{"id":"https://openalex.org/W2323937299","doi":"https://doi.org/10.1021/om400345f","title":"Synthesis, Structures, and Reactivities of Guanidinatozinc Complexes and Their Catalytic Behavior in the Tishchenko Reaction","display_name":"Synthesis, Structures, and Reactivities of Guanidinatozinc Complexes and Their Catalytic Behavior in the Tishchenko Reaction","publication_year":2013,"publication_date":"2013-06-20","ids":{"openalex":"https://openalex.org/W2323937299","doi":"https://doi.org/10.1021/om400345f","mag":"2323937299"},"language":"en","primary_location":{"id":"doi:10.1021/om400345f","doi":"https://doi.org/10.1021/om400345f","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om400345f","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5043002794","display_name":"Jie Li","orcid":"https://orcid.org/0000-0002-4726-9838","observed_orcids":["https://orcid.org/0000-0002-4726-9838"]},"institutions":[{"id":"https://openalex.org/I181877577","display_name":"Shanxi University","ror":"https://ror.org/03y3e3s17","country_code":"CN","type":"education","lineage":["https://openalex.org/I181877577"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jie Li","raw_affiliation_strings":["School of Chemistry and Chemical\rEngneering, Shanxi University, Taiyuan\r030006, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Chemical\rEngneering, Shanxi University, Taiyuan\r030006, People\u2019s Republic of China","institution_ids":["https://openalex.org/I181877577"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113220691","display_name":"Jingchao Shi","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I181877577","display_name":"Shanxi University","ror":"https://ror.org/03y3e3s17","country_code":"CN","type":"education","lineage":["https://openalex.org/I181877577"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Jingchao Shi","raw_affiliation_strings":["School of Chemistry and Chemical\rEngneering, Shanxi University, Taiyuan\r030006, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Chemical\rEngneering, Shanxi University, Taiyuan\r030006, People\u2019s Republic of China","institution_ids":["https://openalex.org/I181877577"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5113220692","display_name":"Hongfei Han","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I181877577","display_name":"Shanxi University","ror":"https://ror.org/03y3e3s17","country_code":"CN","type":"education","lineage":["https://openalex.org/I181877577"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Hongfei Han","raw_affiliation_strings":["School of Chemistry and Chemical\rEngneering, Shanxi University, Taiyuan\r030006, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School of Chemistry and Chemical\rEngneering, Shanxi University, Taiyuan\r030006, People\u2019s Republic of China","institution_ids":["https://openalex.org/I181877577"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5032912484","display_name":"Zhiqiang Guo","orcid":"https://orcid.org/0000-0001-5444-7455","observed_orcids":["https://orcid.org/0000-0001-5444-7455"]},"institutions":[{"id":"https://openalex.org/I181877577","display_name":"Shanxi University","ror":"https://ror.org/03y3e3s17","country_code":"CN","type":"education","lineage":["https://openalex.org/I181877577"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Zhiqiang Guo","raw_affiliation_strings":["Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, People\u2019s Republic\rof China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, People\u2019s Republic\rof China","institution_ids":["https://openalex.org/I181877577"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5091236400","display_name":"Hongbo Tong","orcid":"https://orcid.org/0000-0001-9222-9563","observed_orcids":["https://orcid.org/0000-0001-9222-9563"]},"institutions":[{"id":"https://openalex.org/I181877577","display_name":"Shanxi University","ror":"https://ror.org/03y3e3s17","country_code":"CN","type":"education","lineage":["https://openalex.org/I181877577"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Hongbo Tong","raw_affiliation_strings":["Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, People\u2019s Republic\rof China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, People\u2019s Republic\rof China","institution_ids":["https://openalex.org/I181877577"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5087961054","display_name":"Xuehong Wei","orcid":"https://orcid.org/0000-0002-9490-7265","observed_orcids":["https://orcid.org/0000-0002-9490-7265"]},"institutions":[{"id":"https://openalex.org/I181877577","display_name":"Shanxi University","ror":"https://ror.org/03y3e3s17","country_code":"CN","type":"education","lineage":["https://openalex.org/I181877577"]}],"countries":["CN"],"is_corresponding":true,"raw_author_name":"Xuehong Wei","raw_affiliation_strings":["Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, People\u2019s Republic\rof China","School of Chemistry and Chemical\rEngneering, Shanxi University, Taiyuan\r030006, People\u2019s Republic of China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, People\u2019s Republic\rof China","institution_ids":["https://openalex.org/I181877577"]},{"raw_affiliation_string":"School of Chemistry and Chemical\rEngneering, Shanxi University, Taiyuan\r030006, People\u2019s Republic of China","institution_ids":["https://openalex.org/I181877577"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5029449509","display_name":"Dian\u2010Sheng Liu","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I181877577","display_name":"Shanxi University","ror":"https://ror.org/03y3e3s17","country_code":"CN","type":"education","lineage":["https://openalex.org/I181877577"]}],"countries":["CN"],"is_corresponding":false,"raw_author_name":"Diansheng Liu","raw_affiliation_strings":["Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, People\u2019s Republic\rof China"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Institute of Applied Chemistry, Shanxi University, Taiyuan 030006, People\u2019s Republic\rof China","institution_ids":["https://openalex.org/I181877577"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5077804559","display_name":"Michael F. L\u00e4ppert","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I162608824","display_name":"University of Sussex","ror":"https://ror.org/00ayhx656","country_code":"GB","type":"education","lineage":["https://openalex.org/I162608824"]}],"countries":["GB"],"is_corresponding":true,"raw_author_name":"Michael F. Lappert","raw_affiliation_strings":["Department of Chemistry, University of Sussex, Brighton, BN1 9QJ, U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"Department of Chemistry, University of Sussex, Brighton, BN1 9QJ, U.K","institution_ids":["https://openalex.org/I162608824"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":2,"corresponding_author_ids":["https://openalex.org/A5077804559","https://openalex.org/A5087961054"],"corresponding_institution_ids":["https://openalex.org/I162608824","https://openalex.org/I181877577"],"apc_list":{"value":4500,"currency":"USD","value_usd":4500},"apc_paid":null,"fwci":2.3626,"has_fulltext":false,"cited_by_count":28,"citation_normalized_percentile":{"value":0.8825662,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"32","issue":"13","first_page":"3721","last_page":"3727"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.27000001072883606,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10092","display_name":"Organometallic Complex Synthesis and Catalysis","score":0.27000001072883606,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12228","display_name":"Coordination Chemistry and Organometallics","score":0.14509999752044678,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10013","display_name":"Asymmetric Synthesis and Catalysis","score":0.09719999879598618,"subfield":{"id":"https://openalex.org/subfields/1605","display_name":"Organic Chemistry"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/tishchenko-reaction","display_name":"Tishchenko reaction","score":0.9610000252723694},{"id":"https://openalex.org/keywords/diethylzinc","display_name":"diethylzinc","score":0.8080000281333923},{"id":"https://openalex.org/keywords/n-n-dicyclohexylcarbodiimide","display_name":"N,N'-dicyclohexylcarbodiimide","score":0.9869999885559082},{"id":"https://openalex.org/keywords/guanidine-synthesis","display_name":"guanidine synthesis","score":0.5830000042915344},{"id":"https://openalex.org/keywords/solvent-free-catalysis","display_name":"solvent-free catalysis","score":0.8510000109672546},{"id":"https://openalex.org/keywords/secondary-amines","display_name":"secondary amines","score":0.36800000071525574},{"id":"https://openalex.org/keywords/carbonyl-reduction","display_name":"carbonyl reduction","score":0.4020000100135803},{"id":"https://openalex.org/keywords/crystal-structure","display_name":"crystal structure","score":0.5199999809265137},{"id":"https://openalex.org/keywords/nmr-characterization","display_name":"NMR characterization","score":0.6010000109672546}],"concepts":[{"id":"https://openalex.org/C2781194912","wikidata":"https://www.wikidata.org/wiki/Q420423","display_name":"Diethylzinc","level":4,"score":0.9896798729896545},{"id":"https://openalex.org/C2781083472","wikidata":"https://www.wikidata.org/wiki/Q5891406","display_name":"Homoleptic","level":3,"score":0.9753058552742004},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.969657301902771},{"id":"https://openalex.org/C161790260","wikidata":"https://www.wikidata.org/wiki/Q82264","display_name":"Catalysis","level":2,"score":0.6797583699226379},{"id":"https://openalex.org/C131779359","wikidata":"https://www.wikidata.org/wiki/Q471875","display_name":"Amine gas treating","level":2,"score":0.6544997692108154},{"id":"https://openalex.org/C2781014771","wikidata":"https://www.wikidata.org/wiki/Q413961","display_name":"Tris","level":2,"score":0.5765973925590515},{"id":"https://openalex.org/C535196362","wikidata":"https://www.wikidata.org/wiki/Q758","display_name":"Zinc","level":2,"score":0.5748605132102966},{"id":"https://openalex.org/C134121241","wikidata":"https://www.wikidata.org/wiki/Q899301","display_name":"Yield (engineering)","level":2,"score":0.5174884796142578},{"id":"https://openalex.org/C155647269","wikidata":"https://www.wikidata.org/wiki/Q243455","display_name":"Medicinal chemistry","level":1,"score":0.4857359528541565},{"id":"https://openalex.org/C2780471494","wikidata":"https://www.wikidata.org/wiki/Q146505","display_name":"Solvent","level":2,"score":0.478779673576355},{"id":"https://openalex.org/C2994067411","wikidata":"https://www.wikidata.org/wiki/Q125264","display_name":"Molar ratio","level":3,"score":0.4646351635456085},{"id":"https://openalex.org/C188027245","wikidata":"https://www.wikidata.org/wiki/Q750446","display_name":"Polymer chemistry","level":1,"score":0.42667174339294434},{"id":"https://openalex.org/C2777077568","wikidata":"https://www.wikidata.org/wiki/Q150440","display_name":"Hexane","level":2,"score":0.4205326735973358},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.39850130677223206},{"id":"https://openalex.org/C544153396","wikidata":"https://www.wikidata.org/wiki/Q11426","display_name":"Metal","level":2,"score":0.21817362308502197},{"id":"https://openalex.org/C146686406","wikidata":"https://www.wikidata.org/wiki/Q898628","display_name":"Enantioselective synthesis","level":3,"score":0.08311969041824341},{"id":"https://openalex.org/C192562407","wikidata":"https://www.wikidata.org/wiki/Q228736","display_name":"Materials science","level":0,"score":0.0},{"id":"https://openalex.org/C55493867","wikidata":"https://www.wikidata.org/wiki/Q7094","display_name":"Biochemistry","level":1,"score":0.0},{"id":"https://openalex.org/C191897082","wikidata":"https://www.wikidata.org/wiki/Q11467","display_name":"Metallurgy","level":1,"score":0.0}],"mesh":[],"locations_count":1,"locations":[{"id":"doi:10.1021/om400345f","doi":"https://doi.org/10.1021/om400345f","is_oa":false,"landing_page_url":"https://doi.org/10.1021/om400345f","pdf_url":null,"source":{"id":"https://openalex.org/S4924609","display_name":"Organometallics","issn_l":"0276-7333","issn":["0276-7333","1520-6041"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-a","jufo-1","norway-2","poland-100","russia-white-list-1"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"Organometallics","raw_type":"journal-article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[],"funders":[],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":31,"referenced_works":["https://openalex.org/W1967594864","https://openalex.org/W1969777565","https://openalex.org/W1975602792","https://openalex.org/W1975650978","https://openalex.org/W1978712974","https://openalex.org/W1989797017","https://openalex.org/W1990148488","https://openalex.org/W1996371859","https://openalex.org/W1997194549","https://openalex.org/W2009277063","https://openalex.org/W2014926538","https://openalex.org/W2015583046","https://openalex.org/W2028920654","https://openalex.org/W2030790409","https://openalex.org/W2037369098","https://openalex.org/W2042174221","https://openalex.org/W2049690183","https://openalex.org/W2051389332","https://openalex.org/W2053000517","https://openalex.org/W2057857093","https://openalex.org/W2065093952","https://openalex.org/W2070738837","https://openalex.org/W2077979546","https://openalex.org/W2082277261","https://openalex.org/W2083846738","https://openalex.org/W2098553564","https://openalex.org/W2102208605","https://openalex.org/W2122565312","https://openalex.org/W2166103811","https://openalex.org/W2321230304","https://openalex.org/W2950978876"],"related_works":["https://openalex.org/W2952218714","https://openalex.org/W2051704760","https://openalex.org/W2083749600","https://openalex.org/W2424615751","https://openalex.org/W4285176528","https://openalex.org/W2597621348","https://openalex.org/W2103893981","https://openalex.org/W2166103811","https://openalex.org/W7029908177","https://openalex.org/W2158995251"],"abstract_inverted_index":{"Treatment":[0],"of":[1,59,73,88,96],"a":[2,53],"secondary":[3],"amine":[4],"(pipH,":[5],"Bz":[6],"2":[7,10],"NH,":[8],"Et":[9],"NH)":[11],"with":[12,63,84],"sequentially":[13],"diethylzinc":[14,64,89],"and":[15,35,50,65],"N,":[16,66],"N":[17,67],"\u2032-dicyclohexylcarbodiimide":[18,68],"in":[19,23,69],"hexane":[20],"has":[21,32],"afforded":[22],"good":[24,100],"yield":[25],"the":[26,70,77,97,106],"new":[27],"crystalline":[28],"guanidinatozinc":[29],"complexes.":[30],"Each":[31,95],"been":[33],"X-ray":[34],"solution":[36],"NMR":[37],"spectrally":[38],"characterized.":[39],"Three":[40],"are":[41,46],"dimeric":[42,78,92],"(mono)guandinatozinc":[43,79,93],"alkyls,":[44],"two":[45],"dinuclear":[47,60],"(tris)guanidinatozinc":[48,61],"amides,":[49],"one":[51],"is":[52],"homoleptic":[54,81],"zinc":[55,82],"bis(guanidinate).":[56],"The":[57],"reactions":[58],"amides":[62],"molar":[71],"ratios":[72],"1:2:1":[74],"led":[75],"to":[76,101],"alkyls;":[80],"bis(guanidinate)":[83],"an":[85],"equimolar":[86],"portion":[87],"also":[90],"yielded":[91],"alkyls.":[94],"complexes":[98],"exhibited":[99],"excellent":[102],"catalytic":[103],"activity":[104],"for":[105],"solvent-free":[107],"Tishchenko":[108],"reaction":[109],"under":[110],"mild":[111],"conditions.":[112]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":1},{"year":2024,"cited_by_count":1},{"year":2023,"cited_by_count":1},{"year":2022,"cited_by_count":1},{"year":2021,"cited_by_count":2},{"year":2019,"cited_by_count":1},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":5},{"year":2015,"cited_by_count":8},{"year":2014,"cited_by_count":3},{"year":2013,"cited_by_count":1}],"updated_date":"2026-09-29T14:09:16.559479","created_date":"2016-06-24T00:00:00"}