Lin","raw_affiliation_strings":["Shanghai\rKey Laboratory of Molecular Catalysis and Innovative Material, Department\rof Chemistry, Fudan University, Shanghai 200433, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shanghai\rKey Laboratory of Molecular Catalysis and Innovative Material, Department\rof Chemistry, Fudan University, Shanghai 200433, People\u2019s Republic of China","institution_ids":["https://openalex.org/I24943067"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5101992381","display_name":"Zhen Hua Li","orcid":"https://orcid.org/0000-0002-5636-9865","observed_orcids":["https://orcid.org/0000-0002-5636-9865","https://orcid.org/0009-0000-3276-744X"]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhen Hua Li","raw_affiliation_strings":["Shanghai\rKey Laboratory of Molecular Catalysis and Innovative Material, Department\rof Chemistry, Fudan University, Shanghai 200433, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shanghai\rKey Laboratory of Molecular Catalysis and Innovative Material, Department\rof Chemistry, Fudan University, Shanghai 200433, People\u2019s Republic of China","institution_ids":["https://openalex.org/I24943067"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5100773079","display_name":"Huadong Wang","orcid":"https://orcid.org/0000-0001-9129-0004","observed_orcids":["https://orcid.org/0000-0001-9129-0004"]},"institutions":[{"id":"https://openalex.org/I24943067","display_name":"Fudan University","ror":"https://ror.org/013q1eq08","country_code":"CN","type":"education","lineage":["https://openalex.org/I24943067"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Huadong Wang","raw_affiliation_strings":["Shanghai\rKey Laboratory of Molecular Catalysis and Innovative Material, Department\rof Chemistry, Fudan University, Shanghai 200433, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Shanghai\rKey Laboratory of Molecular Catalysis and Innovative Material, Department\rof Chemistry, Fudan University, Shanghai 200433, People\u2019s Republic of China","institution_ids":["https://openalex.org/I24943067"]}]}],"institutions":[],"countries_distinct_count":1,"institutions_distinct_count":1,"corresponding_author_ids":["https://openalex.org/A5100773079"],"corresponding_institution_ids":["https://openalex.org/I24943067"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.473,"has_fulltext":false,"cited_by_count":36,"citation_normalized_percentile":{"value":0.88318483,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"32","issue":"22","first_page":"6753","last_page":"6758"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.9413999915122986,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11441","display_name":"Organoboron and organosilicon chemistry","score":0.9413999915122986,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11593","display_name":"Carbon dioxide utilization in catalysis","score":0.03720000013709068,"subfield":{"id":"https://openalex.org/subfields/1508","display_name":"Process Chemistry and Technology"},"field":{"id":"https://openalex.org/fields/15","display_name":"Chemical Engineering"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10807","display_name":"Synthesis and characterization of novel inorganic/organometallic compounds","score":0.008799999952316284,"subfield":{"id":"https://openalex.org/subfields/1604","display_name":"Inorganic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/frustrated-lewis-pairs","display_name":"frustrated Lewis pairs","score":0.9990000128746033},{"id":"https://openalex.org/keywords/co2-activation","display_name":"CO2 activation","score":0.8019999861717224},{"id":"https://openalex.org/keywords/hydrogen-activation","display_name":"hydrogen activation","score":0.7139999866485596},{"id":"https://openalex.org/keywords/trifluoromethylborane","display_name":"trifluoromethylborane","score":0.6700000166893005}],"concepts":[{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9604975581169128},{"id":"https://openalex.org/C2776442012","wikidata":"https://www.wikidata.org/wiki/Q2302144","display_name":"Trifluoromethyl","level":3,"score":0.8390154838562012},{"id":"https://openalex.org/C108204754","wikidata":"https://www.wikidata.org/wiki/Q353392","display_name":"Adduct","level":2,"score":0.763826847076416},{"id":"https://openalex.org/C2778826510","wikidata":"https://www.wikidata.org/wiki/Q15634214","display_name":"Borane","level":3,"score":0.7368993759155273},{"id":"https://openalex.org/C2778270854","wikidata":"https://www.wikidata.org/wiki/Q283917","display_name":"Formamide","level":2,"score":0.7000638246536255},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.6317604780197144},{"id":"https://openalex.org/C2781014771","wikidata":"https://www.wikidata.org/wiki/Q413961","display_name":"Tris","level":2,"score":0.6272760629653931},{"id":"https://openalex.org/C131779359","wikidata":"https://www.wikidata.org/wiki/Q471875","display_name":"Amine gas treating","level":2,"score":0.6187745928764343},{"id":"https://openalex.org/C2779303437","wikidata":"https://www.wikidata.org/wiki/Q422899","display_name":"Carbamate","level":2,"score":0.6025177836418152},{"id":"https://openalex.org/C2776910235","wikidata":"https://www.wikidata.org/wiki/Q18574","display_name":"Reactivity (psychology)","level":3,"score":0.5471493601799011},{"id":"https://openalex.org/C2779870022","wikidata":"https://www.wikidata.org/wiki/Q190901","display_name":"Ammonium","level":2,"score":0.5213797688484192},{"id":"https://openalex.org/C75079739","wikidata":"https://www.wikidata.org/wiki/Q1571801","display_name":"Intramolecular force","level":2,"score":0.5105081796646118},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.3559788763523102},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.2363433837890625},{"id":"https://openalex.org/C204787440","wikidata":"https://www.wikidata.org/wiki/Q188504","display_name":"Alternative medicine","level":2,"score":0.0},{"id":"https://openalex.org/C142724271","wikidata":"https://www.wikidata.org/wiki/Q7208","display_name":"Pathology","level":1,"score":0.0},{"id":"https://openalex.org/C2780263894","wikidata":"https://www.wikidata.org/wiki/Q335268","display_name":"Alkyl","level":2,"score":0.0},{"id":"https://openalex.org/C71924100","wikidata":"https://www.wikidata.org/wiki/Q11190","display_name":"Medicine","level":0,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/om4007246","doi":"https://doi.org/10.1021/om4007246","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om4007246","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[{"id":"https://openalex.org/F4320321001","display_name":"National Natural Science Foundation of China","ror":"https://ror.org/01h0zpd94"},{"id":"https://openalex.org/F4320321885","display_name":"Science and Technology Commission of Shanghai Municipality","ror":"https://ror.org/03kt66j61"},{"id":"https://openalex.org/F4320325509","display_name":"National Institute of Polar Research","ror":"https://ror.org/05k6m5t95"},{"id":"https://openalex.org/F4320327803","display_name":"Shanghai Rising-Star Program","ror":null},{"id":"https://openalex.org/F4320335654","display_name":"Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences","ror":"https://ror.org/01y3hvq34"}],"has_content":{"pdf":false,"grobid_xml":false},"content_urls":null,"referenced_works_count":49,"referenced_works":["https://openalex.org/W122765331","https://openalex.org/W1901176552","https://openalex.org/W1964733002","https://openalex.org/W1964740687","https://openalex.org/W1969321380","https://openalex.org/W1977704235","https://openalex.org/W1983320282","https://openalex.org/W1986672150","https://openalex.org/W1986875656","https://openalex.org/W1994567008","https://openalex.org/W1995053726","https://openalex.org/W2012134512","https://openalex.org/W2013668323","https://openalex.org/W2017267600","https://openalex.org/W2018382784","https://openalex.org/W2031385379","https://openalex.org/W2033923150","https://openalex.org/W2037935642","https://openalex.org/W2038613461","https://openalex.org/W2039396938","https://openalex.org/W2046998392","https://openalex.org/W2049709653","https://openalex.org/W2079418194","https://openalex.org/W2079925142","https://openalex.org/W2098036485","https://openalex.org/W2101330455","https://openalex.org/W2107525189","https://openalex.org/W2109275877","https://openalex.org/W2115378983","https://openalex.org/W2118296450","https://openalex.org/W2124065737","https://openalex.org/W2126875005","https://openalex.org/W2128608980","https://openalex.org/W2128643931","https://openalex.org/W2135844230","https://openalex.org/W2136252185","https://openalex.org/W2138520102","https://openalex.org/W2141754854","https://openalex.org/W2143453620","https://openalex.org/W2150195378","https://openalex.org/W2153802466","https://openalex.org/W2166732153","https://openalex.org/W2169262306","https://openalex.org/W2171515789","https://openalex.org/W2319863753","https://openalex.org/W2324586646","https://openalex.org/W2334648975","https://openalex.org/W2335133995","https://openalex.org/W4243555454"],"related_works":["https://openalex.org/W2312934384","https://openalex.org/W2163482739","https://openalex.org/W1408793833","https://openalex.org/W2900333853","https://openalex.org/W3209741387","https://openalex.org/W2128703814","https://openalex.org/W3194622385","https://openalex.org/W4234876400","https://openalex.org/W2596492618","https://openalex.org/W2333392729"],"abstract_inverted_index":{"Frustrated":[0],"Lewis":[1],"pairs":[2],"(FLPs)":[3],"comprised":[4],"of":[5,56,59,97],"bis(2,4,6-tris(trifluoromethyl)phenyl)borane":[6],"(":[7],"1":[8,57],")":[9,23],"and":[10,85,99],"a":[11],"secondary":[12],"amine":[13],"(such":[14],"as":[15,72],"HN":[16],"i":[17,64],"Pr":[18],"2":[19,22,28,37,61],"or":[20],"HNEt":[21],"readily":[24],"react":[25],"with":[26,54],"CO":[27],"at":[29,45],"room":[30],"temperature":[31],"to":[32,76,94],"afford":[33],"ammonium":[34,81],"carbamatoborate":[35],"salts":[36],".":[38,62,89],"When":[39],"the":[40,95],"reaction":[41,91],"was":[42],"carried":[43],"out":[44],"80":[46],"\u00b0C,":[47],"carbamate":[48,66],"boryl":[49,67],"esters":[50],"3":[51],"were":[52],"obtained":[53],"release":[55],"equiv":[58],"H":[60,78],"The":[63],"Pr-substituted":[65],"ester":[68],"3a":[69],"can":[70],"function":[71],"an":[73],"intramolecular":[74],"FLP":[75],"activate":[77],"2,":[79],"affording":[80],"borylformate":[82],"salt":[83],"4a":[84,98],"formamide":[86],"adduct":[87],"5a":[88,100],"Two":[90],"pathways":[92],"leading":[93],"formation":[96],"are":[101],"proposed.":[102]},"counts_by_year":[{"year":2023,"cited_by_count":2},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":5},{"year":2019,"cited_by_count":6},{"year":2017,"cited_by_count":1},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":8},{"year":2014,"cited_by_count":5},{"year":2013,"cited_by_count":1}],"updated_date":"2026-11-12T12:28:57.059296","created_date":"2016-06-24T00:00:00"}