{"id":"https://openalex.org/W2326219956","doi":"https://doi.org/10.1021/jp406228t","title":"Ionic and Tautomeric Composition of Cytosine in Aqueous Solution: Resonance and Non-Resonance Raman Spectroscopy Study","display_name":"Ionic and Tautomeric Composition of Cytosine in Aqueous Solution: Resonance and Non-Resonance Raman Spectroscopy Study","publication_year":2013,"publication_date":"2013-11-12","ids":{"openalex":"https://openalex.org/W2326219956","doi":"https://doi.org/10.1021/jp406228t","mag":"2326219956","pmid":"https://pubmed.ncbi.nlm.nih.gov/24215239"},"language":"en","primary_location":{"id":"doi:10.1021/jp406228t","doi":"https://doi.org/10.1021/jp406228t","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp406228t","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"},"volume":null,"type":"article","indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5033213112","display_name":"Tatiana G. Burova","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I125219893","display_name":"Saratov State University","ror":"https://ror.org/05jcsqx24","country_code":"RU","type":"education","lineage":["https://openalex.org/I125219893"]}],"countries":["RU"],"is_corresponding":true,"raw_author_name":"Tatiana G. Burova","raw_affiliation_strings":["Saratov State University, 155\rMoskovskaya Street, Saratov 410026, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Saratov State University, 155\rMoskovskaya Street, Saratov 410026, Russia","institution_ids":["https://openalex.org/I125219893"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5083436554","display_name":"Vladimir V. Ermolenkov","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I392282","display_name":"University at Albany, State University of New York","ror":"https://ror.org/012zs8222","country_code":"US","type":"education","lineage":["https://openalex.org/I392282"]}],"countries":["US"],"is_corresponding":false,"raw_author_name":"Vladimir V. Ermolenkov","raw_affiliation_strings":["University at Albany, State University of New York, 1400 Washington Avenue, Albany, New York 12222, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University at Albany, State University of New York, 1400 Washington Avenue, Albany, New York 12222, United States","institution_ids":["https://openalex.org/I392282"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113725847","display_name":"Galina N. Ten","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I125219893","display_name":"Saratov State University","ror":"https://ror.org/05jcsqx24","country_code":"RU","type":"education","lineage":["https://openalex.org/I125219893"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Galina N. Ten","raw_affiliation_strings":["Saratov State University, 155\rMoskovskaya Street, Saratov 410026, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Saratov State University, 155\rMoskovskaya Street, Saratov 410026, Russia","institution_ids":["https://openalex.org/I125219893"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5111767911","display_name":"D. M. Kadrov","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I125219893","display_name":"Saratov State University","ror":"https://ror.org/05jcsqx24","country_code":"RU","type":"education","lineage":["https://openalex.org/I125219893"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Dmitriy M. Kadrov","raw_affiliation_strings":["Saratov State University, 155\rMoskovskaya Street, Saratov 410026, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Saratov State University, 155\rMoskovskaya Street, Saratov 410026, Russia","institution_ids":["https://openalex.org/I125219893"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5040192126","display_name":"M. N. Nurlygaianova","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I125219893","display_name":"Saratov State University","ror":"https://ror.org/05jcsqx24","country_code":"RU","type":"education","lineage":["https://openalex.org/I125219893"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Marina N. Nurlygaianova","raw_affiliation_strings":["Saratov State University, 155\rMoskovskaya Street, Saratov 410026, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Saratov State University, 155\rMoskovskaya Street, Saratov 410026, Russia","institution_ids":["https://openalex.org/I125219893"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5009851558","display_name":"Victor I. Baranov","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I1313323035","display_name":"Russian Academy of Sciences","ror":"https://ror.org/05qrfxd25","country_code":"RU","type":"government","lineage":["https://openalex.org/I1313323035"]},{"id":"https://openalex.org/I4210160179","display_name":"V.I. Vernadsky Institute of Geochemistry and Analytical Chemistry","ror":"https://ror.org/053pwmv60","country_code":"RU","type":"facility","lineage":["https://openalex.org/I1313323035","https://openalex.org/I4210145551","https://openalex.org/I4210160179"]}],"countries":["RU"],"is_corresponding":false,"raw_author_name":"Victor I. Baranov","raw_affiliation_strings":["Vernadsky\rInstitute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, 19 Kosygin Street, Moscow 119991, Russia"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Vernadsky\rInstitute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, 19 Kosygin Street, Moscow 119991, Russia","institution_ids":["https://openalex.org/I1313323035","https://openalex.org/I4210160179"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5030625987","display_name":"Igor K. Lednev","orcid":"https://orcid.org/0000-0002-6504-531X","observed_orcids":["https://orcid.org/0000-0002-6504-531X"]},"institutions":[{"id":"https://openalex.org/I392282","display_name":"University at Albany, State University of New York","ror":"https://ror.org/012zs8222","country_code":"US","type":"education","lineage":["https://openalex.org/I392282"]}],"countries":["US"],"is_corresponding":true,"raw_author_name":"Igor K. Lednev","raw_affiliation_strings":["University at Albany, State University of New York, 1400 Washington Avenue, Albany, New York 12222, United States"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"University at Albany, State University of New York, 1400 Washington Avenue, Albany, New York 12222, United States","institution_ids":["https://openalex.org/I392282"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":4,"corresponding_author_ids":["https://openalex.org/A5030625987","https://openalex.org/A5033213112"],"corresponding_institution_ids":["https://openalex.org/I125219893","https://openalex.org/I392282"],"apc_list":null,"apc_paid":null,"fwci":0.3427,"has_fulltext":false,"cited_by_count":11,"citation_normalized_percentile":{"value":0.60037343,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":89,"max":96},"biblio":{"volume":"117","issue":"48","first_page":"12734","last_page":"12748"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.7031000256538391,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T11177","display_name":"Spectroscopy and Quantum Chemical Studies","score":0.7031000256538391,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T11324","display_name":"Spectroscopy Techniques in Biomedical and Chemical Research","score":0.26339998841285706,"subfield":{"id":"https://openalex.org/subfields/1304","display_name":"Biophysics"},"field":{"id":"https://openalex.org/fields/13","display_name":"Biochemistry, Genetics and Molecular Biology"},"domain":{"id":"https://openalex.org/domains/1","display_name":"Life Sciences"}},{"id":"https://openalex.org/T11129","display_name":"Photochemistry and Electron Transfer Studies","score":0.016200000420212746,"subfield":{"id":"https://openalex.org/subfields/1606","display_name":"Physical and Theoretical Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/cytosine","display_name":"cytosine","score":0.9980000257492065},{"id":"https://openalex.org/keywords/aqueous-solutions","display_name":"aqueous solutions","score":0.7839999794960022},{"id":"https://openalex.org/keywords/tautomerism","display_name":"tautomerism","score":0.7990000247955322},{"id":"https://openalex.org/keywords/ph-dependence","display_name":"pH dependence","score":0.6650000214576721},{"id":"https://openalex.org/keywords/resonance-raman-spectra","display_name":"resonance Raman spectra","score":0.8619999885559082},{"id":"https://openalex.org/keywords/temperature-dependence","display_name":"temperature dependence","score":0.5609999895095825},{"id":"https://openalex.org/keywords/electronically-excited-states","display_name":"excited electronic states","score":0.7139999866485596},{"id":"https://openalex.org/keywords/quantum-chemical-calculations","display_name":"quantum chemical calculations","score":0.5619999766349792}],"concepts":[{"id":"https://openalex.org/C40003534","wikidata":"https://www.wikidata.org/wiki/Q862228","display_name":"Raman spectroscopy","level":2,"score":0.9125257730484009},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.8460054397583008},{"id":"https://openalex.org/C2776023528","wikidata":"https://www.wikidata.org/wiki/Q178425","display_name":"Cytosine","level":3,"score":0.83918297290802},{"id":"https://openalex.org/C139210041","wikidata":"https://www.wikidata.org/wiki/Q2145840","display_name":"Resonance (particle physics)","level":2,"score":0.7654077410697937},{"id":"https://openalex.org/C111233374","wikidata":"https://www.wikidata.org/wiki/Q334640","display_name":"Tautomer","level":2,"score":0.601266622543335},{"id":"https://openalex.org/C2781340169","wikidata":"https://www.wikidata.org/wiki/Q7315737","display_name":"Resonance Raman spectroscopy","level":3,"score":0.5840260982513428},{"id":"https://openalex.org/C2182769","wikidata":"https://www.wikidata.org/wiki/Q62500","display_name":"Ionic bonding","level":3,"score":0.5251020193099976},{"id":"https://openalex.org/C184651966","wikidata":"https://www.wikidata.org/wiki/Q906356","display_name":"Aqueous solution","level":2,"score":0.5230401754379272},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.5227991938591003},{"id":"https://openalex.org/C181500209","wikidata":"https://www.wikidata.org/wiki/Q215328","display_name":"Excited state","level":2,"score":0.4721643626689911},{"id":"https://openalex.org/C187428577","wikidata":"https://www.wikidata.org/wiki/Q898396","display_name":"Ionic strength","level":3,"score":0.44280120730400085},{"id":"https://openalex.org/C169573571","wikidata":"https://www.wikidata.org/wiki/Q466824","display_name":"Raman scattering","level":3,"score":0.4421215355396271},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.43982887268066406},{"id":"https://openalex.org/C83581075","wikidata":"https://www.wikidata.org/wiki/Q1361503","display_name":"Excitation","level":2,"score":0.4104354679584503},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.19130688905715942},{"id":"https://openalex.org/C184779094","wikidata":"https://www.wikidata.org/wiki/Q26383","display_name":"Atomic physics","level":1,"score":0.09536850452423096},{"id":"https://openalex.org/C71240020","wikidata":"https://www.wikidata.org/wiki/Q186011","display_name":"Stereochemistry","level":1,"score":0.07085418701171875},{"id":"https://openalex.org/C552990157","wikidata":"https://www.wikidata.org/wiki/Q7430","display_name":"DNA","level":2,"score":0.059925734996795654},{"id":"https://openalex.org/C127413603","wikidata":"https://www.wikidata.org/wiki/Q11023","display_name":"Engineering","level":0,"score":0.0},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.0},{"id":"https://openalex.org/C119599485","wikidata":"https://www.wikidata.org/wiki/Q43035","display_name":"Electrical engineering","level":1,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C120665830","wikidata":"https://www.wikidata.org/wiki/Q14620","display_name":"Optics","level":1,"score":0.0},{"id":"https://openalex.org/C121332964","wikidata":"https://www.wikidata.org/wiki/Q413","display_name":"Physics","level":0,"score":0.0},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.0}],"mesh":[{"descriptor_ui":"D003596","descriptor_name":"Cytosine","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":true},{"descriptor_ui":"D007477","descriptor_name":"Ions","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D011789","descriptor_name":"Quantum Theory","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D012996","descriptor_name":"Solutions","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D013059","descriptor_name":"Spectrum Analysis, Raman","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D014867","descriptor_name":"Water","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D015394","descriptor_name":"Molecular Structure","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false}],"locations_count":2,"locations":[{"id":"doi:10.1021/jp406228t","doi":"https://doi.org/10.1021/jp406228t","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp406228t","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"},{"id":"pmid:24215239","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/24215239","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The journal of physical chemistry. A","raw_type":"Journal Article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":34,"referenced_works":["https://openalex.org/W200503784","https://openalex.org/W1791966007","https://openalex.org/W1966397398","https://openalex.org/W1970445503","https://openalex.org/W1980618018","https://openalex.org/W1989461676","https://openalex.org/W1992493010","https://openalex.org/W1997117830","https://openalex.org/W1999485331","https://openalex.org/W2000862563","https://openalex.org/W2003809560","https://openalex.org/W2006740340","https://openalex.org/W2023921797","https://openalex.org/W2027421013","https://openalex.org/W2036777925","https://openalex.org/W2038603672","https://openalex.org/W2043395118","https://openalex.org/W2043801774","https://openalex.org/W2049010489","https://openalex.org/W2052895619","https://openalex.org/W2059003576","https://openalex.org/W2063311279","https://openalex.org/W2064359109","https://openalex.org/W2068861774","https://openalex.org/W2069175822","https://openalex.org/W2072337278","https://openalex.org/W2084517298","https://openalex.org/W2086643828","https://openalex.org/W2312918820","https://openalex.org/W2494690972","https://openalex.org/W2953145470","https://openalex.org/W3043028315","https://openalex.org/W4245691468","https://openalex.org/W4251497185"],"related_works":["https://openalex.org/W2090349775","https://openalex.org/W4386038302","https://openalex.org/W2312918820","https://openalex.org/W4322772339","https://openalex.org/W2012277121","https://openalex.org/W2385345609","https://openalex.org/W1989461676","https://openalex.org/W2324915806","https://openalex.org/W2027012412","https://openalex.org/W2086643828"],"abstract_inverted_index":{"A":[0],"complex":[1],"experimental":[2,74],"and":[3,17,26,34,46,55,76,80,96,101,117,123,158,161],"theoretical":[4],"study":[5],"of":[6,10,21,42,52,57,68,86,90,94,120,137,170,180,184,191,194],"the":[7,53,58,65,73,83,87,92,107,111,121,128,134,138,145,152,174,181,189,195,199],"structural":[8,84,178],"composition":[9,85,179],"cytosine":[11,22,95,122,157,185],"in":[12,23,64,127,151,173,198],"water":[13,28,88,182],"was":[14,62],"performed.":[15],"Raman":[16,19,60,75,78,140,201],"resonance":[18,59,77,139,200],"spectra":[20,79,93,116,141],"acidic,":[24],"neutral,":[25],"alkaline":[27,175],"solutions":[29],"(pH":[30],"=":[31],"3,":[32],"7,":[33],"10,":[35],"respectively)":[36],"were":[37,104,142],"recorded":[38],"at":[39,106],"excitation":[40,135],"wavelengths":[41,136],"514,":[43],"266,":[44],"218,":[45],"200":[47],"nm.":[48],"The":[49,114,148,177],"temperature":[50,66],"dependence":[51],"frequencies":[54],"intensities":[56],"bands":[61],"obtained":[63],"interval":[67],"4-80":[69],"\u00b0C.":[70],"To":[71],"interpret":[72],"to":[81,133],"determine":[82],"solution":[89,154,183],"cytosine,":[91],"its":[97,124,159],"cation,":[98],"anion,":[99],"oxoimine,":[100],"hydroxoamine":[102,162],"forms":[103,126],"calculated":[105,143],"B3LYP/6-311++G(d,p)":[108],"level":[109],"using":[110,144],"SCRF":[112],"method.":[113,147],"electronic":[115,130],"geometric":[118],"parameters":[119],"molecular":[125],"excited":[129],"states":[131],"close":[132],"DFT":[146],"cation":[149],"exists":[150],"acidic":[153],"together":[155],"with":[156,166],"oxoimine":[160],"tautomeric":[163],"forms.":[164],"Cytosine":[165],"a":[167],"small":[168],"amount":[169],"anion":[171],"dominates":[172],"medium.":[176],"is":[186],"confirmed":[187],"by":[188],"results":[190],"quantum-mechanical":[192],"calculations":[193],"intensity":[196],"distribution":[197],"spectra.":[202]},"counts_by_year":[{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":2},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":1},{"year":2015,"cited_by_count":1}],"updated_date":"2026-10-31T12:09:11.096373","created_date":"2016-06-24T00:00:00"}
