{"id":"https://openalex.org/W2322017535","doi":"https://doi.org/10.1021/jp5010192","title":"Sensitivity and Selectivity of Switchable Reagent Ion Soft Chemical Ionization Mass Spectrometry for the Detection of Picric Acid","display_name":"Sensitivity and Selectivity of Switchable Reagent Ion Soft Chemical Ionization Mass Spectrometry for the Detection of Picric Acid","publication_year":2014,"publication_date":"2014-02-21","ids":{"openalex":"https://openalex.org/W2322017535","doi":"https://doi.org/10.1021/jp5010192","mag":"2322017535","pmid":"https://pubmed.ncbi.nlm.nih.gov/24559481"},"language":"en","primary_location":{"id":"doi:10.1021/jp5010192","doi":"https://doi.org/10.1021/jp5010192","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp5010192","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"},"volume":null,"type":"article","is_traditional":true,"indexed_in":["crossref","pubmed"],"open_access":{"is_oa":false,"oa_status":"closed","oa_url":null,"any_repository_has_fulltext":false},"authorships":[{"author_position":"first","author":{"id":"https://openalex.org/A5010025041","display_name":"Bishu Agarwal","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I190249584","display_name":"Universit\u00e4t Innsbruck","ror":"https://ror.org/054pv6659","country_code":"AT","type":"education","lineage":["https://openalex.org/I190249584"]},{"id":"https://openalex.org/I4210095688","display_name":"Ionicon Analytik (Austria)","ror":"https://ror.org/008gaha58","country_code":"AT","type":"company","lineage":["https://openalex.org/I4210095688"]}],"countries":["AT"],"is_corresponding":false,"raw_author_name":"Bishu Agarwal","raw_affiliation_strings":["IONICON Analytik Gesellschaft m.b.H., Eduard-Bodem-Gasse 3, A-6020 Innsbruck, Austria","Institut\rf\u00fcr Ionenphysik und Angewandte Physik, Leopold-Franzens-Universit\u00e4t Innsbruck, Technikerstr.\r25, A-6020 Innsbruck, Austria"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IONICON Analytik Gesellschaft m.b.H., Eduard-Bodem-Gasse 3, A-6020 Innsbruck, Austria","institution_ids":["https://openalex.org/I4210095688"]},{"raw_affiliation_string":"Institut\rf\u00fcr Ionenphysik und Angewandte Physik, Leopold-Franzens-Universit\u00e4t Innsbruck, Technikerstr.\r25, A-6020 Innsbruck, Austria","institution_ids":["https://openalex.org/I190249584"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5015915563","display_name":"Ram\u00f3n Gonz\u00e1lez\u2010M\u00e9ndez","orcid":"https://orcid.org/0000-0002-6481-456X","observed_orcids":["https://orcid.org/0000-0002-6481-456X"]},"institutions":[{"id":"https://openalex.org/I79619799","display_name":"University of Birmingham","ror":"https://ror.org/03angcq70","country_code":"GB","type":"education","lineage":["https://openalex.org/I79619799"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Ram\u00f3n Gonz\u00e1lez-M\u00e9ndez","raw_affiliation_strings":["School\rof Physics and Astronomy, University of Birmingham, Edgbaston, Birmingham, B15 2TT, U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School\rof Physics and Astronomy, University of Birmingham, Edgbaston, Birmingham, B15 2TT, U.K","institution_ids":["https://openalex.org/I79619799"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5000457848","display_name":"Matteo Lanza","orcid":"https://orcid.org/0009-0003-1287-4530","observed_orcids":["https://orcid.org/0009-0003-1287-4530","https://orcid.org/0000-0002-9290-6672"]},"institutions":[{"id":"https://openalex.org/I4210095688","display_name":"Ionicon Analytik (Austria)","ror":"https://ror.org/008gaha58","country_code":"AT","type":"company","lineage":["https://openalex.org/I4210095688"]}],"countries":["AT"],"is_corresponding":false,"raw_author_name":"Matteo Lanza","raw_affiliation_strings":["IONICON Analytik Gesellschaft m.b.H., Eduard-Bodem-Gasse 3, A-6020 Innsbruck, Austria"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IONICON Analytik Gesellschaft m.b.H., Eduard-Bodem-Gasse 3, A-6020 Innsbruck, Austria","institution_ids":["https://openalex.org/I4210095688"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5004885653","display_name":"Philipp Sulzer","orcid":"https://orcid.org/0000-0002-3316-1367","observed_orcids":["https://orcid.org/0000-0002-3316-1367","https://orcid.org/0009-0004-2475-295X"]},"institutions":[{"id":"https://openalex.org/I4210095688","display_name":"Ionicon Analytik (Austria)","ror":"https://ror.org/008gaha58","country_code":"AT","type":"company","lineage":["https://openalex.org/I4210095688"]}],"countries":["AT"],"is_corresponding":false,"raw_author_name":"Philipp Sulzer","raw_affiliation_strings":["IONICON Analytik Gesellschaft m.b.H., Eduard-Bodem-Gasse 3, A-6020 Innsbruck, Austria"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IONICON Analytik Gesellschaft m.b.H., Eduard-Bodem-Gasse 3, A-6020 Innsbruck, Austria","institution_ids":["https://openalex.org/I4210095688"]}]},{"author_position":"middle","author":{"id":"https://openalex.org/A5105459021","display_name":"T.D. M\u00e4rk","orcid":"https://orcid.org/0009-0005-5675-1262","observed_orcids":["https://orcid.org/0009-0005-5675-1262"]},"institutions":[{"id":"https://openalex.org/I190249584","display_name":"Universit\u00e4t Innsbruck","ror":"https://ror.org/054pv6659","country_code":"AT","type":"education","lineage":["https://openalex.org/I190249584"]},{"id":"https://openalex.org/I4210095688","display_name":"Ionicon Analytik (Austria)","ror":"https://ror.org/008gaha58","country_code":"AT","type":"company","lineage":["https://openalex.org/I4210095688"]}],"countries":["AT"],"is_corresponding":false,"raw_author_name":"Tilmann D. M\u00e4rk","raw_affiliation_strings":["IONICON Analytik Gesellschaft m.b.H., Eduard-Bodem-Gasse 3, A-6020 Innsbruck, Austria","Institut\rf\u00fcr Ionenphysik und Angewandte Physik, Leopold-Franzens-Universit\u00e4t Innsbruck, Technikerstr.\r25, A-6020 Innsbruck, Austria"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"IONICON Analytik Gesellschaft m.b.H., Eduard-Bodem-Gasse 3, A-6020 Innsbruck, Austria","institution_ids":["https://openalex.org/I4210095688"]},{"raw_affiliation_string":"Institut\rf\u00fcr Ionenphysik und Angewandte Physik, Leopold-Franzens-Universit\u00e4t Innsbruck, Technikerstr.\r25, A-6020 Innsbruck, Austria","institution_ids":["https://openalex.org/I190249584"]}]},{"author_position":"middle","author":{"id":null,"display_name":"Neil Thomas","orcid":null,"observed_orcids":[]},"institutions":[{"id":"https://openalex.org/I79619799","display_name":"University of Birmingham","ror":"https://ror.org/03angcq70","country_code":"GB","type":"education","lineage":["https://openalex.org/I79619799"]}],"countries":["GB"],"is_corresponding":false,"raw_author_name":"Neil Thomas","raw_affiliation_strings":["School\rof Physics and Astronomy, University of Birmingham, Edgbaston, Birmingham, B15 2TT, U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School\rof Physics and Astronomy, University of Birmingham, Edgbaston, Birmingham, B15 2TT, U.K","institution_ids":["https://openalex.org/I79619799"]}]},{"author_position":"last","author":{"id":"https://openalex.org/A5013635280","display_name":"Chris A. Mayhew","orcid":"https://orcid.org/0000-0002-5014-7241","observed_orcids":["https://orcid.org/0000-0002-5014-7241"]},"institutions":[{"id":"https://openalex.org/I79619799","display_name":"University of Birmingham","ror":"https://ror.org/03angcq70","country_code":"GB","type":"education","lineage":["https://openalex.org/I79619799"]}],"countries":["GB"],"is_corresponding":true,"raw_author_name":"Chris A. Mayhew","raw_affiliation_strings":["School\rof Physics and Astronomy, University of Birmingham, Edgbaston, Birmingham, B15 2TT, U.K"],"raw_orcid":null,"affiliations":[{"raw_affiliation_string":"School\rof Physics and Astronomy, University of Birmingham, Edgbaston, Birmingham, B15 2TT, U.K","institution_ids":["https://openalex.org/I79619799"]}]}],"institutions":[],"countries_distinct_count":2,"institutions_distinct_count":3,"corresponding_author_ids":["https://openalex.org/A5013635280"],"corresponding_institution_ids":["https://openalex.org/I79619799"],"apc_list":null,"apc_paid":null,"fwci":0.9631,"has_fulltext":false,"cited_by_count":46,"citation_normalized_percentile":{"value":0.6723835,"is_in_top_1_percent":false,"is_in_top_10_percent":false},"cited_by_percentile_year":{"min":88,"max":99},"biblio":{"volume":"118","issue":"37","first_page":"8229","last_page":"8236"},"is_retracted":false,"is_paratext":false,"is_xpac":false,"primary_topic":{"id":"https://openalex.org/T10683","display_name":"Mass Spectrometry Techniques and Applications","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},"topics":[{"id":"https://openalex.org/T10683","display_name":"Mass Spectrometry Techniques and Applications","score":0.9994999766349792,"subfield":{"id":"https://openalex.org/subfields/1607","display_name":"Spectroscopy"},"field":{"id":"https://openalex.org/fields/16","display_name":"Chemistry"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T10523","display_name":"Atomic and Molecular Physics","score":0.00019999999494757503,"subfield":{"id":"https://openalex.org/subfields/3107","display_name":"Atomic and Molecular Physics, and Optics"},"field":{"id":"https://openalex.org/fields/31","display_name":"Physics and Astronomy"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}},{"id":"https://openalex.org/T12166","display_name":"Ion-surface interactions and analysis","score":9.999999747378752e-05,"subfield":{"id":"https://openalex.org/subfields/2508","display_name":"Surfaces, Coatings and Films"},"field":{"id":"https://openalex.org/fields/25","display_name":"Materials Science"},"domain":{"id":"https://openalex.org/domains/3","display_name":"Physical Sciences"}}],"keywords":[{"id":"https://openalex.org/keywords/picric-acid","display_name":"picric acid","score":0.9629999995231628},{"id":"https://openalex.org/keywords/proton-transfer","display_name":"proton transfer","score":0.7670000195503235},{"id":"https://openalex.org/keywords/charge-transfer","display_name":"charge transfer","score":0.9290000200271606},{"id":"https://openalex.org/keywords/ion-molecule-reactions","display_name":"ion-molecule reactions","score":0.5649999976158142},{"id":"https://openalex.org/keywords/detection-sensitivity","display_name":"detection sensitivity","score":0.6650000214576721},{"id":"https://openalex.org/keywords/electronic-structure-calculations","display_name":"electronic structure calculations","score":0.6380000114440918}],"concepts":[{"id":"https://openalex.org/C2781352634","wikidata":"https://www.wikidata.org/wiki/Q189298","display_name":"Picric acid","level":2,"score":0.9483275413513184},{"id":"https://openalex.org/C185592680","wikidata":"https://www.wikidata.org/wiki/Q2329","display_name":"Chemistry","level":0,"score":0.9345794916152954},{"id":"https://openalex.org/C40875361","wikidata":"https://www.wikidata.org/wiki/Q2356542","display_name":"Reagent","level":2,"score":0.7345360517501831},{"id":"https://openalex.org/C145148216","wikidata":"https://www.wikidata.org/wiki/Q36496","display_name":"Ion","level":2,"score":0.6903961896896362},{"id":"https://openalex.org/C162356407","wikidata":"https://www.wikidata.org/wiki/Q180809","display_name":"Mass spectrometry","level":2,"score":0.6074094176292419},{"id":"https://openalex.org/C113196181","wikidata":"https://www.wikidata.org/wiki/Q485223","display_name":"Analytical Chemistry (journal)","level":2,"score":0.5767536163330078},{"id":"https://openalex.org/C198291218","wikidata":"https://www.wikidata.org/wiki/Q190382","display_name":"Ionization","level":3,"score":0.5398508906364441},{"id":"https://openalex.org/C102931765","wikidata":"https://www.wikidata.org/wiki/Q189673","display_name":"Dissociation (chemistry)","level":2,"score":0.5093177556991577},{"id":"https://openalex.org/C2992829418","wikidata":"https://www.wikidata.org/wiki/Q1255409","display_name":"Drift tube","level":3,"score":0.4967530369758606},{"id":"https://openalex.org/C119128265","wikidata":"https://www.wikidata.org/wiki/Q900165","display_name":"Detection limit","level":2,"score":0.4714841842651367},{"id":"https://openalex.org/C43617362","wikidata":"https://www.wikidata.org/wiki/Q170050","display_name":"Chromatography","level":1,"score":0.23012250661849976},{"id":"https://openalex.org/C147789679","wikidata":"https://www.wikidata.org/wiki/Q11372","display_name":"Physical chemistry","level":1,"score":0.10102877020835876},{"id":"https://openalex.org/C178790620","wikidata":"https://www.wikidata.org/wiki/Q11351","display_name":"Organic chemistry","level":1,"score":0.08978953957557678}],"mesh":[{"descriptor_ui":"D007202","descriptor_name":"Indicators and Reagents","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D007726","descriptor_name":"Krypton","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D009569","descriptor_name":"Nitric Oxide","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D010100","descriptor_name":"Oxygen","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D010851","descriptor_name":"Picrates","qualifier_ui":"Q000032","qualifier_name":"analysis","is_major_topic":true},{"descriptor_ui":"D010851","descriptor_name":"Picrates","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false},{"descriptor_ui":"D011789","descriptor_name":"Quantum Theory","qualifier_ui":null,"qualifier_name":null,"is_major_topic":false},{"descriptor_ui":"D013058","descriptor_name":"Mass Spectrometry","qualifier_ui":"Q000379","qualifier_name":"methods","is_major_topic":true},{"descriptor_ui":"D014867","descriptor_name":"Water","qualifier_ui":"Q000737","qualifier_name":"chemistry","is_major_topic":false}],"locations_count":3,"locations":[{"id":"doi:10.1021/jp5010192","doi":"https://doi.org/10.1021/jp5010192","is_oa":false,"landing_page_url":"https://doi.org/10.1021/jp5010192","pdf_url":null,"source":{"id":"https://openalex.org/S146709414","display_name":"The Journal of Physical Chemistry A","issn_l":"1089-5639","issn":["1089-5639","1520-5215"],"is_oa":false,"is_in_doaj":false,"is_core":true,"listed_in":["anvur-scientific","cwts-core","dongbi-c","jufo-1","ki-jl-1","medline","norway-1","poland-100","russia-white-list-2","vabb-shw"],"host_organization":"https://openalex.org/P4310320006","host_organization_name":"American Chemical Society","host_organization_lineage":["https://openalex.org/P4310320006"],"host_organization_lineage_names":["American Chemical Society"],"type":"journal"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The Journal of Physical Chemistry A","raw_type":"journal-article"},{"id":"pmid:24559481","doi":null,"is_oa":false,"landing_page_url":"https://pubmed.ncbi.nlm.nih.gov/24559481","pdf_url":null,"source":{"id":"https://openalex.org/S4306525036","display_name":"PubMed","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I1299303238","host_organization_name":"National Institutes of Health","host_organization_lineage":["https://openalex.org/I1299303238"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"publishedVersion","is_accepted":true,"is_published":true,"raw_source_name":"The journal of physical chemistry. A","raw_type":"Journal Article"},{"id":"pmh:oai:pure.atira.dk:openaire_cris_publications/402d7045-41c9-4e1e-a2fb-10b3d10e1847","doi":null,"is_oa":false,"landing_page_url":"https://research.birmingham.ac.uk/en/publications/402d7045-41c9-4e1e-a2fb-10b3d10e1847","pdf_url":null,"source":{"id":"https://openalex.org/S4306402634","display_name":"University of Birmingham Research Portal (University of Birmingham)","issn_l":null,"issn":null,"is_oa":false,"is_in_doaj":false,"is_core":false,"listed_in":[],"host_organization":"https://openalex.org/I79619799","host_organization_name":"University of Birmingham","host_organization_lineage":["https://openalex.org/I79619799"],"host_organization_lineage_names":[],"type":"repository"},"license":null,"license_id":null,"version":"submittedVersion","is_accepted":false,"is_published":false,"raw_source_name":"Agarwal, B, Gonzalez Mendez, R, Lanza, M, Sulzer, P, M\u00e4rk, T D, Thomas, N & Mayhew, C A 2014, 'Sensitivity and selectivity of switchable reagent ion soft chemical ionization mass spectrometry for the detection of picric acid', The Journal of Physical Chemistry A, vol. 118, no. 37, pp. 8229-8236. https://doi.org/10.1021/jp5010192","raw_type":"article"}],"best_oa_location":null,"sustainable_development_goals":[],"study_designs":[],"awards":[{"id":"https://openalex.org/G8550465024","display_name":"Proton Ionization Molecular Mass Spectrometry","funder_award_id":"287382","funder_id":"https://openalex.org/F4320320300","funder_display_name":"European Commission"}],"funders":[{"id":"https://openalex.org/F4320320300","display_name":"European Commission","ror":"https://ror.org/00k4n6c32"}],"has_content":{"grobid_xml":false,"pdf":false},"content_urls":null,"referenced_works_count":19,"referenced_works":["https://openalex.org/W115884593","https://openalex.org/W1602915547","https://openalex.org/W1847770208","https://openalex.org/W1955346805","https://openalex.org/W2015674670","https://openalex.org/W2015930521","https://openalex.org/W2016435395","https://openalex.org/W2023675823","https://openalex.org/W2033230301","https://openalex.org/W2041713105","https://openalex.org/W2065155023","https://openalex.org/W2067434579","https://openalex.org/W2072561146","https://openalex.org/W2078275517","https://openalex.org/W2111155943","https://openalex.org/W2119790221","https://openalex.org/W2146996243","https://openalex.org/W2170408518","https://openalex.org/W2323170603"],"related_works":["https://openalex.org/W2030624290","https://openalex.org/W4399974748","https://openalex.org/W7155045823","https://openalex.org/W2265812894","https://openalex.org/W4401899240","https://openalex.org/W3195473626","https://openalex.org/W2060213474","https://openalex.org/W2062533577","https://openalex.org/W3141440363","https://openalex.org/W2799890545"],"abstract_inverted_index":{"We":[0],"have":[1],"investigated":[2],"the":[3,82,90,100,103,128,137,161,165],"reactions":[4],"of":[5,70,78,102,131,136,151,168],"NO(+),":[6],"H3O(+),":[7],"O2(+),":[8],"and":[9,52,86,105,147,153],"Kr(+)":[10,53],"with":[11,23,39,55,74,93],"picric":[12],"acid":[13],"(2,4,6":[14],"trinitrophenol,":[15],"C6H3N3O7,":[16],"PiA)":[17],"using":[18],"a":[19,24,31,75,110,113,125,134,157],"time-of-flight":[20],"mass":[21],"spectrometer":[22],"switchable":[25],"reagent":[26,83],"ion":[27,34],"source.":[28],"NO(+)":[29],"forms":[30],"simple":[32],"adduct":[33],"PiA\u00b7NO(+),":[35],"while":[36],"H3O(+)":[37,85],"reacts":[38],"PiA":[40,56,132],"via":[41],"nondissociative":[42,58],"proton":[43],"transfer":[44,60],"to":[45,61],"form":[46],"PiAH(+).":[47],"In":[48],"contrast,":[49],"both":[50,108],"O2(+)":[51,87],"react":[54],"by":[57,144],"charge":[59],"produce":[62],"PiA(+).":[63],"For":[64,81],"Kr(+),":[65],"we":[66,97,155],"also":[67],"observe":[68],"dissociation":[69],"PiA,":[71],"producing":[72],"NO2(+)":[73],"branching":[76],"percentage":[77],"approximately":[79],"40%.":[80],"ions":[84,107],"(and":[88,140],"operating":[89],"drift":[91],"tube":[92],"normal":[94],"laboratory":[95],"air),":[96],"find":[98],"that":[99],"intensities":[101],"PiAH(+)":[104],"PiA(+)":[106],"exhibit":[109],"peak":[111,126,163],"at":[112],"given":[114],"drift-tube":[115,138],"voltage":[116,139],"(which":[117],"is":[118],"humidity":[119],"dependent).":[120],"This":[121],"unusual":[122],"behavior":[123],"implies":[124],"in":[127,164],"detection":[129,166],"sensitivity":[130,167],"as":[133],"function":[135],"hence":[141],"E/N).":[142],"Aided":[143],"electronic-structure":[145],"calculations":[146],"our":[148],"previous":[149],"studies":[150],"trinitrotoluene":[152],"trinitrobenzene,":[154],"provide":[156],"possible":[158],"explanation":[159],"for":[160],"observed":[162],"PiA.":[169]},"counts_by_year":[{"year":2026,"cited_by_count":2},{"year":2025,"cited_by_count":5},{"year":2024,"cited_by_count":5},{"year":2023,"cited_by_count":7},{"year":2022,"cited_by_count":4},{"year":2021,"cited_by_count":3},{"year":2020,"cited_by_count":2},{"year":2019,"cited_by_count":8},{"year":2018,"cited_by_count":2},{"year":2017,"cited_by_count":2},{"year":2016,"cited_by_count":4},{"year":2015,"cited_by_count":1},{"year":2014,"cited_by_count":1}],"updated_date":"2026-11-04T10:54:05.112534","created_date":"2016-06-24T00:00:00"}